18 results about "Sodium thiocyanate" patented technology

The invention discloses a self-cleaning filter for processing a sodium thiocyanate product and a use method, and relates to the technical field of chemical equipment. The filtering machine comprises a shell, a feeding pipe, a filtering tank, a filtering plate and a containing and receiving disc, and further comprises a lifting mechanism, a stirring mechanism, an overturning driving mechanism, a vibrating mechanism, a moving mechanism and a mounting mechanism. The lifting mechanism consists of a cylinder on the upper side of the shell and a lifting plate connected with the lower end of a piston rod; the stirring mechanism is arranged on the lifting plate and used for stirring materials in the filter tank; the overturning driving mechanism is connected with the filter tank and drives the filter tank to overturn and pour impurities; the vibration mechanism acts on the filter tank and assists in discharging residual impurities; the moving mechanism is arranged at the lower end in the shell and drives the containing disc to move horizontally. The mounting mechanism is connected with the moving mechanism and the containing disc, and the containing disc is detachably mounted. The at least two containing discs can be switched between the inner station and the outer station through the moving mechanism, and automation and high efficiency of the sodium thiocyanate processing and filtering link are achieved.

The invention provides a method for preparing a repair material for hydraulic concrete by using a solid waste material. The preparation method comprises the following steps: mixing 55-65% of a material A (water-quenched slag and copper slag), 30-40% of a material B (citric acid gypsum, red mud and spontaneous combustion coal gangue) and 4-6% of a catalytic complexing activator (cane molasses, iron ion catalytic complexing agent sodium thiocyanate leftovers, polyether amine, calcium ion catalytic complexing agent diisopropanolamine borate and water), and carrying out ball milling to obtain the concrete; the repairing material and water are uniformly stirred according to the ratio and then are brushed or sprayed on the base surface of the defective concrete, so that the effects of resisting scouring, resisting erosion and freezing and thawing can be achieved, the effect of further cracking and falling off of the concrete is inhibited, and the durability of the hydraulic concrete is improved.

The present application belongs to the technical field of adsorbents, and relates to a kind of for adsorbing and settling palladium amidoxime polyacrylonitrile-based microspheres and preparation method thereof.The present application utilizes chitosan quaternary ammonium salt (Q-CS), polyacrylonitrile (PAN) and sodium thiocyanate-containing amidoxime polyacrylonitrile (PAO / NaSCN) to obtain palladium adsorption performance stable amidoxime polyacrylonitrile microspheres;Among them, amidoxime and functional groups such as hydroxyl, amino and the like in chitosan can play the role of palladium adsorption, thiocyanate in sodium thiocyanate plays the role of settlement, and polyacrylonitrile enhances the mechanical strength of microspheres.The microspheres can adsorb and settle nearly 76% of palladium ions in solution within 5min at room temperature, reach adsorption and settlement equilibrium after 600min, and the adsorption capacity can reach 242mg / g when adsorption and settlement reach saturation.

The application discloses a FeNi2P / PCN-NaCA photocatalyst and a preparation method and application thereof, belongs to the field of photocatalysts, and solves the problem of the restriction of existing carbon nitride materials on the hydrogen peroxide production efficiency of photocatalysis. The preparation method comprises the following steps: dissolving iron chloride, nickel nitrate and terephthalic acid in N,N-dimethylacetamide, and performing a hydrothermal reaction to obtain a FeNi2P precursor; heating the FeNi2P precursor and anhydrous sodium phosphate in a nitrogen atmosphere to obtain FeNi2P; calcining melamine to obtain PCN; and mixing the PCN, sodium thiocyanate solid and FeNi2P, and calcining in a nitrogen atmosphere to obtain the FeNi2P / PCN-NaCA photocatalyst. The FeNi2P / PCN-NaCA photocatalyst can efficiently utilize light to produce hydrogen peroxide, and has the characteristics of good stability and reusability.

