3185 results about "Acetic acid solution" patented technology

The invention discloses a preparation method of essence microcapsules. The preparation method comprises the following steps: (1) dissolving chitosan in acetum; (2) adding emulsifier and essence into the chitosan acetum for high-speed emulsification and dispersion to obtain the chitosan essence emulsion; (3) adding the mixed solution of sodium alginate and sodium tripolyphosphate dropwise into the chitosan essence emulsion; (4) adjusting the pH value of the system to 5-7 with NaOH solution to obtain the condensed essence microcapsules; and (5) adding cross-linking agent into the condensed essence microcapsule system to perform chemical cross-linking process on the condensed essence microcapsules to obtain the essence microcapsules. For the essence microcapsules prepared according to the method disclosed by the invention, as chemical cross-linking process is implemented on the walls of the capsules, the density of the capsule walls and the resistance to the solution alkalinity/acidity are improved, and the application stability of the essence microcapsules is increased; moreover, with small size, the capsules can easily permeate into textile fiber, and the water-washing resistance of the textile fiber is greatly improved.

The present invention relates to a low fat cocoa extract having a high level of cocoa flavors and cocoa flavor precursors, and a high level of antioxidants. It also relates to a cocoa flavor concentrate, an antioxidant concentrate, and a foodstuff containing them. It also relates to the use of in-vitro fermented beans as naturally fermented beans. The process used to obtain such extracts comprises the steps of placing cocoa seeds in acetic acid solution, heating the mixture, and concentrating the solids of the mixture after having removed the seeds.

A nanometer superfine chitosan fibrous membrane material and its preparation process are disclosed. It belongs to tissue repair material technology. The film material with the diameter being 10 ª–mí½50ª–m, is made by chitosan with mass percent of 10-90% and polyvinyl alcohol or polyethylene oxide superfine fiber with diameter of 50nm -500nm The preparation process is: dissolving chitosan to acetic acid solution, adding PVA pr PEO into the solution, the mass ratio of chitosan with PVA/PEO being 10/90í½90/10, injecting the prepared 4%-8% spinning solution to the electrostatic spinning device for spinning to film material, therein, voltage being 5kVí½30kV, liquid inventory being 0.1mL/hí½0.5mL/h, receiving range being 5cmí½25cm. The advantages of the invention : large volume absorbing ability, favorable cell affinity, capable of degrading in vivo and promoting defect tissue repairing when the film material is utilized as artificial skin or artificial cartilage. In addition, the preparation process is simple.

The invention discloses a method for preparing an antipollution chitosan-nonwoven fabric composite porous filter membrane and belongs to the technical field of microfilter and ultrafilter composite membranes. The method is characterized in that the method adopts nonwoven fabric with nominal aperture of between 0.1 and 10 microns as a base membrane; a crosslinking agent is adopted to carry out pretreatment on the base membrane; 0.1 to 10 mass percent amylose is dissolved in an acetic acid solution; the crosslinking agent and a hole formation agent are added into the acetic acid solution; after the crosslinking reaction, a casting film liquid is obtained; at negative pressure, the casting film liquid is evenly coated on the surface and pores of the porous base membrane; and after treatment by a sodium hydroxide solution and a hot water bath, the antipollution chitosan-nonwoven fabric composite porous filter membrane is formed. The method has the advantages that the prepared composite membrane has good mechanical performance and chemical stability; and the surface of the membrane is levelled and smooth. The composite membrane has dual functions of hydrophile and antibiosis, can lighten adsorption of pollutants on the surface of the membrane, inhibit the growth and reproduction of thalli on the surface of the membrane, and keep the penetrating performance of the membrane and is widely applied to the water treatment process of various fields.

