2195results about How to "Process conditions are easy to control" patented technology

A meso-porous silicon aluminum material with thin diaspore-like phase structure is disclosed. The preparing process includes the following steps: aluminum materials and alkali solution are neutralized to glue, and then silicon materials are added, finally the product is given by aging, ion exchange, drying and baking. The meso-porous silicon aluminum materials possess good hydrothermal stability and can be used as catalyst carrier with strong macromolecule cracking capacity, higher raw oil conversion efficiency and lower heavy oil yield.

The invention relates to the technical field of lithium-ion cathode material, in particular to silicon cathode material coated with graphene and a preparation method of the silicon cathode material coated with the grapheme. The preparation method comprises the following steps: A, preparing oxidized graphene suspension liquid; B, preparing nanometer silicon particle suspension liquid; and C, preparing silicon cathode material coated with grapheme. The preparation method adopts the electrostatic self-assembly synthetic technology and is wide in source of raw material, low in price, simple in synthetic method, easy for control of process conditions, strong in operability and good in repeatability. The silicon cathode material coated with grapheme is high in specific capacity and good in cycle performance and rate capability, wherein the specific discharge capacity for the first time under the electric current density of 0.01-1.2V, 200mA/g can reach 2746mAh/g, and the specific discharge capacity after 100 times of cycles can maintain 803.8mAh/g.

The invention provides a sludge-dewatering compound conditioning agent and an application method thereof. The sludge-dewatering compound conditioning agent comprises a Fenton reagent or / and similar Fenton reagent and a skeleton construct, and the weight ratio of the Fenton reagent or / and similar Fenton reagent and the skeleton construct is 1: (0.05-300); and the skeleton construct adopts a powder body. The application method comprises the following steps: adding the Fenton reagent or / and similar Fenton reagent into sludge slurry, and mixing for oxidation; and adding the skeleton construct into the sludge slurry with the Fenton reagent or / and similar Fenton reagent, and mixing. Due to synergy of the Fenton reagent or / and similar Fenton reagent and the powder type skeleton construct, extracellular polymeric substances in sludge can be destructed effectively, the compressibility of organic substances can be reduced, and the sludge dewatering performance of the sludge-dewatering compound conditioning agent can be improved greatly. The procedures of the application method are simple, the conditions can be controlled easily, the sludge dewatering time can be shortened, and the large-scale treatment of the sludge can be realized.

The invention discloses a lithium ion battery electrode, a preparation method thereof, a lithium ion battery, and a preparation method and application of the lithium ion battery. The preparation method for the electrode of the lithium ion battery comprises a step of preparing slurry containing a pore forming agent and a step of drying, rolling and slitting the electrode of the lithium ion battery. The lithium ion battery comprises the lithium ion battery electrode prepared by the preparation method for the lithium ion battery electrode. The preparation method for the lithium ion battery electrode is simple, high in efficiency and suitable for industrial production, and conditions are easy to control. Voids in the prepared lithium ion battery electrode are uniformly distributed, and a void ratio is higher than that of an ordinary electrode. The lithium ion battery has low internal resistance, high cycle performance and high energy density, so that the application range of the lithium ion battery is widened.

The invention provides a conductive polymer composite material and a preparation method thereof. The composite material includes following blended components: a. thermoplastic resin; b. rubber particles having crosslinking structures; c. a conductive filling material; and d. low-melting-point metal. Gel content in the component b is, by weight, 60% or more than 60%. An average particle size of the rubber particles is 0.02-1 [mu]m. The component c is not melted at a processing temperature of the thermoplastic resin. The component d is at least one of a single-component metal and a metal alloy. A melting point of the component d ranges from 20-480 DEG C and is lower than the processing temperature of the thermoplastic resin. The conductive polymer composite material is low in filling amount of the conductive filling material and the low-melting-point metal, is more excellent in conductive performance, can be prepared through a conventional melt blending method, can be used for manufacturing electronic production devices and tools which have an anti-static function and an electromagnetic wave interference resistant function and is of a dust-free requirement, can be used for manufacturing shells of electronic instruments and meters, can be used as a decoration material in a dust-free production workshop and can be used as shells and circuit boards of various flexible electronic products.