The invention relates to the technical field of salt extraction and recovery of sodium-process desulfurization waste liquid, in particular to a method and device for extracting product-grade sodium thiocyanate from sodium-process desulfurization waste liquid, and the method comprises the following steps: step a, primary decoloring treatment, step b, primary concentration crystallization, step c, secondary decoloring treatment, step d, freezing crystallization, step e, precise desalting, and step f, secondary concentration crystallization. A stepped process design of two-time decoloration, fractional crystallization and precise desalination is adopted, aiming at the physicochemical property difference of three core salts of sodium sulfate, sodium thiosulfate and sodium thiocyanate in the sodium-process desulfurization waste liquid, efficient separation is realized by accurately controlling process parameters, the sodium sulfate is preferentially separated out by utilizing the characteristic that the solubility of the sodium sulfate is relatively low at high temperature, and the sodium thiosulfate is separated out by utilizing a high-temperature crystallization method. The sodium thiocyanate is separated out in a targeted manner on the premise of ensuring that the sodium thiocyanate is in an unsaturated state, so that the technical problem that the sodium thiocyanate is easy to co-crystallize at low temperature is solved.

This invention relates to the field of oilfield chemical technology, and discloses a low-molecular-weight, high-viscosity ternary polymer flooding agent, its preparation process, and its application. The low-molecular-weight, high-viscosity ternary polymer flooding agent comprises the following raw materials by weight: simulated formation water: 986.2-995.9 g; sodium thiocyanate: 0.2-1.2 g; partially hydrolyzed polyacrylamide: 1.0-3.0 g; dodecyl hydroxypropyl sulfobetaine: 2.0-6.0 g; sodium salicylate: 0.9-3.6 g. The simulated formation water is prepared from deionized water, sodium chloride, calcium chloride, and magnesium chloride. Sodium thiocyanate is added to the simulated formation water to obtain a basic conditioning fluid; partially hydrolyzed polyacrylamide is added to obtain a polymer-based fluid; dodecyl hydroxypropyl sulfobetaine is added to obtain a mixed solution; and sodium salicylate is added to induce a rheological property transformation. This invention constructs a double interpenetrating network structure, solving the problems of insufficient viscosity enhancement and poor plugging.

The invention relates to the technical field of organic synthesis, and provides a continuous synthesis method of 1-isothiocyanate-2-chloro-2-propylene, which comprises the following steps: S1, dissolving sodium thiocyanate in a mixed solvent, adding 2, 3-dichloropropene, and carrying out nucleophilic substitution reaction to obtain an oil phase and a saline water phase; s2, the oil phase is subjected to a rearrangement reaction, a 1-isothiocyanate-2-chloro-2-propylene crude product is obtained, rectification is carried out, and 1-isothiocyanate-2-chloro-2-propylene is obtained; s3, after the saline phase is extracted, an organic matter phase and a saline raffinate phase are obtained, an extracting agent in the organic matter phase is recycled to serve as a regeneration extracting agent to be reused in extraction treatment, desalting treatment is conducted on the saline raffinate phase, and a sodium chloride solid is obtained; the mixed solvent is water and polyhydric alcohol. According to the technical scheme, the problem of low yield of the 1-isothiocyanate-2-chloro-2-propylene in the prior art is solved.

The application discloses a method for recovering cobalt from waste residues in the production of cobalt acetate by a hydrogen peroxide method, and adopts sodium thiocyanate and acetic acid to treat cobalt waste residues to obtain [Co(NCS)4] 2‑ solution, an oxide and unreacted metal cobalt; the obtained unreacted metal cobalt can be directly put into a synthesis kettle to participate in the production of cobalt acetate after being leached by sodium thiocyanate to remove surface impurities; the obtained oxide is reacted with sulfuric acid and hydrogen peroxide to obtain a cobalt sulfate solution; the obtained cobalt sulfate solution and the obtained [Co(NCS)4] 2‑ solution are reacted with sodium carbonate to obtain cobalt carbonate precipitation; the obtained cobalt carbonate precipitation is reacted with an acetic acid solution to obtain a cobalt acetate solution. The application does not produce toxic thiocyanic acid gas, and the sodium thiocyanate can be reused in the recovery process, so that the generation of waste liquid can be reduced, the cobalt recovery rate is high, and economic benefits are good.

The invention discloses a low-cost T800-grade carbon fiber as well as a preparation method and application thereof. The preparation method comprises the following steps: polymerizing an acrylonitrile monomer, a comonomer, an initiator and a composite additive in a sodium thiocyanate aqueous solution to obtain a spinning solution; performing dry-jet wet spinning on the spinning solution to obtain nascent fibers; the nascent fiber is subjected to washing water drawing, drying densification, multi-stage steam drawing, pre-oxidation, carbonization and surface treatment, and the low-cost T800-grade carbon fiber is prepared. According to the invention, by adding the carbon nanotube and graphene composite additive, the initial temperature of pre-oxidation is reduced, and the energy consumption is reduced; and through a waste heat recovery system and process parameter optimization, the production cost and the energy consumption are reduced. The tensile strength of the prepared carbon fiber is larger than or equal to 5.8 GPa, the tensile modulus is larger than or equal to 295 GPa, the performance stability is high (the CV value is smaller than 4%), the cost is reduced by 30% compared with that of traditional T800-grade carbon fiber, and the carbon fiber is suitable for the fields of aerospace, wind power generation and the like.

