286 results about "Reactive dye" patented technology

The invention relates to the technical field of wastewater recovery, in particular to a recovery device and process for reactive dye dyeing wastewater, and the recovery device comprises a tank body which is internally provided with a filter plate and a cleaning assembly, and the cleaning assembly comprises a cleaning plate; the collecting assembly comprises a collecting box mounted above the cleaning plate; the flushing assembly comprises a plurality of groups of connecting rods, and nozzles are mounted on the plurality of groups of connecting rods; the device has the beneficial effects that reactive dye dyeing wastewater is filtered through the filter plate, when the motor drives the cleaning plate to rotate, the elastically arranged scraping plate can scrape residues attached to the surface of the filter plate, the residues are prevented from blocking filter holes in the filter plate, and when the cleaning plate rotates, the residues scraped by the scraping plate are accumulated in the collecting frame, so that the cleaning effect is good. And under the flowing of the water flow, the water flows into the collecting box through the through groove, so that the residues are collected.

The invention belongs to the technical field of textile printing and dyeing, relates to an efficient reactive dye ink-jet dyeing process and application, and aims to solve the problems that the traditional dyeing proofing process is tedious, the color difference of front and back surfaces of ink-jet dyeing is large, and the dye utilization rate is low. The process comprises the following steps: firstly, padding a fabric in an aqueous solution until the pick-up rate is controlled to be 60-120%, and carrying out ink-jet printing on reactive dye ink (the viscosity is 3-10 mPa.s and the surface tension is 20-50 mN / m) in a wet fiber swelling state; after printing, a 1%-10% alkali solution is immediately padded to promote permeation of the dye; and then pre-drying at 60-70 DEG C, steaming with saturated steam at 100-102 DEG C for 5-15 minutes, and washing with water to complete color fixation. According to the technology, the K / S ratio of the front face and the back face of the dyed fabric is larger than or equal to 0.95, the color fastness of the dry friction level 4-5 or above, the color fastness of the wet friction level 4-5 and the color fastness of the soaping level 4-5 are achieved, and the technology is suitable for green efficient dyeing of small-batch multi-variety fabric.

The invention belongs to the technical field of textile dyeing, and provides a salt-free alkali-free electrostatic spray dyeing method for cellulosic fibers, which comprises the following steps: uniformly mixing polyethylene oxide, reactive dye and solvent to obtain electrostatic dye liquor; the method comprises the following steps: dissolving a cationic modifier and an alkaline color fixing agent in water to prepare a cationic modified solution, padding a cellulose fiber fabric, and drying to obtain a cationic modified cellulose fiber fabric; and spraying the electrostatic dyeing liquid to the surface of the cationic modified cellulose fiber fabric through electrostatic spraying, and carrying out open-width steaming color fixation and cleaning to obtain the electrostatic spraying dyed cellulose fiber fabric. The electrostatic spraying technology is adopted to replace traditional water bath dyeing, excellent K / S value, dye uptake and color fastness can be achieved without consuming a large amount of salt, alkali and water, water resource consumption and environmental pollution are remarkably reduced, and high-salinity and high-chroma printing and dyeing wastewater is avoided.

The invention relates to the technical field of ink-jet printing, and discloses reactive dye ink-jet printing ink based on ionic association regulation and a printing method of the reactive dye ink-jet printing ink. According to the method, on the basis of a cationic compound with the relative molecular weight of 50-1000 in an ink system, the aggregate structure of the anionic surfactant is accurately induced to be controllably converted from a spherical structure to a wormlike or layered structure by virtue of the action of ionic bonds; under the action of not additionally adding a viscosity modifier, the rheological property and dynamic surface tension of reactive dye ink are accurately regulated and controlled, and the dynamic surface tension response rate is remarkably improved, so that the uniformity and stability of the morphology of ink droplets in inkjet printing are improved, the dynamic wetting behavior in the collision process of the ink droplets and a base material is effectively improved, and the printing quality is improved. And high-precision ink-jet printing of the reactive dye ink on the textile fabric is realized.

