2128results about "Electrolyte immobilisation/gelification" patented technology

The invention relates to the technical field of solid-state lithium batteries, in particular to a cellulose acetate modified PEO-based solid-state electrolyte membrane, a solid-state lithium battery and a preparation method thereof.The preparation method comprises the steps that lithium bis (trifluoromethanesulfonyl) imide, cellulose acetate and polyethylene oxide are dissolved in a solvent, and a mixed solution is obtained; and curing the mixed solution in a mold to obtain the cellulose acetate modified PEO-based solid electrolyte membrane. According to the invention, the cellulose acetate is introduced to modify the polyethylene oxide solid electrolyte, and the prepared cellulose acetate modified PEO-based solid electrolyte membrane can generate a stable solid electrolyte interface rich in Li2O and LiF on the surface of a lithium negative electrode in situ in the application of a solid lithium battery, so that the growth ability of lithium dendrites is effectively inhibited, and the performance of the lithium battery is improved. The interface impedance is reduced, and the operating temperature range of the solid-state lithium battery is widened.

The invention discloses a difunctional filler synergistically enhanced polymer solid electrolyte and a solid-state battery, and belongs to the field of solid-state batteries. The electrolyte adopts a polymer matrix, a lithium salt and two functional fillers: the first filler has a high dielectric constant, and can accelerate dissociation of the lithium salt, fix negative ions of the lithium salt and improve the transference number of lithium ions under the action of self polarization; and the second filler has high electrochemical window and ionic conductivity, can inhibit high-voltage decomposition, and is adaptive to a high-voltage positive electrode material. Through cooperation and balance design of the two kinds of filler, ion transmission, interface stability and high-pressure compatibility can be considered at the same time. In addition, the invention further designs a composite negative pole piece, the surface of the negative pole piece is coated with the solid electrolyte, and the ion transmission kinetics in the pole piece can be remarkably improved. On the basis, the invention develops a high-performance solid-state battery which is excellent in electrochemical performance and can play an important role in the fields of consumer electronics, electric automobiles, energy storage systems, low-altitude flight and the like.

The invention discloses a solid electrolyte membrane and a preparation method and application thereof. The solid electrolyte membrane comprises a first electrolyte close to the positive pole piece and a second electrolyte layer close to the negative pole piece. The first electrolyte layer comprises a polymer, a lithium salt and an additive, and the second electrolyte layer comprises a solid electrolyte, a polymer, a lithium salt and an additive. The first electrolyte layer has a wide electrochemical window and relatively high mechanical properties, and can be matched with a high-voltage positive electrode material and improve solid-solid interface contact. The solid electrolyte of the second electrolyte layer is mainly composed of a continuous vertical array micro-mesoporous material, has a micro-mesoporous structure and high surface adsorption energy, and can accelerate lithium salt dissociation, reduce molecular interaction between polymer chains, form a three-dimensional continuous fast ion transmission channel and a heat conduction network, and improve ionic conductivity and safety performance. The solid electrolyte membrane disclosed by the invention has excellent ionic conductivity, wide electrochemical window, high safety performance and excellent electrochemical performance.

The invention discloses a preparation method of a lithium-phosphorus-sulfur-bromine solid-state electrolyte, and relates to the technical field of solid-state lithium batteries. The material is subjected to raw material pretreatment, mechanochemical ball milling, high-temperature crystallization treatment and post-treatment processes, so that the solid electrolyte with high crystallinity, high ionic conductivity and good processability is obtained. According to the method, dynamic bromine atmosphere control is adopted, sulfur partial pressure adjustment and particle size gradient design are combined, and the structural stability and the ion transmission performance of the material are improved.

