1813 results about "Polyethylenimine" patented technology

The invention relates to the field of membrane materials, and discloses an epoxy modified starch-based degradable membrane and a preparation method thereof, the epoxy modified starch-based degradable membrane comprises epoxidized starch, modified nanocellulose and a plasticizer; the modified nano cellulose is prepared by mixing a modified composite filler, a nano cellulose dispersion liquid and a zinc acetate dihydrate aqueous solution; the nano-cellulose dispersion liquid is prepared by adhering polytannic acid formed by oxidation and self-polymerization of tannic acid to the surface of nano-cellulose; the modified composite filler is prepared by performing carboxylation modification on nano titanium dioxide coated fumed silica nanoparticles by using succinic anhydride and gamma-aminopropyltriethoxysilane, then reacting with polyethyleneimine to obtain an aminated composite filler, and finally grafting glycidyl dodecyl dimethyl ammonium chloride to the surface of the aminated composite filler. The prepared film material is high in tensile strength, has certain hydrophobicity, and has good heat resistance, antibacterial property and flame retardant property.

The invention provides a flame-retardant heat-insulating fabric for fire-fighting clothes and a preparation process thereof, and belongs to the technical field of fire-fighting fabrics. The preparation process comprises the following steps: preparing coated modified ammonium polyphosphate; modified expanded perlite; preparing a flame-retardant outer-layer fabric; preparing a heat insulation core layer fabric; preparing an antibacterial inner layer fabric; and bonding. The flame-retardant heat-insulating fabric for the fire-fighting clothes comprises a flame-retardant outer-layer fabric, a heat-insulating core-layer fabric and an antibacterial inner-layer fabric, ammonium polyphosphate is dispersed in deionized water, polyethyleneimine is added under the acidic condition, amino on the polyethyleneimine and ammonia ions of the ammonium polyphosphate are subjected to an ion exchange reaction, and the flame-retardant heat-insulating fabric for the fire-fighting clothes is obtained. According to the flame-retardant outer-layer fabric, ammonium polyphosphate is preliminarily coated, then a hydroxyethylidene diphosphonic acid solution is added for a salt forming reaction, coated modified ammonium polyphosphate with a core-shell structure is prepared, the coated modified ammonium polyphosphate and polyester powder are mixed and granulated, then the flame-retardant outer-layer fabric is prepared, and the flame-retardant property of the flame-retardant outer-layer fabric can be effectively improved.

The invention relates to the field of spinning, and particularly discloses a curtain fabric with an antibacterial function and a preparation method thereof.The curtain fabric comprises a base fabric layer, an antibacterial layer and a surface layer, and the antibacterial layer is formed after the surface of the base fabric layer is coated with an antibacterial agent; the antibacterial agent at least comprises composite modified titanium dioxide particles loaded with nano-silver and an OPHB bio-based antibacterial stock solution; wherein the modified titanium dioxide particles are prepared by loading nano-silver on titanium dioxide and then modifying the titanium dioxide through polyethyleneimine and a silane coupling agent; the preparation method comprises the following steps: coating the surface of the base cloth layer with an antibacterial agent, and then drying to form the antibacterial layer; the side, provided with the antibacterial layer, of the base cloth layer is attached to the surface layer and subjected to hot press molding, and the curtain cloth with the antibacterial function is prepared and has the advantages that the curtain cloth with the good antibacterial effect is prepared, meanwhile, the cost is reduced, and the antibacterial durability is improved.

The invention provides a robot joint dynamic cable made of a self-repairing polyurethane material and a preparation method of the robot joint dynamic cable, and belongs to the field of cables. Polytetrahydrofuran glycol and hexamethylene diisocyanate react to form a soft and hard segment structure, 1, 4-butanediol is added for chain extension, dopamine hydrochloride is introduced, the hard segment structure is enhanced, and a self-repairing hydrogen bond network is formed; carbon nanotubes are introduced, and through plasma treatment and silane coupling agent modification, the tensile resistance, fatigue resistance and electrical properties of the material are improved; montmorillonite is compounded with polyethyleneimine through organic treatment, so that the cracking resistance and wear resistance of the material are enhanced; epoxy groups are introduced to the surface of boron nitride, and dopamine hydrochloride is self-polymerized, so that excellent heat dissipation capability and dimensional stability are provided. Through the synergistic effect of the components, the composite material has excellent mechanical properties, electrical properties, heat dissipation, wear resistance and the like, is especially suitable for a dynamic cable of a robot, and can stably work in a complex environment for a long time.

