700 results about "Metakaolin" patented technology

The invention belongs to the technical field of building materials, and discloses a high-activity composite auxiliary cementing material based on carbonated steel slag-carbide slag as well as a preparation method and application of the high-activity composite auxiliary cementing material. The high-activity composite auxiliary cementing material is prepared from the following raw materials in parts by mass: 40 to 55 parts of carbonated steel slag-carbide slag composite micro powder, 30 to 40 parts of high titanium slag, 20 to 25 parts of metakaolin, 3 to 5 parts of ardealite, 3 to 5 parts of calcium carbonate, 3 to 5 parts of calcium carbonate and 3 to 5 parts of calcium carbonate. Wherein the carbonated steel slag-carbide slag composite micro powder is obtained by carrying out carbon sequestration reaction on steel slag and carbide slag in a solution consisting of a carbonization enhancer, an additive and water. On one hand, the CO2 storage amount of the steel slag and the carbide slag is increased, the stability and the activity are improved, on the other hand, the carbonized steel slag-carbide slag and other industrial solid waste are cooperated to achieve a composite superimposed effect, the cement mortar or the concrete can be improved in strength, stability and durability, the comprehensive performance is good, and the cost is low. And the method is green, low-carbon, energy-saving, environment-friendly and wide in popularization and application

The invention discloses a sulfur-manganese composite autotrophic denitrification filler as well as a preparation method and application thereof, and belongs to the technical field of environmental functional materials and polluted water treatment. The sulfur-manganese composite autotrophic denitrification filler contains manganese salt, a sulfur-based component and a cement-based component, the manganese salt comprises one or more of manganese carbonate, calcium manganese ore and rhodochrosite; the sulfur-based component comprises sulfur and sulfur manganese ore; the cement-based component comprises cement, fly ash pottery sand, silica fume, blast furnace slag and metakaolin; the cement comprises one or more of Portland cement, iron aluminate cement and sulphoaluminate cement. The nitrogen removal efficiency of the sulfur-manganese composite autotrophic denitrification filler is superior to that of a sulfur autotrophic denitrification system, the sulfate concentration and nitrite nitrogen accumulation in effluent are remarkably reduced, the service life of the filler is prolonged, and the efficient utilization rate of the material is improved.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The invention provides an ultrahigh-ductility cement-based composite material for ocean engineering and a preparation method of the ultrahigh-ductility cement-based composite material for ocean engineering. The concrete is prepared from the following raw materials in parts by weight: 250 to 500 parts of cement clinker, 400 to 600 parts of fly ash, 200 to 300 parts of mineral powder, 100 to 150 parts of silica fume, 160 to 240 parts of metakaolin, 600 to 900 parts of quartz sand, 10 to 20 parts of organic synthetic fiber, 20 to 30 parts of organic corrosion inhibitor, 180 to 240 parts of water and 1 to 8 parts of water reducing agent. The organic corrosion inhibitor provided by the invention can be combined with chloride ions to form a passive film, so that the corrosion of reinforcing steel bars and the invasion of the chloride ions into concrete are inhibited, and the durability of the concrete is improved; by regulating and controlling the mixing ratio of the four mineral admixtures and the mixing amount of the synthetic fiber component, the concrete can well consider high strength, high ductility, high durability, high flow state and excellent deformation resistance. The ultrahigh-ductility concrete for ocean engineering, which can meet the toughness requirements of high compression resistance, fracture resistance and impact resistance and the requirements of high chloride ion permeation resistance and steel bar corrosion resistance, can be obtained.

The invention belongs to the technical field of new building materials, and provides a low-alkalinity and early-strength ardealite filling and curing material and a preparation method thereof.The low-alkalinity and early-strength ardealite filling and curing material is prepared from ardealite, a curing agent and water, the curing agent comprises silica fume, limestone powder, superfine granulated blast furnace slag powder, metakaolin, calcium aluminate powder, Portland cement clinker powder, a suspension stabilizer and hydroxypropyl methyl cellulose ether. The problems of delayed coagulation, low early strength and high alkalinity of a common cement-based ardealite filling material can be solved, and the technical requirements of ardealite cemented filling are met.