The application discloses a preparation method of active chitosan quaternary ammonium salt modified cellulose fabric based on a dispersion system, and belongs to the field of textile chemistry. The effective grafting of chitosan quaternary ammonium salt and nitrogen-containing heterocyclic monomers is realized by using a dispersion system, the active sites on the chitosan quaternary ammonium salt are increased, the covalent grafting effect of the active chitosan quaternary ammonium salt and the cellulose fabric is improved, the cellulose fabric is endowed with durable antibacterial function, the dyeing performance of the cellulose fabric in natural dyes and active dyes is improved, and when the cellulose fabric prepared by the method is dyed by using active dyes, the amount of neutral salt can be reduced.

The invention relates to the technical field of non-woven fabric processing, and discloses a non-woven fabric dyeing process which comprises the following steps: step 1, pretreatment; the method comprises the following steps: (1) solution preparation: preparing an aqueous solution containing a surfactant and a penetrant, selecting fatty alcohol-polyoxyethylene ether as the surfactant and controlling the mass concentration at 0.5%-1%, and adopting JFC as the penetrant and controlling the mass concentration at 0.2%-0.5%; and (2) soaking treatment: completely soaking the non-woven fabric into the solution, keeping the soaking temperature at 30-40 DEG C, and setting the soaking time to be 15-25 minutes. According to the dyeing process of the non-woven fabric, a specific surfactant and a penetrating agent are used in the pretreatment step, reactive dye and a proper amount of dyeing assistant are adopted in the dyeing process, dyeing is carried out under the conditions of proper temperature, pH value and time, a cationic color fixing agent is selected in the color fixing step, and the cationic color fixing agent can chemically react with the dye to form stable chemical bonds; therefore, the effects of ensuring uniform dyeing and color brightness of the non-woven fabric and reducing the cost can be achieved.

The invention provides a reactive dye with a high fixation rate and a preparation method thereof. The reactive dye is prepared from the following raw materials in parts by mass: 25 parts of modified reactive dye, 0.3-0.7 part of a metal ion agent and 60-80 parts of water, wherein the modified reactive dye is obtained by inclusion of reactive dye molecules with beta-cyclodextrin-pyridine carboxylic acid, and beta-cyclodextrin and pyridine carboxylic acid in the beta-cyclodextrin-pyridine carboxylic acid are connected through an alkyl chain; metal ions provided by the metal ion agent can be chelated with the picolinic acid. Reactive dye molecules and beta-cyclodextrin-pyridine carboxylic acid form an inclusion structure, the hydrolysis probability of active groups is reduced, and an alkyl chain regulates steric hindrance and molecular spacing, so that pyridine nitrogen and carboxylic acid more efficiently form a more stable chelate with metal ions and further form coordinate bonds with hydroxyl groups on the fiber surface, and the fixation rate of the reactive dye is improved.

The application discloses a low-temperature one-bath dyeing process for polyester-cotton blended fabric, which comprises the following steps: soaking the polyester-cotton blended fabric in an aqueous solution of alkaline ionic liquid for pretreatment to obtain a pretreated fabric with liquid; then mixing the pretreated fabric with liquid with reactive dyes and disperse dyes, and then performing supercritical CO2 fluid dyeing to obtain dyed fabric; the alkaline ionic liquid contains hydrophobic alkyl groups and has alkalinity; during the pretreatment, the alkaline anions form a hydrogen bond network with the hydroxyl groups of cellulose, thereby destroying the crystalline region of cellulose and increasing the dyeing rate; during the dyeing, the alkaline ionic liquid is distributed on the interface between water and CO2 fluid as a surfactant to form an inverse emulsion, thereby providing a microenvironment for the dyeing of cotton fibers by the reactive dyes; in addition, the alkaline anions of the alkaline ionic liquid can exchange with CO2 to generate carbonates, so that the polarity of the microenvironment is enhanced to be alkaline, and the reactivity of the reactive dyes and cotton fibers is improved, thereby improving the dyeing rate.

