113 results about "Dimethoxyethane" patented technology

The invention provides a gel-state polymer electrolyte as well as a preparation method and application thereof, and belongs to the field of batteries. The gel-state polymer electrolyte provided by the invention comprises the following preparation raw materials: a polar organic solvent, a lithium salt, a lithium salt additive, a liquid flame retardant, a liquid monomer and an initiator, the polar organic solvent comprises 1, 3-dioxolame and ethylene glycol dimethyl ether; the dosage ratio of the lithium salt to the polar organic solvent is 1 mmol: (0.5-2) mL; the mass of the lithium salt additive is 1.5-5% of the total mass of the lithium salt and the polar organic solvent; the volume of the liquid flame retardant is 10-20% of the volume of the polar organic solvent; the volume of the liquid monomer is 10-20% of the volume of the polar organic solvent; the mass of the initiator is 0.5-2% of the total mass of the lithium salt, the polar organic solvent and the monomer. And Li < + > in the lithium salt is released after the type of the solvent is adjusted, so that the Li < + > transference number and the ionic conductivity are improved.

Described herein are lithium-metal rechargeable electrochemical cells comprising a lithium-metal negative electrode, a positive electrode, and a liquid electrolyte. The liquid electrolyte comprises a core mixture and a diluent. The diluent comprises a fluorinated ether. The core mixture comprises a set of salts and a set of solvents. The set of solvents comprises a pyrrolidinium-containing ionic liquid and a molecular solvent. The molecular solvent is a non-fluorinated ether, for example including but not limited to 1,2-dimethoxyethane. In some examples, the electrolyte further comprises an electrolyte additive, for example including but not limited to tris(trimethylsilyl)phosphate. In some examples, the set of salts comprises one or more imide-containing lithium salts. In some examples, the set of salts comprises lithium bis(fluorosulfonyl)imide and an additional salt and the mole fraction of lithium bis(fluorosulfonyl)imide in the set of salts is 0.5 or greater.

The invention discloses a wide-voltage wide-temperature-range sodium-ion battery electrolyte and a preparation method and application thereof, and belongs to the technical field of sodium-ion battery electrolytes.The wide-voltage wide-temperature-range sodium-ion battery electrolyte comprises sodium salt, an organic solvent and an additive, the organic solvent is selected from one or more of ethylene carbonate, propylene carbonate, ethyl methyl carbonate, dimethyl carbonate, diethyl carbonate, ethylene glycol dimethyl ether, diethylene glycol dimethyl ether and triethylene glycol dimethyl ether, and the additive is selected from one or more of fluoroethylene carbonate, allyl-1, 3-propane sultone, 1, 3-propylene sultone, 1, 3-propylene sultone and 1, 3-propylene sultone. The additive is one or more of 1, 3-propyl sultone, methylene methane disulfonate, ethylene sulfate, trifluoromethanesulfonic anhydride, pentaerythritol bicyclic sulfate, tri (trimethylsilane) phosphate, tri (trimethylsilane) phosphite, tri (trimethylsilane) borate, acesulfame sodium and aluminum trifluoromethanesulfonate, and the additive is one or more of 2, 3-propylene sultone, methylene methane disulfonate, ethylene sulfate, trifluoromethanesulfonic anhydride, pentaerythritol dicyclosulfate, tri (trimethylsilane) phosphate, tri (trimethylsilane) phosphite, tri (trimethylsilane) borate, tri (trimethylsilane) phosphate and tri (trimethylsilane) borate. The electrolyte provided by the invention not only keeps high coulombic efficiency at low temperature, but also has good cycle stability at high temperature.

In one example of a method for improving the performance of a silicon-based negative electrode, the silicon-based negative electrode is pre-lithiated in an electrolyte containing a lithium salt dissolved in a solvent mixture of dimethoxyethane (DME) and fluoroethylene carbonate (FEC). DME and FEC are present in a volume-to-volume ratio of 10:1 to 1:10. The pre-lithiation forms a solid electrolyte intermediate phase on an exposed surface of the negative electrode.