The invention belongs to the field of modified self-repairing calcium aluminate cement 3D printing, and particularly relates to a phosphate modified self-repairing calcium aluminate cement 3D printing material and a preparation method thereof. The phosphate modified self-repairing calcium aluminate cement 3D printing material prepared by the invention is prepared from the following raw materials in parts by mass: 60 to 70 parts of calcium aluminate cement, 3 to 7 parts of silica fume, 2 to 4 parts of metakaolin, 0.5 to 3.5 parts of double-template modified calcium bentonite, 0.8 to 1.5 parts of amino modified sodium polyphosphate and 0.15 to 0.8 part of basalt fiber. The invention relates to a concrete anti-microbial agent, which is prepared from the following raw materials in parts by weight: 20-30 parts of water, 20-30 parts of water, 20-30 parts of water, 20-30 parts of nano calcium carbonate, 20-30 parts of nano calcium carbonate, 20-30 parts of magnesium phosphate cement coated bacteria-loaded porous microspheres, 20-30 parts of a polycarboxylate superplasticizer, 20-30 parts of an organic silicon defoaming agent and 25-35 parts of mixing water. The technical-economic cooperation requirement of building 3D printing under complex working conditions is met, and various indexes of phosphate modified calcium aluminate cement applied to the 3D printing technology are met.

The invention discloses high-strength concrete and a preparation method thereof in the field of concrete. The high-strength concrete is prepared from the following raw materials in parts by weight: superfine sulphoaluminate cement; coarse aggregate; quartz sand; silica fume; coal ash; nano metakaolin; silicon carbide whiskers; a graphene oxide; a pH responsive microcapsule; coating the steel fibers with liquid metal; a carbon nanotube; and a polycarboxylic acid water reducer. Release of the repairing agent is accurately regulated and controlled by adopting the pH response microcapsule, the interface performance is enhanced by combining with the liquid metal coating steel fiber, and the composite dispersion process of the nano material is optimized. Wherein the environment response efficiency of the microcapsule is remarkably improved through the collaborative design of a calcium oxide-slow release agent system and a methyl methacrylate / acrylic acid copolymerization shell layer; according to the gallium-based liquid metal coating, metallurgical bonding of fibers and a matrix is achieved through the low-melting-point characteristic, and traditional physical bonding limitation is broken through.

The invention relates to hybrid fiber reinforced ultrahigh-performance geopolymer concrete as well as a preparation method and application thereof. Slag, metakaolin and silica fume are used as precursor materials of geopolymer concrete, a sodium hydroxide-water glass solution is adopted to compound an alkali activator, and steel fibers, polyvinyl alcohol fibers and modified glass chopped fibers of different sizes are mixed and doped, so that the brittleness of the geopolymer concrete is remarkably improved, and the service life of the geopolymer concrete is prolonged. The early strength and the high temperature resistance are improved. The hybrid fiber reinforced ultrahigh-performance geopolymer concrete has the characteristics of low carbon emission, ultrahigh strength, high temperature resistance, high durability and the like, and can meet the use of the geopolymer concrete in actual engineering. According to the ultrahigh-performance geopolymer concrete, solid waste resources are utilized at the same time, carbon emission in the concrete production process is reduced, and the ultrahigh-performance geopolymer concrete is environmentally friendly, low in carbon, ultrahigh in strength, easy to prepare and capable of being suitable for complex environmental engineering structures such as tunnels, bridges and high-rise buildings.

The invention discloses high-performance fluid-state solidified soil for backfill based on composite ardealite of building residue soil, which is prepared by taking the building residue soil as a core raw material, taking a compound of a polycarboxylic acid water reducer and hydroxypropyl methyl cellulose as a fluidization regulator, and mixing the fluidization regulator and the building residue soil to prepare the high-performance fluid-state solidified soil for backfill. Superfine slag powder, fly ash, nano silicon dioxide, metakaolin and ardealite are used as curing agents, so that the fluid-state solidified soil with strong performance is obtained. Through the synergistic effect of all the components and innovative processes such as liquid nitrogen low-temperature grinding, nano material compounding and a segmented vacuum stirring process, the effect that the ultrahigh strength of the construction waste soil reaches 7.5 MPa within 14 days is achieved for the first time and is improved by 40% or above compared with that of conventional solidified soil, and the industrial problem that traditional waste soil is insufficient in solidification strength is solved; and collaborative optimization of strength and fluidity is realized. Meanwhile, efficient resource utilization of the construction waste is achieved, land occupation and environmental pollution caused by muck landfill are greatly reduced, and the requirement for green and sustainable development is met.

