1488results about "Electrolyte immobilisation/gelification" patented technology

The invention discloses a preparation method and application of a sulfide solid electrolyte membrane based on a gradient polymer / ionic liquid composite binder, and an all-solid-state battery, and belongs to the technical field of all-solid-state batteries. The method comprises the following steps: firstly coating a polymer / ionic liquid / sulfide electrolyte composite layer through a gradient coating process, filling particle gaps under low pressure by utilizing the plasticizing effect of ionic liquid, and reducing the porosity of an interface; and then coating a polymer / sulfide electrolyte surface layer to provide mechanical support and inhibit side reaction of the electrode. According to the design, the electrolyte membrane still keeps high ionic conductivity under the working pressure of a commercial power battery module, and the interface impedance is reduced compared with that of a traditional homogeneous membrane. Through the innovative gradient structure and material combination, the ion transmission bottleneck of the sulfide electrolyte under the low-pressure condition is solved, excellent interface stability and process compatibility are achieved, and a key technical scheme is provided for all-solid-state battery industrialization.

The invention provides an aerogel reinforced composite electrolyte thin film for a solid-state lithium battery and a preparation method of the aerogel reinforced composite electrolyte thin film, and belongs to the technical field of composite electrolytes.The thin film comprises a three-dimensional porous aerogel skeleton, a solid-state electrolyte compound and lithium salt nanocrystals; wherein the three-dimensional porous aerogel skeleton is prepared from inorganic oxide nanoparticles and a polymer precursor through a sol-gel method; pores of the three-dimensional porous aerogel skeleton are filled with the solid electrolyte compound, the solid electrolyte compound comprises lithium lanthanum zirconium oxide nanowires and a polyoxyethylene-lithium salt composite matrix, and the lithium lanthanum zirconium oxide nanowires are directionally arranged in the thickness direction of the film; the lithium salt nanocrystals grow on the surface of the pore wall of the three-dimensional porous aerogel in situ; the mass ratio of the aerogel skeleton to the solid electrolyte compound is (1: 3)-(1: 15). According to the thin film, the ionic conductivity, the mechanical strength and the interface stability of the electrolyte are remarkably improved.

The invention relates to the technical field of solid-state battery energy conversion, and discloses a high-safety sodium-ion battery energy conversion method based on a solid-state electrolyte, which comprises the following steps: identifying an interface dynamic mismatch risk time period in a charging and discharging process, and applying micro-amplitude high-frequency acoustic vibration disturbance to a solid-state electrolyte and a sodium negative electrode interface in the time period, sodium ion microscopic distribution is regulated and controlled through the acoustic streaming effect, contact stress is dredged, dendritic crystal early nucleation is inhibited, dynamic reconstruction and optimization of the interface state are achieved, the solid-state sodium-electricity interface is converted into dynamic self-adaption from static mismatch, the ion transmission uniformity is actively maintained through the acoustic streaming effect, and dynamic reconstruction and optimization of the interface state are achieved. And meanwhile, real-time sensing of an interface state and dynamic adjustment of acoustic vibration parameters are realized in combination with an acoustic probing mechanism, so that the interface stability and dendritic crystal inhibition capability are effectively improved, and the energy conversion efficiency and the safety performance of the battery are remarkably enhanced.

The invention discloses a sulfide-based composite solid-state electrolyte, a preparation method thereof and a lithium metal solid-state battery, sulfide is subjected to specific bifunctional surface grafting modification by using a silane coupling reagent with sulfydryl and epoxy bonds, then the sulfide is introduced into a polymer precursor liquid, and the sulfide-based composite solid-state electrolyte is prepared through light-heat curing reaction synergy. A flexible and rigid cross-linked network is formed, the sulfide-based composite solid-state electrolyte with high ionic conductivity and high mechanical strength is obtained, the interface stability of the sulfide-based composite solid-state electrolyte in the charge-discharge process is ensured, for example, the sulfide-based composite solid-state electrolyte in the embodiment 1 has high ionic conductivity (3.81 mS / cm), and the interface stability of the sulfide-based composite solid-state electrolyte in the embodiment 2 is ensured. The lithium-lithium symmetric battery prepared by the method has the advantages of excellent flexibility, high tensile strength (7.9 Mpa) and wide electrochemical window (5.1 V), the lithium-lithium symmetric battery can stably circulate for 2000h, and the whole battery can stably circulate for 2000 circles at the room temperature at the rate of 4C, so that the lithium-lithium symmetric battery has great industrial application value.