The invention discloses an aluminum alloy complex cavity diffusion welding method, which is characterized in that a uniform and compact organic molecule adsorption protection layer is formed on the surface of aluminum by completely immersing a cleaned blank in a diethylene glycol dimethyl ether solution for ultrasonic-assisted treatment. The protective film can effectively isolate air at normal temperature and prevent the oxidation film from regenerating; and in the initial stage of diffusion welding temperature rise, the aluminum alloy can be completely decomposed and volatilized, no impurity is left, and the high-activity clean aluminum surface is exposed. According to the method, diffusion welding is carried out under the conditions that the vacuum degree is high, the temperature is 500-560 DEG C and the pressure is 5-15 MPa in cooperation with a positioning tool system matched with the thermal expansion coefficient, aluminum atoms are fully diffused under the condition that no oxidation film hinders exist, and high-quality metallurgical bonding is formed. By means of the technical scheme, the problem that the welding rate is low due to an oxidation film on the surface of the aluminum alloy is successfully solved, meanwhile, the defects of ultrahigh vacuum equipment input and middle layer material introduction are overcome, and the manufacturing quality and production efficiency of complex aluminum alloy components are greatly improved.

The invention belongs to the technical field of organic synthesis. The invention particularly relates to a synthesis method of chiral beta-diaryl ethanol. The physiological activity, the pharmacological action and the material performance of the chiral molecule are directly determined by the spatial configuration of the chiral molecule. Therefore, efficient construction of chiral compounds is always the core research direction of organic synthesis and medicinal chemistry. Wherein the chiral beta-diaryl ethanol is a kind of key intermediates with irreplaceable application value. According to the invention, the Suzuki-Miyaura type asymmetric ring-opening coupling reaction of nickel catalyzed aryl epoxy and aryl boric acid with high stereoselectivity is realized, and the asymmetric ring-opening coupling reaction is used for synthesizing chiral beta-diaryl alcohol compounds. The method is wide in substrate compatibility and raw material source, mild in reaction condition, free of exogenous alkali and convenient to operate. An aryl epoxy compound and arylboronic acid are used as raw materials, diethylene glycol dimethyl ether nickel bromide is used as a catalyst, chiral biimidazoline is used as a ligand, under the promotion of sodium iodide, reaction is performed in an ethanol solvent according to the following reaction formula at the temperature of 50 DEG C for 10 hours, and the chiral beta-diaryl ethanol compound with the high ee value is obtained.

This invention relates to the field of electrochromic thin film technology, and more particularly to a dithiophene derivative, its preparation method, and its application, as well as an electrochromic thin film and its preparation method. This invention involves reacting dithiophene with tributyltin chloride to generate tin-modified dithiophene, reacting dithiophene with isopropanol pinacol boronic acid ester to generate boron-modified dithiophene, and then reacting the tin-modified or boron-modified dithiophene with 1,4-diiodo-2,5-bis-(6-hexynyl)-benzene to generate 1,4-dithiophene-2,5-bis-(6-hexynyl)-benzene. This product is then reacted with dimethylboron hydride generated from lithium aluminum hydride and dimethoxyethane to finally obtain the dithiophene derivative. This derivative can be applied in electrochromic thin films. This invention successfully prepares an electrochromic thin film with fast response and fluoride ion detection capability by electrochemically polymerizing the dithiophene derivative.

The application discloses a developing etching process for producing a PCB (Printed Circuit Board), and belongs to the field of PCB processing, which comprises the following steps: S1, using a pre-etching agent to pre-etch the PCB; S2, using an etching-resistant agent to etching-resistantly treat the line sidewall of the PCB after pre-etching; S3, using a main etching agent to etch the PCB after pre-etching after etching-resistant treatment; the pre-etching agent comprises the following components in parts by weight: 30-40 parts of citric acid, 5-8 parts of EDTA, 3-5 parts of a non-ionic or anionic surfactant, and 1-3 parts of a coupling agent; the main etching agent comprises the following components in parts by weight: 40-50 parts of ferric chloride, 10-15 parts of maleic acid, 10-15 parts of an amino acid, 3-5 parts of hydrogen peroxide, 1-3 parts of a pH regulator, and 1-2 parts of a rare earth oxide; the etching-resistant agent is a resin containing a double bond and ethylene glycol dimethyl ether, and the mass ratio of ethylene glycol dimethyl ether to the resin containing a double bond is 1:10. The application can guarantee high-quality etching effect and solve the problem of etching measurement.

