979 results about "Ammonium bromide" patented technology

The invention relates to the technical field of environmental materials and water treatment, in particular to a graphene amino silica gel composite adsorbent for heavy metal wastewater treatment and a preparation method thereof.The graphene amino silica gel composite adsorbent is prepared from # imgabs0 nanoparticles, an amino-functionalized silicon dioxide coating layer, carboxylated reduced graphene oxide, a polydopamine modification layer and tetraethyl orthosilicate; the coating is prepared from the following raw materials: 3-aminopropyltriethoxysilane, 3-mercaptopropyltrimethoxysilane, N-((4-vinyl benzyl) amino) diacetic acid, chitosan, beta-cyclodextrin, hexadecyl trimethyl ammonium bromide, polyethylene glycol, L-ascorbic acid, 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide. The composite adsorbent shows excellent adsorption performance on various heavy metal ions, and the adsorption performance is far higher than that of traditional adsorption materials and existing composite adsorbents.

The invention relates to the field of coating materials, and provides an antiskid coating based on carbon fibers and a preparation method thereof. The coating is composed of a component A and a component B, the component A comprises KH-570 silane coupling agent surface modified carbon fibers, dog bone-shaped nano silicon dioxide, epoxy modified hydroxy acrylic resin, quartz sand antiskid aggregate, propylene glycol methyl ether acetate, iron oxide pigment and other auxiliaries, and the component B is an HDI tripolymer curing agent. The surface modified carbon fiber is prepared through the steps of cleaning and activating, silane coupling agent dipping, drying and curing and the like, and the dog bone-shaped nano silicon dioxide is prepared through a sol-gel method with hexadecyl trimethyl ammonium bromide and polyvinylpyrrolidone as morphology guiding agents. The preparation method comprises the steps of iron oxide color paste preparation, functional component dispersion, quartz sand addition, curing treatment, double-component mixing and curing and the like. The coating has excellent dry skid resistance, wet skid resistance, wear resistance and durability, and is suitable for the field of ground skid resistance coating.

The invention relates to the technical field of reverse osmosis membrane supports, in particular to a polyester non-woven fabric and a preparation method and application thereof.The preparation method comprises the steps that S1, polyester main body fibers and polyester adhesive fibers are used as raw materials to prepare high-quantitation original cloth M0 and low-quantitation original cloth H0; carrying out hot pressing pretreatment on the H0 to obtain a product H0 '; s2, overlapping and hot-pressing M0 and H0 'to obtain a composite non-woven fabric M1H1; s3, the M1H1 is impregnated with a functional solution, and the functional solution contains para-aramid nanofibers and nano calcium carbonate modified by hexadecyl trimethyl ammonium bromide; and then carrying out cold pressing on the composite non-woven fabric impregnated with the functional solution to obtain the nano-material modified composite non-woven fabric. And S4, carrying out secondary hot pressing treatment to obtain the polyester non-woven fabric. The polyester non-woven fabric can effectively avoid the problems of excessive curling, excessive permeation of a polysulfone solution and the like during curing after being coated with polysulfone, and is more beneficial to application in a reverse osmosis membrane.

The invention discloses a two-phase electrolyte, a preparation method thereof and a liquid energy storage battery system, and belongs to the technical field of electrochemical energy storage. According to the invention, a liquid-liquid double-phase electrolyte is composed of a water-phase electrolyte and an organic-phase electrolyte, wherein the organic-phase electrolyte contains a coupling system of 1-(methyl-decyl)-3-methylimidazolium bromide, tris (methyl-decyl) methyl ammonium bromide and (10-octadecyl) alkyl trimethyl ammonium bromide in a molar ratio of (5-7): (2-4): 1. During charging, positive electrode bromide ions are subjected to an oxidation reaction to generate a bromine simple substance, and meanwhile, the bromine simple substance and a coupling system of the quaternary ammonium bromide compound and the bromine complexing agent provided by the invention form a stable polybromine complex product, so that the polybromine complex product is prevented from being migrated into a water-phase electrolyte, and the purpose of improving the stability of the water-phase electrolyte in the absence of a diaphragm is achieved. The self-discharge reaction of bromine is significantly inhibited at a high temperature exceeding the boiling point temperature of bromine, the coulombic efficiency and energy efficiency of the liquid energy storage battery are improved, the system cost is reduced, and the long-term cycle stability of the liquid energy storage battery is improved.

