The invention discloses a method for preparing
pigment-grade
chromium oxide green directly from chromic
hydroxide. The method comprises the steps of
grinding and mixing chromic
hydroxide and a certain quantity of additives, activating and
sintering a mixture for 0.5 to 3 hours at a temperature between 800 and 1,100 DEG C, washing,
drying and grading the mixture so as to obtain the
pigment-grade
chromium oxide green, wherein the chromic
hydroxide can be obtained from the prior industrial production and various types of waste (waste residue and
wastewater), or can be obtained by a low-temperature
hydrogen reduction method in a patent (application number: 200510089010.8), and the additives are
silicon compounds,
titanium compounds,
boron compounds,
phosphorus compounds, aluminum compounds,
barium compounds,
zinc compounds and other compounds, such as SiO2, K2SiO3, Na2SiO3, TiO2, K2TiO3, B2O3, H2BO3, H3PO4, P2O3, Al2O3, Al(OH)3, Al2(SO4)3, AlCl3, Al(NO3)3, BaO, Ba(OH)2, BaSO4, BaCl2, Ba(NO3)2, ZnO, ZnCl2, ZnSO4, Zn(NO)3, Sb2O3, NiO, Ni(OH)2, CoO, Co(OH)2 and other substances. After the chromic hydroxide is activated and sintered at a temperature between 700 and 1,300 DEG C in an
air atmosphere, the alkali-
metal content of obtained
chromium oxide is less than 0.3 percent, and cannot influence the properties of the
pigment-grade
chromium oxide green.