The invention discloses a crystalline polyaryletherketone porous membrane with an adjustable pore diameter, a preparation method and application of the membrane, and belongs to the technical field ofpolymer materials. A soluble polyaryletherketone precursor solution is prepared into a porous membrane by means of an immersion phase inversion method or a steam induction phase inversion method or atemplate method, then the porous membrane is crystallized through acidification and heat treatment, and therefore the crystalline polyaryletherketone porous membrane with the adjustable pore diameteris prepared. The crystallinity of the crystalline polyaryletherketone porous membrane with the adjustable pore diameter is 26-29%, the pore diameter of the membrane is within the range of 0.01-5 microns, the porosity of the membrane is 50-80%, pores are finger-shaped pores or sponge-shaped pores, and the thickness is 10-130 microns. The operation of the method is simple, the cost is low, large-scale production can be achieved, the immersion phase inversion method and the steam induction phase inversion method do not require external auxiliaries, the process cost is further reduced, and the crystalline polyaryletherketone porous membrane can be widely applied to fuel cells, super capacitors, lithium ion batteries, ultrafiltration membranes and the like.