2398 results about "Coal gangue" patented technology

The invention provides a method for preparing aluminum oxide and other products from aluminiferous materials such as bauxite, high iron bauxite, alunite, kaoline, alumina, fly ash, coal gangue, aluminum ash, nepheline, clay and the like. The method comprises the following steps: (1) crushing, grinding and mixing the aluminiferous materials with ammonium sulfate and then roasting; (2) dissolving the roasted product (clinker aggregate) in water, and filtering to obtain aluminum ammonium sulfate solution and filter residues; (3) carrying out deferrization, aluminum deposition or recrystallization on the aluminium ammonum sulfate solution with ammonia to prepare aluminum oxide, and meanwhile, recycling the ammonium sulfate; (4) preparing silicon dioxide from the filter residues, and taking the remaining residues containing ferrum as the raw material for ironmaking. The method is suitable for treating various aluminiferous materials, has the advantages of simple technical process, simple equipment, no emission of solid, liquid and gas wastes, and no secondary pollution, and realizes the high-added-value green complex utilization of the aluminiferous materials such as bauxite, high ironbauxite, alunite, kaoline, alumina, fly ash, coal gangue, aluminum ash, nepheline, clay and the like.

The invention discloses a composite tailing non-fired and non-steamed building block brick and a preparation method thereof. The brick comprises the following raw materials in parts by weight or volume: 50-300 parts of tailing and 3-30 parts of cement; and at least two components are selected from the active wastes such as fly ash, coal gangue, shale slag, alkaline residue, carbide slag, chemical gypsum and the waste residue of metallurgical industry to be mixed with the raw materials. The preparation method comprises the following steps: mixing to stir, compressing and shaping, performing natural curing or utilizing the solar heaing hydrating maintenance to prepare the composite tailing building block brick. By adopting the preparation method of the invention, the single performances of the tailings and slags can be changed, thus the product can have higher strength and quality owning to the interaction of materials; the technology does not adopt firing and steaming, the cost is low; different sizes of solid bricks, perforated bricks, hollow blocks, floor tiles, grass planting bricks, roadside bricks and artistic rails can be prepared by changing the mould; and various harmful slags such as tailings can become good, the Chinese development direction of the comprehensive utilization of resources is satisfied and the brick of the invention has development and application prospect.

The invention relates to a burning-free block brick prepared from bulky industrial waste residues. The burning-free block brick is characterized in that the block brick comprises the following raw materials in parts by weight or volume: 10-80 parts of at least one of tailing, magnesium slag, basic slag, mountain flour, cinder, fly ash, coal gangue, oil shale waste and sulfuric acid slag, 0-80 parts of at least one of gravel, waste sand, construction waste, garbage to be burnt, steel slag, mineral slag, copper slag, iron slag with gold, ardealite, phosphorous slag and carbide slag, 0-50 parts of active cementing material, 0-30 parts of cement clinker, 2-15 parts of cement and a defined amount of water. The preparation method of all types of burning-free and steaming-free standard bricks, perforated bricks, hollow blocks, paving tiles, road edge bricks and fence railings which have low cost and high strength, is as follows: proportioning, stirring for 1-6 minutes, adding a defined amount of water to stir, placing in moulds to form in a machine and performing natural curing for 7-28 days. The burning-free block brick has high raw material selectability, simple technology and wide development and application prospects, and is environmental-friendly.

The invention relates to a low-density ceramic proppant and a preparation method thereof, which belong to the field of exploring petroleum and natural gas. The preparation method of the low-density ceramic proppant comprises the steps of forming an inner core made of bauxite and coal gangue and a shell made of bauxite and trimanganese tetroxide into a ball and sintering to obtain low-density ceramic. The ceramic has higher strength and low density and is applicable to a ceramic proppant for fracturing a deep-level oil-gas well with high closed pressure and low permeability; the sintering temperature is relatively reduced in the range of 1,300-1,380DEG C, so that thus the energy consumption is effectively reduced and the energy can be saved by 20 percent; and meanwhile, the effect with low crushing rate can be achieved.

