The invention discloses a
graphene integrated water
system energy storage device and application thereof, and belongs to the technical field of battery manufacturing. The preparation method comprises the following steps: (1) preparing a
graphene modified
electrolyte: adding high-purity water, inorganic salt and TEMPO or a derivative thereof into
graphene oxide slurry, and mixing the high-purity water, the inorganic salt and the TEMPO or the derivative thereof; 2) mixing the graphene
oxide slurry, the additional carbon material
powder and high-purity water to form
slurry, blade-
coating the slurry to form a film, and forming
aerogel to prepare an
electrode; and 3) assembling the graphene modified
electrolyte, an
electrode and a diaphragm into an
energy storage device. According to the graphene integrated water
system energy storage device and the application thereof, the graphene modified
electrolyte effectively inhibits the shuttle effect and
side reaction, and the coulombic efficiency of the
system is remarkably improved; the three-dimensional porous structure of the
aerogel electrode accommodates electrolyte ions and limits the
diffusion of the electrolyte ions, so that the specific capacity is improved; through the synergistic effect of the two, the energy storage device has excellent electrochemical performance, is convenient to assemble and high in safety, and has huge application value in the field of large-scale energy storage.