1166 results about "Biphenyl" patented technology

The invention relates to an anion exchange membrane based on isopropyl piperidone and biphenyl and a preparation method of a membrane electrode, the preparation method comprises the following steps: respectively dissolving an aromatic monomer and IPD in a first solvent, and mixing to obtain a mixed solution, the aromatic monomer being BP or TP; dropwise adding an acidic initiator into the mixed solution for reaction at the reaction temperature of-5 DEG C to 0 DEG C to obtain a nitrogen heterocyclic ring polymer intermediate; adding a quaternization reagent into the nitrogen-containing heterocyclic ring polymer intermediate to realize quaternization modification of nitrogen atoms to obtain a quaternization ionomer; and forming a film to obtain the AEM film. The preparation method of the membrane electrode comprises the following steps: respectively forming a cathode catalyst layer and an anode catalyst layer on two opposite sides of an AEM membrane through ultrasonic spraying to obtain the MEA. The AEM membrane and the MEA obtained according to the invention have the characteristics of excellent stability and high water electrolysis performance, can significantly improve the efficiency and durability of AEMWE, and are suitable for the fields of hydrogen production by water electrolysis and the like.

The invention belongs to the technical field of pharmaceutical preparations, and relates to traditional Chinese medicine self-assembled nanoparticles for enhancing anti-inflammatory activity as well as a preparation method and application of the traditional Chinese medicine self-assembled nanoparticles. The traditional Chinese medicine self-assembled nanoparticles are prepared from biphenyl cyclooctene type lignan and an oleanane type pentacyclic triterpenoid compound, wherein the mass ratio of the biphenyl cyclooctene type lignan to the oleanane type pentacyclic triterpenoid compound is 1 to (0.125 to 8). Through an anti-solvent exchange method, the carrier-free nanoparticles based on self-assembly of the traditional Chinese medicine active ingredients are prepared by utilizing spontaneous non-covalent interaction between the biphenyl cyclooctene lignan and the oleanane pentacyclic triterpenoid, so that the cytotoxicity is remarkably reduced, the biocompatibility is enhanced, and the toxic and side effects are reduced; meanwhile, the traditional Chinese medicine self-assembled nano-particles have a remarkable cellular uptake effect, the absorption and utilization efficiency of the medicine is improved, and more efficient anti-inflammatory biological activity is shown.

The invention provides a sodium ion battery as well as a preparation method and application thereof, and belongs to the technical field of battery materials. The sodium ion battery comprises a positive electrode, a negative electrode and an electrolyte, the positive electrode is a sodium-supplemented positive plate treated by a biphenyl sodium complex solution; the electrolyte comprises a NaPF6 basic electrolyte and an additive; and the additive is selected from at least one of 3-trimethylsilyl-2-oxazolidinone and N, N-dimethyl formamide. The resistance and capacity of the positive electrode are improved by supplementing sodium to the positive electrode, and the charge-discharge cycle life of the battery is prolonged by adding a polar reagent into the electrolyte to capture PF5 and remove trace water and harmful gas HF generated in charge and discharge.

The invention discloses a phenanthridine-6-formaldehyde derivative and a preparation method and application thereof.The preparation method comprises the steps that 2, 4, 5, 6-tetra (9-carbazolyl)-isophthalonitrile serves as a photocatalyst, 1-azabicyclo [2.2. 2] octane serves as a hydrogen atom transfer catalyst, a biphenyl isocyanide compound, the photocatalyst, the hydrogen atom transfer catalyst and an alkali additive are jointly dissolved in 1, 3-dioxolane, the mixture is stirred to be uniform, and the phenanthridine-6-formaldehyde derivative is obtained. And carrying out free radical tandem cyclization and acid-catalyzed hydrolysis reaction to obtain the phenanthridine-6-formaldehyde derivative. The invention also provides a specific reaction equation. According to the developed synthesis method of the phenanthridine-6-formaldehyde derivative, the compound can be efficiently and conveniently prepared, the technical bottlenecks of harsh reaction conditions and tedious steps in a traditional process are successfully overcome, raw materials which are low in price and easy to obtain are adopted, operation is carried out under mild conditions, the synthesis method has the outstanding advantages of being high in yield, safe and simple to operate, environmentally friendly and the like, and the method is suitable for industrial production. Good industrial application potential is shown.