The application relates to a preparation method and application of a performance-adjustable reactive cationic polymer, and belongs to the field of textile printing and dyeing. The preparation method of the performance-adjustable reactive cationic polymer comprises the following process steps: mixing an epoxy reactive monomer with concentrated hydrochloric acid, reacting for a certain time under ice bath, and adjusting the pH of the reaction system to be neutral; adding a cationic monomer into the above reaction system, simultaneously adding a phase transfer catalyst or an organic solvent, adding an initiator drop by drop under a nitrogen atmosphere, stirring to carry out a free radical polymerization reaction, naturally cooling after the reaction is completed, and drying to obtain the reactive cationic polymer. According to the application, salt-free high-color-yield dyeing of reactive dyes can be realized when the amount of the cationic polymer is very low.

The invention discloses a preparation method of a multifunctional silk / fungus grass interwoven fabric. The preparation method comprises the following steps: (1) pretreating fibers; (2) weaving the interwoven fabric; (3) dyeing the fabric; (4) after-finishing the fabric; the advantages of the silk fibers and the fungus grass fibers are reserved at the same time, the long-acting antibacterial effect of the silk / fungus grass interwoven fabric is achieved through the antibacterial property of the fungus grass fibers, the fabric has the temperature adjusting function, the fragrance function, the machine washable function and the like at the same time through wet finishing, and the prepared silk / fungus grass interwoven fabric can be used for the fields of clothes, home textiles and the like. According to the method, the cohesive force lifting agent is utilized to conduct pretreatment on the silk fiber and the Juncao fiber before weaving, the equivalence of the cohesive force of the two fibers is guaranteed, the end breaking phenomenon in the weaving process is reduced, and meanwhile the smoothness of the interwoven fabric is guaranteed. The homochromatic coloring of the silk / fungus grass interwoven fabric is realized by utilizing the double-active-group reactive dye through a one-bath method, and the silk / fungus grass interwoven fabric has the advantages of high efficiency, good homochromatic property and the like.

The invention discloses a bisazo blue reactive dye for high-temperature dip dyeing as well as a preparation method and application of the bisazo blue reactive dye. The reactive dye is shown in a structural general formula (I). A color body of the reactive dye is of a bisazo structure, the color body contains two naphthalene ring structures and a benzene ring structure, and an active group in a dye molecular structure is quaternary ammonium salt containing a nicotinic acid structure. According to the present invention, the binding force between the dye and the fiber can be improved through the coplanarity of the chromophore molecules, the dissociation between the dye and the fiber at the high temperature can be reduced, and the dye uptake of the dye at the high temperature can be improved, such that the fixation rate between the dye and the fiber can be improved; meanwhile, quaternary ammonium salt containing a nicotinic acid structure can react with fibers under the high-temperature neutral condition, an alkaline agent does not need to be added in the whole dyeing process, the problem of environmental pollution caused by the alkaline agent in the printing and dyeing wastewater is solved, and wide application prospects are achieved.

This invention relates to the field of textile printing and dyeing, and discloses a high-colorfastness polyamide 56 fabric and its preparation method. The polyamide 56 fabric contains 70-100% polyamide 56 fiber and 0-30% spandex. The fabric has been dyed at least once, and the dye used for dyeing is a reactive dye. The polyamide 56 fabric dyed with reactive dyes of this invention has the advantages of higher dye uptake, wider pH adaptability, no need for large amounts of calcium salts for dyeing, and minimal or no use of color-fixing crosslinking agents.

This invention provides an antistatic dyeable spandex fiber and its preparation method. During spandex production, N-(2-hydroxyethyl)ethylenediamine is used as a terminating agent for chain extension, combined with the use of the stabilizer TAD, to prepare antistatic dyeable spandex fiber. This improves the dyeing rate and color fastness of spandex fiber to acid dyes and reactive dyes. Furthermore, the heat-resistant dyeable spandex can meet the high-temperature dyeing requirements in the polyester / spandex field. Simultaneously, the improved antistatic properties of the spandex fiber reduce the amount of oiling agents used by spandex manufacturers, thereby lowering production costs. For subsequent processes, it reduces the defect rate in dyeing, finishing, and weaving, saving costs.