The invention belongs to the field of coal solid waste resource utilization, and relates to a method for preparing a NaP type molecular sieve by utilizing kaolinite rock type coal gangue. The method comprises the following steps: 1) crushing and grinding blocky kaolinite rock type coal gangue into powder; 2) roasting and activating the coal gangue powder to obtain metakaolin; 3) mixing and stirring metakaolin, sodium hydroxide, a silicon source and deionized water to obtain an initial solution; 4) standing and aging the initial solution to obtain a precursor solution; 5) performing dynamic hydrothermal crystallization treatment on the precursor solution to obtain crystals; and 6) washing, neutralizing, centrifuging and drying the crystal to obtain the NaP type molecular sieve. The kaolinite rock type coal gangue is used as a raw material to replace a traditional chemical raw material required by molecular sieve synthesis, and resource utilization of aluminosilicate solid waste is promoted. According to the method, seed crystals or guiding agents are not required to be added in the molecular sieve crystallization process, and special crystallization methods such as microwaves and ultrasound are also not required, so that the process is simple, the cost is low, and the method is environment-friendly.

The invention relates to the technical field of cement-based anticorrosive materials, and particularly discloses a modified magnesium phosphate cement anticorrosive material as well as a use method and application thereof. The anticorrosive material comprises the following components in parts by weight: 100 parts of modified magnesium phosphate cement, 3-15 parts of a retarder, 1-10 parts of an epoxy resin glue solution, 0.5-5 parts of metakaolin and 15-20 parts of water. The modified magnesium phosphate cement comprises dead burned magnesium oxide and modified phosphate in a mass ratio of (1-4): 1. The modified phosphate is prepared from the following raw materials: nano aluminum oxide, sodium citrate and phosphate in a mass ratio of (0.5-1.5): (0.5-1.5): (20-25). The epoxy resin glue solution comprises uncured epoxy resin glue and a curing agent. The anti-corrosion material provided by the invention has the technical advantages of strong adhesive property and excellent anti-corrosion property, and can better provide protection for a steel structure serving in a marine environment.

The invention discloses a rapid concrete repairing material based on microbial mineralization as well as a preparation method and application of the rapid concrete repairing material. According to the method, hydrophobic modified porous particles are used as a carrier, microbial bacteria, nutrient substances and a calcium source with mineralization behaviors are soaked into pores of the porous particles through vacuum impregnation, the pores of the particles are properly sealed by adopting waterborne epoxy, and then the particles are packaged by using metakaolin and sodium silicate, so that the porous particles are obtained. And finally, compounding with fiber composite mortar to prepare the concrete rapid repairing material. The rapid concrete repairing material has the advantages of strong interface adhesion, environment friendliness, light weight, excellent surface compactness improvement effect, crack self-repairing and the like, and can be used for coating and repairing the defect surface of concrete.

The invention belongs to the technical field of solid waste resource utilization, and discloses an activity-enhanced solid waste-based sludge curing agent as well as a preparation method and application thereof. The sludge curing agent comprises the following raw materials in percentage by mass: 30-40% of cement, 15-25% of S95 mineral powder, 15-23% of steel slag powder, 16-26% of an activity enhancing component and 0.5-3% of a composite exciting agent, wherein the activity enhancing component is prepared from the following raw materials in percentage by mass: 35 to 40 percent of desulfurized gypsum, 35 to 40 percent of carbide slag and 20 to 30 percent of biomass ash; the composite exciting agent comprises the following raw materials in percentage by mass: 30-35% of metakaolin, 30-35% of sodium sulfate, 15-20% of sodium silicate and 15-20% of sulfonated oil. According to the sludge curing agent, the industrial solid waste accounts for 57% or above, the desulfurized gypsum, the carbide slag and the biomass ash form an activity enhancing component, the activity enhancing component is matched with the composite exciting agent to jointly enhance and excite the activity of the metallurgical slag solid waste, and therefore the excellent curing effect is achieved, and when the sludge curing agent is used for sludge curing, the 3d unconfined compressive strength of a sludge curing body is larger than or equal to 0.5 MPa; and the 28d unconfined compressive strength is greater than or equal to 1.4 MPa.