The invention discloses a traditional Chinese medicine inclusion compound with an antibacterial effect and a textile finishing method of the traditional Chinese medicine inclusion compound. The traditional Chinese medicine inclusion compound is prepared from traditional Chinese medicine extract liquid with the total ingredient percentage being 100 percent and beta-cyclodextrin through a saturated water solution method, wherein the traditional Chinese medicine extract liquid comprises the following ingredients in percentage by mass: 25 percent to 60 percent of honeysuckle, 15 percent to 50 percent of folium Artemisiae argyi, 20 percent to 35 percent of liquorice and 5 percent to 15 percent of scutellaria baicalensis. The traditional Chinese medicine inclusion compound and cross linking agents are added into chitosan acetic acid solution to be prepared into antibacterial finishing liquid. A simple rolling baking process is adopted for carrying out antibacterial finishing on the cellulose fiber, the process is simple, the finished textile has the broad-spectrum antibacterial performance on common germs such as staphylococcus aureus, escherichia coli and the like, and in addition, the water washing resistance performance is good.

The invention relates to a method for preparing an NCC/CS/PVA composite nanofiber membrane. NCC is rod-shaped particles, wherein the diameter of each particle ranges from 20 nm to 60 nm, and the particles are highly crystallized. The method comprises the steps that (1) an NCC/CS solution is prepared, wherein the concentration of the NCC, by weight, ranges from 0.09% to 0.21%; (2) an NCC/PVA solution is prepared, wherein the concentration of the NCC, by weight, ranges from 0.4% to 0.8%; (3) an acetic acid solution, tetraethyl orthosilicate, the NCC/CS solution obtained in the step (1) and processed through ultrasound, and the NCC/PVA solution obtained in the step (2) and processed through ultrasound are mixed to obtain a spinning solution, and the nanofiber membrane is obtained through the electrospinning technology, wherein the mass ratio of the acetic acid solution to the tetraethyl orthosilicate to the NCC/CS solution to the NCC/PVA solution is (2.5-3.5):(1.5-2.5):5:5; (4) the obtained nanofiber membrane is immersed in an alkaline solution for 2-6 hours at the normal temperature, and the membrane structure can be stable. The method for preparing the NCC/CS/PVA composite nanofiber membrane has the advantages that the nanofiber material preparation process is simple, the preparation process is environmentally friendly and free of pollution, nanofibers are excellent in mechanical performance, the surface of the nanofiber membrane is rich in modifiable functional groups, and the nanofiber membrane has a remarkable affinity effect on biomacromolecule.

The invention discloses a sulfide functionalized covalent organic frame material, The material has a structural unit shown in the specification, and is obtained by the following steps: adding 2,5-Bis(3-(ethylthio)propoxy)-terephthalohydrazide and benzenetricarboxaldehyde into a mixed solvent of 1,4-dioxane and mesitylene, adding an aqueous acetic acid solution into the above mixture and reacting at 120 DEG C for 1-3 days. The material has a mesoporous structure, has BET specific surface area of 470-480 m<2>?g<-1>, has good selective identification for mercury ions, and can be used for removal of the mercury ions.

The invention provides a method for preparing pigment yellow 83. The method comprises the following steps: 3, 3'-dichlorobenzidine, 3, 3'-dimethylbenzidine, hydrochloric acid and water are stirred, dissolved and added to sodium nitrite for diazotization, so as to obtain a diazonium solution; a sodium hydroxide solution containing 4-chlorine-2, 5-dimethoxy acetyl acetanilide is dripped into an acetic acid solution at the temperature between 20 and 40 DEG C, so as to prepare a coupling solution; the acetic acid solution contains an emulsion formed by well mixing anionic surfactant, nonionic surfactant, solvent and water; the diazonium solution is dripped into the coupling solution within 1 to 5 hours; the emulsion formed by compounding the anionic surfactant and non-polar hyper-dispersant is added to the coupling solution, reacts for 1 hour, and is heated to 90 to 100 DEG C; polyethylene wax is added in the mixture; and then the mixture, is insulated for 1 to 3 hours, pumped, filtered, washed, dried and ground, so as to obtain a finished product. The preparation method has the advantage of obtaining the pigment yellow 83 which is bright in color light, high in tinting strength, high in covering power and good in dispersibility.

