The invention relates to an additive product suitable for coal-fired boilers in the petroleum, chemical and power industries and provides a boiler coal combustion-improving denitrifying agent composition. The composition comprises the following raw materials in parts by weight: 2-8 parts of sodium carbonate, 3-7 parts of aluminium hydroxide, 2-5 parts of ferric trichloride, 6-15 parts of urea, 4-10 parts of ammonium carbonate, 4-10 parts of ammonium chloride, 3-9 parts of ferric oxide, 7-22 parts of potassium permanganate, 7-22 parts of potassium chlorate, 15-40 parts of activated attapulgite clay, 4-8 parts of chromium sesquioxide, 2-6 parts of manganese oxide, 4-8 parts of zinc oxide, 4-8 parts of copper chloride, 2-6 parts of copper oxide, 2-6 parts of copper carbonate, 3-7 parts of zinc sulfate, 2-5 parts of zinc nitrate, 0.5-1.5 parts of barium molybdate, 1-2 parts of titanium oxide, 0.5-1.5 parts of vanadium pentoxide, 0.2-0.5 part of copper sulfate, 0.2-0.5 part of cerium oxide, 1-3 parts of penetrating agent JFC and 0.1-0.2 part of lignosulphonate. The composition is efficient in combustion improving, has high coal saving rate and prolongs the service lives of the boilers.