The invention relates to the technical field of building materials, and particularly discloses a slag and ardealite synergetic activated gypsum batten and a preparation method thereof.The slag and ardealite synergetic activated gypsum batten comprises pretreated ardealite, superfine slag powder, a composite exciting agent, reinforced fibers, self-repairing microcapsules, a foaming agent and water, and the composite exciting agent is formed by compounding nano SiO2, CaO and metakaolin; the preparation method comprises the following steps: mixing nano silica sol and a lignin solution, performing spray drying, and performing heat treatment to obtain the self-repairing microcapsule; the preparation method comprises the following steps: carrying out dry mixing on pretreated phosphogypsum, superfine slag powder and a composite exciting agent, adding water, adding reinforced fibers, self-repairing microcapsules and a foaming agent, stirring to form slurry, carrying out injection molding on the slurry, and carrying out stepped maintenance of pre-maintenance, main maintenance and carbonization treatment to prepare the modified red mud-pretreated phosphogypsum-based self-repairing self-repairing composite phosphogypsum-based self-repairing self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum. The composite excitant synergistically activates the activity of the slag, and is matched with the reinforced fibers, the self-repairing microcapsules and stepped curing, so that solid waste resource utilization is realized, the compression resistance, bending resistance and impact resistance of the batten are improved, and the environment-friendly and high-performance effects are achieved.

The invention relates to the technical field of concrete waterproofing agents, in particular to a high-efficiency concrete anti-crack waterproofing agent and a preparation method thereof, and the high-efficiency concrete anti-crack waterproofing agent is prepared from the following raw materials in parts by weight: a calcium sulphoaluminate expanding agent; light burning of magnesium oxide; re-burning the magnesium oxide; nano-scale silicon dioxide; metakaolin; polypropylene fibers; basalt fibers; styrene-acrylic emulsion; a silane emulsion; silica fume; hydroxypropyl methyl cellulose; and a polycarboxylic acid water reducer compatilizer. According to the high-efficiency concrete anti-crack waterproof agent disclosed by the invention, the nano-silica, the metakaolin and the styrene-acrylic emulsion synergistically block nano-to-macroscopic multi-stage pores, so that double waterproofing of physical filling and chemical film forming is realized; the polypropylene and the basalt fiber are subjected to ultrasonic dispersion and interface combination optimization to form a three-dimensional anti-crack network, the component uniformity and the functional stability are ensured through precise proportioning, graded mixing and directional granulation, meanwhile, the waterproof agent is compatible with industrial production fluctuation, large-scale application reliability is ensured, and the problems that a traditional waterproof agent is single in function and insufficient in durability are solved.

The invention discloses multi-scale toughened full-solid-waste ultrahigh-ductility concrete, which is prepared from the following raw materials in parts by weight: 500 to 650 parts of full-solid-waste cementing materials, 110 to 150 parts of calcined coal gasification slag, 190 to 250 parts of calcined fly ash, 20 to 40 parts of silica fume, 10 to 30 parts of metakaolin, 780 to 930 parts of washed sand, 10 to 25 parts of fly ash fibers, 0.6 to 0.9 part of hydroxypropyl methyl cellulose, 20 to 30 parts of polycarboxylic acid water reducing agents and 300 to 400 parts of water. The calcined coal gasification slag is subjected to gradient heating to 800-960 DEG C, heat preservation is conducted for 30-60 min, then the calcined coal gasification slag is cooled to the room temperature at the cooling rate of 10-15 DEG C / min, and the calcined coal gasification slag is obtained after powder grinding. According to the multi-scale toughened full-solid-waste ultrahigh-ductility concrete provided by the invention, the toughness and the mechanical property of the concrete can be enhanced, the performance of the concrete in an extreme environment is improved, meanwhile, the solid waste utilization rate is increased, and the production cost of the concrete is reduced.

The invention relates to the technical field of mortar, in particular to cement self-leveling anti-crack and anti-seepage mortar and a preparation method thereof. The cement self-leveling anti-cracking and anti-seepage mortar is prepared from the following raw materials in parts by mass: 50 to 70 parts of Portland cement, 70 to 90 parts of quartz sand, 5 to 10 parts of nano metakaolin, 1 to 3 parts of calcium sulfate, 5 to 10 parts of polyethylene fiber, 1 to 2 parts of nonionic surfactant, 1 to 2 parts of silane coupling agent, 3 to 8 parts of composite basalt fiber, 0.5 to 1.5 parts of polycarboxylate superplasticizer and 1 to 3 parts of defoaming agent. 1-3 parts of hydroxypropyl methyl cellulose, 1-2 parts of a retarder and 0.5-1.5 parts of a coagulant. The mortar material has good anti-cracking performance and anti-seepage performance and excellent durability, can effectively solve the problem that the anti-cracking performance and the anti-seepage performance of the mortar material in the prior art cannot meet the environmental requirements, and is suitable for large-scale popularization and application.