The invention relates to a compound containing a thiophene group, a device and equipment. In the structural formula of the compound, R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are independently selected from hydrogen, halogen, cyano, trifluoromethyl, triphenylamine and derivatives thereof, methoxyl, aryl and derivatives thereof, cyanobiphenyl and naphthyl; the compound can be used for preparing a photovoltaic device and photovoltaic equipment and is used for improving the efficiency and stability of the photovoltaic device.

The invention relates to the technical field of negative-electrode-free solid-state batteries, and particularly discloses a construction method of a negative-electrode-free solid-state sodium battery interface, which specifically comprises the following steps: dropwise adding a biphenyl sodium solution to a three-dimensional porous skeleton constructed by a solid-state electrolyte to obtain a stable quasi-liquid-state interface layer. The solid electrolyte with the interface layer is applied to the negative-electrode-free solid sodium battery, and the interface layer is applied to a negative electrode side, so that the stability of a negative electrode interface of the negative-electrode-free solid sodium battery can be effectively improved, the nuclear potential of sodium can be effectively reduced, the electric field distribution can be adjusted, dendritic crystal generation can be inhibited, uniform sodium deposition can be promoted, and the cycling stability of the battery can be improved.

The invention relates to the technical field of oilfield exploitation, and discloses a polysaccharide-containing solid-free drilling fluid and a preparation method and application thereof.The drilling fluid is formed by mixing a plugging anti-collapse agent, a polysaccharide fluid loss agent, a tackifier and the like as raw materials, the functional monomer is prepared by carrying out emulsion cross-linking polymerization under the action of an initiator, the functional monomer structure contains a large number of quaternary ammonium cations and sulfonic acid groups and also contains a biphenyl structure, and the quaternary ammonium cations can generate a strong adsorption effect with shale and silt, so that the plugging effect and temperature resistance of the drilling fluid are improved; polysaccharide is adopted as the filtrate reducer of the drilling fluid, high-viscosity colloid can be formed after the polysaccharide is dissolved in water, stratum pores are effectively blocked, filtrate invasion is reduced, the filter loss is reduced, and the polysaccharide filtrate reducer can improve the viscosity of the drilling fluid, enhance the rock-carrying capacity of the drilling fluid and improve the cleaning effect of a well hole.

The invention discloses an imidazole derivative molecule modified solar cell and a preparation method thereof, and belongs to the technical field of solar cells. The cell sequentially comprises an ITO (Indium Tin Oxide) conductive glass layer, a nickel oxide passivation layer, a [4-(3, 6-dimethoxy-9H-carbazole-9-yl) butyl] phosphonic acid hole transport layer, an ITO (Indium Tin Oxide) conductive glass layer and a nickel oxide passivation layer from bottom to top, the thin film solar cell is characterized in that the thin film solar cell comprises a substrate, a metal Ag electrode layer, a Cs0.05 (FA0. 95MA0. 05) 0. 95Pb (I0. 95Br0. 05) 3 narrow-band gap perovskite thin film PVSK modified by 2-(2 ', 6'-dichloroanilino)-2-imidazoline, a (6, 6)-phenyl-C61-butyric acid methyl ester electron transport layer, a 2, 9-dimethyl-4, 7-biphenyl-1, 10-phenanthroline hole blocking layer and a metal Ag electrode layer; according to the scheme, perovskite defects are passivated through imidazole derivative molecules, double-interface passivation and crystallization regulation are achieved, the film quality is improved, and the crystal quality of the perovskite film is remarkably improved; due to effective passivation of the double interfaces, ion migration is obviously inhibited, the carrier transmission efficiency is effectively improved, and the moisture resistance of the perovskite thin film and the device stability are improved.