The invention discloses a preparation method and application of a sulfide solid electrolyte membrane based on a gradient polymer / ionic liquid composite binder, and an all-solid-state battery, and belongs to the technical field of all-solid-state batteries. The method comprises the following steps: firstly coating a polymer / ionic liquid / sulfide electrolyte composite layer through a gradient coating process, filling particle gaps under low pressure by utilizing the plasticizing effect of ionic liquid, and reducing the porosity of an interface; and then coating a polymer / sulfide electrolyte surface layer to provide mechanical support and inhibit side reaction of the electrode. According to the design, the electrolyte membrane still keeps high ionic conductivity under the working pressure of a commercial power battery module, and the interface impedance is reduced compared with that of a traditional homogeneous membrane. Through the innovative gradient structure and material combination, the ion transmission bottleneck of the sulfide electrolyte under the low-pressure condition is solved, excellent interface stability and process compatibility are achieved, and a key technical scheme is provided for all-solid-state battery industrialization.

A solid electrolyte material and a preparation method therefor, a solid electrolyte, a semi-solid electrolyte, a positive electrode, and a battery. The solid electrolyte material comprises a compound represented by the following general formula: Aa(M1bM2c)Xd, wherein A comprises one or more of Li, Na, K, Cu and Ag, X is halogen, M1 is a main element, M1 is selected from among one of Ga, Y, In, Mg, Sr, Sc, Al, Fe, Zr, Hf, Ta, Nb, W, Mn, Zn, Co, Mo, Sn, Ca, Pb, Ti, Ru and a lanthanide metal element, M2 is a doping element, M2 comprises one or more elements of groups IIA, IIB, IIIA, IIIB, IVA, IVB, VA and VB, b is greater than the molar ratio of any element in M2, 0.5≤a≤5, 0.2≤b≤2, 0.2≤c≤2, d=a*ε1+b*ε2+c*ε3, ε1 is the weighted average valence of A, ε2 is the weighted average valence of M1, and ε3 is the weighted average valence of M2.

The invention relates to the technical field of all-solid-state lithium metal batteries, in particular to a cellulose paper-based polymer solid electrolyte as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing N-methylacetamide and lithium bis (trifluoromethanesulfonyl) imide to obtain a eutectic solvent; the preparation method comprises the following steps: mixing a eutectic solvent, polyethylene glycol oxalate, acrylamide and a thermal initiator to obtain a eutectic polymer electrolyte precursor; and soaking cellulose paper in the eutectic polymer electrolyte precursor, and carrying out hot-pressing polymerization to obtain the cellulose paper-based polymer solid electrolyte. The cellulose paper-based polymer solid electrolyte prepared by the invention is soft in texture and can be better attached to an electrode, the problem of poor contact between the electrode and an electrolyte interface is solved, and the interface impedance is reduced by fusing the characteristics of low viscosity and high conductivity of the eutectic solvent and the supporting effect of the cellulose paper; the ion transmission efficiency is improved, and conditions are provided for long-term stable circulation of the battery.

The invention provides a composite solid electrolyte and a preparation method thereof, and belongs to the technical field of solid electrolyte materials. The solid electrolyte powder, the photosensitive resin monomer, the lithium salt, the plasticizer and the photoinitiator are used as raw materials to prepare the composite solid electrolyte, the plasticizer can be inserted between polymer chains, the compatibility of the solid electrolyte powder and a polymer is improved, electrode interface contact is improved, the flexibility of the composite solid electrolyte is improved, and the service life of the composite solid electrolyte is prolonged. The ionic conductivity of the composite solid electrolyte is further improved; the photosensitive resin monomer and the photoinitiator can be subjected to photopolymerization in-situ curing, so that the composite solid electrolyte has better mechanical property and flexibility, electrode interface contact is improved, and the ion conductivity is improved.

The invention provides an aerogel reinforced composite electrolyte thin film for a solid-state lithium battery and a preparation method of the aerogel reinforced composite electrolyte thin film, and belongs to the technical field of composite electrolytes.The thin film comprises a three-dimensional porous aerogel skeleton, a solid-state electrolyte compound and lithium salt nanocrystals; wherein the three-dimensional porous aerogel skeleton is prepared from inorganic oxide nanoparticles and a polymer precursor through a sol-gel method; pores of the three-dimensional porous aerogel skeleton are filled with the solid electrolyte compound, the solid electrolyte compound comprises lithium lanthanum zirconium oxide nanowires and a polyoxyethylene-lithium salt composite matrix, and the lithium lanthanum zirconium oxide nanowires are directionally arranged in the thickness direction of the film; the lithium salt nanocrystals grow on the surface of the pore wall of the three-dimensional porous aerogel in situ; the mass ratio of the aerogel skeleton to the solid electrolyte compound is (1: 3)-(1: 15). According to the thin film, the ionic conductivity, the mechanical strength and the interface stability of the electrolyte are remarkably improved.