The invention discloses a light isolated material and a preparation method thereof, including an aluminates polymer, the molar ratio of silicon (Si) and aluminum (Al) in which is more than or equal to one and less than or equal to three and which includes solid raw materials containing silicon and aluminum of 50-85 weight percent of fly ash, kaolin, coal gangue, coal slag, etc.; 14.5-48 percent of liquid alkaline activator; 0.5-2 percent of foaming agent. The liquid alkaline activator includes caustic solution and water glass, which are mixed and stirred with the solid raw materials and the foaming agent to produce a roof heat insulation plate, which is applied to both the direct pouring and the die molding prefabrication and can be used both for the heat insulation or the cold insulation of cold or heat equipment and for making large size building wallboards for heat insulation, deafening and fireproofing.

The invention provides a raw coal washing process capable of realizing non-polar ash conditioning. The process comprises the following steps: a, desliming and screening the part of raw coal with granularity less than 50 to 100mm; b, carrying out single stage jigging separation on screen products on a desliming screen; c, crushing lump coal obtained from the step b, namely screen products on an oscillating screen, by a crushing machine; d, feeding the crushed products from the step c into a three-product heavy medium cyclone for separation; e, respectively treating underflows and overflows obtained from a hydroclone in the step c; f, carrying out TBS separation or centrifugal dehydration treatment on the underflows of the hydroclone from the step e; g, respectively carrying out primary medium removal on clean coal, middlings coal and gangue obtained from the step d; h, respectively carrying out secondary medium removal and dehydration on the three products from the step g; and i, carrying out magnetic separation on undersize dilute medium obtained by secondary medium removal on the coal gangue in the clean coal in the step h, feeding the separated magnetite powder into a qualified medium tank, collecting residues, and carrying out coal slurry concentration.

A sintered insulating hollow building block is prepared from coal gangue, powdered coal ash, steel slags, metallurgical tailings, red mud, and rejected solid (building garbage, life garbage and city mud) or shale through proportionally adding adhesive and millipore forming agent and sintering.

The invention relates to an automatic separator of coal gangue, which comprises a raw material feeding copper, a coal receiving copper, a gangue receiving copper, a conveying-belt conveyor, an identification and separation controlling mechanism and an executing mechanism, wherein the conveying-belt conveyer is arranged among the raw material feeding copper, the coal receiving copper and the gangue receiving copper; the identification and separation controlling mechanism comprises a single-energy gamma ray source, an X-ray sensor, a measure and control instrument and an ultrasonic transmitter-receiver; the single-energy gamma ray source is arranged below a conveying belt, the X-ray sensor is arranged above the conveying belt and corresponds to the single-energy gamma ray source, the measure and control instrument is electrically connected with the X-ray sensor, and the ultrasonic transmitter-receiver is arranged above the conveying belt and electrically connected with the measure and control instrument; the executing mechanism is a high-frequency air valve arranged above the coal receiving copper and the gangue receiving copper; and the valve port of the high-frequency air valve isarranged towards a throwing track of coal and gangue. As the single-energy gamma ray source is adopted, only one nuclear radiation material exists, and only one spectral line is radiated, the mutualinterference among a plurality of spectral lines can not be generated; and the invention has accurate measurement and good separation effect.

The invention provides a geopolymer gel material for rush repairs and rush constructions, which is prepared by adding water to 13-17 percent by weight of exciting agent and 82-87 percent by weight of slag containing aluminosilicate. The slag comprises one or the combination of more of blast furnace slag, steel slag, coal ash and coal gangue, and the exciting agent comprises the following components in percentage by weight: 35-75 percent of SiO2, 0-55 percent of Na2O, 0-65 percent of K2O, 0-1 percent of CaO and 0-1 percent of SO3. The geopolymer gel material which has the characteristic of quick setting and hardening is prepared by using the industrial waste slag as a main raw material and matching the exciting agent, and the geopolymer gel material has excellent mechanical property and controllable setting time and can replace gel materials such as fast setting and hardening cement, and the like in the processes of rush repairs and rush constructions. The industrial solid wastes such as the blast furnace slag, the steel slag, the coal ash, the coal gangue, and the like containing the aluminosilicate series are used as main raw materials, metakaolin is not added and the raw materials do not need to be calcined, thus the invention has low energy consumption, less pollution, simple process, low cost, environmental protection and energy saving.

