244 results about "Toluidine" patented technology

An electric smoking system includes a cigarette including a cylindrical tobacco web partially filled with tobacco material to define a filled tobacco rod portion and an unfilled tobacco rod portion, and an electric lighter. The wrapper includes a filler of ammonium-containing compounds effective to reduce the gaseous constituents of the smoke produced during smoking. The system includes a pilot burner including at least one heating vane and a controller adapted to control heating of the heating vane. The lighter is configured to at least partially contain the cigarette such that the heater blade heats the heating region of the cigarette. Manipulating the controller to limit the heating of the heater blades to a predetermined temperature range which allows the delivery of the smoke generated when the portion of the tobacco rod is heated while at least reducing the amount of smoke present in the smoke as compared to smoking a cigarette having only calcium carbonate as filler. A gaseous component. The gaseous components that can be reduced include carbon monoxide, 1,3 butadiene, isoprene, acrolein, acrylonitrile, hydrogen cyanide, 0-toluidine, 2-naphthylamine, nitrogen oxide, benzene, NNN, Phenol, catechol, benzanthracene and benzopyrene.

The invention provides a preparation method and application of an anti-soil polymer. The prepared polymer is used as a dispersant for a hydraulic cementing agent and/or an aqueous dispersion for potential hydraulic cementing agent and has good anti-soil performance. The preparation method the anti-soil polymer comprises a step of subjecting polyether macromonomer A with a special structure, monomer B containing a phosphoric acid or phosphorous acid group, optional monomer D and aldehyde C to condensation polymerization so as to prepare the anti-soil polymer, wherein the monomer D is selected from the group consisting of phenol, aniline, p-/o-aminobezene solfonic acid, p-/o-hydroxybenzoic acid, p-/o-aminobenzoic acid, p-/o-hydroxyezene solfonic acid, p-/o-toluidine and p-/o-methylphenol, a mol ratio of the polyether macromonomer A to the monomer B to the monomer D is 1: (0.5-12): (0-8.0), and a mol ratio of the polyether macromonomer A to the monomer B and the monomer D is 1: (0.5-12.0).

A method for detecting 10 types of aromatic amines compounds (including aniline, ortho toluidine, m-toluidine, p-aminotoluene, m-phenylenediamine, m-methoxyaniline, 1- naphthylamine, 2- naphthylamine, 3- aminobphenyl and 4- aminobphenyl) in cigarette mainstream smoke by liquid chromatography-tandem mass spectrometry is characterized in that a Cambridge filter and an absorbing bottle containing 5%of HC1 solution respectively gather the aromatic amines compounds in a particle phase matter and a gas phase matter of mainstream smoke, after the 5%HCI solution is used for extracting the aromatic amines compounds on the filter, the aromatic amines compounds are purified by an HLB (hydrophile-lipophile balance) solid-phase extraction column, and a liquid chromatography-tandem mass spectrometry instrument is used for determining the 10 types of aromatic amines in the mainstream smoke in cigarettes. Compared with an existing GC-MS (gas chromatography-mass spectrometer) analysis method for detecting aromatic amines in mainstream smoke of cigarettes, the method does not need derivatization reaction or liquid-liquid extraction operation, greatly simplifies pretreatment steps of samples, improves analysis efficiency, and can more comprehensively detect harmful aromatic amines compounds in mainstream smoke of cigarettes.

The invention relates to a hole-transporting blue color compound, which is a fluorine derivative based on 9, 9-bi-(4-(bi-p-methypheny) aminophenyl). The preparation method is to first mix 9, 9-bi-[4-(N, N-bi-p-toluidine) phenyl]-2-dibromofluorine and boric acid pinacol ester of conjugate radicle, or to mix 9, 9-bi-[4-(N, N-bi-p-tolyl-amino) phenyl] fluorine -2, 7-bi-boric acid pinacol ester and bromide of conjugate radicle; and then add in toluene, potash solution, aliquat336 and catalyst tetrakis (triphenylphosphine) palladium, and heat and reflow for 10 to 30 hours in nitrogen environment; when the reaction is done, decompress, remove the solution and get the target product, the derivative based on 9, 9-bi-(4-(bi-p-methypheny) aminophenyl) fluorine substituted by unilateral conjugate radical. The compound can be used as the hole-transporting layer and the luminescent layer as well in electroluminescent devices.

