The present invention relates to an accumulator with a bipolar architecture, comprising two end current collectors between which a stack of n electrochemical cells is arranged, where n is an integer at least equal to 2: each
electrochemical cell comprises a positive
electrode, a negative
electrode, and an
ion-conducting membrane interposed between the positive and negative electrodes, and a liquid
electrolyte contained within the electrodes and the
ion-conducting membrane; and the n electrochemical cells are separated from each other by n-1 bipolar current collectors, characterized in that the positive and negative electrodes of each
electrochemical cell are gel electrodes comprising a
composite material comprising a
polymer matrix made from at least one gelling
polymer (FF), an
electrode active material, and optionally one or more electronically conductive additives, the
polymer matrix
trapping the liquid
electrolyte, and the one or more gelling polymers (FF) selected from
fluorinated polymers comprising at least one repeating unit derived from the
polymerization of a fluorinated
monomer and at least one repeating unit derived from the
polymerization of a
monomer comprising at least one
carboxylic acid group, optionally in the form of a salt. Applications: Any of the fields in which accumulators with bipolar architecture are likely to be used, in particular in the production of electric or
hybrid vehicles, devices for the stationary storage of energy, and portable electronic devices (telephones, touch tablets, computers, cameras, video cameras, etc.).