The invention relates to a composite solid electrolyte and a preparation method and application thereof. The preparation method of the composite solid electrolyte comprises the following steps: S1, mixing an inorganic filler and a fluorine-containing compound, and reacting at 70-90 DEG C under an acidic condition to obtain an inorganic filler wrapped by a fluorinated layer; then adding a fluorine ion complexing agent and a silane coupling agent for reaction to obtain a modified filler; adding a thermal decomposition type cross-linking agent into the polymer, and carrying out melt blending to obtain a cross-linked polymer; s2, uniformly mixing the modified filler, a cross-linked polymer, a lithium salt and a solvent to obtain a plurality of slurries containing the modified filler with different volume concentrations; and molding the slurry to prepare the composite solid electrolyte. According to the method, the fluorinated layer and the siloxane network are constructed step by step, so that the interface impedance is reduced, and efficient dissociation of the lithium salt is promoted; a three-dimensional network structure is combined, so that the tensile strength is improved; the modified filler is further designed in a gradient manner to improve the lithium ion transference number.

The invention relates to a preparation technology of a gel polymer lithium ion battery cell electrolyte, and belongs to the field of battery preparation technologies, the preparation technology comprises the following steps: mixing methacrylate monomers and silane monomers according to a mass ratio of 3: 1-5: 1, adding 1-3% of an initiator, and carrying out prepolymerization at 60-80 DEG C for 1-3 h to prepare a prepolymer solution; mixing with a non-aqueous solvent containing lithium hexafluorophosphate according to a mass ratio of (1: 4)-(1: 6) to form a precursor mixed solution, and controlling the injection rate to be 1.5-2.5 g / Ah to a gap between a battery cell pole piece and a diaphragm; after standing for 2-4 hours at the vacuum degree of less than or equal to-0.08 MPa, curing for 3-6 hours at the temperature of 60-70 DEG C to form a gel polymer electrolyte; the wettability is improved through pole piece surface hydrophilic treatment, 1-5% of vinylene carbonate is added to optimize an SEI film, the prepolymerization temperature fluctuation is controlled to be smaller than or equal to + / -2 DEG C through microwave-assisted heating, the pressure of 0.2-0.5 MPa is applied after injection to promote uniform permeation, a polyvinylidene fluoride coating of 5-10 microns is coated after curing to enhance protection, and the interface performance is ensured through an alternating-current impedance test.

The invention relates to a composite diaphragm with high ionic conductivity, a composite solid electrolyte and a preparation method thereof. The composite diaphragm is composed of a lithium lanthanum-based fluorine-doped solid electrolyte LLMOF and a base membrane, the chemical general formula of the LLMOF is Li < x > La < y > M < 1 > < z > M < 2 > < w > M < 3 > O < 6 > F, wherein M1 is a tetravalent cation, M2 is a pentavalent cation, and M3 is a hexavalent cation; 1 < x + 3y < 5, 0 < x < = 2, and 1 / 3 < y < 5 / 3; 0 < = z < = 2, 0 < = w < = 2, 0 < = u < = 2, z + w + u = 2; the base membrane is a large-aperture base membrane, and the aperture r is more than or equal to 200nm and less than or equal to 1mu m; the particle size D50 of the LLMOF is 50 nm to 1 [mu] m, and the particle size D50 of the LLMOF is less than or equal to the aperture r of the base film. According to the composite diaphragm disclosed by the invention, the LLMOF solid electrolyte with an ion channel function is introduced, so that efficient conduction of ions is realized; the particle size is matched with that of a large-aperture base membrane, the membrane can be uniformly embedded into membrane holes, a continuous conduction path is constructed, and the ionic conductivity is improved; meanwhile, the composite diaphragm has excellent thermal stability and interface wettability, interface impedance is effectively reduced, and growth of lithium dendrites is inhibited.