The invention relates to the technical field of batteries, and discloses an electrolyte and application thereof, and a lithium carbon fluoride battery. The electrolyte comprises a lithium salt and an organic solvent; wherein the lithium salt is lithium bis (fluorosulfonyl) imide; the organic solvent is selected from one of ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene carbonate, propylene carbonate, dimethyl carbonate, ethyl methyl carbonate, dimethylformamide, dimethylacetamide and dimethyl sulfoxide. The electrolyte can be applied to preparation of a lithium primary battery. The invention also relates to a lithium carbon fluoride battery comprising the electrolyte. The electrolyte system provides an optimized solution for the preparation of the high-energy-density lithium carbon fluoride battery, has a wide application prospect, can remarkably improve the performance of the battery, reduces the production cost, and promotes the further development of the lithium carbon fluoride battery technology.

The present application relates to an electrolyte composition for a lithium secondary battery and a lithium secondary battery comprising the same, the electrolyte composition comprising a lithium salt and an organic solvent. The organic solvent includes a first ether solvent (R-O-R ') having a fluorinated alkyl group, and a second ether solvent. The first ether solvent may be 5-ethoxy-1, 1, 2, 2, 3, 3, 4, 4-octafluoropentane, 1, 1, 2, 2, 3, 3, 4, 4-octafluoro-5-methoxypentane, or a mixture thereof, and the second ether solvent may be selected from the group consisting of dimethoxyethane, diethyl ether, and similar ethers. The lithium salt includes a compound such as LiTFSI, LiFSI, or LiPF6. The first ether solvent accounts for 30% to 90% by volume of the electrolyte, wherein the concentration of the lithium salt ranges from 0.1 M to 3.0 M. The electrolyte composition enhances battery stability and makes it suitable for use in lithium secondary batteries and lithium metal secondary batteries.

In order to solve the problems that the high-temperature cycle life and the low-temperature cycle life of the battery are short due to the fact that an electrolyte used by an existing lithium metal battery contains a strong-strong solvent pair or a strong-anti-solvent pair in LHCE, the invention provides a high and low temperature resistant electrolyte and a lithium metal battery. The high and low temperature resistant electrolyte comprises an organic solvent, the organic solvent comprises a strong solvating solvent and a weak solvating solvent, the weak solvating solvent is 4-methyl-1, 3-dioxane, and the strong solvating solvent is ethylene glycol dimethyl ether. At low temperature, due to the dipole interaction of MeDX-DME, a layered solvation structure is formed, and the interaction of Li < + >-DME is weakened, so that the Li < + > desolvation energy is reduced, the Li < + > transmission kinetics is increased, and the low-temperature cycle life of the battery is prolonged; and at high temperature, due to the dipole interaction of MeDX-DME, a layered solvation structure is formed, so that the ring-opening reaction of MeDX is slowed down, the generation of side reactions is reduced, the high-temperature stability of the electrolyte is improved, and the high-temperature cycle life of the battery is prolonged.

This invention relates to the field of organic synthesis technology, specifically to a highly efficient and stable Grignard preparation and its green preparation method. By weight, it comprises 8-18 parts of a magnesium source, 40-92 parts of a halogenated hydrocarbon, 150-200 parts of a green solvent, 15-20 parts of ethylene glycol dimethyl ether, and 2.3-3.2 parts of a synergistic stabilizer. The green solvent is 2-methyltetrahydrofuran, or a composite solvent with a weight ratio of 2-methyltetrahydrofuran:methyl tert-butyl ether of 150-160:40-50. The synergistic stabilizer is composed of 1.5-2.0 parts of N,N,N',N'-tetramethylethylenediamine and 0.8-1.2 parts of butylated hydroxytoluene, or composed of 1.5-2.0 parts of N,N,N',N'-tetramethylethylenediamine and 1.0 part of phenothiazine. This invention uses a green solvent system to replace traditional toxic and harmful solvents, and combines it with a solvent recovery process to achieve solvent recycling, which greatly reduces waste emissions and makes the production process safer and more environmentally friendly, in line with the development direction of green chemical industry.