The invention discloses a coal gangue-based reinforced cement composite material and a preparation method thereof, and relates to the technical field of building materials. The coal gangue-based reinforced cement composite material is prepared from a coal gangue-based reinforced admixture, calcium ion doped modified multi-walled carbon nanotubes, polypropylene fibers, P.O42.5 Portland cement, metakaolin, silica fume, a polycarboxylate superplasticizer and water, calcium ion doped modified multi-walled carbon nanotubes and a coal gangue based reinforced admixture are cooperatively added into a cement matrix, seamless filling from nanometer to micrometer is achieved, a tough interface transition area is formed, pressure is jointly borne by a compact matrix and a strong interface, the compressive strength and breaking strength of the material are remarkably enhanced, and meanwhile, the compressive strength and breaking strength of the material are greatly improved. Migration of moisture and ions is effectively blocked, and the anti-permeability performance of the material is improved.

The invention relates to the technical field of concrete materials, and particularly discloses a composite mineral admixture, a preparation method thereof and concrete. The preparation method of the composite mineral admixture comprises the following steps: mixing and modifying dolomite powder, gypsum and calcium hydroxide to obtain pre-modified dolomite powder; then adding hexadecyl trimethyl ammonium chloride and octylphenol polyoxyethylene ether to obtain modified dolomite powder; and adding nickel slag, metakaolin, desulfurized fly ash and a grinding aid, and grinding to obtain the composite mineral admixture. The concrete prepared from the composite mineral admixture is excellent in compressive strength, shrinkage resistance, permeation resistance and the like, and the strength and durability of the concrete can be remarkably improved.

The invention discloses a low-carbon concrete material containing solid wastes and a preparation method of the low-carbon concrete material, and relates to the technical field of concrete materials. The concrete material is prepared from the following components in parts by weight: 520 to 660 parts of a cementing material, 1380 to 1650 parts of aggregate, 1.218 to 1.845 parts of an additive and 25 to 45 parts of other additives, specifically, the cementing material is prepared from 250 to 300 parts of cement, 120 to 150 parts of fly ash, 100 to 130 parts of slag powder, 20 to 30 parts of silica fume and 30 to 50 parts of metakaolin. A large amount of solid wastes are used in the formula, so that the pollution pressure on the environment is effectively reduced by utilizing the wastes; by reducing the use amount of the cement and replacing part of the cement with various solid wastes, the carbon emission in the concrete production process is effectively reduced, and the raw material cost is reduced.

The invention discloses steel fiber reinforced metakaolin-based recycled concrete and a preparation method thereof, and belongs to the technical field of civil engineering materials. The concrete is prepared from the following components in percentage by mass: 60wt%-80wt% of recycled aggregate, 20wt%-40wt% of a cementing material, 0.5 wt%-1.4 wt% of steel fibers and 0.1 wt%-0.7 wt% of an additive, wherein the cementing material comprises cement and metakaolin, and the mass ratio of the metakaolin to the cement is (1-3): (7-9). A nano silicon dioxide coating is arranged on the surface of the steel fiber. The preparation method adopts a step-by-step stirring process. The problem that dynamic impact resistance and green low carbon are difficult to cooperate in the prior art is solved, through component optimization and process control, the dynamic compressive strength of the concrete is improved, the energy absorption capacity is improved, the damage mode is converted into ductility from brittleness, fiber distribution is uniform, and the concrete is suitable for impact-resistant projects such as airport runways and protective structures.

The invention provides high chloride ion permeation resistance steel fiber fine aggregate concrete and a preparation method thereof. The high chloride ion permeation resistance steel fiber fine aggregate concrete comprises the following raw materials in parts by weight: 200-300 parts of cement; 30 to 50 parts of metakaolin; 100 to 200 parts of fly ash; 50 to 100 parts of mineral powder; 1-8 parts of nano silicon dioxide; 800 to 1000 parts of sand; 800 to 1000 parts of stone; 10 to 60 parts of steel fiber; 150 to 200 parts of water; and 5-20 parts of a water reducing agent. The steel fiber fine aggregate concrete with high chloride ion permeation resistance has the advantages of improved mechanical properties and durability, extremely high chloride ion permeation resistance, excellent volume stability, low material cost, economic feasibility of large-scale application, and wide application prospect. And the strict service requirements of the urban rail transit ballast bed under the long-term dynamic load, stray current and erosion medium coupling effect are precisely met.