The invention discloses a high-dispersion graphene conductive adhesive solution for a battery and a preparation method of the high-dispersion graphene conductive adhesive solution, and belongs to the technical field of conductive adhesive solutions. The high-dispersion graphene conductive adhesive solution for the battery prepared by the invention is prepared from the following raw material components in parts by mass: 6 to 8 parts of high-dispersion graphene, 4.5 to 13.5 parts of an adhesive and 60 to 90 parts of a solvent, the preparation method comprises the following steps: ultrasonically dispersing graphene in a mixed solution of hexadecyl triyl ammonium bromide and deionized water, sequentially adding hexadecyl triyl ammonium bromide, sodium molybdate dehydrate, bismuth nitrate pentahydrate and cerium nitrate hexahydrate, uniformly stirring and dispersing, performing hydrothermal reaction, washing, drying, grinding and sieving to obtain the high-dispersion graphene. The adhesive is prepared from an amphiphilic polyethylene glycol-polycaprolactone block copolymer and amphiphilic polyacrylate.

The present invention provides a carbon fiber reinforced silicon carbide ceramic and a preparation method thereof, belonging to the technical field of silicon carbide ceramics; the preparation method includes steps of preparing functional carbon fibers, preparing modified silicon carbide microspheres, preparing a mixture, forming and calcining; the step of preparing modified silicon carbide microspheres is as follows: placing silicon carbide in an ethanol solution, adding sodium dodecyl aminopropionate for ball milling treatment, after the ball milling ends, filtering and drying to obtain ball milled silicon carbide; placing the ball milled silicon carbide in dimethyl sulfoxide, stirring evenly, adding modified sodium alginate and hydroxyethyl cellulose, heating to 70 - 74 °C, adding tetrabutylammonium bromide, carrying out a heat preservation reaction for 10.0 - 11.5 h, after the reaction ends, filtering, washing and drying to obtain modified silicon carbide microspheres; the ceramic product prepared by the present invention has high strength performance and toughness, a low thermal expansion coefficient, and excellent high temperature oxidation resistance.

The invention discloses a concrete sewage pipeline antibacterial anticorrosive coating material and a preparation method thereof, the concrete sewage pipeline antibacterial anticorrosive coating material is prepared from the following raw materials: water, water supply aluminum sludge ash, a water reducing agent, Portland cement, aggregate and antibacterial agents, the antibacterial agents are three antibacterial agents with different representativeness, respectively zinc oxide ZnO, copper phthalocyanine C32H16CuN8 and dihexadecyl dimethyl ammonium bromide C34H72BrN. Compared with a traditional concrete anticorrosive coating material, the prepared antibacterial anticorrosive coating material for the sewage pipeline has the advantages that the water supply aluminum sludge ash modified cement-based material is used as a carrier, and the antibacterial agent is used as a functional component to be doped to prepare a functional antibacterial coating, so that the microbial corrosion resistance and the stability of the coating are remarkably improved, and the antibacterial anticorrosive coating material is green and environment-friendly, and has a good application prospect. The method is low in cost, simple in process and convenient to prepare.

The invention provides a method for preparing a catalyst material based on a hydrothermal method, and relates to the technical field of exhaust gas aftertreatment catalytic materials. The method comprises the following steps: dissolving cerium salt and transition metal salt in deionized water to form a precursor solution; taking hexadecyl trimethyl ammonium bromide as a template agent, and dissolving the template agent in the precursor solution; dropwise adding ammonia water into the precursor solution to adjust the pH value to alkalescence; putting the precursor solution into a reaction kettle for high-temperature hydrothermal treatment; filtering, drying and grinding the solution subjected to hydrothermal treatment, and then carrying out high-temperature roasting treatment; and performing segmented reduction on the roasted sample by using hydrogen to obtain the catalyst material. The preparation method has remarkable technical effects in the aspects of increase of active sites of the catalyst, increase of specific surface area, remarkable improvement of future application prospect and performance and the like.

