2725 results about "Sodium phosphates" patented technology

The invention provides a sodium ferric pyrophosphate positive electrode material cooperatively doped with anions and cations, a preparation method of the sodium ferric pyrophosphate positive electrode material and a sodium ion battery, and relates to the field of sodium ion batteries. The anion and cation synergistically doped ferric sodium phosphate pyrophosphate positive electrode material comprises an inner core and a coating layer covering the outer surface of the inner core, the inner core comprises ferric sodium phosphate pyrophosphate, the coating layer comprises carbon, the chemical formula of the ferric sodium phosphate pyrophosphate is Na4-2yFe2.91-xQx (PO4) 2-yP2O7Fy, x is more than 0 and less than or equal to 0.3, and y is more than or equal to 0.03 and less than or equal to 0.08; q comprises at least one of Sn, Ni, Cu, Mg and Mn. The introduced Q positive ions and F negative ions can keep the crystal structure of the body material stable, and the positive ions and the negative ions have a synergistic effect, so that the band gap of the positive electrode material is reduced, the state density near the Fermi level of the positive electrode material is increased, the conductivity of the positive electrode material is enhanced, the specific capacity of the positive electrode material is improved, and the rate and the cycle performance are promoted.

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

The invention relates to the technical field of lithium dihydrogen phosphate, and discloses a method for preparing battery-grade lithium dihydrogen phosphate by using lithium precipitation mother liquor. The method comprises the following steps: (1) mixing a hydrochloric acid solution with a lithium precipitation mother solution until the pH value of the obtained reaction solution is 4-5; (2) heating the reaction solution, adding the sodium phosphate solution into the reaction solution to adjust the pH value to 9-10, and reacting to obtain crude lithium phosphate; (3) adding a phosphoric acid solution into the crude lithium phosphate until the pH value of the obtained mixed solution is 3-5.5; (4) carrying out first reduced pressure evaporation on the crude lithium dihydrogen phosphate solution, and carrying out solid-liquid separation on a first concentrate to obtain a first solid phase and a first mother solution; (5) dissolving the first solid phase in hot water, carrying out second reduced pressure evaporation, and carrying out solid-liquid separation on a second concentrate to obtain a second solid phase and a second mother solution; the solid content of the second concentrate is higher than that of the first concentrate. The lithium dihydrogen acid prepared by the method is high in purity, and the comprehensive yield of lithium is high.

The invention provides a preparation method for regenerating waste lithium iron phosphate into sodium ferric pyrophosphate, and belongs to the technical field of battery material production.The recovery process comprises the steps that a high-grade oxide serves as an oxidizing agent, a waste lithium iron phosphate positive electrode material and a current collector are stripped under the acid or strong alkaline condition, and lithium iron phosphate is oxidized; recovering to obtain iron phosphate containing impurities and a solution containing lithium ions; in the regeneration process, recycling slag obtained in the recycling process is uniformly mixed with a sodium source and a phosphorus source, sintering regeneration is performed to prepare ferric sodium pyrophosphate, conductive carbon in waste lithium iron phosphate is used as a reducing agent, and a high-performance ferric sodium pyrophosphate positive electrode material is obtained without an additional reducing agent; recycled slag obtained in the recycling process mainly comprises high-purity iron phosphate, and the content of impurities can be controlled to be 0.1% or below by controlling the solid-to-liquid ratio, the temperature and the reaction time in the recycling process.

The invention discloses a multifunctional water-retaining agent adapted to acid soil and a preparation method thereof, and the multifunctional water-retaining agent is prepared from the following raw materials in parts by weight: 9-11 parts of a chitosan solution with the concentration of 0.019-0.021 g / mL, 9-11 parts of a sodium polyphosphate solution with the mass concentration of 0.5-1%, 24-25 parts of an acrylic acid solution with the neutralization degree of 80-85%, 9-11 parts of a guar gum solution with the concentration of 0.019-0.021 g / mL and the balance of water. The mass of the methylene bisacrylamide accounts for 0.01-0.03% of the total dry matter mass of the chitosan, the guar gum and the acrylic acid, the mass of the ammonium persulfate accounts for 0.25-0.35% of the total dry matter mass of the chitosan, the guar gum and the acrylic acid, and the clay mineral accounts for 10-12 parts; the preparation method comprises the following steps: S1, pre-preparation; S2, mixing; and S3, post-treatment. The prepared water-retaining agent not only can greatly improve the water absorption and water retention performance of the chitosan water-retaining agent, but also can reduce the acidity of acid soil and improve the CEC and fertilizer retention capacity of the soil, and is a multifunctional acid red and yellow soil conditioner.