The invention relates to preparation of a magnetic nano adsorbent and a method for removing organic cationic dyes from waste water by the same, and belongs to the technical field of wastewater treatment. The magnetic nano adsorbent uses Fe3O4 particles as a carrier, and coated humic acid as an active adsorbing component. The method comprises the following steps: adding mixed solution of ferric chloride and ferrous sulfate to alkaline humic acid solution, reacting under anaerobic, heating and stirring conditions, and obtaining the magnetic nano adsorbent after magnetic separation, washing, drying and grinding. The removal rate of methylene blue and neutral red reaches more than 95% by treating organic cationic dye wastewater with the magnetic nano adsorbent. The magnetic nano adsorbent after magnetic solid-liquid separation is regenerated by methanol-acetic acid solution, a desorption solvent recovers methanol and acetic acid by distillation for recycling use. The magnetic nano adsorbent has the advantages of nanoscale size, high active surface radicals, extremely high adsorption removal rate for cationic dyes, simple process, high efficiency and easy control.

The invention relates to a method for recycling acetic acid from diluted acetic acid, and aims at solving the problem that the recycling of acetic acid in the hydrolysis of furfural and methyl acetate as well as the Fischer-Tropsch combined production is difficult. The invention comprises the steps as follows: a) diluted acetic acid is extracted by a pulse filling extracting tower, the extractionphase containing extracting agent, the acetic acid and little water for the tower top is acquired, and the residual extraction phase of water containing micro acetic acid from the tower kettle is acquired; b) the extraction phase in an extracting agent recycling tower is conveyed; c) acetic acid 1 is fed into an azeotropic rectifying tower which utilizes one kind of benzene, cyclohexane, ethyl acetate, isopropyl acetate and butyl acetate as the extrainer, two-phase mixture of the extrainer and the water at a phase separator at the top of the tower is acquired, the water is extracted out from the tower top, and the retrainer returns into the tower. The utility model has the technical proposal of producing pure acetic acid at the tower top, solves the problems above, and adapts the industrial productions including recycling of acetic acid from wasted aldehyde water and extracting and refining acetic acid in the methyl acetate hydrolysis technique.

The present invention is the preparation process of electrostatic spun chitosan/carbon nanotube film, and belongs to the field of antibiotic and antistatic material preparing technology. The preparation process includes the following steps: dissolving carbon nanotube in acid mixture to compound solution, heating the solution to boil, filtering, washing to weak acid and vacuum drying; dissolving chitosan inside glacial acetic acid solution to obtain yellowish glacial acetic acid solution of chitosan; mixing the carbon nanotube solution and the chitosan solution to obtain molecule level composite solution; mixing the molecule level composite solution with glacial acetic acid solution of PVA; and spinning. The preparation process is simple, and the obtained electrostatic spun chitosan/carbon nanotube material has high solubility, good filming performance, high conductivity, excellent antibiotic performance and excellent electromagnetic shielding performance.

The acid soluble fish skin collagen is prepared with sea fish skin as material and through the steps of cutting, NaCl solution soaking to eliminate impurity, alcohol and acetone defatting, soaking in mixed citric acid-acetic acid solution to extract, centrifugally separating to obtain acid soluble fish skin collagen solution, solid NaCl salt separation to obtain acid soluble fish skin collagen precipitate, dissolving in acetic acid solution, dialysis in Na2HPO4 solution or ultrafiltering with hollow acetate fiber film of molecular weight greater than 60 KDa, and vacuum freeze drying to obtain the product. The product is white, without fishy smell and spongy, and has purity over 97 %. It contains rich glycin, proline and hydroxyproline, as well as physiologically active peptide in its hydrolysate, and the collagen has molecular weight greater than 60 KDa.