The invention provides a photocatalytic porous composite material for sewage treatment and a preparation method and application thereof, and the preparation method comprises the following steps: dropwise adding an organic ligand solution into a precursor solution composed of a nano cellulose solution and a cobalt source solution, mixing a reaction solution with polyvinyl alcohol, injecting the mixture into a mold, and carrying out directional freezing to obtain an aerogel matrix; carrying out hydrophobic modification on the aerogel matrix to obtain a modified aerogel matrix; the preparation method comprises the following steps: dissolving tetrabutyl titanate and cetyltrimethylammonium bromide in absolute ethyl alcohol, stirring and heating to obtain precursor sol, adding a ferric nitrate solution into the precursor sol for hydrothermal reaction, and filtering and calcining after the reaction is finished to obtain doped titanium dioxide particles; and dispersing the doped titanium dioxide particles in deionized water to obtain a dispersion liquid, and dipping the modified aerogel matrix. According to the invention, a composite material composed of a nanocellulose / ZIF-67 composite aerogel matrix and doped titanium dioxide particles is constructed, and efficient sewage treatment of adsorption-catalysis-regeneration cycle is realized.

The invention belongs to the technical field of insulating oil, and provides a slow-release antioxidant as well as a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing octadecyl trimethyl ammonium bromide, 2, 6-butylated hydroxytoluene, tetraethoxysilane, water and ammonia water, and reacting to obtain the antioxidant; and (2) in a protective atmosphere, mixing the antioxidant, ethanol, water and gamma-mercaptopropyltriethoxysilane, and carrying out a reaction so as to obtain the slow-release antioxidant. The slow-release antioxidant suitable for the synthetic ester insulating oil is prepared through a physical coating means and oleophylic modification, has excellent solubility, can effectively inhibit the increase of the acid value of the synthetic ester insulating oil, delays the oxidation process of the synthetic ester insulating oil, and remarkably prolongs the service life of the insulating oil. Meanwhile, through a slow release mechanism, the antioxidant can prolong the antioxidant effect of the antioxidant, improve the antioxidant stability in long-time operation and meet the higher antioxidant requirement of high-performance equipment such as a transformer for the insulating oil.

The invention relates to the technical field of analysis and detection, in particular to a fluorescent switch sensor based on quantum dot-nano porphyrin and application. The specific technical scheme is as follows: the fluorescent switch sensor is constructed by utilizing cadmium telluride quantum dots modified by mercaptosuccinic acid and a 5, 10, 15, 20-tetra (4-nitrophenyl) porphyrin nano material modified by a cationic surfactant hexadecyl trimethyl ammonium bromide. And the method has a good enrichment effect on zearalenone. The sensor has high sensitivity, high selectivity and anti-interference performance, can accurately analyze trace zearalenone in actual grain samples (corn, rice, soybean and the like), and has the advantages of simplicity in operation, low detection limit, high sensitivity, low cost and the like.

The invention belongs to the technical field of molecular sieve synthesis, and discloses a ZSM-5 type molecular sieve as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, carrying out calcination treatment and low-temperature plasma treatment on rectorite to obtain modified rectorite; then adding the modified rectorite and a supplementary silicon source into water, sequentially adding butane-1, 4-bis (dodecyl dimethyl ammonium bromide) and hexadecyl trimethyl ammonium bromide, raising the temperature, adding a template agent, adjusting the pH value of the system, and quickly aging by microwave treatment to obtain a precursor; and finally, heating the precursor, carrying out hydrothermal crystallization reaction, washing, drying and grinding a product, and calcining to obtain the ZSM-5 type molecular sieve. The rectorite is used as all aluminum sources and part of silicon sources for molecular sieve synthesis, the aluminum activity and nucleation sites of the rectorite are improved through modification, then two surfactants are introduced, and microwave treatment is combined, so that silicon and aluminum species in a system are rapidly nucleated, and the efficient, economical and higher-performance ZSM-5 type molecular sieve is prepared.

4, 4 '-bipyridine (Bpy), 2, 5-thiophenedicarboxylic acid (Tdc), FeCl3. 6H2O, NiCl2. 6H2O, urea and tetrabutylammonium bromide are used as raw materials, a simple hydrothermal-calcination method is adopted to prepare the Fe2O3-coated Ni-MOF composite nanomaterial catalyst, X-ray diffraction (XRD), a scanning electron microscope (SEM) and a N2 adsorption and desorption technology are adopted to characterize a prepared sample, and the electro-catalytic oxygen evolution reaction (OER) activity of the Fe2O3-coated Ni-MOF composite nanomaterial catalyst is tested. Results show that compared with a single component, the activity of the composite nano-material catalyst is greatly improved, especially the composition-optimized Fe2O3-coated Ni-MOF-1 composite nano-material catalyst shows the highest catalytic activity, the composite nano-material catalyst catalyzes OER in 1M KOH, and the overpotential (eta 10) is only 330mV when the current density is 10mA / cm < 2 > and is close to the overpotential 291mV of a noble metal catalyst RuO2.