The invention discloses a multi-effect flame-retardant in-situ gel polymer electrolyte and application thereof. The electrolyte is a gel polymer electrolyte with a three-dimensional network structure prepared from a first flame retardant, a second flame retardant, a cross-linking agent, an initiator and a liquid electrolyte in situ, the first flame retardant is an acrylate liquid-phase monomer containing a phosphorus element, and the content of the first flame retardant accounts for 1-4wt% of the total mass of the electrolyte; the second flame retardant is an acrylate liquid-phase monomer containing a fluorine element, and the content of the second flame retardant accounts for 1-4wt% of the total mass of the electrolyte; the content of the cross-linking agent accounts for 1-2wt% of the total mass of the electrolyte; the content of the initiator accounts for 0.05-1wt% of the total mass of the electrolyte; and the balance is liquid electrolyte. According to the invention, the flame retardant is effectively constructed on a three-dimensional network skeleton, so that the flame-retardant effect of the gel polymer electrolyte is enhanced under the synergistic effect of phosphorus and fluorine while the electrochemical performance is not sacrificed.

The invention relates to the technical field of solid-state battery energy conversion, and discloses a high-safety sodium-ion battery energy conversion method based on a solid-state electrolyte, which comprises the following steps: identifying an interface dynamic mismatch risk time period in a charging and discharging process, and applying micro-amplitude high-frequency acoustic vibration disturbance to a solid-state electrolyte and a sodium negative electrode interface in the time period, sodium ion microscopic distribution is regulated and controlled through the acoustic streaming effect, contact stress is dredged, dendritic crystal early nucleation is inhibited, dynamic reconstruction and optimization of the interface state are achieved, the solid-state sodium-electricity interface is converted into dynamic self-adaption from static mismatch, the ion transmission uniformity is actively maintained through the acoustic streaming effect, and dynamic reconstruction and optimization of the interface state are achieved. And meanwhile, real-time sensing of an interface state and dynamic adjustment of acoustic vibration parameters are realized in combination with an acoustic probing mechanism, so that the interface stability and dendritic crystal inhibition capability are effectively improved, and the energy conversion efficiency and the safety performance of the battery are remarkably enhanced.

The invention provides a bipolar battery and an electric device. The bipolar battery comprises n stacked bipolar electrodes, wherein n is greater than 1; each bipolar electrode comprises a current collector, a positive electrode and a negative electrode; the positive electrode film layer is arranged on one side of the current collector, the side, provided with the positive electrode film layer, of the current collector is a positive electrode side, and the side, opposite to the positive electrode side, of the current collector is a negative electrode side; and a negative electrode film layer or a conductive layer is optionally arranged on the negative electrode side.

The invention discloses a sulfide-based composite solid-state electrolyte, a preparation method thereof and a lithium metal solid-state battery, sulfide is subjected to specific bifunctional surface grafting modification by using a silane coupling reagent with sulfydryl and epoxy bonds, then the sulfide is introduced into a polymer precursor liquid, and the sulfide-based composite solid-state electrolyte is prepared through light-heat curing reaction synergy. A flexible and rigid cross-linked network is formed, the sulfide-based composite solid-state electrolyte with high ionic conductivity and high mechanical strength is obtained, the interface stability of the sulfide-based composite solid-state electrolyte in the charge-discharge process is ensured, for example, the sulfide-based composite solid-state electrolyte in the embodiment 1 has high ionic conductivity (3.81 mS / cm), and the interface stability of the sulfide-based composite solid-state electrolyte in the embodiment 2 is ensured. The lithium-lithium symmetric battery prepared by the method has the advantages of excellent flexibility, high tensile strength (7.9 Mpa) and wide electrochemical window (5.1 V), the lithium-lithium symmetric battery can stably circulate for 2000h, and the whole battery can stably circulate for 2000 circles at the room temperature at the rate of 4C, so that the lithium-lithium symmetric battery has great industrial application value.