The invention discloses a novel automobile back view mirror flexible printed circuit board prepared based on weldable silver paste, and belongs to the technical field of electronic materials and devices, conductor patterns in the flexible printed circuit board comprise a main circuit pattern and an auxiliary function structure formed by weldable low-temperature curing silver paste; the curing temperature of the weldable low-temperature silver paste is 125-135 DEG C, and the weldable low-temperature silver paste comprises conductive filler, a polymer resin system, a high-boiling-point ester solvent, a curing agent, a silane coupling agent, a polyamide wax thixotropic agent, a polysiloxane defoaming agent, modified carbon nanotubes, modified aluminum oxide powder, modified barium sulfate and a low-stress modifier. The polymer resin system comprises novolac epoxy resin, biphenyl epoxy resin and a polyacrylate-CTBN copolymer; through the synergistic effect of all the components and an innovative process, comprehensive improvement of mechanical reliability, environmental durability, conductive stability and power load capacity is achieved, and the strict requirement for high reliability of the automobile rearview mirror in an extreme environment is perfectly met.

A biphenyl derivative, its preparation method and its use in preparing drugs for treating related diseases, specifically relating to a compound represented by formula (I) and a pharmaceutically acceptable salt thereof.

The invention relates to a specific PET molecular probe of a targeted KRASG12D mutant as well as a preparation method and application of the specific PET molecular probe. Pyridopyrimidine compounds and R5 are subjected to cooling reaction under the action of N, N-diisopropylethylamine to generate a compound 2; the compound 2 and (2-fluorotetrahydro-1H-pyrrolizine-7A (5H)-yl) methanol are subjected to a heating reaction under the action of N, N-diisopropylethylamine, and a compound 3 is generated; carrying out heating reaction on the compound 3 and biphenyl boronic acid pinacol ester under the action of N, N-diisopropylethylamine and tetrakis (triphenylphosphine) palladium to generate a compound 4; carrying out heating reaction on the compound 4 and 1, 2-bis (tolyloxy) alkane under the action of potassium carbonate to generate a compound 5; the compound 5, radioisotope < 18 > F and an anion complexing agent are subjected to a heating reaction under the action of potassium carbonate to generate the trisubstituted pyridopyrimidine < 18 > F labeled PET molecular probe. Compared with the prior art, the kit has a positioning diagnosis effect on KRASG12D mutant tumors, and image typing of mutant and non-mutant tumors and pathological evaluation after tumor treatment are realized at the same time.

Disclosed herein are dosage forms comprising a VAV1 degrader. More specifically, disclosed herein are dosage forms comprising 3-(2-chloro-4'-(2-oxopyridin-1(2H)-yl)-[1,1'- biphenyl]-3-yl)piperidine-2,6-dione or a pharmaceutically acceptable salt thereof. These dosage forms are useful, e.g., for treating a subject (e.g., a human subject) having a disorder or disease that can be treated by reducing the level of VAV1, for example an inflammatory or autoimmune disorder, a transplantation setting disorder, or a cancer.

A method of carbon dioxide fixation includes contacting a covalent organic framework material with a co-catalyst and an epoxide in the presence of carbon dioxide to form a cyclic carbonate. The covalent organic framework material includes reacted units of a 2,4,6-trimethyl-1,3,5-triazine, reacted units of a 4,4′-biphenyldicarbaldehyde, and palladium nanoparticles. The reacted units of the 2,4,6-trimethyl-1,3,5-triazine and the reacted units of the 4,4′-biphenyldicarbaldehyde form a COF-701, where the palladium nanoparticles are on an outer surface of the COF-701. The co-catalyst is n-tetrabutylammonium bromide.

The invention provides a diketone biphenyl compound serving as a VAV1 degradation agent and application of the diketone biphenyl compound. Specifically provided are a compound represented by formula (I), a tautomer, a stereoisomer, a pharmaceutically acceptable salt or a prodrug thereof. The compound provided by the invention is good in drug effect and can be used for preparing drugs for treating or preventing VAV1 related diseases.

The invention discloses a 1, 4-bis (4-fluorobenzoyl) benzene production waste utilization process, which belongs to the technical field of 1, 4-bis (4-fluorobenzoyl) benzene production, and comprises the following steps: dissolving waste leftovers in a solvent, and adsorbing and removing pigments and solid particles in the leftovers by activated carbon; carrying out dehalogenation and hydrogenation on the pretreated leftovers in the presence of a hydrogenation catalyst and an alkaline substance to produce 1, 4-biphenyl acyl benzene; and carrying out separation and purification on the hydrogenation product in a solution crystallization manner to obtain 1, 4-biphenyl acyl benzene with the purity of more than or equal to 99.75%. The waste leftovers are used for producing the 1, 4-biphenyl acyl benzene, so that the utilization rate of the raw materials is increased, the discharge of hazardous wastes is reduced, and the method is green and environment-friendly.