The invention relates to an expendable pattern casting (EPC) molding shell paint for casting steel, and the EPC molding shell paint comprises surface a layer fireproof paint and a back layer reinforcing paint, wherein the surface layer fireproof paint comprises the following components in parts by weight: 80-90 parts of high-chromium alundum powder, 10-20 parts of calcined kaolinite, 6-8 parts ofcalcium rectorite powder, 1-3 parts of sodium tripolyphosphate, 3-5 parts of polyvinyl formal solution, 0.3-0.5 part of ethoxylated alkyl sodium sulfate, 0.6-1.0 part of polyether type modified polydimethylsiloxane and 60-75 parts of water; and the back layer reinforcing paint comprises the following components in parts by weight: 75-85 parts of coal gangue sand, 15-25 parts of kaolinite, 3-6 parts of feldspar powder, 8-13 parts of calcium rectorite powder, 8-10 parts of sodium tripolyphosphate, 1.5-2.0 parts of wood fiber and 30-45 parts of water. A molding shell manufactured by the surface layer fireproof paint and the back layer reinforcing paint has the characteristics of high strength and refractoriness, good air permeability and the like.

The invention relates to a method for preparing a foam ceramic self-insulation wall material by utilizing solid wastes. The wall material comprises a main material and an admixture. The main material is prepared from the following components in proportion: 25% to 35% of chromium slags, 19% to 27% of coal gangue, 20% to 26% of waste ceramic polishing residues, 17% to 25% of albite and 1% to 6% of bentonite. The method comprises the following steps of: adding 16 to 20g of the admixture into every 200g of the main material; evenly mixing and screening the mixture; putting the mixture into a die; molding the mixture in a pressing manner and drying; sintering the mixture under a strong reducing atmosphere at the temperature of 1120-1180 DEG C, thereby obtaining the foam ceramic self-insulation wall material. The carbon in the coal gangue can serve as a foaming agent or a reducing agent, so that hexavalent chromium is reduced into chromium sesquioxide at the high temperature and under the strong reducing atmosphere. Thus, the toxicity of the chromium slags is eliminated. The prepared foam ceramic self-insulation wall material is low in pyroconductivity, small in density and low in water absorption rate; the usage temperature can reach 900 DEG C. In addition, the foam ceramic self-insulation wall material is complete in fire resistance, high in strength and long in service life, and can be used for replacing the existing wall materials and flammable insulation materials. The wall material integrates protection and thermal insulation functions; an exterior wall insulating layer is not required. Thus, the construction cost is lowered.

The invention belongs to the technical field of building materials, and provides a method for preparing building material products through processing industrial solid waste by hydration-carbonation coupling technique. The method comprises steps of uniformly mixing the industrial waste comprising at least one of calcium oxide, calcium hydroxide, dicalcium silicate, tricalcium silicate and tobermorite with alkaline excitation material and proper amount of water so as to prepare the blank of the building material product, wherein the industrial waste comprises steel slag, mineral waste residue, furnace slag, coal ash or coal gangue, the alkaline excitation material comprises carbide slag, lime, Portland cement or waste cement; maintaining for a period through hydration, then maintaining through carbonation so as to obtain the carbonate-based building material product. The coupling technique can effectively use the industrial solid wastes such as steel slag, mineral waste residue, furnace slag, coal ash, coal gangue, carbide slag and the like, so that emission of greenhouse gases is reduced, the greenhouse effect is relieved, furthermore, the method can be used for producing the building material products with good properties, effectively uses the waste and is environmentally friendly.

