Soap-free core-shell emulsion type amphiphilic polymer resin and preparation and application thereof in preparation of function humidity controlling coating

A technology of amphiphilic polymer and core-shell emulsion, which is applied in the field of polymers, can solve the problems of high minimum film forming temperature, influence on coating performance, and increase of product cost, and achieve low product cost, superior performance, alkali resistance and The effect of improving the scrub resistance

Inactive Publication Date: 2009-05-06
NORTHWEST NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the minimum film-forming temperature of emulsion-type and soap-free emulsion-type resins is relatively high, generally above 15°C, and it is difficult to form a good film at low temperature without adding film-forming aids, which will affect the coating performance.
However, the film-forming aid is a kind of temporary plasticizer that is easy to disappear and has a certain volatilization rate. The price is relatively high, and the cost of the product will increase after addition. Bioresin is more realistic

Method used

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  • Soap-free core-shell emulsion type amphiphilic polymer resin and preparation and application thereof in preparation of function humidity controlling coating
  • Soap-free core-shell emulsion type amphiphilic polymer resin and preparation and application thereof in preparation of function humidity controlling coating
  • Soap-free core-shell emulsion type amphiphilic polymer resin and preparation and application thereof in preparation of function humidity controlling coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Example 1: Preparation of nano-silica-containing soap-free core-shell emulsion type amphiphilic polymer resin

[0053] Formula: by weight

[0054] 15 parts of methacrylic acid, 60 parts of methyl methacrylate, 20 parts of styrene, 60 parts of butyl acrylate, 10 parts of hydroxypropyl methacrylate, 15 parts of diacetone acrylamide, 3 parts of nano silicon oxide, potassium persulfate 2 parts, 2 parts of sodium bicarbonate, 160 parts of distilled water.

[0055] Process:

[0056] (1) Mix 3 parts of methacrylic acid, 10 parts of methyl methacrylate, 5 parts of styrene, 12 parts of butyl acrylate and 0.5 part of potassium persulfate, stir well and make a mixture of nuclear monomers; 2 parts, 1 part of potassium persulfate and 3 parts of nano-silicon oxide, dissolved in 160 parts of distilled water, poured into the reaction flask, heated to 95 ° C, and dripped the above-mentioned nuclear monomer mixture into the reaction flask with a dropping funnel, After about 0.5 to 1 h...

Embodiment 2

[0059] Example 2: Preparation of soap-free core-shell emulsion type amphiphilic polymer resin

[0060] Formula: by weight

[0061] 8 parts of acrylic acid, 60 parts of styrene, 30 parts of butyl acrylate, 30 parts of hydroxyethyl methacrylate, 20 parts of acrylamide, 12 parts of diacetone acrylamide, 3 parts of ammonium persulfate, 3 parts of sodium bicarbonate, 160 parts of distilled water share.

[0062] Process:

[0063] (1) Mix 2 parts of acrylic acid, 10 parts of styrene, 8 parts of butyl acrylate and 0.5 part of ammonium persulfate, stir well and make a mixture of nuclear monomers; dissolve 3 parts of sodium bicarbonate and 1 part of ammonium persulfate in Pour 160 parts of distilled water into the reaction bottle, and heat up to 90°C; add the nuclear monomer mixture into the reaction bottle with a dropping funnel; drop it for about 1 hour, and then keep it at this temperature for 1 hour to obtain nuclear particles;

[0064] (2) Mix 12 parts of diacetone acrylamide, 6...

Embodiment 3

[0066] Example 3: Preparation of nano-silica-containing soap-free core-shell emulsion type amphiphilic polymer resin

[0067] Formula: by weight

[0068] 5 parts of methacrylic acid, 5 parts of acrylic acid, 50 parts of methyl methacrylate, 20 parts of styrene, 50 parts of butyl acrylate, 10 parts of hydroxypropyl methacrylate, 10 parts of acrylamide, 20 parts of diacetone acrylamide, 160 parts of distilled water, 8 parts of nano silicon oxide, 4 parts of ammonium persulfate, 4 parts of sodium bicarbonate.

[0069] Process:

[0070] (1) Mix 2 parts of acrylic acid, 2 parts of methacrylic acid, 10 parts of methyl methacrylate, 6 parts of styrene, 10 parts of butyl acrylate and 1 part of ammonium persulfate, and stir evenly to make a mixture of nuclear monomers; Dissolve 4 parts of sodium bicarbonate, 2 parts of initiator and 8 parts of nano-silicon oxide in 160 parts of distilled water, pour it into the reaction flask, raise the temperature to 85°C, and drop the above-mention...

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PUM

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Abstract

The invention provides a nonsoap nuclear shell latex type amphipathic polymer resin, which is polymerized from methyl methacrylate, styrene, methyl methacrylate, butyl methacrylate, butyl acrylate, hydroxypropyl methacrylate, hydroxyethyl methacrylate, acrylamide, diacetone acrylamide and other monomers. The nonsoap nuclear shell latex type amphipathic polymer resin is used as a main film forming material for a paint and is combined with various inorganic macromolecular fillers to prepare the paint; the prepared paint integrates decoration, dampness regulation, permeability, heat insulation, dewing resistance, water and alkali resistance, antisepsis and the like, and can also prevent a coating film from falling off caused by various leakage and water condensation of a wall body so that the coating film is more lasting and durable; and the paint contains no organic solvent and no emulsifier, is safer and more environment-friendly, and has more superior coating property.

Description

technical field [0001] The invention belongs to the technical field of macromolecules, and relates to a polymer resin, in particular to a soap-free core-shell emulsion type amphiphilic polymer resin with hydrophilicity and lipophilicity and a preparation method thereof, and the invention also relates to the soap-free core-shell emulsion type amphiphilic polymer resin Application of shell emulsion type amphiphilic polymer resin in the production of functional moisture-regulating coatings. technical background [0002] Relative air humidity is an important parameter to measure the indoor environment. It is closely related to human health and work and life. If it is too high or too low, it will affect people's normal life. Considering various factors such as microbial growth, human disease, item deterioration, and comfort, it is recognized that the optimal relative humidity range is 40% to 60%. It is of great significance to improve the environment, improve the preservation qu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/14C08F212/08C08F220/18C08F2/22C08F2/44C08K3/36C09D133/12C09D133/08C09D125/08C09D5/00C08F220/06C08F220/28C08F220/56C08F222/02
Inventor 王荣民吕维华何玉凤熊玉兵王俊峰
Owner NORTHWEST NORMAL UNIVERSITY
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