The present disclosure relates to the field of sodium-ion battery technology, and specifically, to a method for preparing carbon-coated sodium iron fluorophosphate from waste lithium iron phosphate and the application thereof. The method for preparing carbon-coated sodium iron fluorophosphate from waste lithium iron phosphate includes: mixing a waste lithium iron phosphate material with an alkaline solution for reaction, followed by solid-liquid separation, to obtain an aluminum-containing filtrate and a lithium iron phosphate filter residue; mixing the lithium iron phosphate filter residue, aluminum chloride and sodium chloride uniformly, followed by vacuum calcination, to obtain a calcination material; and mixing the calcination material with at least one of a sodium source, an iron source and a phosphorus source uniformly to obtain a mixture to which a fluorine source, a carbon source and a solvent are added for uniformly mixing, followed by drying and calcination sequentially to obtain the carbon-coated sodium iron fluorophosphate. The method has the advantages of low costs, a high added value, a short process, and a high recovery rate, and the carbon-coated sodium iron fluorophosphate obtained from the method has excellent electrochemical performance.

The invention provides a hemostatic composition, a preparation method thereof and a hemostatic product. The hemostatic composition is prepared from the following raw material components in parts by mass: 0.01 to 0.5 part of cannabidiol, 10 to 150 parts of tannic acid modified carboxymethyl chitosan and 5 to 250 parts of crosslinked starch. The tannic acid modified carboxymethyl chitosan is prepared from the following raw material components in parts by mass: 45 to 55 parts of carboxymethyl chitosan and 0.5 to 1.5 parts of tannic acid. The cross-linked starch is prepared from the following raw materials in parts by mass: 95 to 105 parts of carboxymethyl enzymolysis starch and 2 to 5 parts of sodium trimetaphosphate. The hemostatic composition has a good hemostatic effect, and when the hemostatic composition is used in hemostatic products, the hemostatic products can have a good hemostatic effect.

The invention belongs to the technical field of new energy materials, and particularly relates to a low-sulfur metal cation doped ammonium manganese ferric phosphate precursor, carbon-coated modified sodium manganese ferric pyrophosphate and a preparation method and application thereof. According to the invention, the low-sulfur metal cation doped ammonium manganese ferric phosphate precursor is successfully prepared. A proper amount of phosphoric acid source is added into the prepared metal cation doped ammonium manganese ferric phosphate precursor for treatment, so that the sulfur content of the precursor is remarkably reduced, and the molar ratio of manganese, iron, doped elements and phosphorus elements is regulated and controlled to be slightly smaller than 1. The atomic-scale distribution of elements in the precursor is realized, the tap density is also improved, and the subsequent preparation of a high-performance carbon-coated modified manganese ferric sodium phosphate pyrophosphate material is facilitated. The sodium ion battery constructed based on the material has excellent charge-discharge capacity, capacity retention ratio and cycling stability. In addition, the preparation method of the precursor is simple and convenient to operate and easy to control, and has the advantage of wide application.

The invention discloses a preparation method of an ester polycarboxylic acid water reducer, and belongs to the technical field of concrete admixtures. The preparation method of the ester polycarboxylic acid water reducing agent comprises the following steps: under an alkaline condition, carrying out free radical polymerization reaction on a polyether macromonomer and an unsaturated carboxylic acid monomer under the action of a chain transfer agent A, a chain transfer agent B and an initiator, continuously adding a catalyst, and carrying out dehydration esterification reaction under the action of the catalyst, so as to prepare the ester polycarboxylic acid water reducing agent, the polyether macromonomer is monohydroxy polyether of which the molecular weight is between 500 and 5000; the chain transfer agent A is one of acetone, isopropanol, sodium hydrogen sulfite, sodium hypophosphite, sodium formate and the like; the chain transfer agent B is one of mercaptoethanol, mercaptopropanol, mercaptoacetic acid, mercaptopropionic acid and the like; the catalyst is a phosphonic acid compound with hydroxyl or amino. The preparation method is simple in process and low in energy consumption, and the prepared ester polycarboxylic acid water reducer product is excellent in performance.