The invention relates to a novel lithium metal battery ether electrolyte and a preparation method thereof, the electrolyte comprises the following components: a non-aqueous organic solvent system, a lithium salt and an additive, the non-aqueous organic solvent system is preferably selected from ethylene glycol dimethyl ether and 1, 1, 2, 2-tetrafluoroethyl-2, 2, 3, 3-tetrafluoropropyl ether; the additive is preferably selected from lithium nitrate, lithium difluoro (oxalato) borate, tris (pentafluorophenyl) borane and pentafluorophenoxy cyclotriphosphazene; the lithium salt comprises at least one of lithium bis (fluorosulfonyl) imide, lithium bis (trifluoromethylsulfonyl) imide, lithium difluoro (oxalato) borate, lithium hexafluorophosphate and lithium tetrafluoroborate; the invention also provides a preparation method of the electrolyte and a battery formed by the electrolyte. The electrolyte provided by the invention realizes low impedance, high conductivity and long cycle life while maintaining high energy density, and provides an effective solution for safe and reliable operation of a metal lithium battery under harsh working conditions of high surface capacity, high current density and the like.

The application relates to the technical field of batteries, in particular to an electrolyte suitable for primary lithium-manganese batteries and a preparation method thereof. The electrolyte comprises propylene carbonate, ethylene carbonate, lithium bisfluorosulfonylimide, lithium perchlorate, lithium bisoxalate borate, terminal bisdifluorophosphorylated oligomeric trimethylene carbonate, ethylene glycol dimethyl ether, lithium difluorooxalate borate and 1,3-propane sultone. The electrolyte is prepared through a pre-coordination and segmented dilution process with specific timing. The electrolyte system can synergistically optimize the electrode interface film forming process, has high discharge capacity retention rate and low direct current resistance at low temperature (-20 DEG C), and has high capacity retention rate after high-temperature storage (60 DEG C), thereby significantly improving the comprehensive performance of the primary lithium-manganese battery in a wide temperature range.

The invention discloses a linear ether and cyclic ether mixed electrolyte for a wide-temperature-range sodium-ion battery as well as a preparation method and application of the linear ether and cyclic ether mixed electrolyte, and relates to a wide-temperature-range electrolyte as well as a preparation method and application of the wide-temperature-range electrolyte. The invention discloses a linear ether and cyclic ether mixed electrolyte for a wide-temperature-range sodium-ion battery. The linear ether and cyclic ether mixed electrolyte comprises sodium salt and an ether-based solvent, the sodium salt is sodium trifluoromethanesulfonate; the ether-based solvent is a mixed solution of straight-chain ether and cyclic ether; the straight-chain ether is diethylene glycol dimethyl ether; the cyclic ether is tetrahydrofuran or dimethyl tetrahydrofuran. The straight-chain ether and cyclic ether mixed electrolyte of the wide-temperature-range sodium-ion battery provided by the invention has a low freezing point, low viscosity, high ionic conductivity and high sodium ion transference number in a wide temperature range, and low desolvation energy, and can reduce the interface charge transfer impedance of an electrode-electrolyte, so that the performance of the battery is improved. Sodium ions can be quickly embedded and separated when reaching the electrode, so that the wide-temperature-range performance of the sodium ion battery is improved, and the sodium ion battery has excellent wide-temperature-range charge-discharge specific capacity, cycling stability and high-rate performance.

The invention discloses a low-temperature high-ionic-conductivity ether-ester composite sodium ion electrolyte and a preparation method thereof, and belongs to the technical field of energy storage battery materials, the electrolyte comprises ethylene glycol dimethyl ether, ethylene carbonate and methyl ethyl carbonate as basic solvents, and two brand-new modified compounds, namely methyl-2-(2, 2, 3, 3-tetrafluoropropoxy)-1, 2, 3, 4, 4-tetramethyl-1, 3, 4, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4- According to the invention, 2, 3-dioxolane-4-yl phosphonate and cyclo (2-hydroxypropyl-2 '-hydroxyethyl) sulfate are used as auxiliary materials, and fluoroethylene carbonate, sodium bis (fluorosulfonyl) imide and sodium perchlorate are used as auxiliary materials. Wherein the freezing point of fluoroether phosphonate is reduced through a fluorinated chain segment, and a phosphonic acid group promotes ion dissociation and stabilizes an interfacial film; the cyclic hydroxyl sulfonate inhibits molecular association through a cyclic structure, hydroxyl reduces the viscosity of a solvent, and sulfonate groups optimize the conductivity of an interfacial film. The prepared low-temperature high-ionic-conductivity ether-ester composite sodium ion electrolyte is high in ionic conductivity at low temperature, stable in interfacial film and long in cycle life.