The invention provides a method for detecting seven aromatic amine compounds in human urine through a liquid chromatography-series mass spectrometry. The method is to detect aniline, o-toluidine, m-toluidine, 1-naphthylamine, 2-naphthylamine, 3-aminobphenyl and 4-aminobphenyl, and is characterized by comprising the steps of hydrolyzing urine via concentrated HCl, purifying the sample through PAH (Polycyclic Aromatic Hydrocarbon) molecular imprinting columns, and analyzing through the liquid chromatography-series mass spectrometry (LC-MS/MS). Compared with the prior art, the method has the advantages that the LC-MS/MS method is adopted, so that higher sensitivity is achieved, and the pre-processing of the sample can be greatly simplified (about 2 hours are consumed); the pre-processing through a GC-MS (Gas Chromatography-Mass Spectrometer) method as shown in a literature is complicated and wastes time (by more than 6 hours). The method provided by the invention can effectively improve the analyzing efficiency, and is relatively suitable for analyzing seven aromatic amine compounds in human urine.

The invention relates to a polyalkyl-substituted aromatic diamine monomer, and the general formula of the structural formula is shown in the figure, wherein R is -CH(CH3)2 or -C(CH3)3; and the preparation is as follows: under nitrogen protection, 2,6-methyl toluidine is heated to the temperature of 100 to 120 DEG C, and the mixed liquid of aromatic formaldehyde and hydrochloric acid is slowly dropped in the 2,6-methyl toluidine and then the mixture is heated for carrying out reflux; after being cooled, 10% aqueous sodium hydroxide solution is dropped into the mixture till the pH value thereof is neutral, and then alcohol is added, the obtain sediment is washed with methanol; after drying of the mixture, chromatographic separation and purification is carried out on the mixture by silicagel column, thus obtaining the polyalkyl-substituted aromatic diamine monomer; the application can be used to prepare soluble, high-temperature resistant polyimide film material with high transparency and low dielectric constant. The substituted aromatic diamine monomer containing polyalkyl prepared in the invention has high purity and is table at room temperature; the preparation method has simple operation and low cost without any special requirement for equipment, thereby being applied to industrial production.

The invention provides a method for economically synthesizing 2,5-diaminotoluene and sulfate of the 2,5-diaminotoluene. The method comprises that: ortoluidine(OT) is subjected to diazonium-coupled reaction under the action of sodium nitrite in inorganic acid water solution to form 2-amino azotoluol(C.I.11160); the 2-amino azotoluol is subjected to reduction hydrogenolysis reaction in the presence of metal or catalyst(Zn or Ni, Pd/C or Raney-Ni), simultaneously the by product of ortoluidine is distilled out by vapor for cyclical utilization, and the 2-amino azotoluol is filtered to synthesize 2,5-diaminotoluene water solution; furthermore, serial products of 2,5-diaminotoluene sulfate(2,5-TDAS) and free 2,5-diaminotoluene(2,5-TDA) of the 2,5-diaminotoluene sulfate are prepared. Due to the adoption of the one-pot in situ synthetic technique, the method has the characteristics of convenient operation, high yield, general equipment, higher recovery circulation rate, easy disposal of waste water, the reduction of waste water discharge by more than 40 percent, effective execution of clean production, generation of circular economy and the like.

The invention discloses an aqueous metal antirust agent and a preparation method thereof. The aqueous metal antirust agent is prepared from following raw materials by weight: 10-20 parts of dodecylbenzenesulfonic acid, 20-30 parts of pentaerythritol tetraoleate, 40-45 parts of butyl oleate, 10-15 parts of o-toluidine, 7-15 parts of sodium sulfate, 10-20 parts of sodium hydroxide, 10-15 parts of sodium silicate and 40-50 parts of water. The aqueous metal antirust agent can be uniformly dispersed in water without impurities such as suspended solids, etc. and has good dispersity. The content of volatile organic compounds is 0.3-0.5 ppm. The content of harmful volatile compounds is low, thus having no harm to human health, and therefore the aqueous metal antirust agent is environment friendly and healthy.

