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Binary co-polymerized positive ion formaldehyde-free color-fixing agent and synthetic method thereof

The invention provides a binary co-polymerized positive ion formaldehyde-free color-fixing agent and a synthetic method thereof. The synthetic method includes following steps: adding a weighed monomer 1: dimethyldiallyl ammonium chloride, a weighed monomer 2: diallyl amine, and glacial acetic acid into a four-mouth reaction kettle provided with a reflux condensation tube, a temperature meter and a stirrer; weighing anhydrous sodium hydrogen sulfite and potassium persulfate to prepare an initiator of an oxidation-reduction system; increasing the temperature to about 80 DEG C and adding 1/8 of the potassium persulfate and 1/8 of the anhydrous sodium hydrogen sulfite with temperature increasing degree being controlled to be not more than 10 DEG C; when the temperature increases to about 100 DEG C, adding dropwisely the rest initiator slowly with the temperature being controlled to be not higher than 104 DEG C, wherein the dropwise addition of the rest initiator is finished within 2.5 h, and then carrying out the reaction for 30 min continuously; and decreasing the temperature and discharging the material when the temperature is lower than 50 DEG C. The color-fixing agent is free of formaldehyde, is a quaternary ammonium salt typed environmental-protective color-fixing agent, is applied in color-fixing treatment in fabric dyeing with an active dye and can enable both color fastness to washing and color fastness to rubbing to be increased by 0.5-1 grade.
Owner:ZHEJIANG HONGSHENG DYEING & PRINTING
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