The invention discloses a high-selectivity magnesium-lithium separation nanofiltration membrane based on a polyolefin base membrane and a preparation method and application of the high-selectivity magnesium-lithium separation nanofiltration membrane based on the polyolefin base membrane. The preparation method comprises the steps that the polyolefin base membrane is in single-face contact with an organic phase monomer solution containing an isophthaloyl chloride monomer or a paraphthaloyl chloride monomer, and the redundant solution is poured out; one side, contacted with the organic phase monomer solution, of the obtained membrane is contacted with a polyethyleneimine-containing aqueous phase monomer solution, an interfacial polymerization reaction is carried out, the obtained membrane is placed in a drying oven for heat treatment, then the membrane is soaked in an organic solution for activation, and the polyvinyl composite nanofiltration membrane is obtained. The nanofiltration membrane has high magnesium ion interception and high magnesium-lithium separation selectivity in a mixed solution with a high magnesium-lithium ratio, the preparation process is simple, conditions are mild, amplification and industrial production are easy to realize, and the nanofiltration membrane has good long-term operation stability.

The invention belongs to the technical field of medical dressings for repairing skin injury wounds, and provides a nanofiber wound dressing with a photo-thermal chemical synergistic antibacterial effect and a preparation method. A PVA / CS solution composed of polyvinyl alcohol PVA and chitosan CS is used as an electrospinning matrix, branched polyethyleneimine BPEI modified graphene oxide GO nanoparticles GO-BPEI are added to serve as a photo-thermal antibacterial component, lanthanum chloride is added to serve as a chemical antibacterial component, an electrostatic spinning solution is prepared, the electrostatic spinning solution is subjected to electrostatic spinning, and the PVA / CS / GO-BPEI / La nanofiber wound dressing is obtained. The obtained fiber surface has a good three-dimensional structure, shows obvious chemical antibacterial ability, can be subjected to photothermal conversion under near-infrared light illumination, can achieve the purpose of photothermal bacteriostasis, further improves the antibacterial property, and has good mechanical property, air permeability, water absorption and biocompatibility at the same time.

The present invention relates to the technical field of nanofiltration membranes, and particularly relates to a preparation method for a positively charged nanofiltration membrane for improving a "trade-off" effect. The preparation method comprises the following process: sequentially adding a water phase and an oil phase to the surface of a support layer to perform a reaction, so as to prepare a polyamide layer; pouring in a functionalized graphene dispersion; and sequentially placing same into an N,N-dimethyl propane diamine solution, a sodium borohydride solution and an iodomethane solution to perform a reaction, so as to obtain a nanofiltration membrane, wherein the functionalized graphene is pyrrolidone-based graphene. According to the present invention, a mixture of piperazine and polyethyleneimine is used as a water phase and is subjected to interfacial polymerization with an oil phase 1,3,5-trimesoyl chloride on the surface of the support membrane; and by means of the compounding of micromolecular piperazine and macromolecular polyethyleneimine, the rapid formation of a polyamide layer is promoted, the distance of a system cross-linked network is increased, a positively charged polyamide layer having a large pore diameter and good hydrophilicity is formed, and a good water flux and a good rejection rate are achieved, thereby improving the "trade-off" effect.

The invention discloses a packaging bag with high sealing performance and a preparation process thereof, and belongs to the technical field of packaging materials, the packaging bag comprises the following raw materials: polylactic acid, polycaprolactone, a nano-silver filler composite antibacterial agent and an epoxy compatilizer; the nano-silver filler composite antibacterial agent is formed by depositing a hybrid modified coating on the surface of a nano two-dimensional filler and then loading nano-silver; the hybrid modified coating is prepared from polydopamine and hyperbranched polyethyleneimine. The polylactic acid and the polycaprolactone are used as main base materials, and the packaging bag is endowed with good mechanical properties by utilizing high mechanical strength of the polylactic acid and excellent flexibility of the polycaprolactone; a nano-silver filler composite antibacterial agent and an epoxy compatibilizer are also added, the nano-silver filler composite antibacterial agent takes a nano-two-dimensional filler as a raw material, the nano-two-dimensional filler has a high length-diameter ratio and can block permeation of gas molecules, and the dispersion performance is improved by combining the nano-two-dimensional filler with the epoxy compatibilizer; the barrier property and the mechanical property of the packaging bag are further improved.