The invention relates to a halogen-free flame-retardant long glass fiber reinforced polypropylene material, which comprises the following raw materials in percentage by weight: 49 to 88.8 percent of polypropylene, 0.1 to 0.5 percent of thermal stabilizer, 0.1 to 0.5 percent of lubricating agent, 5 to 20 percent of halogen-free flame retardant, 1 to 5 percent of glass fiber compatilizer and 5 to 25 percent of long glass fiber, wherein the polypropylene is high fluidity polypropylene. The invention also relates to a preparation method for the polypropylene material. The preparation method comprises the following steps of: preparing a long glass fiber master batch and a halogen-free flame-retardant master batch, mixing the two master batches uniformly, and thus obtaining the polypropylene material, wherein when the polypropylene material is used, the polypropylene material is directly used for injection molding of parts. The polypropylene material has excellent flame-retardant property and dimensional stability, high mechanical strength, low shrinkage rate and good creep resistance and thermal oxidation resistance, is suitable for injection molding of thin-wall large pieces and automotive part products with complex structures such as automotive engine bottom guard plates, front-end modules, instrument panel frameworks and the like, saves the automobile manufacturing cost, and is environment-friendly.

The invention relates to a method for comprehensively recovering valuable metals from electroplating waste mud. The method comprises the following steps of: leaching valuable metals contained in the electroplating waste mud by dilute sulphuric acid, and filtering and separating out acid-leaching slag and a filtrate; replacing copper ions in the filtrate by metallic iron, and filtering and separating copper powder and a filtrate; adding an alkali solution in the filtrate, adding a polymeric flocculant, controlling the pH value of the solution and reacting, and filtering and separating ferric hydroxide and a filtrate; adding the alkali solution in the filtrate, controlling the pH value of the solution and reacting, and filtering to obtain a chromium precipitate and a filtrate; adding the alkali solution in the filtrate, controlling the pH value of the solution, and converting zinc and nickel in the solution to nickel carbonate and zinc carbonate; and dissolving a nickel-zinc coprecipitate by the alkali solution, and filtering and separating out nickel carbonate and a sodium zincate solution, and concentrating and crystallizing the sodium zincate solution to obtain sodium zincate. The method disclosed by the invention is easy to control process conditions, low in treatment cost, and easy to realize large-scale production; the purpose of comprehensively recovering valuable metals is achieved by implementing harmless and resourceful treatment for the electroplating waste mud; and the recovery rate of copper is greater than 95%.

The invention provides a conductive thermoplastic elastomer and a preparation method thereof. The thermoplastic elastomer includes following blended components: a. thermoplastic resin; b. rubber particles having crosslinking structures; c. a conductive filling material; and d. low-melting-point metal. Gel content in the component b is, by weight, 60% or more than 60%. An average particle size of the rubber particles is 0.02-1 [mu]m. The component c is not melted at a processing temperature of the thermoplastic resin. The component d is at least one of a single-component metal and a metal alloy. A melting point of the component d ranges from 20-480 DEG C and is lower than the processing temperature of the thermoplastic resin. A weight ratio of the component b to the component a is more than 30:70 and is lower than 75:25. The conductive polymer composite material is low in filling amount of the conductive filling material and the low-melting-point metal, is excellent in conductive performance, can be prepared through a melt blending method, can be used for manufacturing electronic production devices and tools which have an anti-static function and an electromagnetic wave interference resistant function and is of a dust-free requirement, can be used for manufacturing shells of electronic instruments and meters, can be used as a decoration material in a dust-free production workshop and can be used as shells and circuit boards of various flexible electronic products.

The present invention is wet process of extracting vanadium and/or molybdenum form waste petrochemical catalyst alumina carrier containing V, Mo and other elements. The wet process includes high-temperature deoiling the catalyst in natural granularity, mixing with sodium carbonate, high-temperature oxidation and roasting in a kiln or furnace to obtain water soluble sodium vanadate and sodium molybdate; countercurrent water soaking of the chamotte to obtain solution containing V and Mo in certain concentration, adding calcium salt and magnesium salt to eliminate P and other impurities, addingammonium salt solution into the clear solution to obtain ammonium metavanadate, decomposing and melting ammonium metavanadate to obtain V2O5 product; adding acid to the supernatant and organic phase extraction of Mo, ammonia water reverse extraction to obtain ammonium molybdate, and adding acid to precipitate ammonium tetramolybdate or molybdate product.