The invention relates to recycled concrete and a preparation method thereof, and belongs to the technical field of concrete. The recycled concrete comprises (by weight): 150-280 parts of cement, 90-130 parts of water, 800-950 parts of modified recycled coarse aggregate, 400-530 parts of fine aggregate, 40-85 parts of fly ash, 80-100 parts of mineral powder, 50-140 parts of zeolite powder, 30-60 parts of epoxy resin, 4-10 parts of a water reducing agent and 2-6 parts of an air entraining agent. The preparation method of the modified recycled coarse aggregate comprises the following steps: S1, crushing and screening waste concrete to obtain recycled coarse aggregate; S2, soaking the recycled coarse aggregate obtained in the step S1 in an acetic acid solution with the mass concentration of 2-7%, and airing; S3, stirring 80-110 parts of polyvinyl alcohol, 60-110 parts of silica fume, 40-80 parts of sodium silicate and 800-1,000 parts of water to obtain a modified liquid; and S4, soaking the recycled coarse aggregate obtained in the step S2 in the modified liquid obtained in the step S3, taking out the soaked recycled coarse aggregate, and baking the recycled coarse aggregate to obtainthe modified recycled coarse aggregate. The recycled concrete provided by the invention has a good compressive strength effect.

The invention relates to a BiOI-graphene visible light catalyst and a preparation method thereof, belonging to the technical field of inorganic material synthesis and photocatalysis. BiOI and graphene are in the shape of a slice, and the graphene is 1.0%-3.0% by weight. The preparation method of the BiOI-graphene visible light catalyst comprises the following steps of: firstly ultrasonically dispersing graphite oxides into ethanol; then stirring, and adding a certain amount of sodium iodide or potassium iodide water solutions and bismuth nitrate glacial acetic acid solutions at the same time; transferring suspending liquid into a high-pressure reaction kettle with a polytetrafluoroethylene liner, and carrying out crystallization reaction at 120-150 DEG C for 6-12 hours; filtering, washing and drying obtain solid products so as to finally obtain the BiOI-graphene compound light catalyst. The preparation method has environment friendliness and simple process; and the prepared BiOI-graphene visible light catalyst has very high visible light catalytic activity and potential application value in a control technology decomposing organic pollutants by utilizing solar photocatalysis.

The invention belongs to the field of product extraction technology and relates to a method for extracting chitin and antibacterial peptide from fly larvae. The method comprises the following steps of: firstly disinfecting and rinsing fresh fly larvae to be clean, then extruding the cleaned fly larvae to separate the fly larvae skin from visceral mass serous fluid; firstly soaking with hydrochloric acid solution, drying after washing, and then soaking with NaOH solution to remove protein; retaining residual liquid, drying after cleaning, adding the NaOH solution after crushing, carrying out water bath at the temperature of 98 DEG C, and heating for reaction; putting chitosan into acetic acid solution, stopping reaction after the chitosan is dissolved, filtering, cleaning, drying at the temperature of 50 DEG C, and obtaining the chitosan; and then adding acetic acid into the visceral mass serous fluid of the fly larvae, homogenizing, standing over the night at the temperature of 4 DEG C, filtering, adsorbing the filtrate with alginic acid, filtering, then eluting the antibacterial peptide adsorbed on the alginic acid with the hydrochloric acid solution, adjusting the pH value of the eluent to be 3.5, carrying out precipitation with NaCl, carrying out dialysis and desalting, drying and obtaining a crude antibacterial peptide product. The method has the advantages of reasonable technical route, low cost, high yield, large economic value, environmentally-friendly effect and effective utilization of the fly larvae resources for preparing natural product varieties.

The invention belongs to the technical field of biology and particularly relates to preparation and cell transfection application of a CS-based (chitosan-based) and CRISPR/Cas9 plasmid-constructed nano gene drug. The preparation comprises dissolving chitosan into acetic acid solution, dropwise adding the chitosan acetic acid solution into water, adding in CRISPR in mass proportion to the chitosan,encapsulating and carrying CRISPR/Cas9 with the chitosan to prepare a novel gene drug nano particle for good gene transfection effects or targeted exogenous gene introduction and further to achieve the effects of transferring gene drugs into cells. The novel nano compound of CRISPR@CS structured on the CS and the CRIPPR through an optimal feeding ratio can significantly improve the transfection efficiency of genes in cells to convey more genes into the cells to take effects, thereby being expected to being widely applied in the field of gene treatment through gene drug delivery.

