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71 results about "Plastic crystals" patented technology

Plastic crystal polymer electrolyte material prepared by in-situ polymerization and preparation method therefor

The invention relates to a plastic crystal polymer electrolyte material prepared by in-situ polymerization and a preparation method therefor, and belongs to the technical field of an electrolyte material. The plastic crystal polymer electrolyte material prepared by the in-situ polymerization comprises a monomer, an initiator, a cross-linking agent, a lithium salt, and plastic crystals; a mixed solution of the monomer, the initiator, the cross-linking agent, the lithium salt and the plastic crystals is heated to be subjected to the in-situ polymerization to obtain the plastic crystal polymer electrolyte material; the preparation method for the plastic crystal polymer electrolyte material prepared by the in-situ polymerization comprises the steps of mixing and dissolving the monomer, the initiator, the cross-linking agent, the lithium salt and the plastic crystals; and pouring the solution into a polytetrafluoroethylene die, and heating and performing the in-situ polymerization to obtain the plastic crystal polymer electrolyte material. By adoption of a one-step method for synthesis, the preparation process is simple and industrial production can be realized favorably; and in addition, the plastic crystal polymer electrolyte material is high in conductivity at room temperature, high in thermal stability and interface stability, high in mechanical property, excellent in electrochemical performance, and the like.
Owner:CHINA ELECTRONIC TECH GRP CORP NO 18 RES INST

Porous membrane reinforced polymer-plastic solid electrolyte membrane, preparation method thereof and application thereof

The invention discloses a porous membrane reinforced polymer-plastic solid electrolyte membrane, a preparation method thereof and application thereof. The polymer-plastic solid electrolyte membrane includes a support layer including a porous membrane and a polymer-plastic solid electrolyte layer covering at least one side of the surface of the porous membrane, wherein the porous membrane plays therole of a support frame and has a continuous three-dimensional network structure, the mechanical properties of the solid electrolyte membrane can be improved, and at the same time, the preparation ofa thinner solid electrolyte membrane is facilitated by the porous membrane support frame. The polymer-plastic solid electrolyte layer contains a polymer, lithium salt and a plastic crystal compound,and a porous membrane reinforced flexible polymer-plastic solid electrolyte membrane with high voltage resistance and high low-temperature conductivity can be obtained by optimizing the proportions ofthe polymer, the lithium salt and the plastic crystal. The polymer-plastic solid electrolyte membrane can be applied to an all-solid lithium-ion battery, the preparation process is simple, and the polymer-plastic solid electrolyte membrane is suitable for industrial production.
Owner:SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI

Composite solid electrolyte material, preparation method thereof, and all-solid-state battery

The invention discloses a composite solid electrolyte material, a preparation method thereof, and an all-solid-state battery. The all-solid-state battery includes a positive electrode layer, a negative electrode layer, and the composite solid electrolyte material positioned between the positive electrode layer and the negative electrode layer. The composite solid electrolyte material includes polyoxyethylene, an inorganic powder having a high ionic conductivity, a plastic crystal compound and a lithium salt. The preparation method comprises the following steps: weighing the polyoxyethylene andthe lithium salt in proportion, adding the weighed substances to an organic solution, and performing stirring to obtain a solution A; weighing the inorganic powder and the plastic crystal compound inproportion, adding the weighed substances to the solution A, and performing stirring to obtain a uniformly mixed suspension B; and pouring the suspension B into a mold, and drying the suspension B inthe mold to obtain the organic/inorganic composite solid electrolyte material. The composite solid electrolyte material has an obviously improved room-temperature ionic conductivity and an enhanced electrochemical stability, and has a stable interface contact with a positive electrode and a negative electrode, and the capacity attenuation problem of the all-solid-state battery formed by assembling the composite solid electrolyte material is significantly improved.
Owner:ZHUHAI SMOOTHWAY ELECTRONICS MATERIALS +1

Gel-state electrode and preparation method thereof

The invention discloses a gel-state electrode and a preparation method thereof. The electrode comprises an electrode active material, a conductive agent, SN, a lithium salt, a polymer and an additive. The preparation method comprises the following steps of dissolving the lithium salt and the additive in SN at 60-80 DEG C, adding the polymer, and fully stirring and dissolving to form a gel-state substance, and then, mixing the prepared gel-state substance, an electrode active material and a conductive agent, stirring or uniformly grinding, and coating one side of a solid electrolyte with the mixture to serve as the gel-state electrode of the solid-state battery. According to the type of the added polymer, whether cross-linking treatment is carried out or not is determined. The lithium salt can be completely dissolved in SN to form a plastic crystal electrolyte, and the selected polymer can also be dissolved in the plastic crystal electrolyte. According to the gel-state electrode provided by the invention, the contact performance between the electrode and the solid electrolyte can be improved, the ion transmission in the electrode can be improved, and the negative effect on the battery performance caused by the volume change generated in the charging and discharging process of the electrode active material can also be inhibited.
Owner:SHANGHAI INST OF SPACE POWER SOURCES

Solid-state battery based on plastic crystal modified positive electrode and preparation method of solid-state battery

The invention belongs to the technical field of solid-state batteries, and particularly relates to a solid-state battery based on a plastic crystal modified positive electrode and a preparation method thereof.The preparation method of the solid-state battery based on the plastic crystal modified positive electrode comprises the following steps that firstly, plastic crystal, lithium salt, a polymer and inorganic filler are heated and mixed, and the plastic crystal melted into a liquid state serves as a solvent; 2, mixing positive electrode material powder, a conductive agent, the plastic crystal-based composite positive electrode adhesive obtained in the step 1 and an organic solvent, and coating a current collector with the mixture; and 3, preparing a plastic crystal-based positive electrode surface treatment liquid, coating or spraying the plastic crystal-based positive electrode surface treatment liquid on the surface of the positive electrode layer obtained in the step 2, and carrying out in-situ polymerization by adopting heating or irradiation. According to the solid-state battery based on the plastic crystal modified positive electrode and the preparation method of the solid-state battery, the interface compatibility and the compatibility with a high-specific-energy electrode material are improved, and the problem that the battery performance cannot be brought into full play due to poor battery interface contact and low material conductivity is solved.
Owner:CHINA ELECTRONIC TECH GRP CORP NO 18 RES INST
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