The invention discloses a vanadium-doped modified ferric sodium pyrophosphate material based on spray drying as well as a preparation method and application of the vanadium-doped modified ferric sodium pyrophosphate material. The material has a spherical porous morphology, and the particle size is 1-10 microns; the chemical formula is Na (4-x) Fe (3-x) Vx (PO4) 2P2O7, wherein x is more than 0 and less than or equal to 0.1. The material is prepared by adopting a spray drying method, and atomic-scale mixing of vanadium and iron is ensured through a uniform and stable complexing ion solution; and the formation of porous spherical morphology is promoted through the volatilization of the acidic base solution in the rapid drying process. A spray drying method and a trace vanadium doping technology are combined, so that more active sodium sites in the ferric sodium phosphate pyrophosphate positive electrode material can be activated, the reversible de-intercalation sodium capacity can be improved, sodium ion diffusion can be promoted, the polarization voltage can be reduced, and the cycling stability of the material can be improved.

The invention discloses a method for recovering lithium phosphate from lithium iron phosphate black powder. The method comprises the following steps: mixing black powder recovered from waste lithium iron phosphate batteries with sodium persulfate, and calcining; adding water into the obtained calcined product, dissolving, filtering to obtain water extract A and leaching residues, washing the leaching residues with water, and calcining at high temperature to obtain battery-grade iron phosphate; adding a sodium hydroxide solution into the water extract A, and reacting to obtain a water extract B; adding a trisodium phosphate solution into the water immersion liquid B, fully reacting, performing suction filtration to obtain lithium phosphate and filtrate, and cleaning and drying the lithium phosphate to obtain battery-grade lithium phosphate; and freezing and denitrifying the filtrate to obtain a denitrified solution, and adding the denitrified solution into the sodium hydroxide solution for recycling. The method does not generate wastes, recycles the filtrate in the whole process, theoretically realizes zero loss of the lithium element, prevents the iron element from entering the solution, simplifies the preparation steps of the lithium phosphate, and has the advantages of cost reduction and environmental protection.

The invention provides a sodium ferric phosphate pyrophosphate positive electrode material and a preparation method thereof, and a sodium ion battery, the molecular formula of the sodium ferric phosphate pyrophosphate positive electrode material is Na4Fe3 (PO4) 2P2O7 / D1D2, D1 is a first conductive agent, the first conductive agent is a metal oxide, the second conductive agent is phosphate, D2 is a second conductive agent, and D1D2 is a metal oxide. And the molar ratio of the sodium element to the iron element to the phosphorus element to the first conductive agent to the second conductive agent in the ferric sodium phosphate pyrophosphate positive electrode material is (4.0 to 4.1) to (2.8 to 3.0) to (3.0 to 3.1) to (0.001 to 0.0.005) to (0.05 to 0.10). According to the embodiment of the invention, the first conductive agent increases the lattice volume, so that conduction channels of Na < + > and doped ions are increased, and higher electronic conductivity is achieved; and the phosphate of the second conductive agent forms coating points on the surface layers of the sodium iron phosphate particles, so that the interfacial effect in the electrochemical reaction process of the sodium iron phosphate pyrophosphate positive electrode material is slowed down, the electrochemical performance of the sodium iron phosphate pyrophosphate positive electrode material is further improved, and the electrochemical specific capacity is improved.