The process of preparing water soluble chitosan includes adding chitosan into 2-8 wt% concentration acetic acid aqua to compound acetic acid solution of chitosan of 2-10 wt% concentration, adding enzyme or oxidant to degrade chitosan to polymerization degree below 1000, cooling the solution to 0-10 deg.c, adding ethanol or methanol solution of acetic anhydride, stirring first at normal temperature for 2-24 hr and then at 20-40 deg.c for another 20-40 deg.c, adding alkali to regulate pH to over 8 under stirring, adding ethanol to deposit, centrifugation to obtain solid product, soaking in alcohol solution of KOH, centrifugation, alcohol washing, and drying to obtain water soluble chitosan of acetyl degree of 45-55%. The present invention has simple preparation process, and the product is used as material for tumor resisting and immunity raising medicine and health product and as additive for cosmetics and food.

The invention relates to a method for preparing di-dithiocarbamate modified chitosan beads. The method comprises the following steps of: after dissolving 5 g of chitosan in an acetic acid solution at first, solidifying the chitosan in a sodium hydroxide solution to form chitosan beads with the diameter of 2-3 mm, wherein the solidifying time is 8-26 h; and, after carrying out Shiff alkali reaction, etherification, amination and elimination of benzaldehyde of the chitosan beads, grafting carbon disulfide under an alkaline condition to obtain di-dithiocarbamate modified chitosan. Compared with the original chitosan, the chitosan disclosed by the invention as a water treatment agent has stronger adsorption property and can be applied to treatment of heavy metal ions in wastewater, such as electroplating wastewater, battery wastewater, wastewater in mining industries and the like; the adsorption selectivity of the chitosan is increased; furthermore, the chitosan can be recycled for many times; and the purpose of rationally utilizing resources is achieved.

The present invention relates to the preparation process of chitosan base macroporous high water absorption resin. After chitosan is dissolved in dilute acetic acid solution, acrylic acid is made to graft on the molecular chain of chitosan under the initiation of ammonium or potassium persulfate and the product is cross-linked with cross-linking agent, so as to produce high water absorption chitosan grafted acrylic resin with distilled water absorption of 560-1210 g/g and physiological saline absorption of 76-125 g/g. The prepared resin is further modified via solvent deposition process to form macroporous structure to raise the water absorbing rate greatly. High efficiency liquid phase chromatographic test shows that the resin has greatly reduced acrylic acid monomer residue.

The invention discloses a preparation method of a porous biological carbon heavy metal adsorbing material based on cotton straw. The preparation method comprises the following steps: (1) adding the cotton straw into a ZnCl2 solution, carrying out stirring and impregnation for a certain time, and drying; (2) placing the dried cotton straw into an electric tube furnace for high-temperature calcination, grinding the calcined product into powder, adding the powder and ultrapure water into a hydrothermal reaction kettle, stirring till swelling is sufficient, heating for a reaction, and conducting centrifugal drying on the reaction product, so as to obtain a biological carbon material; (3) adjusting the pH of an ethanol aqueous solution with an acetic acid solution, adding 3-mercaptopropyl triethoxy silane into the ethanol aqueous solution, and carrying out oscillation to obtain a modified liquid; adding the biological carbon material into the modified liquid, carrying out oscillation and filtration, drying the obtained solid, washing the dried solid with an ethanol aqueous solution, and drying to obtain the biological carbon heavy metal adsorbing material. The preparation method is simple, and easy to operate; the biological carbon heavy metal adsorbing material prepared according to the method adopts a porous honeycomb-shaped structure, is large in specific surface area, high in heavy metal adsorbing property, and high in economic value and environment-friendly meaning.