The invention relates to the technical field of polymer electrolyte, in particular to a self-repairing type gel polymer electrolyte membrane, a preparation method and application in an energy storage battery, the self-repairing type gel polymer electrolyte membrane is prepared by the following steps: dissolving amino-terminated polyethylene glycol in an organic solvent, adding trimesic acid under the protection of an inert atmosphere, heating, stirring and reacting to form a pre-polymerized solution, cooling, and then adding trimesic acid into the pre-polymerized solution to prepare a self-repairing type gel polymer electrolyte membrane; the preparation method comprises the following steps: adding glyoxylic acid and glacial acetic acid, carrying out a constant temperature reaction to obtain a solution A, adding LiTFSI into the solution A, carrying out ultrasonic dispersion to a homogeneous phase, pouring the obtained slurry onto a template, and carrying out a drying curing reaction to obtain the self-repairing gel polymer electrolyte membrane. A rigid aromatic cross-linking agent is used for inhibiting polymer crystallization and improving mechanical integrity, an imine bond-based dynamic covalent network is introduced to realize an autonomous interface repairing function at the working temperature of the battery, and meanwhile, a polyethylene glycol ether oxygen chain is used for constructing an efficient lithium ion transmission channel; therefore, the technical boundary that the conductivity, the mechanical strength and the interface stability of the traditional GPE are difficult to collaboratively optimize is broken through.

The invention discloses a high-modulus leather / eutectic gel composite electrolyte and a preparation method and application thereof, and belongs to the technical field of energy storage. The preparation method comprises the following steps: 1) preparing a eutectic gel solution containing polyvinyl alcohol, zinc salt, small molecular polyol and water; 2) carrying out vacuum impregnation to obtain leather fibers containing a eutectic gel solution; and (3) obtaining the leather / eutectic gel composite electrolyte with the imitated reinforcing steel bar-concrete structure through freeze-thaw circulation.The composite electrolyte effectively solves the problem that an existing gel electrolyte is low in modulus and difficult to effectively deal with extreme mechanical deformation, and the cycle life of the water-based zinc ion battery is remarkably prolonged.

The system for deicing black ice includes a plurality of laser scanners that are arranged at intervals along a road, each laser scanner including a light source unit, a non-contact temperature sensor, and a control unit that controls an operation of radiating the laser to the area in charge, a weather sensor that measures a temperature and humidity, and an integrated controller that communicates with the plurality of laser scanners. The integrated controller determines whether the laser is radiated to the road surface based on at least one of the measured temperature and humidity, and when the laser radiation is determined, generates a control signal to activate at least one laser scanner, and the control unit determines a heating area, and generates a pulse signal to turn on / off a light source unit so that the laser is radiated in accordance with a shape and range of the heating area.

The invention belongs to the technical field of batteries, and provides a battery cell structure and a manufacturing method and application thereof, the manufacturing method comprises the following steps: forming a plurality of positive electrode insulation partitions arranged at intervals on a to-be-coated surface of a positive electrode current collector, and forming a positive electrode active layer in an area between every two adjacent positive electrode insulation partitions to obtain a positive electrode roll; and unwinding the positive electrode insulation partition, a negative electrode roll and a solid electrolyte membrane roll, carrying out rolling compounding to obtain a composite electrode roll, and cutting the positive electrode insulation partition to obtain the battery cell structure. The positive electrode insulation partition can insulate the periphery of the positive electrode active layer with a smaller area, can compensate the size difference of the positive electrode and the negative electrode, and provides support for the negative electrode in the subsequent rolling compounding process, so that the sizes of the positive electrode and the negative electrode are consistent, and the problem of short circuit caused by edge shearing stress during pressure application is solved; roll-in compounding can effectively improve densification and improve electrolyte interface contact, and the manufacturing method is simple, convenient, economical, efficient and suitable for mass production.

The invention belongs to the field of battery materials, and discloses a PEO-based composite solid electrolyte and a preparation method and application thereof, the PEO-based composite solid electrolyte comprises double transition metal-based pyrophosphate, PEO and an electrolyte lithium salt; wherein the molecular formula of the double transition metal-based pyrophosphate is MaNb (P2O7) c, M is any one or two of Fe and V, N is any one or two of Pb and Cd, a is greater than or equal to 1 and less than or equal to 2, b is greater than or equal to 1 and less than or equal to 5, and c is greater than or equal to 1 and less than or equal to 4. By applying the double-transition-metal-based pyrophosphate to the solid electrolyte, the suitability of the solid electrolyte and a positive electrode material with the charging cut-off voltage of 4V or above is improved, and the application range of the solid electrolyte in a battery system with high energy density and long cycle life and a functional energy storage device is widened; and the electrochemical capacity, the structural stability and the ionic conductivity of the battery can be improved.