The invention discloses a process method for cooperatively and continuously processing waste containing iron and/or zinc, lead, copper and tin, and the like and molten steel slag on line, separating and recycling metal such as iron, zinc, lead, copper and tin as well as molten slag. The cooperative processing and recycling method is characterized in that pellets prepared from waste containing iron, zinc, lead, copper, tin and the like, particles, a blocky material containing iron, zinc, lead, copper, tin and the like and high-temperature molten steel slag are added into a reducing, volatilizing and smelting furnace, molten iron, which is obtained by air-blowing, adding of fuels such as coal gangues and flux such as high silicon and high aluminum, high-temperature reducing and volatilizingtreatment, is discharged from an iron outlet of the reducing, volatilizing and smelting furnace; volatilized substances such as zinc and lead and smoke gas are sucked into a dust collector for being collected and utilized; enriched metal such as gold, silver, copper, tin and lead is discharged from a discharge hole in the bottommost part of the reducing, volatilizing and smelting furnace for beingrecycled; and molten slag is discharged through a slag outlet, water slag and the like or the molten slag is returned into a converter for being recycled. Waste containing iron, zinc, lead, copper, tin and the like, molten steel slag and coal gangue waste slag and the like are cooperatively and continuously treated to separate and recycle useful metal, so that remarkable energy-saving environment-friendly social benefits and economic benefits are achieved.

The present invention discloses a concrete cement foaming insulation brick, taking a concrete perforated brick as a main body. The concrete perforated brick is injected with a cement foam material, so that the cement foam material and the concrete perforated brick are fully combined. By adjusting the formulation and improving the process, the present invention makes full use of industrial wastes such as fly ash and coal gangue, does not need autoclaved curing, and is small in investment and simple in process. The foaming brick produced by the present invention has excellent heat insulation and sound insulation properties, and is high in strength, good in impact resistance, low in moisture absorption, light in weight, compression resistant, good in weather resistance, environmental-friendly and energy-saving, and non-toxic. The brick has great market space and development prospects in the application field of building energy efficiency.

The invention discloses a large mixing amount coal gangue composite cement comprising coal gangue, silicate cement clinker aggregate, exciting agent, gypsum coagulation regulating agent, mineral admixture by right weight portion through a finite process, wherein the content of coal gangue is 20-80% wt. The composite cement according to the invention can be used for making various concrete structure, in particular mass concrete structure.

The invention discloses a method for preparing a foamed ceramic insulation board by a waste glass ceramic wafer, belonging to the field of preparation technology of the foamed ceramic insulation board. The method comprises the steps of: washing the waste glass ceramic wafer with clear water, drying and grinding by ball milling to obtain waste glass ceramic powder with the fineness less than or equal to 100mu m; mixing the waste glass ceramic powder, pulverized fuel ash, furnace slag, coal gangue, ceramic tailings, foaming agent and modifying agent according to the mass ratio of (30-40):(10-15):(5-7):(10-18):(25-35):(1.8-2.2):(1.1-1.5); putting the mixture into a ball grinding mill, carrying out wet grinding and evenly mixing to form mixed slurry; drying by a pressure type spray granulation dryer and putting the dried product into a foaming refractory mould coated with aluminum oxide; heating to 1120-1150 DEG C in a heating furnace; and finally, annealing, cooling and cutting to obtain the foamed ceramic insulation board. The method is low in production cost and simple in technology, and can be used for continuously preparing the porous foamed ceramic insulation board with large size; and the product is good in performances.