The invention relates to a composite solid electrolyte and a preparation method and application thereof. The preparation method of the composite solid electrolyte comprises the following steps: S1, mixing an inorganic filler and a fluorine-containing compound, and reacting at 70-90 DEG C under an acidic condition to obtain an inorganic filler wrapped by a fluorinated layer; then adding a fluorine ion complexing agent and a silane coupling agent for reaction to obtain a modified filler; adding a thermal decomposition type cross-linking agent into the polymer, and carrying out melt blending to obtain a cross-linked polymer; s2, uniformly mixing the modified filler, a cross-linked polymer, a lithium salt and a solvent to obtain a plurality of slurries containing the modified filler with different volume concentrations; and molding the slurry to prepare the composite solid electrolyte. According to the method, the fluorinated layer and the siloxane network are constructed step by step, so that the interface impedance is reduced, and efficient dissociation of the lithium salt is promoted; a three-dimensional network structure is combined, so that the tensile strength is improved; the modified filler is further designed in a gradient manner to improve the lithium ion transference number.

The invention discloses application of metal phthalocyanine in polymer solid electrolyte and an all-solid-state lithium / sodium battery. Metal phthalocyanine is adopted to prepare a PVDF-based polymer solid electrolyte, and then the PVDF-based polymer solid electrolyte is used as a positive electrode component to be used in a polymer all-solid-state sodium battery, or metal phthalocyanine is adopted to prepare a PEO-based polymer solid electrolyte, and then the PEO-based polymer solid electrolyte is used as a negative electrode component to be used in an all-solid-state lithium battery. And the preparation of the high-performance polymer all-solid-state lithium / sodium battery at room temperature can be realized. A metal phthalocyanine network with a plane pi-conjugated structure is introduced into a PVDF or PEO matrix, metal in metal phthalocyanine is Zn, Co or Fe, preparation of the all-solid-state sodium / lithium metal battery is achieved, and the prepared all-solid-state sodium / lithium metal battery has high cycling stability.

The invention belongs to the technical field of new energy materials and devices, and relates to a gel electrolyte, a preparation method and a solid-state lithium battery, a liquid novel initiator with a low freezing point, a cyclic ether polymeric monomer and a plasticizer are mixed to form a homogeneous precursor solution, the precursor solution is injected into a battery shell, standing is performed at normal temperature (20-35 DEG C) for in-situ polymerization, and the solid-state lithium battery is obtained. And the gel electrolyte-based solid-state battery can be obtained. The gel electrolyte is initiated by a novel initiator, and compared with a common initiator, the gel electrolyte has better low-temperature performance, and a high-performance solid-state lithium battery is formed.

The invention relates to a preparation technology of a gel polymer lithium ion battery cell electrolyte, and belongs to the field of battery preparation technologies, the preparation technology comprises the following steps: mixing methacrylate monomers and silane monomers according to a mass ratio of 3: 1-5: 1, adding 1-3% of an initiator, and carrying out prepolymerization at 60-80 DEG C for 1-3 h to prepare a prepolymer solution; mixing with a non-aqueous solvent containing lithium hexafluorophosphate according to a mass ratio of (1: 4)-(1: 6) to form a precursor mixed solution, and controlling the injection rate to be 1.5-2.5 g / Ah to a gap between a battery cell pole piece and a diaphragm; after standing for 2-4 hours at the vacuum degree of less than or equal to-0.08 MPa, curing for 3-6 hours at the temperature of 60-70 DEG C to form a gel polymer electrolyte; the wettability is improved through pole piece surface hydrophilic treatment, 1-5% of vinylene carbonate is added to optimize an SEI film, the prepolymerization temperature fluctuation is controlled to be smaller than or equal to + / -2 DEG C through microwave-assisted heating, the pressure of 0.2-0.5 MPa is applied after injection to promote uniform permeation, a polyvinylidene fluoride coating of 5-10 microns is coated after curing to enhance protection, and the interface performance is ensured through an alternating-current impedance test.