The invention relates to the field of metal surface treatment, and discloses an efficient electroplating process for a cotton picker spindle and an electroplating liquid formula, the efficient electroplating process comprises the following steps: step 1, substrate pretreatment: sequentially carrying out alkali washing, acid washing and plasma activation on the spindle; step 2, preparing an electroplating solution: dissolving nickel sulfate, sodium hypophosphite, a composite nano additive and a complexing agent in water, and adjusting the pH value to 4.8-5.3; step 3, gradient pulse electroplating: carrying out pulse electroplating in three stages, including bottom layer deposition, transition layer deposition and composite layer deposition; 4, post-treatment is conducted, specifically, silane sealing and curing are conducted on the plating layer; the base body pretreatment in the first step comprises the following sub-steps of alkali washing and oil removal, wherein the picking ingot is soaked in a NaOH solution with the concentration being 45-55 g / L. According to the method, high-density hydroxyl active sites are constructed on the surface of the metal base material through a plasma activation process, strong chemical bonding is formed between a plating layer and the base material, and the interface bonding strength is remarkably improved.

The invention discloses a hydrogel compound, a preparation method and application, and belongs to the technical field of hydrogel. The hydrogel compound provided by the invention is prepared from the following raw materials: a hydrogel matrix, sodium glycerophosphate pentahydrate and a functional drug, the hydrogel matrix is prepared from chitosan, hydroxybutyl chitosan and methacrylated gelatin; the functional medicines comprise cannabidiol, tobramycin and acetylsalicylic acid; the hydrogel compound provided by the invention has excellent mechanical properties and water vapor permeability, also has excellent slow release property and wound healing ability, and can be widely applied to preparation of medicines for treating wounds. In addition, the preparation method of the hydrogel compound provided by the invention is simple to operate and beneficial to practical application.

The invention relates to a copper plating electroplating solution as well as a preparation method and application thereof. The copper plating electroplating solution comprises the following components: copper pyrophosphate, a complexing agent, ammonia water, a bath building agent, a gloss agent, a pH regulator and water, the complexing agent is selected from potassium pyrophosphate or sodium pyrophosphate; the mass percentage concentration of the ammonia water is 20%-30%, and the volume concentration of the ammonia water in the copper plating electroplating solution is 2-10 mL / L; the mass concentration of the gloss agent in the copper plating electroplating solution is 10 to 50 mg / L; and the pH value of the copper plating electroplating solution is 7.8-10. When the copper plating solution is used for silver grid line copper plating, on the premise that the cost is reduced, the silver grid line copper plating has a good plating effect, the silver grid line is firm and does not fall off, and good conductive performance is kept.

The invention provides a modified ferric sodium phosphate pyrophosphate positive electrode material and a preparation method and application thereof, the modified ferric sodium phosphate pyrophosphate positive electrode material comprises a ferric sodium phosphate pyrophosphate positive electrode material and a carbon and sodium ion conductor, the carbon and sodium ion conductor is enriched on the surface and grain boundary of the ferric sodium phosphate pyrophosphate positive electrode material in a uniform composite phase, and the sodium ion conductor is NaxMOy. A composite phase material formed by carbon and a sodium ion conductor is used for coating primary particles and secondary particles of the positive electrode material, a three-dimensional conductive / conductive ion network is formed on the grain boundary and the surface of the material, and the charge and ion transmission rate of the material is high; and the three-dimensional coating layer can protect the material from being eroded by electrolyte, the structure stability is good, and the cycle performance and the rate performance of the material are excellent.

The invention belongs to the field of modified self-repairing calcium aluminate cement 3D printing, and particularly relates to a phosphate modified self-repairing calcium aluminate cement 3D printing material and a preparation method thereof. The phosphate modified self-repairing calcium aluminate cement 3D printing material prepared by the invention is prepared from the following raw materials in parts by mass: 60 to 70 parts of calcium aluminate cement, 3 to 7 parts of silica fume, 2 to 4 parts of metakaolin, 0.5 to 3.5 parts of double-template modified calcium bentonite, 0.8 to 1.5 parts of amino modified sodium polyphosphate and 0.15 to 0.8 part of basalt fiber. The invention relates to a concrete anti-microbial agent, which is prepared from the following raw materials in parts by weight: 20-30 parts of water, 20-30 parts of water, 20-30 parts of water, 20-30 parts of nano calcium carbonate, 20-30 parts of nano calcium carbonate, 20-30 parts of magnesium phosphate cement coated bacteria-loaded porous microspheres, 20-30 parts of a polycarboxylate superplasticizer, 20-30 parts of an organic silicon defoaming agent and 25-35 parts of mixing water. The technical-economic cooperation requirement of building 3D printing under complex working conditions is met, and various indexes of phosphate modified calcium aluminate cement applied to the 3D printing technology are met.