The invention discloses a composite solid electrolyte and a preparation method and application thereof, and belongs to the technical field of solid lithium batteries. The composite solid electrolyte comprises a polymer matrix, a lithium salt and a lithium ion modified ionic metal organic framework (MOF) material. The metal center of the ion-conducting MOF material can be selected from Zr, Ti, Hf and the like, and the organic ligand can be selected from organic acids containing sulfydryl, sulfo groups and the like. The MOF material can effectively inhibit crystallization of a polymer matrix and increase the proportion of an amorphous region, Lewis acid sites on the surface of the MOF material can promote dissociation of lithium salt, and a lithium ion coordination channel formed in the MOF material can provide an extra rapid transmission path for lithium ions. When the electrolyte is applied to the solid-state lithium battery, the growth of lithium dendrites can be effectively inhibited, and the rate capability, the cycling stability and the safety of the battery can be remarkably improved.

The invention discloses a manufacturing process for a gel electrolyte battery. The process comprises the following steps: adding an initiator to an electrolyte containing 0-8% of a polymer monomer during battery injection; adding a liquid electrolyte until the interface of the gel electrolyte and the interface of the electrode are in full contact after the electrolyte undergoes a curing process to form a gel electrolyte and undergoes a chemical formation process; and allowing the process to stand for subsequent processes. The curing process involves curing the electrolyte into a gel electrolyte under high-temperature pressurized conditions or high-temperature conditions; and the chemical formation process is performed after the electrolyte has been cured into the gel electrolyte. Compared with the prior art, the present invention utilizes a secondary injection and intermediate curing method to reasonably complete the gelation of the electrolyte and realize the function of the gel electrolyte while ensuring battery performance, while optimizing the electrode interface, thereby ensuring battery performance and improving battery safety.

The invention provides a safe flame-retardant gel electrolyte and a lithium ion battery. The gel electrolyte is obtained by heating, cross-linking and polymerizing a gel electrolyte solution; the gel electrolyte comprises a basic electrolyte, a gel polymerization monomer, a cross-linking agent and an initiator; the basic electrolyte comprises a lithium salt, an organic solvent and an additive; the gel polymerization monomer comprises a phosphorus-containing flame-retardant monomer and a fluorine-containing flame-retardant monomer. Aiming at the pain point of the current liquid electrolyte, a phosphorus-containing flame-retardant element and a fluorine-containing flame-retardant element are innovatively introduced by forming the gel electrolyte through an in-situ polymerization means, so that the two-element synergistic flame retardance and the electrochemical performance are considered, and the defect that the electrochemical performance is reduced due to the introduction of a flame-retardant additive into the existing gel electrolyte is overcome; the compatibility of the gel electrolyte and the electrode is improved, the safety performance of the battery is enhanced, and the cost is reduced.

The invention relates to a sulfide composite solid-state electrolyte membrane, a preparation method thereof and a solid-state battery, and belongs to the technical field of solid-state electrolyte materials. The preparation method comprises the following steps: mixing a component A, a component B and a solvent under anhydrous and anaerobic conditions, and carrying out a heating reaction to obtain a precursor solution containing a high-molecular polymer; mixing the sulfide solid electrolyte with the precursor solution, and adding a solvent to adjust the solid content to 25-60% to obtain electrolyte slurry; coating the electrolyte slurry on the surface of a base material, drying to form a film on the surface of the base material, and removing the base material to obtain a sulfide composite solid electrolyte film; wherein the mass ratio of the effective components in the sulfide solid electrolyte to the effective components in the precursor solution is (99.5-90): (0.5-10). The sulfide composite solid electrolyte membrane has relatively good flexibility, and good contact between the membrane and an electrode can be maintained, so that the interface resistance is reduced.

According to the lithium battery and the preparation method thereof provided by the invention, dual mechanisms of free radical polymerization and ring-opening polymerization are combined, a stable double-crosslinking structure gel electrolyte constructed by two polymers can be obtained in an in-situ polymerization process, and the mechanical strength and the thermal stability are improved; by regulating and controlling the ratio of an epoxy monomer to an acrylate monomer, firstly, room-temperature ring-opening polymerization is performed, so that part of in-situ gel is formed before formation, smooth formation of a gel interface is ensured, the first coulombic efficiency of the battery is not influenced, and meanwhile, the dosage of the acrylate monomer and a corresponding thermal initiator is reduced; high-temperature treatment is carried out after formation, so that the interface aging of the battery is stable, the cycle life of the battery is prolonged, the acrylate monomers are polymerized, the high temperature continues to promote the polymerization of the residual epoxy monomers, the polymerization conversion rate is favorably increased, and the high-pressure resistance and oxidative decomposition resistance of the gel electrolyte are improved.