The present invention relates to a composite sulfide electrolyte, and a preparation method therefor and a use thereof. The composite sulfide electrolyte has a three-dimensional crosslinked structure formed by connecting a sulfide electrolyte and a dynamic bond-containing crosslinked polymer by means of chemical bonds. The polymer contains a sulfur element and exhibits relatively higher stability when interacting with the sulfide electrolyte, the chemical crosslinking between the sulfide electrolyte and the dynamic bond-containing crosslinked polymer is formed by means of multiple chemical bonds, such as a disulfide bond and an amido bond, and a strong binding force and self-healing function are provided, in order to simultaneously solve the problems of interfacial delamination and cracking caused by mechanical stress inside the sulfide electrolyte. When applied in an all-solid-state battery, the composite sulfide electrolyte can improve the limiting current density and cycle stability of the all-solid-state battery.

A gel electrolyte and a separator are provided between the positive electrode current collector and the negative electrode current collector. The plurality of positive electrode current collectors and the plurality of negative electrode current collectors are stacked such that surfaces of negative electrodes with which active material layers are not coated or surfaces of positive electrodes with which active material layers are not coated are in contact with each other.

The invention provides a lignin-based flame-retardant bacterial cellulose gel polymer electrolyte, preparation and application, the lignin-based flame-retardant bacterial cellulose gel polymer electrolyte is prepared by compounding a modified lignin material, a composite lithium salt and bacterial cellulose, when the polymer electrolyte is greater than or equal to 700 DEG C, the carbon residue rate is greater than or equal to 49.52%, the heat release rate peak value is less than or equal to 61.12 kW m <-2 >, and the flame-retardant bacterial cellulose gel polymer electrolyte has a good flame-retardant effect. The smoke release rate peak value is less than or equal to 0.0089 m < 2 > s <-1 >, and T5 is greater than or equal to 246.9 DEG C. Under the condition of room temperature, the ionic conductivity of the gel polymer electrolyte is 2.37-5mS cm <-1 >, the lithium ion transference number is greater than or equal to 0.75, and the electrochemical window is greater than or equal to 4.87 V (vs Li < + > / Li); in addition, when the temperature is less than or equal to-20 DEG C, the ionic conductivity is more than or equal to 0.162 mS cm <-1 >. The lignin-based flame-retardant bacterial cellulose gel polymer electrolyte not only has an excellent flame-retardant effect, but also has relatively good electrochemical performance.

The invention relates to a composite diaphragm with high ionic conductivity, a composite solid electrolyte and a preparation method thereof. The composite diaphragm is composed of a lithium lanthanum-based fluorine-doped solid electrolyte LLMOF and a base membrane, the chemical general formula of the LLMOF is Li < x > La < y > M < 1 > < z > M < 2 > < w > M < 3 > O < 6 > F, wherein M1 is a tetravalent cation, M2 is a pentavalent cation, and M3 is a hexavalent cation; 1 < x + 3y < 5, 0 < x < = 2, and 1 / 3 < y < 5 / 3; 0 < = z < = 2, 0 < = w < = 2, 0 < = u < = 2, z + w + u = 2; the base membrane is a large-aperture base membrane, and the aperture r is more than or equal to 200nm and less than or equal to 1mu m; the particle size D50 of the LLMOF is 50 nm to 1 [mu] m, and the particle size D50 of the LLMOF is less than or equal to the aperture r of the base film. According to the composite diaphragm disclosed by the invention, the LLMOF solid electrolyte with an ion channel function is introduced, so that efficient conduction of ions is realized; the particle size is matched with that of a large-aperture base membrane, the membrane can be uniformly embedded into membrane holes, a continuous conduction path is constructed, and the ionic conductivity is improved; meanwhile, the composite diaphragm has excellent thermal stability and interface wettability, interface impedance is effectively reduced, and growth of lithium dendrites is inhibited.