The invention discloses a preparation method of a Zr-MOF nano material, which comprises the following steps: adding deionized water into a reaction mixture consisting of zircon salt, 4 ', 4', 4 ', 4'-(ethylene-1, 1, 2, 2-tetraalkyl) tetra ([1, 1 '-biphenyl]-4-carboxylic acid), an acid regulator and an organic solvent to form a mixed solution, heating and reacting in a high-pressure reaction kettle, and cooling to room temperature to obtain the Zr-MOF nano material. And centrifugally collecting and cleaning a product, and drying in a dark place to obtain the Zr-MOF nano material. According to the application of the Zr-MOF nano material in the water-based zinc-iodine battery, the Zr-MOF nano material and iodine are prepared into a composite material, then the composite material is prepared into electrode slurry, the surface of a stainless steel mesh is coated with the electrode slurry, and the electrode slurry is dried to serve as an electrode plate of the water-based zinc-iodine battery. The preparation process is simple, Zr-MOF nano-materials with different structures can be obtained by adjusting the deionized water content of the system, and the Zr-MOF nano-materials can be applied to an electrode plate of an aqueous zinc-iodine battery to improve the cycle performance of the battery.

To provide an aqueous coating composition capable of forming a coating film with superior transparency, adhesion, and weather resistance while exhibiting superior coating stability.SOLUTION: An aqueous coating composition comprising emulsion particles (A), an ultraviolet absorber (B) having a biphenyl triazine skeleton, and a non-protonic organic solvent (C) having a boiling point of less than 100°C.SELECTED DRAWING: None

The invention discloses preparation of a nitrogen-rich ionic organic single crystal material and application of the nitrogen-rich ionic organic single crystal material in iodine adsorption, and belongs to the technical field of functional materials and radioactive pollutant treatment. The material is formed by self-assembly at room temperature through a solution method by taking biphenyl tetracarboxylic acid tetrabutylamine as an anion ligand and tetra (4-ethyl pyridine phenyl) ethylene bromide or tetra (4-imidazole phenyl) ethylene bromide as a cation ligand. The method is simple in preparation process, mild in condition and high in yield. The skeleton of the obtained material is rich in nitrogen sites and has a large cavity, the material shows extremely high adsorption capacity and rapid adsorption kinetics for iodine in a gas phase and a liquid phase, the maximum adsorption capacity of the material for iodine steam reaches up to 5.16 g / g, the retention rate of 95% or above can still be kept within 7 days after adsorption, and the material has good recycling performance. The material provides a novel and reliable solution for efficiently capturing and fixing radioactive iodine, and has a wide application prospect in the field of nuclear waste treatment.

Embodiments are directed towards the use of a supported biphenylphenol polymerization catalyst made from a biphenylphenol polymerization precatalyst of Formula I via a gas-phase or slurry-phase polymerization process under gas-phase or slurry-phase polymerization conditions to make a polymer.

The invention belongs to the technical field of membrane separation, and particularly relates to a polyamide composite membrane containing amino-carboxyl bifunctional COFs as well as a preparation method and application of the polyamide composite membrane. The preparation method comprises the following steps: by taking 1, 3, 5-tri (4-aminophenyl) benzene, 4, 4 '-diaminobiphenyl-2, 2'-dicarboxylic acid and 1, 3, 5-trialdehyde phloroglucinol as monomers, carrying out solvothermal reaction to prepare a bifunctional COFs material rich in amino groups and carboxyl groups at the same time; the preparation method comprises the following steps: dispersing a COFs material in a water phase containing polyamine, and carrying out interfacial polymerization on the water phase and an oil phase containing polyacyl chloride to prepare the composite membrane. COFs are firmly anchored in a polyamide network through a covalent reaction between amino and an acyl chloride monomer, so that the problems that the COFs are easy to fall off and non-uniform in dispersion are solved; the water flux is improved by regular pore channels of COFs, the membrane is endowed with strong hydrophilicity and electronegativity by carboxyl, the desalination rate and the pollution resistance are remarkably enhanced, and the COFs-based composite membrane has a wide application prospect in seawater desalination and high-salinity wastewater treatment.