The invention relates to a method for preparing aluminum oxide and other products by aluminum-containing materials of bauxite, alunite, nepheline, fly ash, kaolin, coal gangue and clay. The method comprises the following steps: (1) crushing and grinding an aluminum-containing material, carrying out mixing and baking for the treated aluminum-containing material and ammonium bisulfate; (2) carryingout dissolution and filtering for the baked clinker to obtain a crude ammonium aluminum sulfate solution and aluminum extracting residue; (3) carrying out an iron precipitating treatment for the ammonium aluminum sulfate solution with the concentration more than 1 g/L by adopting a jarosite method, then carrying out an iron precipitating treatment by a goethite method, carrying out an aluminum precipitating treatment for the resulting solution, carrying out calcination for the resulting aluminium hydroxide to prepare aluminum oxide; (4) carrying out an iron precipitating treatment for the ammonium aluminum sulfate solution with the concentration less than 1 g/L by adopting the goethite method, and carrying out an aluminum precipitating treatment to prepare aluminum oxide, or adopting a recrystallization method to carry out purification, adopting a reaction of the ammonium aluminum sulfate crystal and a ammonium carbonate solution to precipitate the aluminum to obtain ammonium aluminumcarbonate, carrying out calcination for the ammonium aluminum carbonate, and adopting a Bayer method to treat the calcined ammonium aluminum carbonate to prepare sandy aluminum oxide; (5) washing anddrying the aluminum extracting residue, wherein the dried aluminum extracting residue is adopted as the silicon dioxide product.

The invention relates to a paste self-flow stuff technique of coal mine and relative paste, which uses the coal gangue as main stuff. The invention is characterized in that the stuff technique comprises that mixing cement and powder coal into water to form pulp; adding coal gangue to form coal gangue suspension paste; using tube to self-flow transmit the paste into under-well stuff area to stuff the mining field. The invention uses coal gangue as main stuff material and uses self-flow stuff technique, with low cost and the application in the underground coal layer, to reduce the pollution of coal gangue. The inventive paste has high water contant and low water leakage, therefore, the stuff has high strength.

The present invention relates to a method for coproducing alumina, white carbon black and low-ash carbon. Said method is characterized by that it uses the minerals of coal gangue and kaolinite containing different S:O2 and Al2O3 contents as raw material, and makes said raw material be undergone the processes of breaking, beating to make extraction by using sulfuric acid solution and separation so as to obtain aluminium sulfate solution, in the course of extraction and separation small quantity of fluoride as activating agent can be added, then the sulfate as cocrystallization agent is added in said solution, then the above-mentioned material is undergone the processes of concentration and crystallization so as to obtain high-grade alum salt crystal, at the same time the acid mother liquor can be circularly utilized to make next extraction, the residuum can be extracted by alkaline liquor to obtain silicon oxide and recover carbon. Said invention is simple, and the extraction rate of alumina is high, the high-grade aluminium salt can be easily obtained.

The invention relates to a curing agent for treating heavy metal pollution and a heavy metal curing method. The curing agent is prepared from following raw materials, by mass, 30-70 parts of a curing framework material, 20-60 parts of a curing cementing material and 5-10 parts of a curing promoter. The curing framework material is at least one of fly ash, blast furnace slag, carbide slag and calcined coal gangue powder; the curing cementing material is at least one of ordinary Portland cement and lime; and the curing promoter is at least one of potassium hydrogen phosphate, sodium hydrogen phosphate and aluminum sulfate. The heavy metal curing method includes following steps: mixing the curing agent, solid waste and water with stirring into paste to form a curing body, wherein a usage amount of the curing agent accounts for 30-50% of the dry weight of the solid waste; and maintaining the mixed curing body at normal temperature under a relative humidity of 90% for at least seven days, thereby finishing the heavy metal curing process. By means of the curing agent and the heavy metal curing method, a heavy metal curing efficiency is high and a treatment cost is low.

The invention discloses a production process for extracting gallium from flyash and coal refuse, which recycles gallium by further deep utilizing the produced waste liquid on the basis of extracting alumina, silica gel from coal series solid waste. According to the invention, gallium chloride is acquired after middle temperature calcinations, leaching, carbon dioxide decomposition, direct adsorption on column, eluting, etc., problems of large slag and low slag utilization added value in current technology are solved, the extraction rate of gallium form flyash and coal refuse can reaches over 80%; the whole process is performed under normal atmosphere, thus the equipment requirement is low, resources are effectively utilized during the whole process, and no new pollution is caused to surrounding environment.