The invention relates to the technical field of cable materials, and provides a flexible EVA cable sheath material and a preparation method thereof. The cable sheath material is prepared from the following raw materials in parts by weight: 25 to 50 parts of ethylene-vinyl acetate copolymer EVA, 15 to 30 parts of ultra-low density polyethylene, 2 to 10 parts of grafted EVA, 2 to 10 parts of flame retardant, 2 to 10 parts of polydopamine modified montmorillonite-boron nitride fiber composite material, 0.5 to 3 parts of flexibilizer, 0.2 to 1 part of silicone and 0.2 to 1 part of organopolysiloxane. A grafting monomer for grafting EVA comprises maleic anhydride and / or an acrylate compound; the polydopamine modified montmorillonite-boron nitride fiber composite material is prepared from montmorillonite, boron nitride fibers, hydroxylated lignin, dopamine hydrochloride and polyethyleneimine through a reaction. Various functional raw materials are compounded, and the obtained cable sheath has good flexibility, flame retardance, thermal deformation resistance, aging resistance and mechanical performance.

The invention relates to the technical field of formaldehyde adsorption, in particular to a preparation method of modified activated carbon for removing formaldehyde, which comprises the following steps: S1, performing acidification pretreatment on coconut shell charcoal, and grafting the pretreated coconut shell charcoal with polyethyleneimine to obtain activated carbon loaded with polyethyleneimine; s2, carrying out dipping treatment and cyclohexanol treatment on the activated carbon loaded with polyethyleneimine to obtain functionalized activated carbon; s3, reacting the magnesium-aluminum hydrotalcite with a quaternary ammonium salt solution and a sodium benzenesulfonate solution to obtain modified hydrotalcite; reacting the modified hydrotalcite with a vinyl silane coupling agent to obtain vinyl hydrotalcite; s4, the vinyl hydrotalcite and 4-amino-3-hydrazino-5-sulfydryl-triazole are subjected to a reaction, and secondary modified hydrotalcite is obtained; and S5, dispersing the secondary modified hydrotalcite and the functionalized activated carbon in water, and adding glutaraldehyde to obtain the modified activated carbon. The modified activated carbon prepared by the preparation method disclosed by the invention realizes selective recognition, efficient adsorption and catalytic degradation of formaldehyde.

The present invention discloses a pH-responsive pesticide slow-release hydrogel sphere and a preparation method thereof, belonging to the technical field of slow-release pesticides. The present invention uses carboxylated nanocrystalline cellulose modified by polyethyleneimine as a raw material, which is self-assembled with modified montmorillonite through electrostatic binding, and then loaded with pesticides in an organic solvent. Then, sodium alginate is used as a coating material and anhydrous calcium chloride is used as a cross-linking agent to prepare a pH-responsive pesticide slow-release hydrogel sphere of nanocrystalline cellulose composite montmorillonite by dropping, which is used for the slow release of pesticides in the soil environment. Under the optimal conditions, the encapsulation rate of fipronil in the organic solvent by the hydrogel sphere of the present invention is above 64.1 wt%, and the loading rate is above 67.3 wt%. In the soil environment with different pH values, the highest release rate of pesticides after 120 h is above 59.7%, and the pesticide release rate increases with the increase of pH until the hydrogel skeleton completely breaks, and the purpose of adjusting the pesticide release rate can be achieved by adjusting the pH.

The invention discloses a carbon fiber / polypropylene composite material as well as a preparation method and application thereof, and belongs to the technical field of composite materials. The invention aims to regulate and control the interface structure and the adhesive property of the carbon fiber / polypropylene composite material. The preparation method comprises the following steps: firstly preparing a polyethyleneimine solution to soak carbon fibers, then preparing a suspension of a modified material to treat the carbon fibers, and carrying out temperature-controlled crystallization to prepare the carbon fiber / polypropylene composite material. The polyethyleneimine solution treatment is the key for the modified material to be adhered to the surface of the carbon fiber, the interface structure of the carbon fiber / polypropylene composite material can be effectively regulated and controlled by selecting the appropriate suspension concentration of the modified material, the interface bonding strength and the mechanical property of the composite material are improved, and the industrial application requirements are better met.