The present invention relates to a hydrocarbon fuel composition comprising (i) at least 99% by weight of a base gas; and (ii) additives comprising (a) 2 to 50 ppm organometallic compound; and (b) 100 to 5000 ppm aniline or substituted aniline and 100 to 5000 ppm toluidine. The present invention discloses addition of an additive or additive mixture to base fuel preferably, liquefied petroleum gas. The addition of additive mixture not only improves the properties of the base fuel for use as torch gas for cutting and welding application, but also reduces the consumption of both fuel and oxygen for cutting applications.

The invention provides an immunohistochemical hematoxylin-toluidine blue double-redyeing method for melanocyte. The method comprises the following steps: (1), carrying out conventional xylene dewaxing on a slice and carrying out gradient alcohol dehydration; (2), blocking and inactivating endogenous peroxide enzyme; (3), repairing an antigen; (4), carrying out serum sealing; (5), dropwise adding primary antibodies; (6) dropwise adding secondary antibodies; (7), carrying out DAB developing; (8), carrying out hematoxylin redyeing and hydrochloric acid alcohol differentiation; (9), redyeing by a toluidine blue working solution and carrying out glacial acetic acid differentiation; (10), dehydrating to be transparent and sealing the slice. According to the invention, positive granules are still brownish yellow after redyeing, and original melanin granules in the tissue become deep green, so that distinction is obvious, the melanin granules are easily distinguished from brown granules, the developing of hematoxylin is not influenced, cell nucleuses of background cells are clearly visible, the color difference of immunohistochemical positive brownish yellow granules, deep green melanin granules and blue cell nucleus is obvious and intuitive, and distinguishing is convenient. Toluidine blue dyeing liquid is prepared simply and conveniently.

The invention belongs to the field of buildings, and relates to an energy-saving texture thermal insulation coating used for a building external wall. The energy-saving texture thermal insulation coating is composed of, by weight, 10 parts to 15 parts of water, 40 parts to 50 parts of hand feeling filler, 15 parts to 20 parts of quartz sand, 8 parts to 13 parts of silica-based adhesives, 6 parts to 9 parts of putty, 12 parts to 18 parts of diphenyl guanidine, 2 parts to 4 parts of zinc stearate, 1 part to 3 parts of organic zirconium complex, 3 parts to 5 parts of methyl toluidine, 4 parts to 7 parts of pentaerythritol, 3 parts to 6 parts of modified floating beads and 1 part to 3 parts of texture particles. The texture particles are prepared by adding, by weight, 6 parts to 10 parts of chlorinated paraffin, 3 parts to 7 parts of ethylene-propylene-diene monomer (EPDM), 1 part to 4 parts of silane coupling agents, aluminic acid ester coupling agents or aluminum-titanium composite coupling agents and 0.6 part to 1.2 parts of a mixture formed by mixing phenols main antioxygen 1010 and auxiliary antioxygen 168, and by conducting blending modification plastification and extrusion granulation. The hand feeling filler is a mixture of polyurethanes fluff powder and elastic powder or a mixture of crylic acid fluff powder and elastic powder. The texture thermal insulation coating has the excellent water-retaining property, and is high in caking property and alkali resistance, safe and environmentally friendly.

An environment-friendly type lubricating oil additive is composed of the following raw materials in parts by weight: 7 to 12 parts of castor oil polyoxyethylene ether, 3 to 6 parts of molybdenum disulfide colloid, 2 to 7 parts of n-octadecanoic acid, 4 to 8 parts of critic acid, 6 to 13 parts of molybdenum dialkyldithiophosphate, 4 to 8 parts of butyl oleate, 3 to 6 parts of tackifier, 5 to 8 parts of o-toluidine/m-toluidine, 6 to 8 parts of methyl citrate, 4 to 7 parts of triphenyl phosphorothionate, 6 to 12 parts of sulfurized isobutylene, 5 to 8 parts of benzotriazole amine, 2 to 6 parts of n-butyl acetate, 1 to 4 parts of p-methoxyl styrene, 8 to 16 parts of linoleic acid, 4 to 6 parts of methanol, 7 to 13 parts of polyethylene glycol monomethyl ether, 4 to 7 parts of magnesium silicate, and 4 to 6 parts of fluorine surfactant. The provided environment-friendly type lubricating oil additive can improve the wear-resistant performance, extreme pressure resistant performance, and oxidation resistant performance of lubricating oil, has the advantages of convenient operation and environment-friendliness, and is according with the green and environment-protection requirements.