The invention belongs to the technical field of photocatalytic materials, and particularly relates to a manganese ferrite / bismuth tungstate heterojunction photocatalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: 1) dissolving sodium tungstate dihydrate, bismuth nitrate pentahydrate and hexadecyl trimethyl ammonium bromide in deionized water, and obtaining bismuth tungstate by using a hydrothermal method; 2) dissolving ferric chloride hexahydrate and manganese chloride tetrahydrate in water, then adding a sodium hydroxide solution, and obtaining manganese ferrite by using a hydrothermal method; and 3) dissolving bismuth tungstate and manganese ferrite into a sodium hydroxide solution, stirring, and drying to obtain the manganese ferrite / bismuth tungstate heterojunction photocatalyst. The formation of the heterojunction can greatly improve the activity of the manganese ferrite / bismuth tungstate in photocatalytic reduction of carbon dioxide.

The invention discloses a recoverable high-barrier-property multilayer composite film and a preparation method thereof. The composite film adopts a five-layer symmetrical structure, namely a heat sealing layer, a first bonding layer, a blocking layer, a second bonding layer and a surface protection layer. Wherein the barrier layer is a montmorillonite modified ethylene-vinyl alcohol copolymer, and montmorillonite is modified by a carboxyl functionalized ammonium bromide intercalator; the bonding layer is maleic anhydride grafted polylactic acid; the heat sealing layer contains modified composite filler; the surface protection layer is a polyethylene / graphene modified coupling agent composite system. The preparation method comprises the steps of intercalation modified montmorillonite preparation, barrier layer material melt blending, five-layer co-extrusion casting, gradient hot pressing and curing treatment. The problems that a traditional high-barrier film is unrecyclable, the interlayer binding force is weak and the high-temperature stability is poor are solved, the ultrahigh barrier performance that the oxygen transmission rate is smaller than or equal to 0.5 cm < 3 > / (m < 2 >. 24 h) and the water vapor transmission rate is smaller than or equal to 1.0 g / (m < 2 >. 24 h) is achieved, and the mechanical property retention rate is larger than or equal to 85% after recycling and re-pelletizing.

The invention belongs to the technical field of flame retardants, and particularly relates to a preparation method of bromotriazine, which comprises the following steps: adding phenol and deionized water into a reaction container, dropwise adding hydrogen peroxide and liquid bromine into a reaction system in a staggered manner, and adding a catalyst; after the reaction is finished, separating the catalyst, firstly carrying out quenching treatment on the filtrate, then carrying out extraction treatment, and carrying out reduced pressure distillation on the extracted organic phase to obtain tribromophenol; dissolving the prepared tribromophenol in dichloromethane, adding triethylamine and tetrabutylammonium bromide, stirring to form a homogeneous system, adding cyanuric chloride into the homogeneous system, and regulating and controlling the pH in stages; concentrating the organic phase which is washed to be neutral, adding n-hexane to initiate primary nucleation, dropwise adding ethyl acetate to adjust the polarity of the solvent, and promoting crystal growth; and filtering and drying in vacuum to obtain the bromo-triazine. Through staged pH / temperature regulation and control, the composite catalyst system realizes efficient synthesis of bromotriazine.

The invention discloses a flame-retardant and self-repairing wood epoxy coating as well as a preparation method and application thereof, and belongs to the technical field of epoxy resin. The preparation method specifically comprises the following steps: (1) uniformly mixing vanillin, epichlorohydrin and tetrabutylammonium bromide, reacting, cooling, dropwise adding a NaOH aqueous solution, continuously reacting, washing, drying, precipitating and drying again to obtain bio-based epoxy resin for later use; (2) uniformly mixing methanol and hydrochloric acid, heating, carrying out condensation reflux, adding gamma-aminopropyltriethoxysilane, reacting, cooling, adding tetrahydrofuran, washing and carrying out vacuum drying to obtain polyhedral oligomeric silsesquioxane; and (3) dissolving polyhedral oligomeric silsesquioxane in the organic solvent, adding the bio-based epoxy resin, uniformly stirring, standing and curing to obtain the composite material. According to the invention, vanillin is used for constructing the epoxy resin containing imine bonds, so that the self-repairing and excellent flame-retardant properties of the epoxy resin are realized.