The invention relates to a surface-coated oxide solid electrolyte and a preparation method thereof, the surface-coated oxide solid electrolyte comprises an oxide electrolyte and a surface coating layer, the chemical formula of the oxide solid electrolyte is Li7-xLa3Zr2MxO12-x (M = Ta, Nb, Hf, Ge, Sc, Ti, Al, Si, Sn, Y, 0 < = x < = 1), the chemical formula of the surface coating layer is LiXON (R = Ta, Nb, Al, Zr, Ga, In, N = F, Cl, Br, I), and a lithium source, a lanthanum source, a zirconium source, an M source, an X source and an N source, or an XN source are connected in series, garnet solid electrolyte powder with a stable surface coating layer is obtained by adopting a solid phase method or a sol-gel method and combining a low-temperature calcination process; and then mixing and reacting with a lithium salt and a polymer electrolyte, and pouring the obtained slurry on a polyfluortetraethylene plate to prepare the composite electrolyte. Compared with the prior art, the high-ion conductor layer formed on the surface of the product in situ constructs a rapid transmission channel for lithium ion transmission in the composite electrolyte, and high ion conductivity is achieved.

The invention discloses a composite solid electrolyte layer, a preparation method and application, the composite solid electrolyte layer comprises a porous membrane laminated on a negative pole piece, and pores in the porous membrane and gaps between the porous membrane and the negative pole piece are filled with in-situ generated polymers. Inorganic solid electrolyte is also dispersed in the porous membrane, and lithium salt is dispersed in the polymer and the porous membrane. The composite solid electrolyte layer is obtained through in-situ polymerization of a polymer in pores in the porous membrane and gaps between the porous membrane and the negative electrode plate, and a novel interface structure with the electrode-electrolyte integration characteristic is constructed. By adopting a collaborative optimization strategy of a polymer matrix and inorganic filler double-crosslinking network system and an interface stable layer, the volume effect problem of a silicon-based negative electrode, the electrolyte interface impedance problem and the battery safety problem can be solved at the same time, so that the cycling stability and the rate capability of the lithium ion battery are remarkably improved.

The invention relates to a self-repairing ionic gel electrolyte, a zinc ion battery and a preparation method and application of the self-repairing ionic gel electrolyte and the zinc ion battery. The ionic gel electrolyte comprises a polymer network, ionic liquid (1-ethyl-3-methylimidazolium tetrafluoroborate) and movable zinc ions, the polymer network is obtained through a reaction of an anionic monomer 2-acrylamido-2-methyl sodium propanesulfonate and a cationic monomer acryloyloxyethyl trimethyl ammonium chloride, and the movable zinc ions are provided by a zinc tetrafluoroborate hydrate. The zinc ion battery takes the ionic gel as an electrolyte, and a positive film electrode and a negative film electrode are arranged on two sides of the ionic gel. Compared with the prior art, the material not only has excellent mechanical properties and efficient ion transmission capability, but also has the capability of quickly repairing mechanical damage, and the completely broken material can be completely repaired after being contacted for 10 seconds under infrared light irradiation. The prepared zinc ion battery has excellent self-repairing performance, flexible performance and electrochemical performance.

The invention discloses a lithium ion battery, a preparation method thereof and a lithium ion battery module. The lithium ion battery comprises a positive electrode, a first solid electrolyte membrane and a negative electrode which are sequentially stacked in the thickness direction, the lithium ion battery also comprises a second solid electrolyte membrane; the second solid electrolyte membrane is positioned between the positive electrode and the first solid electrolyte membrane; wherein the second solid electrolyte membrane is provided with a plurality of first through holes, and the first through holes are filled with a positive electrode lithium supplement agent. The lithium ion battery disclosed by the invention is provided with the double-layer composite solid electrolyte membrane, and the positive electrode lithium supplementing agent is filled in the through hole formed in the solid electrolyte membrane in contact with the positive electrode, so that active lithium consumed when the lithium ion battery is charged for the first time can be effectively supplemented, the total capacity and the energy density of the lithium ion battery are improved, and the cycle life of the lithium ion battery is prolonged.