The invention discloses an SBS modifier and a preparation method and application thereof, an asphalt coating material composition and a preparation method thereof, and a waterproof coiled material. The preparation method of the SBS modifier comprises the following steps: dissolving SBS in a first solvent to obtain an SBS solution; the method comprises the following steps: adding a sulfydryl compound into an SBS solution, and carrying out solution graft polymerization at 50-90 DEG C to obtain graft modified SBS which is grafted with alkyl containing any one of hydroxyl and carboxyl through sulfydryl, or grafted with sulfydryl and grafted with hydroxyl substituted or unsubstituted alkyl through sulfydryl; adding the biomass carbon aerogel and the graft modified SBS into a second solvent according to a mass ratio of 1: (0.5-1.5) to obtain a first mixed solution; adding concentrated sulfuric acid and sodium hypophosphite into the first mixed solution, and reacting at the temperature of 120-130 DEG C to obtain the SBS modifier. According to the preparation method of the SBS modifier, the polarity of the SBS is changed through sulfydryl grafting of the SBS, namely the polarity of the SBS is closer to that of asphalt; and the grafted modified SBS reacts with the biomass carbon aerogel to form a macromolecular compound, so that the performance degradation in the aging process of the coiled material is prevented.

The invention discloses a composite positive electrode material, a positive plate and a secondary battery, the composite positive electrode material comprises a composite sodium ferric sulfate material and a carbon-coated ferric sodium pyrophosphate material, the composite sodium ferric sulfate material comprises a first carbon material and sodium ferric sulfate, and the first carbon material and the sodium ferric sulfate are blended; the carbon-coated ferric sodium phosphate pyrophosphate material comprises a second carbon material and ferric sodium phosphate pyrophosphate, and the second carbon material coats the ferric sodium phosphate pyrophosphate; the composite sodium ferric sulfate material is coated with the carbon-coated sodium ferric pyrophosphate material. The composite sodium ferric sulfate material is coated with the carbon-coated sodium ferric pyrophosphate material, so that the high-temperature resistance of the composite positive electrode material can be improved; through the coating effect of the whole carbon-coated ferric pyrophosphate material on the composite sodium ferric sulfate material, the second carbon material can be coated on the composite sodium ferric sulfate material, equivalently, a carbon coating layer is formed on the surface of sodium ferric sulfate, the coating property is good, sodium ion removal is facilitated, and the service life of the composite sodium ferric sulfate material is prolonged. Further, the gram volume and the energy density of the composite positive electrode material are improved.

A positive electrode material, and a preparation method therefor and the use thereof. The positive electrode material has a core-shell structure, wherein a core part comprises a carbon-coated Cu2+-doped iron-based phosphate sodium-ion material, and a shell layer is CuO. The iron-based phosphate sodium-ion material is selected from ferric sodium pyrophosphate, ferric sodium phosphate or ferric sodium phosphate pyrophosphate. The preparation method for the positive electrode material comprises: mixing the carbon-coated iron-based phosphate sodium-ion material, a copper source and a first solvent, and then subjecting the mixture to first drying and first calcination.

The invention discloses a multiphase ferric sodium pyrophosphate positive electrode material as well as a preparation method and application thereof, and belongs to the technical field of positive electrode materials. The complex-phase phosphoric acid and sodium ferric pyrophosphate positive electrode material has the following chemical formula: xNa4Fe3 (PO4) 2 (P2O7). (1-x) Na3. 12Fe2. 44 (P2O7) 2 / C, C is a carbon coating layer, and the content of the C is 8-10 wt% of the total mass of the composite-phase phosphoric acid and sodium ferric pyrophosphate positive electrode material; xNa4Fe3 (PO4) 2 (P2O7). (1-x) Na3.12Fe2.44 (P2O7) 2 is a core layer, and x is greater than or equal to 0.76 and less than or equal to 0.88. Under the condition that transition metal elements are not added for doping, the electrochemical performance of the complex-phase ferric sodium phosphate pyrophosphate positive electrode material can be obviously improved by regulating and controlling the ratio of positive ions to negative ions of original components of ferric sodium phosphate pyrophosphate, and the complex-phase ferric sodium phosphate pyrophosphate positive electrode material is low in cost, simple to prepare and suitable for large-scale production and application.