The invention relates to the field of shoe materials, and particularly discloses an EVA and PEBAX blended foaming material for shoes and a preparation method of the EVA and PEBAX blended foaming material. The EVA and PEBAX blended foaming material for the shoes is prepared from the following raw materials in parts by weight: 70 to 90 parts of EVA resin, 10 to 30 parts of PEBAX, 0.8 to 1.2 parts of dodecyltrimethylammonium bromide modified rectorite, 2 to 5 parts of a foaming agent, 0.5 to 2 parts of a foaming aid, 3 to 5 parts of filler, 2 to 4 parts of a reinforcing agent, 0.5 to 2 parts of a cross-linking agent, 0.6 to 3 parts of a lubricating agent and 1 to 4 parts of a compatilizer. The material for the shoes has the advantages of being high in tear strength, uniform in foaming, light in weight and small in permanent compression deformation.

The invention belongs to the technical field of silicon dioxide preparation, and relates to a preparation method of spherical porous silicon dioxide, which comprises the following steps: S1, preparing a mixed solution, namely preparing a template solution, namely dissolving 0.5 g of hexadecyl trimethyl ammonium bromide into 100ml of deionized water mixed solution, and stirring by using a stirring mechanism until the solution is clear; adjusting the alkaline environment: adding 1ml of ammonia water, and adjusting the pH value to 10-11; s2, silicon source hydrolysis: slowly dropwise adding 2ml of tetraethyl orthosilicate into the solution in the step S1, and then carrying out stirring reaction; s3, aging and centrifugal washing: aging: stopping stirring, and standing for 12 hours to stabilize the structure; centrifugal washing: centrifuging for 5 minutes at 8000rpm, and sequentially washing for 3 times by using ethanol and water to remove unreacted substances; the spherical silicon dioxide can be protected by a simple sol-gel method without using a complex auxiliary agent, the mesoporous size of the spherical silicon dioxide is relatively uniform, the supercritical carbon dioxide is adopted for drying in a drying box, the pore structure is kept complete, and the use effect is improved.

The invention discloses a polyethylene composite geomembrane and a processing technology thereof in the field of geosynthetic materials. The polyethylene composite geomembrane is prepared from the following raw materials: high-density polyethylene, polyethylene grafted maleic anhydride, a nano montmorillonite / low-density polyethylene composite modifier, an antioxidant, a light stabilizer and a lubricant calcium stearate. Wherein the polyethylene grafted maleic anhydride is prepared by drying high-density polyethylene, mixing the dried high-density polyethylene with maleic anhydride, an initiator and an antioxidant, and performing melt extrusion through a double-screw extruder, so that the surface polarity is improved; the nano-montmorillonite / low-density polyethylene composite modifier is prepared by ultrasonically dispersing Na-montmorillonite, adding hexadecyl trimethyl ammonium bromide, stirring, centrifugally drying to obtain organic modified montmorillonite, mixing the organic modified montmorillonite with low-density polyethylene, performing intercalation reaction, and performing twin-screw extrusion and blending, so that the barrier property is enhanced. The processing technology comprises the steps of raw material mixing, twin-screw extrusion granulation and calendaring molding, and finally the polyethylene composite geomembrane with remarkably improved interface cohesiveness, weather resistance and barrier property is prepared.

The invention discloses a copper-clad plate material containing elastomer resin and a preparation method of the copper-clad plate material, and belongs to the technical field of new materials. The method comprises the following steps: mixing a styrene-butadiene-styrene block copolymer with polybutadiene rubber, adding nano-montmorillonite, and carrying out intercalation modification through hexadecyl trimethyl ammonium bromide to prepare nano-modified elastomer resin; the preparation method comprises the following steps: mixing polybutylene terephthalate with nano silicon dioxide, and carrying out surface modification by gamma-aminopropyltriethoxysilane and hexamethyldisilazane to obtain a resin matrix; mixing the two phases, adding citric acid, and carrying out microwave heating and high-shear dispersion to obtain a discrete material; carrying out hot pressing on the dispersion, adding polyurethane and polylactic acid, uniformly mixing, adding polydimethylsiloxane and sodium dodecyl benzene sulfonate, and curing to obtain a cured product; and coating the surface of the cured product with a nano-copper layer. The material has the characteristics of high peel strength, low dielectric loss, low water absorption and low thermal expansion, and is suitable for the field of high-speed low-loss copper-clad plates.