The invention discloses a cationic super-deformation liposome capable of realizing gene transdermal transfection as well as preparation and application of the cationic super-deformation liposome, and belongs to the field of gene transdermal delivery. Materials such as low-molecular-weight polyethyleneimine, lipidosome and Tween 80 are adopted, and the components are safe and simple; polyethyleneimine is used as a conjugation carrier of the gene to improve the binding capacity of the gene, liposome is used as a delivery carrier to improve the skin delivery capacity of the gene, and Tween 80 is used for improving the stability and transdermal transfection capacity of the carrier again, so that non-invasive targeted transdermal delivery of the gene is realized; in vitro stability is high, gene degradation can be effectively inhibited, and meanwhile in vitro cell experiments, high transfection efficiency and low toxicity are achieved; the cationic super-deformed liposome can successfully realize high-efficiency transdermal penetration of the gene and effectively promote transfection expression of the gene in the skin at the same time, a new idea is provided for gene delivery, and the advantage of treating skin diseases through non-invasive delivery of the gene is expected to be fully exerted.

The invention discloses a high-strength wood-plastic composite material and a preparation method thereof, and belongs to the technical field of wood-plastic composites.The high-strength wood-plastic composite material is prepared from, by mass, 50-80 parts of wood fiber powder, 20-50 parts of thermoplastic plastic, 2-6 parts of compatilizer, 0.5-1 part of lubricant, 0.3-0.6 part of antioxidant and 4-8 parts of reinforcing filler. Wherein the compatilizer is polystyrene grafted polyethyleneimine, and the reinforcing filler is nano inorganic filler. The interface bonding force between the wood fiber powder and the thermoplastic plastic in the system is increased by using the non-polarity of polystyrene and a large number of active groups in polyethyleneimine, and the compatibility of the wood fiber powder and the thermoplastic plastic is improved, so that the mechanical strength of the material is improved. And the nano inorganic filler is adopted for reinforcement, so that internal gaps of the material can be filled, defects are reduced, the mechanical strength of the material is further enhanced, and the loading capacity of the composite material is improved.

The invention provides an all-solid waste geopolymer grouting material and a preparation method thereof, and relates to the technical field of solid waste resource utilization and geopolymer grouting material preparation. The all-solid waste geopolymer grouting material comprises the following raw materials in parts by weight: 100-200 parts of an all-solid waste mixture, 40-50 parts of an alkaline activator, 0.1-0.5 part of an early strength agent, 0.5-1 part of a water reducing agent, 3-7 parts of a modifier and 70-90 parts of water, the all-solid waste material comprises slag powder, steel slag powder, phosphogypsum and fly ash; the modifying agent is prepared from aluminum dihydrogen phosphate, vinyl triacetoxysilane and ethylenediamine terminated polyethyleneimine. The all-solid waste geopolymer grouting material provided by the invention has the characteristics of good working performance, high early strength, micro-expansibility and the like.

The invention provides organic nanoparticles with high osteogenic performance as well as a preparation method and application thereof, and belongs to the technical field of osteogenic drug preparation. The preparation method of the organic nanoparticles with high osteogenic performance comprises the following steps: (1) preparing fluorinated polyethyleneimine, preparing double bonds from the fluorinated polyethyleneimine, and then grafting a targeting peptide E7 to obtain a carrier F-PEI-E7; and (2) entrapping an osteogenesis promoting drug in the carrier F-PEI-E7 to obtain the organic nanoparticles with high osteogenesis performance. The invention provides an innovative strategy: F-PEI is used as a carrier, an osteogenesis promoting drug (beta-GP) is entrapped, and through E7 targeting peptide (EPLQLKM) modification, precise targeting delivery of the drug is realized. The organic nanoparticles are high in stability, the in-vitro osteogenesis promoting effect is equivalent to that of a classical formula for in-vitro osteogenesis induction, and the organic nanoparticles have an excellent in-vivo osteogenesis promoting effect.

The invention relates to the technical field of polyurethane acrylate, and particularly discloses dual-curing polyurethane acrylate resin and a preparation method thereof. Wherein the dual-curing polyurethane acrylate resin is prepared from the following raw materials: polyester polyol, polyether polyol, diisocyanate, hydroxyl acrylate, a chain extender, a photoinitiator, cardanol glycidyl ether, a polymerization inhibitor and modified nanoparticles. Wherein the citric acid and the polyethyleneimine are adopted to carry out synergistic modification on the nano particles, the dispersion stability of the nano particles is improved, so that the mechanical property of the resin is improved, the cardanol glycidyl ether and the photoinitiator generate a synergistic effect, and the resin can be quickly shaped through photocuring promoted by the photoinitiator; the cardanol glycidyl ether participates in the subsequent thermocuring reaction, so that the curing effect is improved, and the adhesive force between the film layer and the base material is enhanced.