The invention discloses an Aspergillus niger detection kit based on SERS (Surface Enhanced Raman Scattering) and a preparation and detection method thereof, the kit comprises an SERS nano-label, the structure of the SERS nano-label takes bionic gold nanoflower as a gold core, and the surface of the gold core is modified with a Raman reactive dye and an Aspergillus niger specific aptamer. The kit has high sensitivity, specificity, reproducibility, uniformity and stability, Raman spectrum can be collected through portable Raman spectrum equipment, the kit can be used for analysis of trace Aspergillus niger in a sample, and the detection limit is lower than 10 CFU / mL. Compared with a traditional bacterial culture method, the method has the advantages in the aspects of simplicity and convenience in operation, detection period, analysis cost and the like. The method is suitable for food safety monitoring.

The invention belongs to the field of reactive dye synthesis, and discloses a preparation process of a reddish brown reactive dye, which comprises the following steps: diazotizing 2-naphthylamine-4, 6, 8-trisulfonic acid, coupling with 1-naphthylamine-7-sulfonic acid to obtain a first-couple material, diazotizing the first-couple material again, coupling with m-toluidine to obtain a second-couple material, refining the second-couple material to obtain a color base, and drying to obtain the reddish brown reactive dye. Carrying out primary condensation on cyanuric chloride and 2, 5-aniline disulfonate to obtain a primary condensation material, carrying out secondary condensation on the primary condensation material and a color base, and filtering the secondary condensation slurry to obtain the reddish brown reactive dye primary stock. The preparation process provided by the invention is stable and low in spray drying energy consumption, and the prepared primary pulp has the advantages of high purity and high solid content, and is excellent in solubility and high in fastness to washing.

The invention discloses a one-paste printing process for dispersing and reactive dye of polyester-cotton fabric. The process flow comprises the following steps: pre-rolling the polyester-cotton fabric with alkali liquor, drying, performing one-paste printing, drying, steaming, drying, baking, washing with cold running water, soaping, washing with warm water, washing with cold water, drying and discharging cloth. The method has the advantages of high fixation rate, short process flow, low wastewater COD (Chemical Oxygen Demand) and the like, and achieves the effects of improving efficiency, saving energy and reducing pollution.

This application relates to the technical field of reactive dyes, specifically to a photochromic red fluorine-containing reactive dye, its preparation method, and its application. The general structural formula of this photochromic red fluorine-containing reactive dye is as follows: [Formula omitted for brevity]. Wherein, R1 and R2 are -H, -SO3M, -CH3, -COOM, -NO2, or -NHCONH; R3 is -Cl or -SO3M; and M is Na, K, or Li. The reactive dye provided in this application exhibits good wash fastness, rubbing fastness, chlorine fastness, and good solubility on cotton fabrics, while also possessing excellent light fastness and superior fixation rate on cotton fabrics during medium-temperature dyeing.

The application discloses an aspergillus niger detection kit based on SERS and a preparation and detection method thereof. The kit comprises a SERS nanolabel, and the structure of the SERS nanolabel is that a bionic gold nanoflower is used as a gold core, and a Raman active dye and aspergillus niger specific aptamer are modified on the surface of the gold core. The kit has high sensitivity, specificity, reproducibility, uniformity and stability, can collect Raman spectrum through a portable Raman spectrum equipment, can be used for analyzing trace aspergillus niger in a sample, and the detection limit is lower than 10 CFU / mL. Compared with a traditional bacterial culture method, the kit has advantages in operation simplicity, detection period and analysis cost. The kit is suitable for food safety monitoring.

