The invention belongs to the technical field of
ceramic pigments, and specifically relates to a preparation method of a
spinel type composite ultrafine blue
ceramic pigment. The preparation method comprises the following steps: (1) dissolving
CoAl2O4 into water to obtain a solution (A); (2) evenly mixing butyl
titanate with
anhydrous ethanol with a volume 2 to 3 times of that of butyl
titanate to obtain a solution (B); (3) adding the solution (B) into the solution (A) under stirring, stirring the
mixed solution at a
room temperature for 5 hours or more, and allowing the
mixed solution to stand still to carry out aging for 24 to 48 hours so as to obtain opaque gel; (4)
drying and
grinding the opaque gel obtained in the step (3) to obtain loosened precursor
powder, transferring the precursor
powder to a
muffle furnace, and burning the precursor
powder in the
muffle furnace for 4 to 6 hours at a temperature of 400 to 500 DEG C so as to obtain the blue
ceramic pigment. The prepared
spinel type composite ultrafine blue ceramic
pigment combines the excellent performances of
CoAl2O4 and TiO2 and has the advantages of good
thermal stability, high
chemical stability, bright color and luster, and unchanged color at a high temperature.