The present application relates to a synthesis method of deuterium-labeled substances containing deuterium atom structural units, which comprises mixing aryl chloride with deuterium water in an organic solvent, adding a catalyst of ethylene glycol dimethyl ether-nickel dichloride and a ligand of 2,9-dimethyl-1,10-phenanthroline, and then reacting under the condition of zinc powder and nitrogen protection to obtain the deuterium element labeled compound. The present application uses ethylene glycol dimethyl ether-nickel dichloride as a catalyst, and aryl chloride can react with deuterium water to generate deuterium atom substitution products under the condition of nitrogen at normal temperature and pressure. The reaction condition is simple and mild. Meanwhile, the range of alternative substrates is more extensive, and the use of inexpensive nickel as a catalyst has higher economic value compared with the previous reports.

This invention relates to a method for preparing a bimetallic cyanide (DMC) catalyst, comprising a reaction of an aqueous solution of a cyanide-free metal salt, an aqueous solution of a basic metal cyanide salt, an organic complexing ligand, and optionally a component forming a complex, wherein the metal cyanide salt is one or more compounds selected from potassium hexacyanocobalt(III), potassium hexacyanoferrate(II), potassium hexacyanoferrate(III), calcium hexacyanocobalt(III), and lithium hexacyanocobalt(III), wherein the organic complexing ligand is one or more compounds selected from dimethoxyethane, tert-butanol, 2-methyl-3-buten-2-ol, 2-methyl-3-butyn-2-ol, ethylene glycol mono-tert-butyl ether, and 3-methyl-3-oxetane-methanol, and wherein the basic metal cyanide salt used has an alkalinity between 0.700 wt% and 3.000 wt% sodium hydroxide (NaOH) based on the total weight of the basic metal cyanide salt used, determined by titration as disclosed in the experimental section. Another subject of the invention includes a bimetallic cyanide catalyst (DMC) obtainable by the method according to the invention, and the use of said DMC catalyst in the preparation of polyoxyethylene polyols.

The present invention addresses the problem of providing an electrolyte solution for a lithium metal secondary battery, which, when using 1, 2-dimethoxyethane (DME) as a solvent, is capable of simultaneously suppressing an increase in the resistance of the lithium metal secondary battery, suppressing the generation of gas, and suppressing an increase in the thickness of the negative electrode. The present invention is an electrolyte solution for a lithium metal secondary battery, the electrolyte solution comprising an electrolyte salt, an organic solvent, and a first additive, the electrolyte salt comprising lithium bis (fluorosulfonyl) imide (LiFSI), the organic solvent comprising 1, 2-dimethoxyethane (DME), the first additive being N, N-dimethyltrifluoromethanesulfonamide (DMTMSA), or N, N-dimethylformamide (DMTMSA), and the electrolyte solution comprising lithium bis (fluorosulfonyl) imide (LiFSI), the organic solvent comprising 1, 2-dimethoxyethane (DME), and the second additive comprising N, N-dimethyltrifluoromethanesulfonamide (DMTMSA), or N, N-dimethyltrifluoromethanesulfonamide (DMTMSA). The electrolyte solution for a lithium metal secondary battery contains at least one of N, N-dimethylaminosulfonyl fluoride (DMSF), and the first additive is contained in an amount of 0.2 parts by mass or more when the total mass of the electrolyte salt and the organic solvent is taken as 100 parts by mass.

The invention belongs to the technical field of organic synthesis, and discloses a preparation method for trifluoromethylation of a 1, 6-enyne substrate. The preparation method comprises the following steps: in a protective gas atmosphere, mixing a 1, 6-eneyne substrate, NaSO2CF3, an oxidant, N-bromosuccinimide and an organic solvent, heating to react, cooling, separating an organic phase, drying and purifying to obtain a product after trifluoromethylation of the 1, 6-eneyne substrate, the organic solvent is selected from any one of dimethoxyethane and 1, 2-dichloroethane. The preparation method is mild in reaction condition, simple and convenient to operate, good in substrate applicability, good in substrate selectivity in reaction and high in target product yield, and a new way is provided for trifluoromethylation of the 1, 6-eneyne compound.