The invention relates to the technical field of polymer electrolyte, in particular to a self-repairing type gel polymer electrolyte membrane, a preparation method and application in an energy storage battery, the self-repairing type gel polymer electrolyte membrane is prepared by the following steps: dissolving amino-terminated polyethylene glycol in an organic solvent, adding trimesic acid under the protection of an inert atmosphere, heating, stirring and reacting to form a pre-polymerized solution, cooling, and then adding trimesic acid into the pre-polymerized solution to prepare a self-repairing type gel polymer electrolyte membrane; the preparation method comprises the following steps: adding glyoxylic acid and glacial acetic acid, carrying out a constant temperature reaction to obtain a solution A, adding LiTFSI into the solution A, carrying out ultrasonic dispersion to a homogeneous phase, pouring the obtained slurry onto a template, and carrying out a drying curing reaction to obtain the self-repairing gel polymer electrolyte membrane. A rigid aromatic cross-linking agent is used for inhibiting polymer crystallization and improving mechanical integrity, an imine bond-based dynamic covalent network is introduced to realize an autonomous interface repairing function at the working temperature of the battery, and meanwhile, a polyethylene glycol ether oxygen chain is used for constructing an efficient lithium ion transmission channel; therefore, the technical boundary that the conductivity, the mechanical strength and the interface stability of the traditional GPE are difficult to collaboratively optimize is broken through.

The invention discloses a high-modulus leather / eutectic gel composite electrolyte and a preparation method and application thereof, and belongs to the technical field of energy storage. The preparation method comprises the following steps: 1) preparing a eutectic gel solution containing polyvinyl alcohol, zinc salt, small molecular polyol and water; 2) carrying out vacuum impregnation to obtain leather fibers containing a eutectic gel solution; and (3) obtaining the leather / eutectic gel composite electrolyte with the imitated reinforcing steel bar-concrete structure through freeze-thaw circulation.The composite electrolyte effectively solves the problem that an existing gel electrolyte is low in modulus and difficult to effectively deal with extreme mechanical deformation, and the cycle life of the water-based zinc ion battery is remarkably prolonged.

The system for deicing black ice includes a plurality of laser scanners that are arranged at intervals along a road, each laser scanner including a light source unit, a non-contact temperature sensor, and a control unit that controls an operation of radiating the laser to the area in charge, a weather sensor that measures a temperature and humidity, and an integrated controller that communicates with the plurality of laser scanners. The integrated controller determines whether the laser is radiated to the road surface based on at least one of the measured temperature and humidity, and when the laser radiation is determined, generates a control signal to activate at least one laser scanner, and the control unit determines a heating area, and generates a pulse signal to turn on / off a light source unit so that the laser is radiated in accordance with a shape and range of the heating area.

The invention discloses an interface modification material with a high failure threshold, a solid electrolyte and an all-solid-state battery, and relates to the technical field of electrochemistry. The interface modification material comprises a lithium salt, polymer particles, nanometer indium oxide particles and nanometer NASICON type solid electrolyte powder, the solid electrolyte is obtained by modifying the NASICON type solid electrolyte through the interface modification material, and the all-solid-state battery can be prepared through the solid electrolyte. According to the interface modification material, the cycle performance of the all-solid-state battery at room temperature can be improved, and meanwhile, the interface critical failure threshold can be increased.

The invention relates to an organic solid electrolyte for an in-situ curing high-voltage positive electrode, a battery and a preparation method. The organic solid electrolyte is formed by in-situ polymerization of ether monomers, ester monomers, a lithium salt and a solvent through synergistic thermal initiation of double initiators. The electrolyte disclosed by the invention has the advantages that the ester polymer monomer and the ether polymer monomer are blended, and then the two monomers are respectively polymerized in a thermal initiation manner to form mutually crossed macromolecular long chains. The strategy can improve the interface stability of the electrode and the electrolyte and reduce the interface impedance of the electrode and the electrolyte. In the formed polymer network structure, the ester chain segment enhances the mechanical strength and widens the electrochemical window; and the ether chain segment provides flexible and lithium ion transmission channels. Due to the chemical complementarity of the ester monomers and the ether monomers, the overall performance of the composite polymer electrolyte is improved.