The present application relates to a kind of water phase method preparation 3-thiocyanate propyl triethoxysilane method, the present application is catalytic synthesis 3-thiocyanate propyl triethoxysilane using water phase method, using the mixed solution of water and ethanol as solvent makes sodium thiocyanate fully dissolved, overcome the problem that sodium thiocyanate cannot be fully dissolved or dissolved time is too long using organic solvent in solvent method, while using sodium bicarbonate as buffer agent makes the pH of system between 8-9, avoid the problem of hydrolysis in subsequent drop and reaction process, improve the reaction yield, the highest yield reaches 92.10%.By the water phase after separation into saturated sodium chloride solution to organic phase is washed, improve the utilization of reaction solution.

The application provides a combination catalyst and application thereof, and belongs to the technical field of fine chemical industry.The combination catalyst is composed of a phase transfer catalyst, an antioxidant and a buffer agent; the phase transfer catalyst is a crown ether phase transfer catalyst; the antioxidant is one or more of dilauryl thiodipropionate, dioctadecyl thiodipropionate, triphenyl phosphite and pentaerythritol diphosphite; and the buffer agent is one or more of potassium carbonate, sodium hydroxide and sodium bicarbonate.The combination catalyst has high activity, and when used in the reaction of synthesizing sodium thiocyanate and chloropropyl triethoxysilane, the combination catalyst has mild conditions, small dosage, easy control, simple operation, short reaction time, high yield, few by-products, reduced production cost, and improved product yield and quality.

The invention belongs to the technical field of sodium thiocyanate extraction, and particularly relates to a process for extracting sodium thiocyanate from coking desulfurization and decyanation waste liquid, which comprises the following steps: S1, carrying out catalytic oxidation on desulfurization waste liquid, adding dilute sulphuric acid, and adding a proper amount of liquid caustic soda to adjust the pH value to weak acidity to obtain a material; s2, centrifugally separating out sulfur solids from the materials, enabling the sulfur solids to fall into a sulfur pulping kettle, pumping the sulfur solids into a coking sulfur foam head tank through a pump, enabling the sulfur solids to enter a sulfur melting kettle to obtain sulfur, and obtaining activated carbon from residual slurry; s3, preparing a product sodium sulfate and / or a product sodium thiocyanate; wherein water in the slurry treated in the step S2 is evaporated until the content of sodium thiocyanate is 48-55%, solid sodium sulfate is obtained through centrifugation, and the product sodium sulfate is obtained through drying; and / or decolorizing the centrifuged liquid with activated carbon, filtering to separate out the activated carbon, evaporating water from the liquid until the content of sodium thiocyanate is 72-80%, crystallizing to separate out sodium thiocyanate, and centrifugally separating and drying to obtain the product sodium thiocyanate.

This invention discloses a nanocomposite phase change antifreeze water-reducing agent and its preparation method, comprising water and the following components in parts by weight: 5-8 parts polycarboxylate superplasticizer mother liquor, 6-10 parts ethylene glycol, 8-10 parts calcium formate, 2-4 parts sodium nitrite, 5-8 parts methanol, 2-5 parts sodium metasilicate, 1-2 parts sodium thiocyanate, 0.3-0.6 parts air-entraining agent, 6-8 parts modified nano titanium dioxide, and 8-10 parts ternary phase change material. This nanocomposite phase change antifreeze water-reducing agent is a composite functional admixture that introduces nanomaterials and phase change materials into traditional antifreeze water-reducing agents. It not only prevents concrete from freezing at low temperatures but also regulates the internal temperature changes of concrete through "phase change" characteristics, thereby improving the durability of concrete under freeze-thaw cycles.