The invention discloses a photosensitizer formula for photodynamically treating periodontitis and an application thereof. A hydrogel preparation for treating periodontitis takes toluidine blue as a photoactive substance and carbopol as a gel. A formula for optimizing the gel preparation comprises the following components by mass concentration: 0.05%-3% of carbopol, 0.001%-1% of toluidine blue, 0.01%-0.4% of sodium hydroxide or 0.07%-2% of triethanolamine and the balance of water. A method for photodynamically treating periodontitis, provided by the invention, can be used for replacing an antibiotic therapy, so that the problem of antibiotics abuse can be prevented; when the preparation is used for treating the oral diseases caused by infections, such as, periodontitis, the antibacterial rate of once irradiation treatment can reach up to 99.99%; serious patients can be repeatedly treated at intervals; and the photosensitizer formula is free from toxic or side effect to normal organ tissues and has wide market prospects and high application values.

The invention provides a method for preparing 3-chloro-p-toluidine-6-sulfonic acid by a liquid-phase baking method. The method comprises the following steps: mixing high-purity 2B oil as a raw material with an organic solvent serving as a liquid dispersant, performing a sulfonation reaction on the 2B oil and concentrated sulfuric acid in the liquid phase dispersant, and dehydrating and drying thesulfonated product to obtain 2B acid. By adopting the method, the high quality 2B acid is directly prepared by dehydrating and translocating in a liquid phase, and refining processes such as alkali dissolving, decolorizing, filtering, acid separating, dehydrating, drying and the like, so that the 'Three Wastes' can be greatly reduced, no solid waste is generated, waste gas and waste water have extremely small amount and can be easily treated, energy consumption can be reduced, and the existing sulfonating process is broken through. The method has the advantages of high conversion rate, low carbonization, few processes and low energy consumption.

The invention relates to a preparation method and application of a polycaprolactone glycol capillary gas chromatographic column. A polycaprolactone glycol polymer is used as a capillary gas chromatographic stationary phase, and the polymer is smeared onto the inner wall of an elastic molten quartz capillary which is pre-roughened by utilizing sodium chloride and methanol suspension by virtue of a static method. The obtained capillary column is high in column efficiency, good in inertness and good in heat stability, can be used for separating components different in polarity such as aliphatic and aromatic hydrocarbons, alcohols, ketones, aldehydes, amines and phenols, and positional isomers of the components, is particularly suitable for effectively separating the isomers which are difficult to separate such as dimethylbenzene, toluidine and methylphenol and has good application prospect.

The invention discloses a kit for simultaneously and rapidly measuring content of glucose, fructose and total sugar and an application method of the kit. The kit is developed based on a principle that carbohydrates are dehydrated to generate hydroxymethyl furfural under the acid action and the hydroxymethyl furfural and a developing agent are condensed to form a colored compound. The kit comprises four reagents, wherein the reagent I refers to a mixed standard substance of glucose, fructose and cane sugar; the reagent II refers to an ortho-toluidine reagent and is used for measuring the content of glucose; the reagent III refers to a resorcinol reagent and is used for measuring the content of fructose; and the reagent IV refers to a phenol reagent and is used for measuring the content of total sugar. The kit is used for simultaneously measuring the content of glucose, fructose and total sugar, has the characteristics of high specificity and high sensitivity, can realize high-flux and rapid detection of the glucose, fructose and total sugar, is large in sample treatment amount and relatively low in cost, is suitable for measuring the content of glucose, fructose and total sugar in honey, fruits and vegetables and other samples and is particularly suitable for large-scale field sample analysis.

The invention discloses a synthetic method for solvent violet 13, and develops a new route for synthesizing violet 13 by employing a one-pot process. The method comprises successively adding methanol, 1,4-dihydroxyanthraquinone, 4-nitrotoluene, iron powder and boric acid into a pressure container, sealing the container and performing nitrogen displacement, then heating with stirring, introducing hydrogen for hydrogenation reduction, after the reaction system stops absorbing hydrogen, performing warm-keeping reaction, heating after the reaction is finished, performing condensation reaction, cooling after the reaction is finished, releasing the pressure, introducing air and performing oxidation reaction, and finally adding hydrochloric acid for beating, filtering, washing and drying, so as to obtain violet 13. According to the method, the initial raw material p-toluidine is replaced by 4-nitrotoluene, direct usage of the highly-toxic raw material p-toluidine is avoided, and the synthetic technology is low in toxicity and friendly to environment. By pouring all of the raw materials into the container, the postprocessing process of the intermediate step is saved, and a large amount of manpower and material resource is saved.