A light-weight refractory brick used for liner of high-temp furnace is prepared from mullite as primary crystal phase, huronite as binding phase, disthene and coal gangue. Its main chemical components are Al2O3 (54-57 wt.%), SiO2 (40-43), CaO (1-2), Fe2O3 (0.1-1) and impurities (0.1-0.7). Its advantages are light weight, low heat conductivity and volume density, and high strength.

A method for comprehensive utilization of red mud, phosphogypsum and coal gangue comprises the following steps: red mud, phosphogypsum and coal gangue are used as main original burning materials, a correction material is taken as a secondary original burning material, a homogeneous moisture material is prepared through two-stage batching process and is shaped or dried and crushed, and then a clinker product including main ingredients of dicalcium silicate, calcium sulphoaluminate and calcium sulphoferrite is prepared through calcination. The clinker produced by the method can be not only directly sold as a product but also further processed into a cementing material or product for sale by utilizing the prior art. The method provided by the invention is simple in process and low in investment, the production scale can be either big or small, a rapid hardening early strength clinker produced by the method is wide in use and relatively higher in value, not only are lots of clay resources and non-renewable burning coal saved, but also environmental pollution caused by waste pollutants are effectively reduced, secondary disasters is prevented, and high industrial competitiveness and favorable investment economical efficiency are realized.

The invention discloses a coal gangue biomass solid briquettes fuel, which comprises the following components in percentage by weight: 40 to 85 percent of coal gangue with the combustion heat value higher than 2,000 kilocalories, 10 to 50 percent of agricultural organic waste, 1 to 5 percent of combustion improver, and 1 to 5 percent of adhesive. The method for preparing the coal gangue biomass solid fuel comprises the following steps: crushing the coal gangue with the combustion heat value higher than 2,000 kilocalories; and adding the agricultural organic waste, the combustion improver, and the adhesive in a certain proportion to directly produce the coal gangue biomass solid forming fuel with a stable combustion value by adopting forming machinery. The solid forming fuel is prepared by reasonably using a large quantity of agricultural organic waste and the coal gangue in a certain proportion; and the combustion heat value is stable. The biomass solid forming fuel can be used as the fuel of boilers, stoves and other combustion devices, and has good social benefits, environmental protection benefits, and economic benefits.

The invention discloses an organic fertilizer which comprises straws, coal gangue, decomposed coal, peat soil, ground phosphate rock, potassium ore powder, wheat middling, soybean meal, rice hull powder, culture powder, urea and polyacrylamide. The organic fertilizer integrates yield increase, high efficiency, long action and capacities of improving quality, improving soil and inhibiting soil-borne diseases into a whole, is low in cost, simple in process and free of residues and pollution and has high popularization and application prospects.

The invention discloses a coal mine underground mining, dress and filling integral method, which comprises the following steps that: a raw coal belt conveyor, a raw coal cabin, a raw coal feeding belt conveyor, a washing system, a cleaned coal belt conveyor, an underground coal storage cabin, a washed coal gangue belt conveyor, a digging coal gangue belt conveyor, a crushing machine, a coal gangue feeding belt conveyor, a coal gangue cabin and a filling coal belt conveyor are adopted; underground mined raw coal is subjected to dressing by washing by the washing system; cleaned coal subjected to dressing by washing is conveyed into the underground coal storage cabin and is hoisted onto the ground; and washed coal gangue obtained after the dressing by washing is crushed by the crushing machine and is then conveyed to a solid filling coal mining work surface for mine goaf filling. The mining, dress and filling integral method has the advantages that the safe and efficient exploitation under a railway, a water body and a building is realized; the mine auxiliary hosting pressure is reduced; the coal quality is improved; and the problems of ground occupation, pollution and the like caused by coal gangue discharge onto the ground are solved.

