The invention discloses inorganic artificial combining stone and a preparation method thereof. The artificial combining stone uses silicon acid-base solution to arouse metakaolin to react and generate geopolymer to serve as an inorganic cementing agent, and the artificial combining stone mainly contains the metakaolin, the silicon acid-base solution, natural stone aggregate, decoration aggregate, a thickening time control agent, inorganic pigment and fibers. The preparation method is firstly enabling the thickening time control agent and the inorganic pigment to be dissolved in the silicon acid-base solution to obtain mixed serous fluid, evenly blending the metakaolin, the natural stone aggregate, the decoration aggregate, the fibers and the mixed serous fluid, preparing the artificial combining stone through model entering or material distribution, vibration under the vacuum condition, molding in a pressing mode, maintaining, cutting, polishing, burnishing and surface protection. The artificial combining stone not only has decoration features which can be equal to that of resin artificial stone, but also is non-toxic, environment-friendly, low in cost, resisting in corrosion of most majority of acid-base salts, durable in high temperature and excellent in durable performance, obviously avoids whiting and saltpetering phenomena after a long time use, and is strong in pollution resisting capability.