The invention belongs to the field of fuel-cell catalysts, and relates to a three-dimensional porous Fe-N-C catalyst based on cetyl trimethyl ammonium bromide as a carbon material pore-forming agent and a preparation method. The three-dimensional porous Fe-N-C electrocatalyst is obtained through high-temperature calcination of o-toluidine as a C source and an N source, FeCl3.6H2O as a metal source, CTAB as a soft template and SiO2 as a hard template under an N2 atmosphere. In the preparation process, the size and the shape of a micelle can be accurately controlled through changing the concentration of the CTAB, a three-dimensional interconnected porous structure with a lot of active sites exposed on the surface can be finally formed after the templates are removed due to CTAB micelle decomposition after high-temperature calcination, the quantity of the active sites for catalytic oxygen reduction reaction is ensured, the mass transfer requirements can be met and improvement of the ORR activity of the catalyst is facilitated. Compared with a traditional Fe-N-C electrocatalyst, the three-dimensional porous Fe-N-C catalyst has the advantages that the three-dimensional porous structure of the catalyst is more beneficial to oxygen transfer and adsorption, the preparation process is flexible and controllable, the raw materials are cheap and available, massive production is facilitated and the three-dimensional porous Fe-N-C catalyst has relatively high practical value.

The invention relates to an anti-light ageing finishing method of aromatic polyamidoester fibre cloth, and the method comprises processing aromatic polyamidoester fibre cloth in anti-light ageing finishing agent for 90+-5 minutes under the temperature of 120+-2 DEG C, washing cloth with surface active agent and drying after finishing, wherein the mass ratio of aromatic polyamidoester fibre cloth and anti-light ageing finishing agent is 100:20+-1, the anti-light ageing finishing agent is emulsion whose solid content is 20+-1% and is formed by N,N-diethylm-toluidine, alkyl phenol polyoxyethylene ether and alkylbenzene polyoxyethylene ether which are dissolved in water according to the mass ration which is 80+-0.5:15+-0.5:5+-0.5. The method can lead the intensity after aramid fiber cloth is aged through ultraviolet to reach 87%, and the method has no influence to the physical and chemical property of aramid fiber cloth, and the mechanical property after finishing has no loss. The method of the invention has the advantages of simple technique, strong operability, convenient operation and low production cost.

The invention discloses unsaturated polyester putty for automobile sheetmetal. Main agent of the unsaturated polyester putty comprises, by weight, 100 parts of unsaturated polyester resin, 5-7 parts of methyl hydroxyethyl toluidine, 1-2 parts of styrene, 0.8-1.2 part of polytetrafluoroethylene wax, 0.5-1 part of hydroquinone, 1-2 parts of gaseous SiO2, 4-6 parts of titanium dioxide, 1-2 parts of hollow glass beads, 5-8 parts of pulvistalci and 5-6 parts of expansion ultrafine powder. Initiator of the unsaturated polyester putty comprises, by weight, 60-70 parts of benzoyl peroxide, 25-35 parts of dibutyl phthalate, and 2-8 parts of silicon dioxide.

The invention discloses novel composite bone cement with biological activity, raw materials comprise powder and liquid, the powder comprises the following parts in percentage by mass: 39%-84.3% of polymethyl methacrylate microspheres, 5%-15% of zirconium dioxide, 0.5%-3% of benzoyl peroxide, 0.2%-2% of gentamicin sulfate and 10%-41% of strontium-magnesium co-doped hydroxyapatite whiskers, The liquid comprises the following parts in percentage by mass: 98-99.6% of methyl methacrylate and 0.4-2% of N, N-dimethyl p-toluidine, mixing the powder and the liquid, stirring, standing, shaping and curing to obtain the novel composite bone cement. Bone-like apatite can be induced to be deposited on the surface of the bone cement in in-vitro simulated human body fluid, new bones can be promoted to grow on the interface of the bone cement and bone tissues in animal model rabbit bodies, good biological activity and osteogenesis promoting capacity are shown, and the compressive strength, bending strength and bending elastic modulus of the bone cement are all higher than those of conventional bone cement.