The invention provides a soap free latex type amphiphilic polymer resin, which is formed by polymerizing unsaturated acid alkyl, styrene, methyl methacrylate, butyl methacrylate, butyl acrylate, hydroxypropyl methacrylate, ethylene glycol methacrylate, acrylamide, diacetone-acryloamide and other monomers. The paint which takes the soap free latex type amphiphilic polymer resin as a main film forming material and combines with multiple kinds of inorganic polymer stuffing integrates with decorative property, humidifying property, permeability, heat preservation, condensation prevention, water and alkali resistance, bacterium resistance and so on, and can prevent the paint film from dropping off due to multiple kinds of seepage and water condensation of a wall body, so that the paint film is more durable; in addition, the paint has no organic solvent, and is more safe and environment friendly.