The invention discloses a low-density ceramic proppant prepared from fly ash and a preparation method thereof. The proppant comprises the following components, by weight: 60%-80% of bauxite, 10%-30% of fly ash and 5%-10% of manganese powder. The fly ash mainly comprises Al2O3 and SiO2, and the Al2O3 and SiO2 have higher content and purity than coal gangue, so that quality of the fly ash will not be influenced; and the fly ash has low density, and is suitable to be used as a raw material for preparation of low-density ceramic. Fly ash has wide distribution, and can be used to replace bauxite resource, which is becoming more and more limited, so as to save non-renewable resources. Compared with ceramic proppant prepared from coal gangue, the low-density ceramic proppant prepared from raw material of fly ash has substantially reduced fracture rate, bulk density and turbidity, improved product quality and reduced cost, so as to solve environmental pollution caused by fly ash emission.

The invention relates to a coal gangue-fly ash-sludge substrate and a mycorrhiza technology for restoring ecology of a mining area. The invention belongs to the technical field of environmental protection, and relates to an ecology restoring technology, in particular to a method for restoring the ecology of an abandoned coal mine area. The method for restoring the abandoned coal mine area by the mycorrhiza technology of the invention adopts a composite substrate prepared by mixing fly ash, coal gangue and sludge, and comprises the following steps: a, preparing an inoculant; b, preparing a basic plant material; c, carrying out inoculating mycorrhiza treatment on the plant by the inoculant obtained in the step a; d, analyzing the physicochemical property of the abandoned coal mine area, and carrying out mixed treatment to form the composite substrate; and e, sowing seeds on the composite substrate surface layer of the treated abandoned coal mine area. The method of the invention can improve the adaptability of plants to the complex adverse environment of the abandoned coal mine area, wherein the adaptability comprises stronger nutrient acquisition capability and cold resistance, thereby fully utilizing waste and sludge in the mining area, and solving the source problem of other soil for melioration in the mining area.

The invention discloses an environment-friendly slow-releasing long-standing compound fertilizer which belongs to polyelement compound fertilizer and a production method thereof. The fertilizer comprises the following raw material ingredient (by parts by weight): 10-40 parts of powdered rock phosphate, 10-40 parts of potassium feldspar, 15-40 parts of coal gangue, 10-20 parts of magnesite powder, 10-30 parts of nitrogenous fertilizer, 8-18 parts of swell soil, 1-3 parts of kieselguhr and 0.3-1 part of trace element; the powdered rock phosphate, the coal gangue and proper amount of coke are roasted for 8-16 hours at 500-800 DEG C, cooled, crushes and screened by a 60-mesh sieve. The invention provides an environment-friendly energy-saving fertilizer capable of improving soil with comprehensive effective fertilizer composition, slow releasing and high fertilizer utilization ratio. Meanwhile, the environment-friendly slow-releasing long-standing compound fertilizer is suitable for various soils and growth of various crops and the preparation method thereof is provided. The problems of low fertilizer utilization ratio, environment pollution, hardening soil, high production cost and the like in the prior art are solved.

The invention relates to an efficient ecotype inorganic formaldehyde adsorbing material which is obtained by mixing and curing 50%-75% of a solid raw material containing aluminosilicate, 10-40% of alkaline solution and 10%-15% of a complex reaction activator, wherein the solid raw material containing the aluminosilicate comprises at least one of the following raw materials: clay, kaolin, coal gangue, fly ash, waste incineration ash, slag, red mud and the like; alkali content of the alkaline solution is 3-12mol/L[OH-]; and the complex reaction activator comprises two components at mass ratio of 75-85% of a silicate substance and 15-25% of Al2O3 particle size of which is more than 1000 meshes. The inorganic adsorbing material is of a net porous gel structure, total pore volume is 0.17mL/g-0.36mL/g, specific surface area is 300-650m<2>/g, and pore distribution mainly adopt two modes of micropores (pore diameter is less than 2nm) and mesopores (pore diameter is 2-50nm), wherein the pore volume of the micropores (45%-60%) and the mesopores (25%-50%) accounts for 85%-95% of the total pore volume. The inorganic adsorbing material comprises 80-95% of an amorphous component and 5-20% of a crystal component based on the total mass of the material.