The application discloses a dyeing boosting agent and a low-temperature salt-free dyeing method for bio-based PLA / regenerated cellulose fiber blended fabric, and relates to the technical field of textile dyeing. A synergistic cross-linking modification system is constructed by using a bio-based small-molecule phenol with double functional groups and a high-density amino polymer. The fabric is pretreated and immersed for modification, a stable ion cross-linking adhesion layer is formed on the surface of the fiber, and then low-temperature dyeing of the electrolyte-free reactive dye is carried out. The process adopts a one-bath one-step method, does not need high temperature, high salt and reduction cleaning procedures, is simple in process, low in carbon and environmentally friendly, can realize synchronous dyeing and uniform color of PLA and regenerated cellulose fiber, effectively improves the fabric dyeing rate and color fastness, and significantly improves the ultraviolet resistance of the product. The application solves the problems of poor uniformity, low color fastness and large pollution existing in the traditional dyeing process, and is suitable for green and efficient production of bio-based blended fabric.

The application discloses a high-fast orange reactive dye and a preparation method thereof, relates to the field of reactive dyes, and comprises a structure general formula as follows: formula 1: formula 2: or formula 3: wherein R1 is halogen; R2 is -H, -SO3M, -CH3, -COOM or -CHO; and M is Na, K or Li. The application has the effects of improving the fixing effect and dyeing performance of the reactive dye.

The application relates to the dye technology field, and particularly discloses a pyrimidine acid observation blue active dye, a preparation method and application thereof. A trichloropyrimidine is introduced as an active group on the basis of the observation blue structure, the reactivity of the trichloropyrimidine is lower than that of the cyanuric chloride structure, the pyrimidine acid observation blue active dye is more stable after being combined with cellulose fibers, is not easy to hydrolyze, the acid and alkali resistance of a 'dye-fiber' covalent bond is better, and the dyeing performance is more superior; in addition, water-soluble groups such as sulfonic acid groups and carboxyl groups are introduced to improve the water solubility of the pyrimidine acid observation blue active dye. Furthermore, the pyrimidine acid observation blue active dye prepared by the application has good dyeing effects on acrylic fibers, spandex and other chemical fiber fabrics and blended fiber fabrics, further improves the adaptability of the observation blue, the dyeing is stable, the color is deep, the fixation effect is good, meanwhile, the acid and alkali resistance of the fabric is improved, and the application prospect is wide.

A method is disclosed for producing denim-effect garments by the following steps: 1) printing a reactive dye ink onto a PET film to form a pattern thereby obtaining a transfer printed PET film; 2) transfer printing a base pulp-treated fabric by attaching the transfer printed PET film thereby obtaining a denim-effect fabric; 3) cutting, sewing, washing to soften, and drying the denim-effect fabric and thereby obtaining a denim-effect garment. The method has the advantages of simple production, being environmentally friendly, having high efficiency, and being suitable for flexible fabrics, and the produced denim-effect garment of the invention has the advantages of having a good color fastness to rubbing, washing resistance, and having a diversity of patterns, and are suitable for large-scale production and application.

The application relates to the technical field of organic dyes, in particular to a double-active-group cationic modified anthraquinone reactive dye as well as a preparation method and application thereof. The preparation method of the double-active-group cationic modified anthraquinone reactive dye comprises the following steps: S1: dissolving 1-amino-4-sulfonic acid-1'-(N,N-dimethylpropylaminomethyl) anthraquinone in ice water, then adding melamine dropwise to carry out reaction, and obtaining an intermediate solution; S2: the intermediate solution is warmed to 20-25 DEG C, and hydroxyethyl sulfone sulfonate is added to carry out reaction; after the reaction is completed, salting-out is carried out, and the double-active-group cationic modified anthraquinone reactive dye is obtained, as shown in formula (1). The reactive dye is synergized through the cooperation of "double active groups + cationic adjustment + precise water-solubility design", can guarantee water-solubility and dyeing fastness, and can completely get rid of the dependence on a large amount of salt.