The invention relates to a platinum-zinc alloy supported nitrogen-doped porous multi-layer carbon material and preparation and application thereof, the carbon material takes a rod-like graded porous carbon nanomaterial as a carrier, and platinum-zinc alloy particles and zinc monatomic are jointly supported on the surface of the carrier; the preparation method comprises the following steps: S1, adding zinc acetate and hexadecyl trimethyl ammonium bromide into DMF (Dimethyl Formamide), carrying out ultrasonic treatment, adding into a polyacrylonitrile solution, and stirring; s2, performing electrostatic spinning on the obtained spinning precursor solution; s3, adding the obtained nanofiber into a zinc acetate dihydrate solution, then adding a dimethylimidazole solution, carrying out hydrothermal reaction, soaking the obtained product in a chloroplatinic acid methanol solution, and then carrying out freeze drying; and S4, heating carbonization is carried out under the protection of an inert atmosphere, then annealing and cooling are carried out, and the PtZn-Zn-N4-HPCNFs material is obtained. Compared with the prior art, the catalytic performance and the like in the reaction processes of oxygen reduction reaction (ORR), chlorine evolution reaction (CER) and the like can be effectively improved.

The invention provides catalyst slurry and a preparation method thereof, a membrane electrode and an electrolytic bath, and belongs to the technical field of water electrolysis hydrogen production, and the catalyst slurry comprises a catalyst, proton exchange resin, a dispersing agent and a solvent. Wherein the dispersing agent comprises at least one of polyvinylpyrrolidone, polyvinyl alcohol, polyethyleneimine, hexadecyl trimethyl ammonium bromide and hydroxyethyl cellulose. According to the catalyst slurry provided by the embodiment of the invention, sedimentation can be slowed down, the stability of the catalyst slurry is improved, the uniformity of the loading capacity of a catalyst in different membrane electrodes prepared from single-batch catalyst slurry is ensured, and the stability is improved.

The invention relates to the technical field of materials, in particular to a fiber-reinforced starch-based fireproof and moisture-proof composite material and a preparation process thereof. Comprising the following steps: toughening and fireproof modification of lignin fibers; carrying out site selection phosphorylation on the starch; and carrying out in-situ bonding of phenylboronic acid and hydrophobic modification of the blended material. The preparation method comprises the following steps: preparing a pre-assembled solution from ellagic acid, tannic acid and tetrabutylammonium bromide, then adding ZrOCl2 powder in batches to form a continuous ceramic phase ZrO6, forming an interlocking structure with a carbon layer to enhance the flame retardant property, then adding lignin fibers in the last batch, adjusting the pH value, and condensing to generate Zr-O-C covalent bonds, so as to obtain the composite material. The prepared modified lignin fiber is subsequently blended with site-selected phosphorylated starch, so that the mechanical property of the modified lignin fiber is enhanced, and heat and mass transfer between a gas phase and a condensed phase can be hindered when the temperature is too high, thereby greatly improving the flame retardant property of the composite material.

The invention belongs to the technical field of membrane separation, and particularly relates to a preparation method and application of a high-permeability polyamide reverse osmosis membrane. According to the invention, the problems of high energy consumption and poor water production quality caused by non-ideal flux and rejection rate of the current reverse osmosis membrane product are solved, tetrabutylammonium bromide and acyl chloride form ion pairs to reduce hydrophobicity, a hydrogen bond network of urea destroys a hydrophobic barrier of an organic phase, and migration of acyl chloride to a water phase interface is promoted; the eutectic solvent is adsorbed on a water phase interface to form a'catalytic microenvironment ', amido of an amine monomer is attracted to be close to the interface, and the concentration of a reaction area is increased. During reaction, tetrabutylammonium bromide enables an amine monomer to stably attack a transition state of acyl chloride through electrostatic interaction, and reaction activation energy is reduced; urea and sodium hydroxide in a water phase can be jointly used as an acid-binding agent to neutralize generated hydrochloric acid so as to prevent amido protonation inactivation. The method is simple to operate and suitable for large-scale production.