A polymer-forming electrolyte can include polymer precursor(s), optional additive(s) (e.g., plasticizers; initiator; inhibitor; performance additives and / or safety additives such as nonflammable additives, flame-retardant additives, redox shuttle additives, SEI-forming additives, SEI-stabilizing additives, self-closing electrolyte additives, etc.; etc.), solvent(s) (e.g., polar solvent; salt-dissolving solvent; salt-coordinating solvent; diluent; safety solvent such as nonflammable solvent, noncombustible solvents, etc.; etc.), and / or salt(s). In some variants, the polymer-forming electrolyte can be cured (e.g., within a battery cell) to form a gel-electrolyte (e.g., between an anode and cathode of the battery cell, interspersed within the anode and the cathode, etc.).

The invention belongs to the technical field of electrolyte materials, and particularly relates to a pH response biopolymer solid electrolyte as well as a preparation method and application thereof. The pH-responsive degradable biopolymer is taken as a main raw material, and one or more functional groups such as pyridine, sulfonic acid, carboxyl, tertiary amine, phosphoric acid and the like are contained. The organic acid and the organic acid salt are selected to adjust the pH value of a medium around the electrolyte, and the contraction / stretching behavior of a molecular chain is influenced by changing the ionization degree of the electrolyte, so that an interpenetrating polymer network structure is formed. The polar functional group of the biopolymer affects the migration behavior of lithium ions under different pH conditions, so that the migration rate and migration quantity of the lithium ions are increased, and the cycle performance of the battery is improved. The electrolyte is suitable for high-performance energy storage devices such as a lithium ion battery, can effectively improve the battery performance, reduces the environmental pollution, and has relatively strong green and environment-friendly advantages.

The invention belongs to the technical field of polymer electrolyte membrane materials, and particularly relates to a high-ionic-conductivity polymer electrolyte membrane and a preparation method thereof.The preparation method comprises the steps that 1, PEO and lithium salt are added into a polar aprotic solvent, and the mixture is rapidly and violently stirred to be completely dissolved; (2) adding a cross-linking agent and a photoinitiator into the mixed solution, and violently stirring to obtain a mixed solution; and (3) coating the mixed solution in a polytetrafluoroethylene template, heating to remove the solvent, and performing ultraviolet radiation. According to the invention, a three-dimensional cross-linked network is formed by photocuring of an acrylate group of the cross-linking agent, PEO chain segment crystallization is inhibited, and lithium salt anions (such as TFSI-) are physically embedded. A benzene ring structure in a cross-linked network endows the electrolyte membrane with flexibility, mechanical property deterioration caused by a plasticizer or a diluent is avoided, the compact structure of the electrolyte membrane can inhibit lithium dendrite growth, the ionic conductivity reaches 1.7 * 10 <-4 > S / cm, and the electrochemical window reaches 4.9 V. The method is simple in process and suitable for large-scale preparation of the high-energy-density solid-state lithium battery.

The invention discloses a lithium metal battery eutectic gel electrolyte and a preparation method and application thereof, and belongs to the field of solid electrolyte. The eutectic gel electrolyte is prepared by carrying out a photocuring reaction on a photocuring precursor solution containing a photoinitiator, and the photocuring precursor solution contains a bi-component liquid compound and a deep eutectic solvent; the two-component liquid compound comprises 4-acryloyl morpholine and a photocurable polyethylene glycol derivative; the deep eutectic solvent is formed from a liquid mixture comprising succinonitrile, lithium bis (trifluoromethylsulfonyl) imide and fluoroethylene carbonate. The eutectic gel electrolyte is composed of a deep eutectic solvent with functional groups such as cyano and sulfonyloxy, and a polymer electrolyte with functional groups such as ether oxygen and a unique skeleton structure. The advantages of high ionic conductivity, wide electrochemical window, high interface stability and the like can be endowed based on the interaction between functional groups and the space confinement effect of a polymer electrolyte skeleton structure.

The invention relates to a composite solid-state electrolyte membrane and a preparation method thereof, a lithium ion battery and an electric device, the composite solid-state electrolyte membrane comprises a lithium phosphorus oxygen nitrogen solid-state electrolyte, the general formula of the lithium phosphorus oxygen nitrogen solid-state electrolyte is LixPOyNz, x is greater than 2.7 and less than or equal to 3, zlt; 0.45, 3 < (y + z) < 4; along the thickness direction of the solid electrolyte membrane, the nitrogen doping ratio of the lithium-phosphorus-oxygen-nitrogen solid electrolyte in the composite solid electrolyte membrane is gradually increased, and the corresponding oxidation stoichiometric number is gradually reduced. According to the composite solid electrolyte membrane, the capacity retention ratio, the cycling stability and the safety of the lithium ion battery are improved.

