The invention discloses a device and a method for preparing green
ammonia by synchronously
coupling gliding arc
discharge and electro-
catalysis, and belongs to the technical field of green
chemical industry and
renewable energy sources. The device comprises an integrated reactor, a gas
distribution system, a high-
voltage alternating-current power supply and a constant-
voltage direct-current power supply, the integrated reactor comprises a gliding arc
discharge unit, a
cathode pool and an
anode pool, and can perform electrocatalytic reduction reaction to synthesize
ammonia in situ while realizing that gliding arc
discharge oxidizes air to generate
nitrogen oxide; and a gas-liquid-
electrode interface stable structure is arranged in the
cathode tank, so that the interference of bubbles on an
electrode interface can be effectively blocked. According to the method, discharge parameters and catalyst performance are optimized, and the area and
electrochemical potential of a
working electrode are regulated and controlled, so that the
plasma oxidation rate is matched with the electrocatalytic
reduction rate, and continuous and stable operation is realized. According to the invention, the short-life
active particles generated by the
plasma directly participate in or promote the electro-catalytic reaction, a remarkable synergistic effect is generated, and efficient, green and continuous synthesis of
ammonia from air and water is realized.