The invention discloses a gold nanocluster and application thereof in electro-catalysis of carbon dioxide reaction. The synthesis method comprises the following synthesis steps: firstly, adding a gold source into a tetrahydrofuran solution, stirring for five minutes, then adding tetra-n-octyl ammonium bromide, stirring until the solution is dark red, adding cyclohexanol, stirring until the solution is transparent, then adding a reducing agent, stirring overnight, then washing with methanol for multiple times, dissolving a crude product into a small amount of methylbenzene, and drying to obtain a target product. And adding a certain amount of cyclohexanol and 3 (2-furyl) phosphorus again, slowly stirring at 60 DEG C for 12 hours to obtain a crude product, washing with methanol for several times again, and purifying and separating to obtain the gold nanocluster. The gold nanocluster provided by the invention has the characteristics of novel structure, good stability, easy synthesis and high yield, and has excellent catalytic performance in electrocatalytic carbon dioxide reaction.

The invention relates to the technical field of catalyst processing, and discloses a high-activity transition metal phosphide electrolyzed water catalyst and a preparation method thereof, and the high-activity transition metal phosphide electrolyzed water catalyst comprises the following components by weight: 1-3 parts of cobalt chloride hexahydrate; 0.5 to 1.5 parts of ruthenium trichloride; 0.5 to 1.5 parts of iridium chloride (III) hydrate; 1-2 parts of copper sulfate pentahydrate; 2 to 4 parts of sodium hypophosphite; 1 to 2 parts of urea; 1 to 2 parts of glucose; 1-2 parts of sodium sulfide nonahydrate; 0.5 to 1 part of crystalline aluminum chloride; 50 to 100 parts of deionized water; and 0.1 to 0.5 part of hexadecyl trimethyl ammonium bromide. By introducing the plasma auxiliary treatment technology, the electronic structure of the catalyst is optimized, the conductivity and stability of the catalyst are improved, and the efficiency and durability of hydrogen production through water electrolysis are enhanced.

The present invention relates to the technical field of concrete materials, and specifically discloses an impermeable concrete containing a polycarboxylate early-strength water reducer and a preparation method thereof. The impermeable concrete containing a polycarboxylate early-strength water reducer comprises the following components in parts by mass: 100 parts of water; 310-320 parts of cement; 33-37 parts of fly ash; 300-310 parts of fine aggregate; 670-680 parts of coarse aggregate; 210-220 parts of modified desert sand; 5.7-6.1 parts of polycarboxylate early-strength water reducer; the modified desert sand is obtained by modifying desert sand with a modifier; the modifying solution is a compound of water, stearylamidopropyldimethyl tertiary amine, dodecyltrimethylammonium bromide, and benzalkonium bromide. The present invention has the advantage of improving the impermeability of concrete.

A method of carbon dioxide fixation includes contacting a covalent organic framework material with a co-catalyst and an epoxide in the presence of carbon dioxide to form a cyclic carbonate. The covalent organic framework material includes reacted units of a 2,4,6-trimethyl-1,3,5-triazine, reacted units of a 4,4′-biphenyldicarbaldehyde, and palladium nanoparticles. The reacted units of the 2,4,6-trimethyl-1,3,5-triazine and the reacted units of the 4,4′-biphenyldicarbaldehyde form a COF-701, where the palladium nanoparticles are on an outer surface of the COF-701. The co-catalyst is n-tetrabutylammonium bromide.

The invention belongs to the technical field of batteries, and particularly relates to lithium supplementing slurry, a lithium supplementing pole piece and a battery. The lithium supplementing slurry comprises a lithium supplementing additive, a conductive agent, a binder and a dispersant, the dispersant is selected from one or more of PVP, hexadecyl trimethyl ammonium bromide, ethanol and NMP, and the particle size of the lithium supplementing additive is 0.01-15 [mu] m. According to the method for prime coating of the lithium supplementing slurry, pretreatment procedures such as slurry mixing are involved, and conventional optimization methods such as particle size control of a lithium supplementing additive and adjustment of the proportion and introduction mode of a conductive agent can be considered; in addition, the stability and the coating uniformity of the prime coat slurry can be realized by introducing the dispersing agent and controlling the gravure prime coat process parameters.