The invention discloses an active mineral admixture for low-grade attapulgite-based sprayed concrete as well as a preparation method and application of the active mineral admixture. The active mineral admixture comprises the following components in parts by mass: 40-60 parts of active attapulgite, 10-20 parts of active rectorite, 5-20 parts of active montmorillonite, 5-15 parts of silica fume, 5-25 parts of metakaolin, 10-20 parts of fly ash and 0.5-6 parts of a water reducing agent. Minerals used in the invention are rich in reserves and low in price, and a stable raw material source is provided for the mineral admixture for the sprayed concrete. When the sprayed concrete obtained on the basis of the active admixture is used for construction operation, the block falling rate and the rebound rate are greatly reduced, the compressive strength is greatly improved, and good economic and environmental benefits and wide application prospects are achieved.

The invention relates to the technical field of building materials, in particular to a cementing material for a fabricated wall prepared from multi-element solid waste and a preparation method of the cementing material. The preparation method comprises the following steps: 25-55 parts of fly ash, 25-65 parts of blast furnace slag, 8-10 parts of lime, 1-5 parts of desulfurized gypsum, 3-6 parts of a first mixture, 2-5 parts of a second mixture and 5-8 parts of an alkali activator; the mass ratio of the metakaolin to the bentonite to the superfine calcium carbonate in the first mixture is 3: 2: 1; the mass ratio of the vermiculite to the expanded perlite to the glass beads in the second mixture is 2: 2: 1. Through the synergistic excitation effect of Ca < 2 + > and Na < + > and the addition of the first mixture and the second mixture, the cementing material forms a more stable microstructure. A hydration product SEM figure shows that C-S-H and C (N)-A-S-H gel are symbiotic to form a three-dimensional network, pores are filled with needle-like ettringite crystals, and in combination with the brucite phase anchoring effect, the mechanical properties, such as strength and durability, of the material are remarkably improved.

The invention discloses sulfate-erosion-resistant metakaolin-slag-based geopolymer concrete, belongs to the technical field of concrete, and aims to solve the problems that the corrosion resistance of traditional silicate concrete is ineffective and the adaptability of conventional alkali-activated concrete is insufficient in a special environment. The concrete comprises the following components in parts by weight: 60-90 parts of a cementing material, 120-170 parts of aggregate, 15-30 parts of a composite activator, 2-8 parts of a function regulator and the like, the cementing material is prepared from nano TiO2 / KH-550 composite modified metakaolin, slag and silica fume-coal gangue powder-HAP composite powder; the aggregate comprises modified limestone macadam (soaked and dried by a sodium dihydrogen phosphate solution) and river sand; the composite exciting agent comprises water glass, sodium hydroxide, sodium pyrophosphate, propylene glycol and the like; the function regulator comprises superfine fly ash, a naphthalene water reducer, HPMC (Hydroxy Propyl Methyl Cellulose) and boric acid. Through the synergistic effect of the components, the sulfate corrosion resistance, the mechanical property and the environmental adaptation performance of the concrete are improved, and the concrete is suitable for engineering construction under the service environment of high-concentration sulfate and the like.

The invention provides anti-erosion hydraulic concrete and a preparation method thereof, and belongs to the technical field of concrete. The concrete comprises the following components: composite cement, high-activity nano-modified metakaolin, blast furnace slag powder, low-calcium fly ash, coarse aggregate, natural river sand fine aggregate, granite machine-made sand fine aggregate, an erosion inhibitor, a functional additive, an early-strength polycarboxylic high-performance water reducer, a composite air entraining agent and the like. The composite cement comprises sulphoaluminate cement, Portland cement and polymer waterproof mortar. The high-activity nano modified metakaolin is obtained by modifying metakaolin with an organic silicon-ZnO composite emulsion and then drying. The erosion inhibitor comprises organic carboxylate, a hydrophobic-crystallization complexing agent and a pH buffer type corrosion inhibitor. The functional auxiliary agent comprises an itaconic acid and acrylic acid copolymer, a JRY-F concrete waterproof agent and polyethylene glycol-400 dilaurate. The composite air entraining agent comprises liquid sodium abietate and sodium alpha-olefin sulfonate. Through component synergism, modification and grading, an anti-erosion barrier is constructed.