The invention belongs to the technical field of lithium metal batteries, and relates to preparation of an ultrathin polymer electrolyte with a wide electrochemical window and application of the ultrathin polymer electrolyte in a solid-state lithium metal battery, a preparation method comprises the following steps: firstly, coating a substrate with polymer slurry, and then soaking, stripping and drying to obtain a porous membrane matrix; the preparation method comprises the following steps: mixing an electrolyte, a conductive lithium salt, a cross-linking agent, 4-fluorine-alpha-methyl styrene and an initiator to obtain an electrolyte precursor solution; and then supporting the electrolyte precursor liquid on the porous membrane substrate, and carrying out in-situ polymerization and curing to obtain the polymer electrolyte. Compared with the prior art, the thickness of the polycarbonate solid electrolyte is 7.8 microns, and the polycarbonate solid electrolyte shows high room-temperature ionic conductivity, a wide electrochemical window and excellent dendritic crystal resistance. And the corresponding 4.5 V high-voltage LiLCO solid-state battery can stably circulate for 1500 circles at room temperature. The electrolyte is ultrathin, the preparation process is simple, the scale is easy to enlarge, and the electrolyte shows a good practical application prospect.

The invention provides a gradient composite solid electrolyte, a preparation method and an in-situ interface repair structure, and belongs to the field of semi-solid / solid-liquid hybrid power batteries. The gradient composite solid electrolyte comprises a flexible polymer layer, a composite layer and a nano-porous layer, the composite layer is located between the flexible polymer layer and the nano-porous layer, and the Young modulus of the flexible polymer layer, the Young modulus of the composite layer and the Young modulus of the nano-porous layer are sequentially increased in a gradient mode. By adopting the gradient increasing design of Young modulus of the flexible layer, the composite layer and the nano porous layer, the thermal expansion coefficient of the structure is matched with that of a silicon negative electrode and a high-nickel positive electrode, so that the cyclic stress dispersion efficiency is improved, and the expansion of interface cracks is effectively inhibited; and finally, the problem of interface failure caused by dynamic stress mismatch between the composite solid electrolyte and the electrode in the semi-solid / solid-liquid hybrid power battery is solved.

The embodiment of the invention provides an electrolyte, a battery and electric equipment, the electrolyte comprises a lithium salt, an organic solvent and a polymer matrix, and monomers of the polymer matrix comprise vinylene carbonate and isocyanate ethyl acrylate. In the electrolyte provided by the embodiment of the invention, the monomers of the polymer matrix comprise vinylene carbonate and isocyanate ethyl acrylate, and the low HOMO energy level of isocyanate ethyl acrylate can weaken the electron loss ability of the polymer matrix and improve the oxidation stability of the electrolyte, so that the relatively poor electrochemical stability is improved; and a copolymerization structure of vinylene carbonate and isocyanate ethyl acrylate reduces the crystallinity of a polymer matrix and provides a smoother path for Li < + > transmission, so that the ionic conductivity of the electrolyte is improved. Therefore, the electrolyte provided by the invention can effectively improve the problems of low room-temperature ionic conductivity and relatively poor electrochemical stability of the existing gel electrolyte, and has a good application prospect.

The invention belongs to the technical field of lithium ion solid-state batteries, and relates to a composite polymer electrolyte membrane as well as a preparation method and application thereof. The preparation method of the composite polymer electrolyte membrane comprises the following steps: generating a precursor salt containing Ba and Ti on the surface of an inorganic solid electrolyte through a wet chemical method, and forming a compact barium titanate coating layer on the surface of the electrolyte in a high-temperature calcination process to obtain the barium titanate surface modified inorganic solid electrolyte; uniformly dissolving a high-molecular polymer material, the barium titanate surface modified inorganic solid electrolyte and a lithium salt in a solvent, heating and stirring to prepare a uniform solution; and drying to form a membrane to obtain the polymer composite electrolyte membrane. Barium titanate has a special piezoelectric property and can be spontaneously polarized in a crystal structure to generate a polarization field, and the polarization field can sensitively sense the nonuniformity of lithium ion transmission dynamics and interact with the nonuniformity to balance the transmission process of lithium ions in the solid electrolyte, so that the bottleneck problem of ion migration in the traditional electrolyte is solved.