The invention discloses a marine low-temperature concrete additive and a preparation method thereof, and belongs to the technical field of concrete admixtures. The marine low-temperature concrete additive is prepared from the following raw materials: silane / polymer hybrid modified silicon dioxide, anti-freezing fibers, an air entraining and water reducing agent, silica fume, sodium hexametaphosphate and calcium chloride. Through scientific proportioning of silane / polymer hybrid modified silicon dioxide, compound anti-freezing fibers and other components, on one hand, cement matrix interface bonding is enhanced, the integrity of the internal structure of concrete is improved, microcrack initiation in the freezing and thawing cycle process is reduced, and the surface hydrophilicity of the hybrid modified silicon dioxide is enhanced; according to the present invention, by adding the cross-linked polymer, the dispersibility can be improved, the pore structure of the concrete can be optimized, the macroporosity can be reduced so as to reduce the freeze-thaw damage risk and improve the freeze-thaw erosion resistance of the concrete, and the cross-linked network structure is formed in the cement matrix so as to improve the strength and the toughness of the concrete and enhance the freeze-thaw resistance.

The invention relates to the technical field of metal material surface treatment, in particular to an antifouling and anti-drag coating for titanium alloy pipeline binding force and a preparation method and application of the antifouling and anti-drag coating. The preparation method comprises the following steps: carrying out micro-arc oxidation treatment on a titanium alloy to form a ceramic film on the surface of the titanium alloy; the titanium alloy subjected to micro-arc oxidation treatment is subjected to a hydrothermal reaction, and a nanoscale porous thorn microstructure and hydroxyl are introduced to the surface of a ceramic membrane; coating the pre-polymerization liquid on the titanium alloy subjected to hydrothermal treatment, and performing irradiation reaction under ultraviolet light to obtain first network gel; the first network gel is soaked in a beta-sodium glycerophosphate solution, and the ion-covalent double network p (SBMA-co-AAc) / CS-beta-GP DN hydrogel is formed. The stability and durability of the coating prepared by the preparation method provided by the invention are improved, and the coating has long-term stable anti-fouling performance, is strongly combined with a titanium alloy substrate, and has excellent anti-fouling effect and anti-drag effect when being applied to the titanium alloy substrate.

The invention provides a metal particle loaded self-supporting electrode material and a preparation method and application thereof, and belongs to the technical field of battery electrodes, the preparation method comprises the following steps: S1, cutting beech into pieces with the thickness of 5-7mm along the vertical growth direction, and calcining to obtain carbonized wood pieces; s2, metal salt is dissolved in the functionalized aqueous solution, the concentration of the metal salt is 0.03-0.05 M, and a soaking solution is obtained; the functionalized aqueous solution comprises dodecyl trimethyl ammonium chloride, sodium pyrophosphate, polyvinylpyrrolidone and water; s3, taking the carbonized wood chip as a working electrode, immersing the carbonized wood chip into the soaking solution, carrying out electro-deposition on a metal precursor, and then cleaning and drying to obtain a metal-loaded wood chip; and S4, pyrolyzing the metal-loaded wood chip in a hydrogen-argon mixed atmosphere, then cooling to room temperature, cleaning and drying to obtain the metal-loaded wood chip. According to the invention, the transition metal particles and the carbonized wood chips are better compounded, and more reliable active sites are provided for bromine electrochemical reaction, so that the overall performance of the zinc-bromine battery is improved.

