The invention discloses a
metal organic framework material as well as a preparation method and application thereof, and belongs to the technical field of
chemical separation. The preparation method of the
metal organic framework material provided by the invention comprises the following steps: taking water and
methanol as solvents, taking 4, 4 '-dipyridyl and
malic acid as organic ligands, adding a
zinc source, reacting, and in the reaction process, connecting
oxygen atoms on the
malic acid with
zinc ion bonds on the
zinc source to form a 2D layered
network structure, the two-dimensional layered network structures are bridged through 4, 4 '-dipyridyl to form a 3D rigid network framework, and after the reaction is finished, the
metal organic framework material is prepared. The
metal organic framework prepared by the invention has a superstrong
capture effect and a large storage space on
acetylene molecules, and also has an excellent separation effect on an
acetylene and
carbon dioxide mixed
system, so that the aim of purifying
acetylene in the acetylene and
carbon dioxide mixture at high purity and high yield is achieved.