This invention relates to a
boron-doped multi-element polyanionic
sodium-
ion battery
cathode material and its preparation method, comprising the following steps: [The method involves] mixing Na₄Fe₂O₃ with... 3‑X B X (PO4) 2‑Y (SiO4) Y The stoichiometric ratio of P2O7 is determined by adding
ferrous source,
boric acid,
sodium source,
phosphorus source, and
silicon source to water, followed by the addition of
carbon source and mixing thoroughly to obtain a mixed
slurry; wherein 0.2≤X≤0.5, 0<Y≤1; the mixed
slurry is then ground to obtain a sand-milled
slurry; the sand-milled slurry is dried to obtain precursor
powder; under a protective
atmosphere, the precursor
powder is sintered at 450~550℃ to obtain
boron-doped multi-element polyanion
sodium-
ion battery
cathode material. The introduction of
boron and
silicon elements in this invention helps reduce
raw material costs, improve the electrochemical performance of the material, especially enhancing the
structural stability, rate performance, and cycle life of the
cathode material, and also lowers the
sintering temperature, meeting the requirements for cost reduction and efficiency improvement.