The invention relates to a method for synthetizing carbamate. The method comprises the following steps: adding sulfonyl hydrazones, amine and solvents in a high-pressure kettle, adding alkali as an accelerant, introducing carbon dioxide, performing a stirring reaction for 6-72 hours at the temperature of 40-150 DEG C, cooling the high-pressure kettle to the room temperature after the reaction is completed, slowly releasing carbon dioxide which is not reacted to constant pressure, filtering a reaction liquid, decompressing and stewing the solvents to obtain crude products, and obtaining a series of carbamate chemical compounds through refining in a column chromatography. The method for synthetizing carbamate is safe and simple to operate, the prices of raw materials are low, the raw materials are easy to obtain, the adaptability for functional groups is high, the adaptability for substrates is wide, the method is environmental-friendly, industrial production is facilitated, and the method is widely applied to the synthesis of agricultural chemicals, medicines and natural products.