The invention discloses a preparation method of an in-situ synergistic modified sodium manganese vanadium phosphate electrode material, which comprises the following steps: taking a phosphorus source, a manganese source, a vanadium source, a sodium source and a carbon source as raw materials to obtain a precursor, and adding a modified material to obtain a composite precursor; and calcining in an inert atmosphere to obtain the in-situ synergistically modified manganese vanadium sodium phosphate. The preparation method has the advantages that the precursor is synthesized by a simple solid-phase method, in-situ synergistic modification is performed by a wet chemical method, a fluoride coating layer is constructed on the surface of the sodium manganese vanadium phosphate material, a cation doping effect is achieved, the structural stability of the sodium manganese vanadium phosphate material is enhanced, and the diffusion rate of sodium ions is increased. An electrochemical test result of a battery assembled by the material subjected to in-situ synergistic modification shows that the material has higher capacity retention ratio and long cycle performance, and the electrochemical performance of the sodium manganese vanadium phosphate electrode material is effectively improved.

The invention relates to a preparation method of a nickel ion doped modified ferric sodium pyrophosphate positive electrode material, and belongs to the technical field of sodium ion battery positive electrode materials. The nickel ion doped modified ferric sodium pyrophosphate positive electrode material is prepared by adopting an integrated process system of liquid phase uniform mixing, spray granulation and precise segmented calcination. According to the process system, atomic-scale uniform doping of nickel ions and a specific microstructure of a precursor are realized through spray drying, and a plurality of inherent key technical problems of low electronic conductivity, low ion diffusion rate, impurity phase generation and the like of an NFPP material are solved together through a synergistic effect with a subsequent calcining process; furthermore, the discharge capacity of the ferric sodium phosphate pyrophosphate composite material at high rate is improved, so that the battery has relatively high cycling stability.

The invention belongs to the technical field of pollutant detection, and relates to an iron-based nano enzyme and application thereof in quinolone antibiotic detection. The preparation method comprises the following steps: adding ferric trichloride hexahydrate and cerium nitrate hexahydrate into water, uniformly mixing to obtain a mixed solution A, uniformly mixing the mixed solution A with an organic polyacid ligand solution, and then carrying out a reflux reaction to prepare a Ce / Fe-MOF precursor; and adding the Ce / Fe-MOF precursor and sodium hypophosphite into a tubular furnace, and calcining in a nitrogen atmosphere to prepare Ce / Fe-P. According to the present invention, the synthesized material has the nanometer prism mesoporous structure, the contact area with the substrate is effectively increased, the visual detection of the NOR can be achieved based on the principles of low-concentration NOR activity improving and high-concentration Ce / Fe-P activity inhibition, and the high sensitivity, the low detection limit, the wide linear response range and the good selectivity and the good stability are provided.

The invention provides a breast milk source exosome as well as a preparation method and application thereof. The preparation method of the breast milk source exosome comprises the following steps: pre-treating breast milk, and then carrying out primary purification concentration and fine purification on the breast milk source exosome after the pre-treatment; wherein the pretreatment comprises the step of mixing degreased breast milk with a sodium phosphate solution; the primary purification concentration comprises tangential flow ultrafiltration treatment; the fine purification comprises purification treatment by adopting a multi-mode chromatography. The invention provides a large-scale purification process of the breast milk exosome, which can be used for treating a large number of samples, improving the purity and yield of the breast milk exosome and ensuring the morphological integrity of the breast milk exosome.

The invention provides a low-temperature electrolyte, positive electrode slurry and a low-temperature sodium ion battery, and belongs to the technical field of battery materials. The low-temperature electrolyte provided by the invention comprises sodium hexafluorophosphate, propylene carbonate, ethylene carbonate, dimethyl carbonate, methyl ethyl carbonate, fluoroethylene carbonate, 2, 2, 3, 4, 4, 4-hexafluorobutyl acrylate and 1, 1, 2, 2-tetrafluoroethyl-2, 2, 3, 3-tetrafluoropropyl ether. The battery provided by the invention comprises the low-temperature electrolyte. The low-temperature electrolyte and the low-temperature sodium-ion battery provided by the invention not only can be compatible with a blended positive electrode material, but also can give consideration to low-temperature performance, ensure that the prepared low-temperature sodium-ion battery has good reaction kinetics and cycle performance, and also can improve the energy density of an electrode and reduce the resistivity of powder.