The invention discloses a high-refractive-index photo-thermal dual-curing optical adhesive and a preparation method thereof, and belongs to the technical field of high polymer materials, and the preparation method comprises the following steps: S1, preparation of high-refractive-index resin: placing biphenyl-4, 4 '-dithiol in a nitrogen atmosphere reaction kettle, adding a free radical thermal initiator, heating to 180-200 DEG C, reacting for 1-2 hours, and cooling to room temperature to obtain the high-refractive-index resin; dropwise adding alkenyl resin under the protection of nitrogen, stirring, reacting for 1-2 hours after dropwise adding, and cooling to room temperature to obtain high-refractive-index resin; s2, preparation of the optical adhesive: mixing the alicyclic epoxy resin, the high-refractive-index resin, the toughened resin, the liquid epoxy resin, the cationic photoinitiator and the cationic thermal initiator, and uniformly stirring in a dark place to obtain the adhesive. The problems that a traditional optical adhesive is poor in optical performance stability and unbalanced in mechanical and optical performance are solved. The application potential of preparing the high-performance optical adhesive is realized.

The invention discloses a high-stability hydrated covalent organic framework membrane which comprises an ionic covalent organic framework and a self-supporting flexible substrate and is prepared by a vacuum-assisted self-assembly method, the thickness of the membrane is less than 100nm, and the pore size of the membrane is 2 + / -0.2 nm; the covalent organic framework is a nanosheet formed by polymerizing an aldehyde monomer 1, 3, 5-triformyl phloroglucinol and an amino monomer 4, 4 '-diamino-3. 3'-biphenyl disulfonic acid through a phase transfer method. According to the application of the membrane in natural gas decarburization, the membrane is applied to a wet natural gas purification system, has high flux and high selectivity in a CO2 / CH4 separation process, can tolerate multi-component conditions such as H2S, heavy hydrocarbons (C2H6, C3H8, n-C4H10, n-C6H14 and the like) and pressure as high as 33 bar, also has excellent separation performance on H2S / CH4, and has excellent separation performance in saturated steam of C6H14, C7H8 and C8H10 (hexane partial pressure is greater than or equal to 20 kPa). And the membrane separation performance is not obviously changed.

The invention provides a crystallization kettle for producing a polyfluorobiphenyl liquid crystal monomer, and relates to the technical field of fine chemical equipment, the crystallization kettle comprises a crystallization kettle main body, the crystallization kettle main body comprises a crystallization kettle body, the bottom end of the crystallization kettle body is communicated with a discharge interface, the top end of the crystallization kettle body is provided with a crystallization kettle cover, the crystallization kettle cover is communicated with an optional connecting pipe, and the optional connecting pipe is connected with the discharge interface. A stirring mechanism is arranged on the crystallization kettle cover, the stirring mechanism comprises a stirring motor, the stirring motor is mounted on the crystallization kettle cover, an instantaneous concentration mechanism and a floating mechanism are arranged in the crystallization kettle body, the instantaneous concentration mechanism comprises a liquid passing pipe, the liquid passing pipe is mounted in the crystallization kettle body, and the floating mechanism comprises a circular truncated cone shell. The crystallization kettle for producing the polyfluorobiphenyl liquid crystal monomer can enable the temperature and the stirring speed to automatically adapt to different stages of crystallization, and has the advantages of high crystallization efficiency, high crystallization quality and high crystallization yield.

The invention discloses a preparation method of a PNLC film and application of the PNLC film in an automobile intelligent dimming awning, and belongs to the technical field of liquid crystal materials for intelligent awning glass and preparation of the liquid crystal materials. The problems that an existing automobile intelligent dimming awning cannot meet the rapid dimming requirement and is poor in reliability and durability and the like are solved. A bifunctional liquid crystal monomer RM82 and a nematic liquid crystal E7 are compounded, acrylate end group polymerization of the RM82 is realized under the initiation of ultraviolet light, meanwhile, a biphenyl core structure and E7 can form a strong pi-pi conjugation effect, a phase separation energy barrier of the PNLC film is remarkably reduced, GQDs serve as a scattering enhancer, the PNLC film is endowed with a dynamic luminescence capability by utilizing the fluorescence characteristic of the GQDs, and the PNLC film has a good application prospect. The orientation of liquid crystal molecules is regulated and controlled through an electric field or temperature, the light scattering state is changed, switching of light transmitting, light scattering and light emitting is achieved, and the starry sky effect is simulated.