The invention relates to the technical field of concrete crack repairing agents, in particular to a triggered precipitation type concrete crack repairing agent as well as a preparation method and application thereof. The repairing agent is prepared from the following raw materials: sulphoaluminate cement, nano anhydrite with a core-shell structure, fluorine-phosphorus composite seed crystal, magnesium oxide, metakaolin and a water reducing agent, wherein the core-shell structure nano anhydrite is prepared by coating mesoporous silica with nano anhydrite, and the fluorine-phosphorus composite seed crystal is prepared from calcium fluoride and monocalcium phosphate through a hydrothermal reaction. According to the trigger precipitation type concrete crack repairing agent prepared by the invention, sulfate ions are slowly released through the core-shell structure nano anhydrite, the crystal form of ettringite is regulated and controlled through the fluorine-phosphorus composite seed crystal, the problems that a traditional repairing agent shrinks and falls off in the later period, the high-temperature strength is suddenly reduced, and the binding power is insufficient are solved, and the trigger precipitation type concrete crack repairing agent is suitable for concrete structure crack repairing and high-temperature environment engineering.

A method of making a silver-silicalite coating on a surface of a stainless-steel substrate is provided. The method includes mixing metakaolin with an aqueous solution of NaOH to form a first mixture. The method further includes mixing silica gel and silver nitrate with the first mixture to form a second mixture. Furthermore, the method includes mixing Zeolites Socony Mobil-5 (ZSM-5) with the second mixture to form a third mixture. The method further includes hydrothermally treating the stainless-steel substrate with the third mixture to form the silver-silicalite coating on the surface of the stainless-steel substrate. The hydrothermal treatment is carried out in the absence of an organic template. The stainless-steel substrate coated with the silver-silicalite coating, prepared by the method of the present disclosure, has lower corrosion in comparison to the same stainless-steel substrate without the silver-silicalite coating.

The invention relates to the field of building materials, and discloses a high-strength low-carbon cementing material regulated and controlled by a pH value and a preparation method and application thereof, the cementing material contains a main agent and an auxiliary agent, and the mass ratio of the main agent to the auxiliary agent is 100: 0.03-0.3; on the basis of the total mass of the main agent, the main agent comprises 60-80 wt% of an active component, 5-25 wt% of gypsum and 1-15 wt% of an exciting agent; the active component contains S95-grade mineral powder and a component A; the component A is selected from at least one of secondary steel slag powder, phosphorus slag powder, slag, secondary fly ash, metakaolin and silica fume; the exciting agent is selected from at least two of sintering process red mud, sulphoaluminate cement, salty mud, carbide slag, papermaking white mud and boric sludge, the exciting agent comprises the sintering process red mud, and the sintering process red mud accounts for 30-60 wt% of the total mass of the exciting agent; the pH value of the cementing material is 12.6-13.2 under the condition that the mass ratio of the cementing material to the water is 1: 10. The cementing material provided by the invention has the advantages of low production cost, no harm, moderate alkalinity and excellent mechanical strength.

The invention discloses an inorganic copolymer anticorrosive paint and a preparation method thereof, and relates to the technical field of paints. The invention discloses inorganic copolymer anticorrosive paint. The coating is prepared from the following raw materials in parts by weight: 20 to 30 parts of silica sol, 8 to 15 parts of sodium hydroxide, 30 to 45 parts of metakaolin, 8 to 20 parts of quartz sand, 15 to 25 parts of water, 0.3 to 2 parts of sodium polyacrylate, 0.2 to 3 parts of polydimethylsiloxane emulsion, 5 to 12 parts of modified nano titanium dioxide, 6 to 10 parts of modified epoxy resin, 10 to 25 parts of hydroxyethyl methylacrylate, 5 to 10 parts of zinc phosphate, 3 to 8 parts of aluminum triphosphate and 2 to 6 parts of iron oxide red. The raw materials of the inorganic copolymer anticorrosive paint are scientifically proportioned, and the anticorrosive performance is enhanced through the modified nano titanium dioxide and the epoxy resin. Material uniformity is ensured through step-by-step feeding and ultrasonic dispersion in preparation, and stability is improved through vacuum defoaming and nitrogen protection. The components such as the silica sol and the zinc phosphate have a synergistic effect to form a compact coating, and the coating is high in corrosion resistance, good in constructability and suitable for various scenes.