The invention provides a high temperature self-repairing conductive silver adhesive. The high temperature self-repairing conductive silver adhesive is prepared from the following raw constituents by parts: 100 parts of epoxy resin, 10-30 parts of curing agent, 10-40 parts of epoxy diluent, 240-990 parts of silver pieces, 3-20 parts of coupling agent and 5-20 parts of self-repairing microcapsule; wherein the self-repairing microcapsule is composed of the following raw constituents by parts: 100 parts of epoxy resin, 8-20 parts of latent curing agent, 30-60 parts of diluents, 0.5-2.5 parts of emulsifying agent, 500-800 parts of nano silver wires, 5-16 parts of coupling agent, 60-120 parts of capsule wall material, 0.5-2 parts of antifoaming agent and 150-900 parts of deionized water. The invention also provides a preparation method of the high temperature self-repairing conductive silver adhesive. The high temperature self-repairing conductive silver adhesive has the positive effects that the repairing efficiency is high, the repairing effect is expanded on the basis of the original conductive network, crack-conductive network double repairing is realized, and the long-term using effect of the conductive adhesive is guaranteed, the cost is saved, and the reliability and service life of the conductive adhesive in high temperature working environment are improved.

The invention discloses a method of removing arsenic from an acid arsenic-containing solution. The method comprises the following steps: the pH value of the acid arsenic-containing solution is adjusted to be 1.0-5.0, an iron-containing material and an oxidizing agent are added, the temperature of the solution is controlled at 25-90 degrees, after reaction, ferric arsenate sediment and arsenic-removed post liquid are obtained, and the removal of arsenic is realized. When copper contained in the acid arsenic-containing solution is greater than or equal to 0.2g/L, iron powder replacement copper removal treatment is required to be carried out first. The method has the advantages that the method is simple in process, low in cost and high in arsenic removal rate and obtained ferric arsenate sediment is stable; valuable metals can be recycled effectively; and the method has very high practicability and economic value.

The invention relates to modified biomass charcoal and a remediation method of heavy metal contaminated soil. The modified biomass charcoal is prepared by the following steps: (1) sieving biomass charcoal, and washing so as to remove surface fly dust and impurities until the pH value of a scrubbing solution is 6.5-7.5; (2) uniformly mixing the biomass charcoal and a phosphoric acid solution according to the mass ratio of 1 to (1.5-2.5), and then soaking at room temperature for 24 hours above, wherein the mass percent concentration of the phosphoric acid solution is 10-40%; and (3) carrying out solid-liquid separation on the soaking solution, and then drying the obtained a solid material, namely the modified biomass charcoal. The modified biomass charcoal is reasonable in design, is simple in technology, and overcomes the technical difficulty for a long time; phosphoric acid is detained in the biomass charcoal in the form of metaphosphoric acid, and especially can form sediment substances together with active heavy metal ions under a water containing condition, thereby intensifying the passivation or fixing effect to the heavy metal ions by the biomass charcoal.

The invention provides a preparation method of an oxidized graphene and sodium alginate composite absorbing material capable of removing ciprofloxacin in an aqueous solution. The preparation method comprises the following steps: dispersing a certain amount of oxidized graphene samples in deionized water, putting the oxidized graphene samples into an ultrasonic cleaner, and performing ultrasonic treatment for 6-10 hours; dissolving a certain amount of sodium alginate into an oxidized graphene solution subjected to ultrasonic treatment, and performing ultrasonic treatment for 20 minutes; dropewise adding the mixed solution into a 0.2mol/L calcium chloride solution by virtue of a peristaltic pump, soaking for 1-3 days, and cleaning with deionized water for 3-4 times, thereby obtaining a sodium alginate and oxidized graphene sphere hydrogel material; and freeze-drying, thereby obtaining oxidized graphene and sodium alginate sphere aerogel. The preparation method is performed under a relatively mild condition, and oxidized graphene is packaged in a sodium alginate network structure by an ion bridge method, so that the nano toxicity of graphene powder is avoided, and a new nano material capable of efficiently absorbing ciprofloxacin antibiotics in the aqueous solution is prepared. The preparation process is simple, easily controllable in condition, low in cost and suitable for large-scale batch production.

The invention discloses a high thermal conductivity flame-retardant nylon composite material and a preparation method thereof. The high thermal conductivity flame-retardant nylon composite material is prepared from the following components in parts by weight: 30 to 60 parts of nylon, 65 to 10 parts of nylon, 10 to 30 parts of carbon micro-nano thermal conductive filler, 10 to 30 parts of metal micro-nano thermal conductive filler, 10 to 30 parts of nonmetal and non-cabonic micro-nano thermal conductive filler, 5 to 15 parts of flame retardant, 0.5 to 2 parts of compatilizer, 0.5 to 1 part of antioxidant, 0.5 to 1 part of lubricating agent and 0 to 3 parts of toner. The high thermal conductivity flame-retardant nylon composite material disclosed by the invention has the advantages of excellent dispersibility, high heat conducting property, small filling content, low density and excellent processing performance; the preparation method of the high thermal conductivity flame-retardant nylon composite material is simple in process, controllable in conditions, low in cost and suitable for industrial production.