This invention relates to the fields of materials science and chemistry, and discloses a method for preparing a metal ion-doped defective FER molecular sieve. The method includes a molecular sieve using Cu and Co as doping ions, with a basic framework of a defective FER molecular sieve having a silicon-to-aluminum ratio of 30-40. The molecular sieve is based on the mass of the defective FER molecular sieve, and the mass percentage of the doping ions is 3-5%. This invention employs a two-step synthesis method. The first step involves hydrothermal crystallization to synthesize a pre-crystallized FER molecular sieve. The second step increases the hydrothermal crystallization temperature, causing the unstable molecular sieve structure to transform into a high silicon-to-aluminum ratio defective crystal form under high temperature and pressure, while simultaneously introducing heteroions into the molecular sieve framework. Compared to traditional techniques, this method can achieve a larger doping amount and is simpler with readily available raw materials. Its application in the catalytic synthesis of ethylene glycol dimethyl ether from ethylene glycol and methanol can achieve high conversion rates and high selectivity, demonstrating significant economic value and market potential.

The present application belongs to the field of activators, and particularly relates to an activator for improving the adhesion of yarn and rubber and the use thereof. The activator is composed of 38-68wt% component A: alkyl silane, 24.2-41.2wt% component B: fatty acid polyoxyethylene ester, 5.5-13wt% component C: triethylene glycol dimethyl ether and 0.6-4.7wt% component D: alkyl phenol polyoxyethylene ether. The activator of the present application can improve the adhesion of yarn and rubber.

The invention discloses a green synthesis method of a fluorine-containing biphenyl liquid crystal material monomer, aiming at the pain points that the traditional synthesis process of the fluorine-containing biphenyl liquid crystal material monomer is serious in pollution, difficult in catalyst recovery and complex in purification. According to the method, a graphene-loaded Pd-Ni bimetallic heterogeneous catalyst is prepared firstly, then an intermediate is prepared through a water-ethylene glycol dimethyl ether system Suzuki coupling reaction, mild deprotection is achieved through a hydrobromic acid-acetic acid mixed system, recrystallization purification is conducted through an ethanol-water mixed solvent, the catalyst can be recycled, the solvent system is environmentally friendly, the process is suitable for industrial production, and the method is suitable for industrial production. The obtained monomer has the excellent performance of adapting to TN type and STN type liquid crystal display devices, and has the advantages of environmental protection, cost and practical adaptability of products.

The invention belongs to the field of synthesis and application of energy storage directional functional ionic liquid, and discloses ionic liquid and application thereof in high-voltage lithium ion battery electrolyte and solid electrolyte. The ionic liquid comprises cations and anions, the cations comprise 1-substituted imidazole groups and 2-substituent structures, the anions are obtained through ion exchange according to the requirements of an electrolyte system, and the ionic liquid is synthesized and prepared through a two-step method. And the 1-substituent imidazole is one of 1-methylimidazole, 1-ethylimidazole, 1-propylimidazole, 1-hydroxymethyl imidazole and 1-hydroxyethyl imidazole. The 1, 2-substituent group structure is one of methyl tetrahydrofuran, methyl dioxo cyclopentane, dimethoxymethane and 1, 2-dimethoxyethane. The ionic liquid can form a positive electrode interface passivation film, reduce side reaction, improve interface performance, combine thermal / electrochemical stability, match a high-voltage positive electrode and improve lithium ion battery performance.

The invention relates to the technical field of electrolyte, in particular to high-voltage ether-based lithium metal battery electrolyte as well as a preparation method and application thereof. The invention provides a high-pressure ether-based lithium metal battery electrolyte. The high-pressure ether-based lithium metal battery electrolyte is prepared from the following raw materials: lithium hexafluorophosphate, ethylene glycol dimethyl ether, a sulfonyl solvent and an additive lithium salt. The high-voltage ether-based lithium metal battery electrolyte can widen the charging voltage of an ethylene glycol dimethyl ether system lithium metal battery to 4.6 V or above.

The invention discloses a composite coating diaphragm, a preparation method thereof and a secondary battery, and relates to the technical field of secondary batteries. The invention provides a composite coating diaphragm with a base membrane, a bottom hydrophilic supporting layer and a surface electrophilic functional layer, the surface electrophilic functional layer takes aminated porous aluminum oxide as a core, quaternized polyether amine and polyethylene glycol dimethyl ether are compounded, electrolyte anions are actively adsorbed through amino and quaternary ammonium groups, and an ion transmission energy barrier is reduced; the bottom hydrophilic supporting layer is formed by compounding acrylic acid grafted gradient particle size ceramic particles, sodium carboxymethyl cellulose and polyethylene glycol dimethyl ether, and rapid spreading and stable storage of the electrolyte are achieved through hydrophilic groups; the two layers are tightly combined through the hydrogen-bond interaction of amino and carboxyl to form an adsorption-spreading-storage synergistic system, so that the electrolyte infiltration rate, the electrolyte retention stability, the ionic conduction efficiency and the coating binding force are synchronously improved, and the requirements of high-voltage and long-cycle-life batteries are met.