The invention relates to the technical field of optical thin films, and particularly discloses a high-birefringence laminated reflecting film and a preparation method thereof. According to the laminated reflecting film, 4, 4 '-biphenyl dicarboxylate modified PET is used as a raw material of an A layer, PMMA or PETG is used as a raw material of a B layer, the difference value of the glass transition temperatures Tg of the raw material of the A layer and the raw material of the B layer is controlled to be smaller than or equal to 5 DEG C, and the laminated reflecting film formed by alternately laminating the raw material of the A layer and the raw material of the B layer is subjected to synchronous two-way stretching and heat setting treatment; according to the application, PET is modified by the BB monomer, and a biaxial stretching process and the content of the BB monomer are regulated and controlled for the first time, so that Tg difference values of the raw materials of the layer A and the raw materials of the layer B are close, meanwhile, a refractive index difference value is increased, the reflecting film with excellent optical performance and mechanical performance can be obtained with a small number of lamination layers, and the reflecting film has high in-plane birefringence, high in-plane birefringence, high in-plane birefringence, high in-plane birefringence, high in-plane birefringence and high in-plane birefringence. And the reflectivity reaches 74% or above.

The present invention relates to the early treatment, including pre-diagnosis treatment, of sepsis and acute inflammatory syndromes such as systemic inflammatory response syndrome (SIRS) by PLA2 and metalloprotease inhibitors to improve the performance of antibiotics and outcomes prior to and after confirmation of the diagnosis of sepsis and / or SIRS in a patient or subject. Additional embodiments include methods of treating sepsis, anthrax and severe acute respiratory syndrome coronavirus (SARS and SARS-CoV2) and related inflammatory syndromes and compositions, including pharmaceutical compositions and blood sample compositions. In further embodiments, the present invention is directed to embodiments which evidence that LY315920, LY333013 and related sPLA2 inhibitors are particularly effective COVID-19 / cytokine release syndrome therapeutics-prophylactics. In embodiments, the PLA2 inhibitor is varespladib (LY315920), methyl varespladib (LY333013), AZD2716-(R)-3-(5′-benzyl-2′-carbamoyl-[1,1′-biphenyl]-3-yl)-2-methylpropanoic acid—as a racemic mixture or separately, as the “R” enantiomer), compound 4 (3-(5′-benzyl-2′-carbamoyl-[1,1′-biphenyl]-3-yl)-propanoic acid) and LY433771 ((9-[(phenyl)methyl]-5-carbamoylcarbazol-4-yl) oxyacetic acid), a pharmaceutically acceptable salt thereof or a mixture thereof. In embodiments, the metalloprotease inhibitor is Prinomastat, Batimastat, marimastat or vorinostat dosed alone or in combination with preferred sPLA2 inhibitors for the treatment of infection, inflammatory and wound conditions arising from various causes. Methods and compositions for achieving accelerated treatment of wounds and burns, anthrax metalloprotease toxin (lethal factor) driven complications, ARDS, neo-natal and pediatric acute respiratory distress syndrome (neo-natal / pediatric ARDS), including meconium aspiration syndrome and other disease states and conditions are also disclosed.

To provide an alignment film composition that can improve the hardness of a first alignment layer and an anchoring force of the first alignment layer to a liquid crystal effectively, thus remedying the phenomenon of light leakage in the display panel.SOLUTION: A display panel 1 includes a first substrate 11, a second substrate 12, and a first alignment layer 21. The first substrate is disposed opposite to the second substrate. The first alignment layer is disposed on a side of the first substrate closer to the second substrate, and the first alignment layer has a first polyimide molecular chain, and the first polyimide molecular chain comprises a unit represented below, wherein A is a group comprising at least one of a phenoxy group or a biphenyl group, n is an integer greater than or equal to 1, and m is an integer greater than or equal to 1.SELECTED DRAWING: Figure 1