The present invention provides an electrically conductive paste for a front electrode of a solar cell and a preparation method thereof. The electrically conductive paste is composed of a corrosion binder, a metallic powder and an organic carrier. The corrosion binder is one or more glass-free Pb—Te based crystalline compounds having a fixed melting temperature in a range of 440° C. to 760° C. During a sintering process of the electrically conductive paste for forming an electrode, the corrosion binder is converted into a liquid for easily corroding and penetrating an antireflective insulating layer on a front side of the solar cell, so that a good ohmic contact is formed. At the same time, the electrically conductive metallic powder is wetted, and the combination of the metallic powder is promoted. As a result, a high-conductivity front electrode of a crystalline silicon solar cell is formed.

The invention discloses hybridized particles, a polymer-based composite material, their preparation methods and a use of the polymer-based composite material. The hybridized particles comprise insulating ceramic particles and conductive microparticles loaded on the surfaces of the insulating ceramic particles. The conductive microparticles are granularly and discretely distributed on the surfaces of the insulating ceramic particles. The preparation method of the hybridized particles adopts an in-situ chemical-reduction technology, a sol-gel technology, an in-situ polymerization technology, a high-temperature heat treatment technology or a mechanical milling technology. The polymer-based composite material comprises the hybridized particles and a polymer filled with the hybridized particles. The polymer-based composite material comprises 20-80wt% of the hybridized particles. The hybridized particles have stable structures and stable performances. The polymer-based composite material has the excellent performances such as high dielectric constant, low dielectric loss and stable performances. The preparation methods of the hybridized particle and the polymer-based composite material have the advantages of simple process, easy control of conditions, high production efficiency and industrial production applicability.

The invention discloses a ceramic coating membrane and a preparation method thereof. The steps are as follows: the preparation of stem grafting ceramic powder, the preparation of functional power containing lithium-ion, the preparation of coating slurry and the preparation of ceramic coating membrane. The preparation method of ceramic coating membrane, provided by the invention is that: benzene sulfonate containing lithium is grafted on the surface of the ceramic powder, and then the ceramic powder grafted is coated on a polyolefin microporous membrane, thereby obtaining the ceramic coating membrane is obtained. The preparation method has the advantages of simple process, low requirements to equipment, easiness in condition control and low cost, and is suitable for industrial production. Due to the ion exchange capacity and hydrophily of the ceramic coating membrane prepared by the method, the ceramic coating membrane has a strong electrolyte infiltrating capability, is high in membrane breaking temperature, and has improved safety.

The invention discloses a functionalized graphene adsorbent and a preparation method and application of the functionalized graphene adsorbent. The adsorbent is mainly composed of grapheme and cetyl trimethyl ammonium bromide. The cetyl trimethyl ammonium bromide inserts into the edge or surface layer of the layered grapheme and or embeds into the edge or surface layer of the layered grapheme through the function of non-covalent bond. The mass fraction of the cetyl trimethyl ammonium bromide in the adsorbent is 40%-50%. The invention discloses the preparation method of the functionalized graphene adsorbent. The method comprises the steps of dispersing the graphene oxide into the water, adding cetyl trimethyl ammonium bromide to the dispersed suspension liquid and stirring to make reaction, then adding suspension liquid to the heated reaction system and conducting suction filtration, washing and drying to the black cotton-shaped precipitate obtained by reduction. The functionalized graphene adsorbent can wipe out the chrome in the waste. The adsorbent is added into the chromate waste water, control the temperature of the waste, then after the full adsorption and complete oscillatory removal of the chromate is completed. The functionalized graphene adsorbent and a preparation method and application of the functionalized graphene adsorbent has the advantages of being simple, high efficient, green, economical and environmental and the like.

