The application relates to a preparation process of synthesizing
hybrid zinc aluminate by using
solid waste
sodium tetrachloroaluminate, and belongs to the technical field of chemical dangerous
waste treatment, and comprises the following synthesis steps: S1,
zinc compounds are added in water, and the
zinc compounds are completely dissolved or uniformly dispersed; S2,
solid waste
sodium tetrachloroaluminate is added, and the
solid waste
sodium tetrachloroaluminate is completely dissolved and reacted by continuing to stir; S3, an
oxidizing agent is added, and the reaction is continued by keeping warm and stirring, then
filtration is carried out, and the
phosphorus content in the filtrate is detected; S4, after the
phosphorus content is qualified,
sodium hydroxide solution is added into the filtrate, the pH value is controlled, and white zinc
aluminate precursor precipitate is generated; S5, the white zinc
aluminate precursor precipitate is transferred into a high-pressure reaction kettle to carry out
hydrothermal reaction, and
hybrid zinc aluminate liquid is generated; S6, negative pressure suction
filtration is carried out, the obtained filter solid is washed by using deionized water, the filter solid is subjected to
spray drying, and solid
hybrid zinc aluminate is obtained. The application fully utilizes aluminum resources in the solid waste sodium tetrachloroaluminate, and
total phosphorus impurities in the solid waste sodium tetrachloroaluminate are also utilized to generate effective components, so that waste is turned into treasure.