The invention discloses a moisture-proof and pressure-resistant packaging carton and a preparation method thereof, and relates to the technical field of packaging cartons, the structure of the moisture-proof and pressure-resistant packaging carton is sequentially provided with an outer lining, a corrugated core paperboard and an inner lining from top to bottom, and the outer lining, a corrugated core and the inner lining are bonded through polyvinyl alcohol; soaking the prototype paper in a carboxymethyl cellulose aqueous solution, taking out the prototype paper, soaking the prototype paper in a copper sulfate metal ion solution and an aluminum chloride metal ion solution respectively, and performing hot pressing to obtain lining prototype paper and outer lining prototype paper; the preparation method comprises the following steps: adding polyethyleneimine and methanol into deionized water, uniformly stirring, soaking the outer lining prototype paper into the deionized water, heating to 35-36 DEG C, preserving heat, taking out the outer lining prototype paper, soaking the outer lining prototype paper into the solution A, adding glutaraldehyde, reacting at 25-30 DEG C, taking out the outer lining prototype paper, carrying out vacuum drying for 30-45 minutes, coating the surface of the outer lining prototype paper with the solution B, and carrying out vacuum drying to obtain the outer lining.

The invention provides a nanoparticle capable of releasing EGCG (epigallocatechin gallate) in response to ROS (reactive oxygen species) as well as a preparation method and application of the nanoparticle. The nanoparticles comprise a carrier and EGCG (epigallocatechin gallate) loaded on the carrier; the carrier is Prussian blue nanoparticles of which the surfaces are modified with polyethyleneimine and phenylboronic acid compounds. The preparation method of the nanoparticles is simple and easy to operate, the nanoparticles are good in dispersity, and through research, the nanoparticles have CAT-like, SOD-like and other multi-enzyme activities, can remove. OH, have a high EGCG drug loading rate and release EGCG in the presence of ROS. Besides, the nanoparticles show a good effect of improving myocardial ischemia reperfusion injury in cell level and rat in-vivo experiments, through comparison of EGCG and PB NPs single-drug treatment, synergistic treatment in the composite material achieves an effect of '1 + 1 > 2', and the composite material has good biological safety.

The invention relates to the field of copper-clad plates, and discloses a high-performance flame-retardant low-dielectric-loss copper-clad plate and a preparation method thereof.The copper-clad plate comprises epoxy resin, benzoxazine resin, composite filler, carboxyl-terminated nitrile rubber, an active diluent, a curing agent and the like; the composite filler is prepared by compounding flame-retardant modifier grafted graphene oxide and epoxy silane modified silicon dioxide hollow spheres; according to the flame-retardant modifier, boric acid and pentaerythritol are used for preparing a double-terminal hydroxyl boron-containing intermediate, then dichlorodiphenyl silane and phenylphosphonic dichloride react with hydroxyl groups at the two ends of the intermediate to prepare a flame-retardant intermediate, and amino silane and vanillic aldehyde react with chlorine atoms at the two ends of the intermediate to prepare an aldehyde modified flame-retardant intermediate; the copper-clad plate prepared by the preparation method disclosed by the invention is low in dielectric constant and dielectric loss, high in heat conductivity coefficient and good in flexibility, and also has excellent heat resistance and flame retardance.

The invention discloses a preparation method of a 3-micron ultrathin lithium battery copper foil. The preparation method comprises the following steps: preparing a copper sulfate electrolyte; a wetting agent, a brightening agent and a high resistance agent are added into the copper sulfate electrolyte, the high resistance agent is at least one of thiazolidinethione, polyethyleneimine, 2-mercaptobenzimidazole and ethylene thiourea, and a mixed additive is formed; polishing and grinding a cathode roller by adopting a flying wing wheel, and carrying out electrolytic treatment on the mixed additive through the polished and ground cathode roller to obtain a first-stage copper foil; and the first-stage copper foil is placed in a nitrogen furnace to be subjected to annealing treatment, and the 3-micron ultrathin lithium battery copper foil is obtained. The invention aims to solve the technical problems that in the prior art, edge tearing, foil breaking, warping, dark appearance oxidation and the like are prone to occurring in the production process of the ultrathin copper foil, the tensile strength and the ductility are difficult to consider at the same time, and stable mass production of the 3-micron copper foil is still difficult.