The invention belongs to the technical field of batteries, and provides a battery cell structure and a manufacturing method and application thereof, the manufacturing method comprises the following steps: forming a plurality of positive electrode insulation partitions arranged at intervals on a to-be-coated surface of a positive electrode current collector, and forming a positive electrode active layer in an area between every two adjacent positive electrode insulation partitions to obtain a positive electrode roll; and unwinding the positive electrode insulation partition, a negative electrode roll and a solid electrolyte membrane roll, carrying out rolling compounding to obtain a composite electrode roll, and cutting the positive electrode insulation partition to obtain the battery cell structure. The positive electrode insulation partition can insulate the periphery of the positive electrode active layer with a smaller area, can compensate the size difference of the positive electrode and the negative electrode, and provides support for the negative electrode in the subsequent rolling compounding process, so that the sizes of the positive electrode and the negative electrode are consistent, and the problem of short circuit caused by edge shearing stress during pressure application is solved; roll-in compounding can effectively improve densification and improve electrolyte interface contact, and the manufacturing method is simple, convenient, economical, efficient and suitable for mass production.

The invention belongs to the field of battery materials, and discloses a PEO-based composite solid electrolyte and a preparation method and application thereof, the PEO-based composite solid electrolyte comprises double transition metal-based pyrophosphate, PEO and an electrolyte lithium salt; wherein the molecular formula of the double transition metal-based pyrophosphate is MaNb (P2O7) c, M is any one or two of Fe and V, N is any one or two of Pb and Cd, a is greater than or equal to 1 and less than or equal to 2, b is greater than or equal to 1 and less than or equal to 5, and c is greater than or equal to 1 and less than or equal to 4. By applying the double-transition-metal-based pyrophosphate to the solid electrolyte, the suitability of the solid electrolyte and a positive electrode material with the charging cut-off voltage of 4V or above is improved, and the application range of the solid electrolyte in a battery system with high energy density and long cycle life and a functional energy storage device is widened; and the electrochemical capacity, the structural stability and the ionic conductivity of the battery can be improved.

The invention discloses a composite solid electrolyte and a preparation method and application thereof, and belongs to the technical field of solid lithium batteries. The composite solid electrolyte comprises a polymer matrix, a lithium salt and a lithium ion modified ionic metal organic framework (MOF) material. The metal center of the ion-conducting MOF material can be selected from Zr, Ti, Hf and the like, and the organic ligand can be selected from organic acids containing sulfydryl, sulfo groups and the like. The MOF material can effectively inhibit crystallization of a polymer matrix and increase the proportion of an amorphous region, Lewis acid sites on the surface of the MOF material can promote dissociation of lithium salt, and a lithium ion coordination channel formed in the MOF material can provide an extra rapid transmission path for lithium ions. When the electrolyte is applied to the solid-state lithium battery, the growth of lithium dendrites can be effectively inhibited, and the rate capability, the cycling stability and the safety of the battery can be remarkably improved.

The invention discloses a manufacturing process for a gel electrolyte battery. The process comprises the following steps: adding an initiator to an electrolyte containing 0-8% of a polymer monomer during battery injection; adding a liquid electrolyte until the interface of the gel electrolyte and the interface of the electrode are in full contact after the electrolyte undergoes a curing process to form a gel electrolyte and undergoes a chemical formation process; and allowing the process to stand for subsequent processes. The curing process involves curing the electrolyte into a gel electrolyte under high-temperature pressurized conditions or high-temperature conditions; and the chemical formation process is performed after the electrolyte has been cured into the gel electrolyte. Compared with the prior art, the present invention utilizes a secondary injection and intermediate curing method to reasonably complete the gelation of the electrolyte and realize the function of the gel electrolyte while ensuring battery performance, while optimizing the electrode interface, thereby ensuring battery performance and improving battery safety.