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4 results about "Plastic crystal" patented technology
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A plastic crystal is a crystal composed of weakly interacting molecules that possess some orientational or conformational degree of freedom. The name plastic crystal refers to the mechanical softness of such phases: they resemble waxes and are easily deformed. If the internal degree of freedom is molecular rotation, the name rotor phase or rotatory phase is also used. Typical examples are the modifications Methane I and Ethane I. In addition to the conventional molecular plastic crystals, there are also emerging ionic plastic crystals, particularly organic ionic plastic crystals (OIPCs) and protic organic ionic plastic crystals (POIPCs). POIPCs are solid protic organic salts formed by proton transfer from a Brønsted acid to a Brønsted base and in essence are protic ionic liquids in the molten state, have found to be promising solid-state proton conductors for high temperature proton exchange membrane fuel cells. Examples include 1,2,4-triazolium perfluorobutanesulfonate and imidazolium methanesulfonate.
Organic ionic plastic crystal facilitating the conduction of anions and cations and a preparation method thereof
This invention relates to the field of new materials, specifically to an organic ionic plastic crystal that facilitates the conduction of anions and cations and its preparation method. The method involves adding different concentrations of anion and cation additives to a tetrafluoroborate-based quaternary ammonium salt plastic crystal, dissolving them in an appropriate amount of acetonitrile, stirring thoroughly, removing the solvent by rotary evaporation, and then vacuum drying to obtain a mixture doped with different concentrations of anions and cations. The tetrafluoroborate-based quaternary ammonium salt plastic crystal obtained by the above method exhibits an ionic conductivity close to practical values after the introduction of anions and cations. The internal conduction of anions and cations can improve the conductivity of the organic ionic plastic crystal, providing a possibility for developing solid electrolytes with high conductivity.
Owner:SHANDONG AGRICULTURAL UNIVERSITY
Polymer electrolyte
The present disclosure relates to a polymer electrolyte. The polymer electrolyte includes a lithium salt polymer including an anionic functional group and a salt with lithium, and a substance having plastic crystal properties. The present disclosure provides the polymer electrolyte improved in electrical performance, in particular, the polymer electrolyte improved in lithium ion transport number.
Owner:TOYOTA JIDOSHA KK +1
Anti-circulation fatigue packaging structure plastic crystal pressure card material and preparation method
PendingCN122357097APlastic crystalPressure cycle
This invention relates to the field of solid-state refrigeration materials with pressure-sensitive effects, and discloses a technical method for improving the adiabatic temperature change decay of plastic crystal materials under constant pressure cycling conditions. The method involves uniformly mixing ammonium iodide plastic crystal grains with silicone oil to form a coating composite system with lubricating and isolating functions. A spherical shell encapsulation structure is then fabricated using PA12 nylon powder via laser sintering 3D printing. The composite system is filled and sealed within the spherical shell to form a stable encapsulation unit. During programmed pressurization and depressurization cycles of the encapsulation unit under constant pressure conditions, the silicone oil effectively reduces inter-grain friction and stress concentration, while the spherical shell structure prevents the loss of the coating medium and maintains the integrity of the system, thereby significantly suppressing the decay of the adiabatic temperature change of the plastic crystal material with increasing cycle count.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI
Electrolytic capacitor and method of manufacturing
Provided is an electrolytic capacitor capable of maintaining a low ESR while using a conductive polymer and a plastic crystal, and a method for manufacturing the same. The electrolytic capacitor has an electrolyte layer between a pair of electrodes. The electrolyte layer includes: a conductive polymer obtained by adhering a conductive polymer solution containing a conductive polymer and a neutralizing agent; and a plastic crystal. The electrolyte layer does not contain metal ions derived from the neutralizing agent. The method for manufacturing the electrolytic capacitor includes an electrolyte layer formation step of impregnating a conductive polymer solution in which a conductive polymer is dispersed or dissolved between the pair of electrodes and performing drying, and the conductive polymer solution does not contain metal ions.
Owner:NIPPON CHEMI CON CORP