A surgical instrument wrap having at least one or a plurality of fibrous layers that cooperate with at least one agent or dye layer that is generally not visible until the at least one or plurality of fibrous layers is damaged or disrupted. The at least one diffusible agent or dye layer diffuses or wicks into the disrupted or damaged area. A fluorescent dye, a reactive dye, a conjugant dye or an absorption wavelength of approximately 200-400 nanometers in one embodiment and an emission wavelength in the visible spectrum so that when the surgical wrap is damage or disrupted and then exposed to, for example, a fluorescent or ultraviolet light source, the agent or dye fluoresces to provide an indication to the user that damage to the wrap has occurred. The user can presume that the items or instruments in the surgical tray may be contaminated.

Described herein is a method for producing centrally colored silicone hydrogel contact lenses. The method comprises a step of cast molding of a lens-forming composition including a hydroxyl-containing polymerizable component to form an unprocessed silicone hydrogel contact lens having hydroxyl groups covalently incorporated into its polymer matrix and steps of applying and fixing a reactive dye to the polymer matrix only in its central circular region concentric with the central axis of the unprocessed silicone hydrogel contact lens. The obtained centrally colored silicone hydrogel contact lens has a central circular region that is only colored to selectively filter radiations of certain wavelengths, e.g., HEVL.

The present invention is related to reactive dyes each of which comprises a dichlorotriazine, chlorotriazine or vinylsulphonyl group and is capable of absorbing HEVL. They are suitable for method for producing colored silicone hydrogel contact lenses each made of a silicone hydrogel material having hydroxyl groups. The present invention is also related to a colored silicone hydrogel contact lens comprising a colored circular region in which a reactive dye is applied and thereby covalently attached.

The present application belongs to the field of fine chemical industry and textile printing and dyeing, and relates to a reactive dye which can be used for fixing color of dyed polyester fabric by dry heat setting process, a preparation method and dyeing application thereof. The reactive dye provided by the present application has a general structure, and the present application also simultaneously provides the use of the reactive dye, i.e. fixing color of dyed polyester fabric by dry heat setting process. Through ingenious design and application of the carbene type dye, the present application realizes high color fastness effect of dyed polyester fabric, eliminates the adverse factors of high temperature heat setting, and expands the optional range of setting heat setting process (temperature, time).

The invention relates to the field of spinning, and discloses a multistage self-polymerization cross-linking agent as well as a preparation method and application thereof. The method comprises the following steps: (1) preparing raw materials including cyanuric chloride, para-ester, monoamino hydroxyaniline, diaminobenzene sulfonic acid, a neutralizer and a composite solvent; (2) carrying out a reaction on cyanuric chloride, para-ester, monoamino hydroxyaniline and diaminobenzene sulfonic acid in a composite solvent, and controlling the pH value of a system in the reaction process to be 4-7 by adopting a neutralizer to prepare a multistage self-polymerization cross-linking agent dispersion liquid; and (3) carrying out reduced pressure distillation on the multi-stage self-polymerization cross-linking agent dispersion liquid to remove the composite solvent in the multi-stage self-polymerization cross-linking agent dispersion liquid to prepare the multi-stage self-polymerization cross-linking agent. The multistage self-polymerization cross-linking agent provided by the invention can realize cross-linking reaction with fibers under the condition of dyeing natural fibers by reactive dyes and in the dyeing process, the implementation process is simple and easy to implement, and the multistage self-polymerization cross-linking agent is convenient to use.

Described herein is a method for producing centrally colored silicone hydrogel contact lenses. The method comprises a step of cast molding of a lens-forming composition including a hydroxyl-containing polymerizable component to form an unprocessed silicone hydrogel contact lens having hydroxyl groups covalently incoporated into its polymer matrix and steps of applying and fixing a reactive dye to the polymer matrix only in its central circular region concentric with the central axis of the unprocessed silicone hydrogel contact lens. The obtained centrally colored silicone hydrogel contact lens has a central circular region that is only colored to selectively filter radiations of certain wavelengths, e.g., HEVL.