The application provides a positive photoresist composition, which comprises a phenolic resin, a photosensitive compound and a mixed solvent, wherein the mixed solvent comprises a first solvent and a second solvent, the first solvent is selected from at least one of ethyl lactate, ethyl 3-ethoxypropionate, 4-methyl-2-pentanone and 2-heptanone; and the second solvent is selected from at least one of ethylene glycol monomethyl ether, propylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol dimethyl ether, propylene glycol methyl ether acetate, ethyl acetate and n-butyl acetate. The photoresist composition provided by the application has better stability than a photoresist composition using a single solvent, and can be better applied to an organic electroluminescent display.

The application relates to a preparation method and application of a low-temperature-resistant ester-based electrolyte. The method comprises the following steps: firstly, dissolving lithium bistrifluoromethylsulfonylimide into a mixed solution of difluoropropionic acid ethyl ester and fluorinated ethylene carbonate to obtain solution A; secondly, dissolving lithium nitrate into ethylene glycol dimethyl ether to obtain solution B; and thirdly, adding solution B into solution A to obtain the low-temperature-resistant ester-based electrolyte. The weak-solvent electrolyte is composed of three solvents and two lithium salts, the carboxylic acid ester has a low melting point and a strong salt-dissolving capacity, the freezing point of the electrolyte can be significantly reduced, the electrolyte still has strong fluidity at low temperature, the migration rate of lithium ions at low temperature is improved, and the low-temperature performance of the battery is improved. The low-temperature-resistant ester-based electrolyte prepared by the application provides valuable insights for the next-generation electrolyte of lithium ion batteries operated under extreme conditions.

This invention discloses a bio-based high-efficiency antibacterial polyester fiber and its preparation method, belonging to the field of synthetic fiber technology. It solves the problems of high hue, low bio-based content, and weak antibacterial performance in existing technologies. The fiber is copolymerized from a first, second, third, and fourth ester. The first ester is formed by esterification of oxalic acid and 1,3-propanediol; the second ester is formed by esterification of an aliphatic diacid and 1,3-propanediol; the third ester is formed by esterification of a quaternary ammonium salt of hydroxy fatty acids; and the fourth ester is formed by esterification of terephthalic acid and ethylene glycol. This invention uses oxalic acid, aliphatic diacids, 1,3-propanediol, and quaternary ammonium salts of hydroxy fatty acids to prepare polyester fibers, achieving a bio-based carbon content of over 30%. The entire preparation process eliminates the need for diethylene glycol dimethyl ether, a solvent required in existing technologies, thus solving the problem of high hue caused by solvent residue. The fiber maintains highly efficient and long-lasting broad-spectrum antibacterial properties, with an antibacterial rate exceeding 99%.

The invention discloses a dianion salt-based magnesium fuel cell electrolyte and a preparation method, and belongs to the technical field of magnesium fuel cells, the electrolyte is composed of dianion composite magnesium salt, propylene carbonate (PC), tetrahydrofuran (THF), magnesium fluoride (MgF) nanoparticles, 1, 3-dioxolane (DOL), diethylene glycol dimethyl ether (G2) and trimethyl phosphate (TMP) according to a specific mass percentage, and the dianion salt-based magnesium fuel cell electrolyte is prepared from dianion composite magnesium salt, propylene carbonate (PC), tetrahydrofuran (THF), magnesium fluoride (MgF) nanoparticles, 1, 3-dioxolane (DOL), diethylene glycol dimethyl ether (G2) and trimethyl phosphate (TMP) according to a specific mass percentage. The mass ratio is 1: (1.6-2.0). The preparation method comprises the four steps of composite salt preparation, solvent dehydration, salt dissolution and additive mixing, and the ionic conductivity and thermal stability of the electrolyte are improved through specific ultrasonic parameters, dehydration conditions and annealing treatment.