The invention discloses a compound grapheme absorption agent which comprises grapheme, nanometer zero-valent iron and cetyl trimethyl ammonium bromide. The invention further discloses a method for preparing the compound grapheme absorption agent. The method for preparing the compound grapheme absorption agent includes the following steps that firstly, oxidized grapheme is dispersed in water with ultrasonic waves and oxidized grapheme suspension liquid is obtained; secondly, the nanometer zero-valent iron and the cetyl trimethyl ammonium bromide are added into the oxidized grapheme suspension liquid obtained in the first step, fully stirred and fully reacted and a reaction solution is obtained; thirdly, the reaction solution obtained in the second step is added with reductive agents and fully reacted and black flocks are obtained; fourthly, the black flocks obtained in the third step are filtered, washed and dried to obtain the compound grapheme absorption agent. The compound grapheme absorption agent is efficient, green, economic, friendly to environment, and suitable for large-scale production. The preparing method is simple and conditions are easy to control.

The present invention relates to the preparation process of chitosan base macroporous high water absorption resin. After chitosan is dissolved in dilute acetic acid solution, acrylic acid is made to graft on the molecular chain of chitosan under the initiation of ammonium or potassium persulfate and the product is cross-linked with cross-linking agent, so as to produce high water absorption chitosan grafted acrylic resin with distilled water absorption of 560-1210 g/g and physiological saline absorption of 76-125 g/g. The prepared resin is further modified via solvent deposition process to form macroporous structure to raise the water absorbing rate greatly. High efficiency liquid phase chromatographic test shows that the resin has greatly reduced acrylic acid monomer residue.

The invention discloses nanoscale zero-valent iron stable in air, wherein nanoscale zero-valent iron is taken as a core, and silicon dioxide is covered on the surface thereof. The preparation method comprises the following steps of: (1) adding isopropanol aqueous solution in ferrous sulphate, charging nitrogen, mechanically stirring for 15 to 30 minutes, dropping sodium borohydride solution containing sodium hydroxide while stirring, after that, adding polyethylene glycol, and continuing to react for 0.5 to 1 hours while stirring; (2) adding tetraethoxysilane in the solution, controlling the molar ratio of the sodium hydroxide to the sodium borohydride in the solution to be in a certain range, continuously stirring, and continuously charging nitrogen, after the reaction is finished, staying, vacuum-filtrating, then washing by absolute ethyl alcohol and deionized water respectively; and (3) vacuum-drying the obtained nano-iron to obtain the stable nanoscale zero-valent iron. The nanoscale zero-valent iron has a good inoxidizability in air; and the whole reaction process has the advantages of low material price, simple device, convenient operation, and easily-controlled and safe process condition.

The invention relates to a method for preparing a high-purity pitch-adjustable metal nanoparticle dimer at high yield. The method is characterized in that two length-adjustable double-stranded DNA molecules respectively modified by a dual-thiol molecule at the tail ends are used as the connection part; Au (gold) nanoparticles are assembled to a discrete dimer through the chemical bond formed between the thiol and the surface of the Au nanoparticles; and the discrete dimer is separated by one-step electrophoresis method to obtain the high-purity target product. The method provided by the invention can be also used for preparing high-purity Au nanoparticle dimer with symmetric and asymmetric compositions. The method has the advantages of less steps, simple operation, easily-controlled conditions, and good repeatability, and solves the problems of single-DNA-modified Au nanoparticles, such as low assembly purity and complicated steps. The method can provide a firm platform for the basic research of plasmon resonance photonics, and can be used for molecular spectrum studies, such as surface-enhanced Raman scattering and metal-enhanced fluorescence. The prepared high-purity pitch-adjustable metal nanoparticle dimer can be used as an ultrahigh-sensitivity sensor based on plasmon resonance.

The invention discloses a modified PP (polypropylene) material with long carbon fiber and reinforced conductivity and a preparation method thereof. The modified PP material with the long carbon fiber and the reinforced conductivity comprises the following components in percentage by weight: 40-70% of PP resin, 3-5% of compatilizer, 5-10% of flexibilizer, 3-5% of coupling agent, 1-3% of conductive carbon black, 5-40% of long carbon fiber and 1-3% of plastic processing additive. According to the modified PP material with the long carbon fiber and the reinforced conductivity, the PP resin is employed as matrix resin, the long carbon fiber is employed as packing, and the both are in synergistic effect when in melt extrusion process, therefore the modified PP material with the long carbon fiber and the reinforced conductivity is endowed with excellent comprehensive mechanical properties, such as tensile strength, bending strength, bending modulus and impact strength, and excellent conductivity. The modified PP material with the long carbon fiber and the reinforced conductivity is simple in process, easy in controlling of conditions, low in cost, low in requirements on equipment, and applicable to industrial production.