The invention discloses a modified thermal insulation coating and a preparation method and application thereof, and belongs to the field of building energy-saving materials. One modified compound is a thermo-sensitive polyelectrolyte layer-by-layer self-assembled alumina microsphere formed by alternately depositing polyethyleneimine and polyacrylic acid through electrostatic interaction, and the polyelectrolyte layer can dynamically swell or shrink along with the temperature to adjust the heat conductivity coefficient; and the other is magnesium silicate nanofiber coated with silicon dioxide and then grafted with fluorosilane, the hydrophobicity is improved by utilizing the low surface energy of the fluorosilane, and meanwhile, the binding force with a polymer interface is enhanced. The coating further comprises fumed silica, a dispersing agent, a defoaming agent and other auxiliaries. The preparation method comprises the following steps: sequentially adding the components into a high-speed dispersion machine, mixing, adjusting the viscosity, filtering and packaging. The coating has the advantages of intelligent temperature-sensitive adjustment, low heat conductivity, strong adhesion and weather resistance; the material is suitable for long-acting heat preservation in the fields of buildings, industrial equipment and cold chains.

The invention relates to a metallized microbubble and a preparation method thereof, a construction method of a multifunctional composite probe, and a rapid bacterium capturing and sterilizing method, and belongs to the technical field of functional material preparation. The method aims at solving the technical problems that in the prior art, a metal coating on the surface of the hollow glass microbubble is not uniform, combination is not firm, and stability is poor. According to the technical scheme, the method is characterized by comprising the following steps: mixing surface-activated hollow glass microbubbles with a polyethyleneimine solution for reaction, and washing and drying to obtain polyethyleneimine-coated hollow glass microbubbles; then reacting with a single-stranded DNA buffer solution to obtain an intermediate product loaded with DNA; then introducing a silver nitrate solution to load silver ions on the surface of the compound; and finally, reducing through a sodium borohydride solution to prepare the metallized microbubbles. The metalized microbubbles prepared by the method can be used for constructing a multifunctional composite probe to realize efficient capture and synergistic antibiosis of targets such as bacteria.

The invention provides a preparation method and application of coating enhanced nano silver powder. The preparation method comprises the following steps: S1, preparing nano silver by taking silver nitrate as a silver source and polyethyleneimine as a reducing agent; s2, carrying out coating modification on the nano-silver by adopting aniline and ammonium persulfate under an acidic condition; s3, modifying the polyaniline coated nano-silver by adopting chloroacetic acid to obtain chloroacetic acid modified polyaniline coated nano-silver; s4, preparing a modified graphene oxide dispersion liquid; s5, partially reducing the graphene oxide; s6, partially reduced graphene oxide is adopted to load the chloroacetic acid modified polyaniline coated nano-silver, polyaniline coating and reduced graphene oxide compounding are carried out, and the dispersity and stability of nano-silver particles are effectively improved. The oxidation state of polyaniline promotes the release of silver ions through an electron transfer effect, so that the antibacterial effect is enhanced; and the partially reduced graphene oxide synergistically accelerates the release of silver ions, so that the antibacterial property is further improved.

The invention provides an exosome enrichment method based on a modified cellulose material, which comprises the following steps: carrying out TEMPO oxidation on plant residue cellulose to prepare a cellulose material with a carboxyl structure; the cellulose structure is further refined by adopting mechanical shearing and high-pressure homogenizing means, so that the specific surface area and the dispersion stability are remarkably improved; through polyethyleneimine PEI grafting, a large number of amino functional groups are introduced, the surface electropositivity of the material is enhanced, and efficient adsorption and enrichment of exosomes with negative charges are achieved. The invention also provides the exosome prepared by the method. The modified cellulose material disclosed by the invention is wide in source, simple and convenient to prepare and mild in enrichment process, the separation purity and the enrichment efficiency of the exosome can be remarkably improved, and the modified cellulose material has good biocompatibility and environmental friendliness; compared with existing ultracentrifugation, density gradient centrifugation and immunoaffinity separation methods, the method has the advantages that the operation process is simplified, the equipment dependence and reagent cost are reduced, and the potential of large-scale production and clinical application is achieved.