The present application relates to wastewater treatment material technical field, specifically to a kind of nanometer cuprous thiocyanate, preparation method and application;The preparation method includes the following steps: S1, copper sulfate is stirred and dissolved in water and stirred uniformly, and blue transparent solution is obtained;S2, slowly drop sodium thiosulfate solution into blue transparent solution, and green transparent solution is obtained;S3, slowly drop sodium thiocyanate solution into green transparent solution and react to obtain white precipitate;S4, filter and collect white precipitate and repeatedly clean with anhydrous ethanol and distilled water to remove sodium thiocyanate impurities on the surface of white precipitate, then dry, grind to obtain nanometer cuprous thiocyanate.The application of nanometer cuprous thiocyanate prepared by the present application to adsorb tetracycline antibiotics in wastewater has the advantages of strong stability compared with copper sulfide, not easy to be oxidized by air, and can be recycled multiple times, so that resources are maximized.

This invention relates to a method for preparing 2-nitro-5-cyanothiobenzoic acid, comprising: (1) dissolving 5-amino-2-nitrobenzoic acid and an acid in a first reaction solvent, water, adding a nitrosating agent dropwise to the reaction system, reacting at a temperature of -20 to 20°C for 1 to 12 h, to obtain intermediate 3-carboxy-4-nitrobenzene diazonate M; the first reaction solvent is one or a mixture of water, acetonitrile, and ethanol; (2) reacting the intermediate 3-carboxy-4-nitrobenzene diazonate M obtained in step (1) with a thiocyanating agent and a catalyst in a second reaction solvent to undergo a nucleophilic substitution reaction, reacting at a temperature of -20 to 30°C for 1 to 24 h, to obtain 2-nitro-5-cyanothiobenzoic acid; the thiocyanating agent is selected from one or a mixture of cuprous thiocyanate, sodium thiocyanate, or potassium thiocyanate; the second reaction solvent is one or a mixture of water, acetonitrile, and ethanol. The raw materials of this invention are readily available, the cost is controllable, the reaction is mild, it is green and environmentally friendly, and it has high selectivity and high yield.

This invention discloses the application of sodium thiocyanate in the preparation of a kit for coagulation assays. The kit detects coagulation parameters based on coagulation methods, chromogenic substrate methods, or immunoturbidimetric assays. These coagulation parameters include prothrombin time, activated partial thromboplastin time, thrombin time, fibrinogen, fibrin(ogen) degradation products, D-dimer, antithrombin III, and anti-Xa. By adding sodium thiocyanate to the coagulation assay kit, this invention optimizes the clinical relevance of the assay kit by adjusting reaction time (coagulation method), improving the linear range (chromogenic substrate method), and enhancing the differentiation between low and high values ​​(immunoturbidimetric assay), thereby improving the accuracy of the test.

The application relates to a light emitting diode, in particular to a quantum dot light emitting diode, a preparation method and a light emitting device, which provides a prefabricated quantum dot solution, the prefabricated quantum dot solution comprises quantum dot main materials and long-chain ligands, the prefabricated quantum dot solution is mixed with an ethanol solution of sodium thiocyanate, and stirring is carried out at 70 DEG C-100 DEG C for 20 min-60 min, post-treatment is carried out, and a ligand quantum dot solution is formed; the ligand quantum dot solution is spin-coated on a hole transport layer, and first annealing treatment is carried out, so that a preliminary quantum dot layer is formed; an ethanol solution of zinc iodide is spin-coated on the preliminary quantum dot layer, is placed, is rinsed, and second annealing treatment is carried out, so that a quantum dot light emitting layer is formed; and an electron transport layer and a cathode are sequentially formed on the quantum dot light emitting layer. Through the method of liquid-solid ligand exchange and passivation of quantum dots, the light emitting efficiency and brightness of the device are effectively improved, and the stability of the device is improved.

The application discloses a kind of high-performance solid waste-based cementitious materials, each component and its weight percentage include: slag powder 40~60 parts, steel slag powder 15~30 parts, desulfurization gypsum 5~15 parts, cement clinker 5~15 parts, calcination aid 3~5 parts, chemical activator 1~3 parts;The calcination aid is obtained by sodium chloride, calcium chloride, sodium silicate compound;Chemical activator is obtained by sodium thio cyanate, sodium methylbenzenesulfonate, monoethanol diisopropanolamine, polyglycerol compound.The application realizes the resource utilization of steel slag, desulfurization gypsum, construction waste and other solid waste at the same time, can effectively take into account good early strength and later strength and other properties, effectively broaden the application range of solid waste-based cementitious materials, and is suitable for popularization and application.