The invention relates to a production method of straw feed, comprising the following steps: 1) smashing straw into particle materials; 2) carrying out ammoniation treatment on part of the straw particles with ammonia water or urea solution to obtain ammoniated straw; 3) adding plant lactic acid bacteria to the part of straw particle material for silage treatment so as to obtain silage straw; 4) adding water to uniformly mix the part of ammoniated straw with corncob particle, adding lactic acid or acetum to regulate the pH to 5-6, adding zymophyte solvent and uniformly mixing, and carrying out fermentation to obtain a straw degeneration enzyme strain; 5) uniformly mixing the ammoniated straw, the silage straw and the straw degeneration enzyme strain, adding a zymophyte solution, and carrying out fermentation to obtain a water-containing straw yeast; and 6) drying or pelleting the yeast to obtain the straw feed. The production method has the advantages that high-efficient fiber lignin degradation bacterium is adopted to produce the straw degeneration enzyme strain, and the degeneration efficiency and the nutrient content in feed are improved; equipment needed for material fermentation is simple, the operation is simple and convenient, and the cost for producing feed is lowered.

The invention discloses a method for preparing sulfured magnetic chitosan and a method for treating waste water containing heavy metals by using the sulfured magnetic chitosan, which belong to the technical field of material preparation. The method for preparing the sulfured magnetic chitosan comprises: dispersing a ferrous salt and a ferric salt in acetic acid solution of chitosan in advance; dripping the mixed solution into alkaline solution by using an injector to form magnetic chitosan spheres; crosslinking the spheres by using glutaraldehyde to form crosslinked magnetic chitosan spheres;and drying under vacuum, grinding into powder and obtaining the sulfured magnetic chitosan. The prepared material is used for treating waste water containing heavy metals.

The present invention discloses a method for extracting collagen and method for preparing collagen protein by using said collagen. Said method for extracting collagen includes the following steps: using Java tilapia skin as raw material, cutting said Java tilapia skin, adding n-hexane, defatting, using NaOH solution to remove heteroprotein, using acetic acid solution to extract collagen protein, concentrating and freeze-drying so as to obtain collagen. The method for preparing collagen protein by using extracted collagen includes the following steps: adding water to dissolve the collagen, then utilizing proteinase to make zymolysis, concentrating and spray-drying so as to obtain hydrolytic collagen protein.

The present invention discloses a preparation method of a stable high internal phase gelatinous wheat gliadin Pickering emulsion. The preparation method comprises the following steps: (1) wheat gliadin is dissolved into an alcohol solution; (2) an chitosan acetic acid solution is prepared; (3) the obtained solution in the step (1) is poured into the chitosan acetic acid solution, homogenization is conducted, and the homogenized solution is subjected to rotary evaporation; (4) a pH value of the obtained solution in the step (3) is adjusted to be 4.0-6.0; and (5) the obtained solution in the step (4) is mixed with oil and the mixture is subjected to shear emulsification to obtain the stable high internal phase gelatinous wheat gliadin emulsion. The obtained wheat gliadin Pickering emulsion by the method is high in stability and good in viscoelasticity, and can be used for embedding a large amount of oil. The stable high internal phase gelatinous wheat gliadin Pickering emulsion is low in requirement for devices, and simple and easy to operate in the method, and has relatively good prospect in the application aspects of novel nutrient delivery carriers and food structure modification base materials.

The invention belongs to the technical field of biomass nanometer materials and discloses a nano-crystalline cellulose fiber high in carboxyl group content and preparation and application thereof. A preparation method comprises the steps of preheating fiber slurry for 0.5-1.5h with sodium periodate at the temperature of 50-60 DEG C; adding a sodium chlorite solution and acetum into the slurry to be reacted for 1-3h at the temperature of 30-50 DEG C, adding TEMPO, NaClO2 and NaClO, and performing microwave heating to the temperature of 55-65 DEG C to enable the mixture to be reacted for 1-3h; performing ultrasonic dispersion and freeze drying to obtain the nano-crystalline cellulose fiber high in carboxyl group content. According to the nano-crystalline cellulose fiber, hydroxyl at the positions of C2 and C3 of cellulose is oxidized into a formyl group which is oxidized into carboxyl by sodium chlorite, hydroxyl at the position of C6 is selectively oxidized into carboxyl through a TEMPO neutral oxidation system, and accordingly the total carboxyl group content of the fiber is greatly increased, and obtained products can be used for advanced treatment of waste water at the middle section of paper making.