The invention relates to the field of plastics, in particular to a scented polyethylene garbage bag and a preparation method thereof. The composite silica aerogel microcapsules use porous silica aerogel as a carrier of natural plant essential oil to prepare silica aerogel microcapsules, load a polydopamine outer layer on the surface of the microcapsules through oxidative self-polymerization of dopamine, and then graft composite quaternized polyethyleneimine on the surface; bio-based diols are obtained by reacting bio-vanillin and cystamine dihydrochloride, and then the bio-based diols are synthesized with natural castor oil and isophorone diisocyanate under the action of a catalyst to synthesize a prepolymer, use 2,2-dihydroxymethylbutyric acid as a hydrophilic chain extender, use 4-amino-3-methylphenol with a rigid hydrophobic benzene ring structure and antibacterial phenolic hydroxyl groups as a capping agent, and use composite quaternized polyethyleneimine as a crosslinking agent to synthesize a modified bio-based polyurethane emulsion.

The invention discloses a protein-based adsorbent capable of efficiently adsorbing perfluorinated compounds and application of the protein-based adsorbent. The adsorbent is obtained by coating polyethyleneimine in a phase transition aggregate formed by unfolding protein through a disulfide bond reducing agent. The use method of the adsorbent comprises the step of feeding the adsorbent into a solution containing the perfluorinated compound to realize efficient adsorption of the perfluorinated compound. The adsorbent has the advantages of being low in cost, efficient, easy to operate, environmentally friendly, free of secondary pollution, good in biocompatibility and the like, efficient selective adsorption of perfluorinated compounds can be achieved through the adsorbent, the adsorbent can be repeatedly used, and industrial application and popularization are easy.

The invention discloses a silicon shell protected magnetic quantum dot nanoprobe, a preparation method, a kit and application. The nanoprobe comprises a nanomaterial and a specific antibody, the nanometer material is of a core-shell structure, and the outer surface of a core is sequentially coated with an interlayer and a protective shell layer outwards. The interlayer comprises a multi-layer laminated structure formed by alternately arranging a plurality of layers of positive electricity interlayers and negative electricity interlayers; the positive electric interlayer is polyethyleneimine, the negative electric interlayer is quantum dots, the quantum dots are CdSe / ZnS or carbon quantum dots, amino groups on the surface of the shell layer and a dialkynyl polyethylene ethanol solution are subjected to general coupling of specific antibodies in a click chemistry mode by taking diyne molecules as connecting arms. The magnetic nanoprobe with the core-shell structure not only has strong magnetic responsiveness and a high fluorescence signal, but also can adapt to a complex environment, after the magnetic nanoprobe is integrated with an immunochromatography test strip, to-be-detected targets including pathogenic bacteria and inflammatory markers can be rapidly captured in a whole blood sample at the same time, and the magnetic nanoprobe has huge application potential in early diagnosis of sepsis.

The invention discloses a coking inhibition additive for heat absorption type hydrocarbon fuel. The coking inhibition additive comprises hydrazine monohydrate, distilled water and stearic acid terminated hyperbranched polyethyleneimine CHPEI. The invention also provides a preparation method of the heat absorption type hydrocarbon fuel coking inhibition additive, which comprises the following steps: weighing hydrazine monohydrate, adding distilled water, and stirring until the hydrazine monohydrate and the distilled water are uniformly mixed; adding CHPEI particles, and stirring until the CHPEI particles are completely dispersed; the mixture is put into a high-speed homogenizer to be stirred, and it is ensured that the mixture is in a uniform sticky paste shape; the invention also provides an application of the heat absorption type hydrocarbon fuel coking inhibition additive. According to the coking inhibition additive and the application thereof provided by the invention, high-temperature coking of aerospace engine fuel can be effectively inhibited; and a pseudo-homogeneous system which is low in freezing point, good in overload resistance stability and uniform in appearance can be formed with hydrocarbon fuel.

The invention provides a semi-aromatic polyamide material easy to process and form and a preparation method thereof. Comprising the following components in parts by weight: 40-78 parts of PA MXD6, 4-15 parts of long carbon chain nylon, 0.3-3 parts of polyethyleneimine, 20-60 parts of a reinforcing material, 0.2-5 parts of other auxiliaries and 0-50 parts of a filling material. The long carbon chain nylon with a specific length and the polyethyleneimine with a specific molecular weight are fully utilized to be matched, so that more shear sensitivity characteristics are obtained, and the problems of poor flowability of the aromatic ring nylon PA MXD6 material, lack of glue in thin-wall multi-cavity processing, tape casting, scorching, appearance fiber floating and the like are solved.