2047 results about "Adipic acid" patented technology

The invention belongs to the field of paper products, and particularly relates to a heat-sealing coating composition for paper products and application of the heat-sealing coating composition, the coating composition comprises a component A, a component B, a component C and a component D, the component A is one or two of a biomass material with a dendritic or network structure or a cationized biomass material with a dendritic or network structure; the component B is selected from one, two or more of polyhydroxyalkanoate, alkyl ketene dimer, polyglycolide, polylactide, copolymer of butylene adipate and butylene terephthalate, cellulose ester and cellulose ether; and the component C is selected from one, two or more of thermoplastic cellulose and derivatives thereof, thermoplastic starch, rosin, cardanol-based epoxy resin, epoxidized soybean oil, epoxidized castor oil, tannic acid and malic acid. The coating composition is simple in preparation process and easy to industrialize, a target mixture can be obtained through physical blending, and the coating composition is low in production cost, energy-saving and environment-friendly.

The invention discloses a method for preparing a modified PHA composite material by using a twin-screw extruder and application of the modified PHA composite material. The method comprises the following steps: carrying out in-situ melt blending on polyhydroxyalkanoate (PHA), poly (butylene adipate terephthalate)-poly (butylene adipate terephthalate) (PBAT), polyvinyl alcohol (PVOH) and chain extenders in a twin-screw extruder, so that the chain extenders such as polyfunctional group epoxy or isocyanate react with molecular terminal groups of the PHA, the PBAT and the PVOH to form a partially crosslinked or grafted structure; therefore, the compatibility is enhanced, the thermal stability is improved, and the barrier property is remarkably improved. Experiments prove that the obtained modified PHA composite material has the characteristics of high strength, high elongation, excellent water and oxygen resistance and biodegradability, and meets the strict requirements of multiple fields such as food packaging, agricultural plastic mulching films, medical consumables and the like on mechanical properties and barrier properties. The preparation method is simple, convenient and efficient, and large-scale continuous production can be achieved on existing double-screw extrusion equipment.

The invention discloses a biodegradable paper-plastic composite material and a preparation method thereof. The biodegradable paper-plastic composite material is prepared from the following components in parts by mass: 70-90 parts of poly (butylene adipate-co-terephthalate), 10-30 parts of carbon dioxide-based polyester-polycarbonate and 0.2-0.5 part of a processing aid. Polybutylene adipate terephthalate (PBAT) not only has better mechanical properties, but also has higher ductility and elongation at break, but has the defects of low modulus, easiness in curl deformation, higher melt viscosity, easiness in adhesion to equipment and poor barrier property. PPCP belongs to an amorphous polymer, is high in tensile strength and excellent in barrier property, but is low in elongation at break (-5%), is a brittle polymer and is poor in melt strength, and the higher the temperature is, the poorer the melt strength is. Therefore, the PPCP is ingeniously used for modifying the PBAT blown film, the obtained film combines the properties of the two plastics, the good ductility and elongation at break are kept, the modulus of the film is also improved, and meanwhile, the melt strength is also easy to process.

An absorbent retail paper product comprised of cellulosic fibers having a concentration of 1, 3-dichloro-2-propanol that is not detected to 50 ppb, as measured using the ACOC official method 2000.0150, a concentration of 3-monochloro-1, 2-propanediol that is not detected to 1000 ppb, as measured using the ACOC official method 2000.0150, as measured by the "adipic acid test", as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150. Polyaminoamide-epihalohydrin at a concentration of not detected to 0.09% has a lateral wet strength of from 80 n / m to 200 n / m wherein all of the cellulosic fibers contained in the absorbent paper product are non-synthetic, the cellulosic fibers and the absorbent paper product are substantially free of formaldehyde.

The invention discloses a flame-retardant high-temperature-resistant fiber and a preparation method thereof, and relates to the technical field of fibers. When the flame-retardant high-temperature-resistant fiber is prepared, 1, 6-hexamethylenediamine, 1, 6-adipic acid, tetrahydrodifuran [3, 4-B: 3 ', 4'-D] furantetraone and a phosphorus-sulfur composite flame retardant are copolymerized to generate a polyamide-polyamide acid solution; 4-aminopyridine and the polyamide-polyamide acid solution are subjected to a reaction, and modified polyamide is prepared; the modified polyamide is subjected to melt spinning, and polyamide fibers are prepared; the preparation method comprises the following steps: pretreating nano titanium dioxide by using 4-bromobutyl trimethoxy silane to prepare modified nano titanium dioxide; mixing the modified nano titanium dioxide and ethanol to prepare a light-resistant antibacterial finishing agent; and carrying out post-treatment on the polyamide fiber by using an anti-light antibacterial finishing agent to prepare the flame-retardant and high-temperature-resistant fiber. The prepared fiber is excellent in comprehensive performance, particularly outstanding in flame retardance and high temperature resistance, and suitable for the fields of special protective clothing, high-temperature filtering materials and the like.

The invention discloses a nylon elastomer preparation method, which comprises: S1, weighing preparation raw materials of a nylon elastomer according to a feeding ratio, and weighing the preparation raw materials by using a weighing device, the nylon elastomer is prepared from the following raw materials: tridecane diamine, tridecane dibasic acid, dodecanediamine, dodecanedioic acid, undecanediamine, undecanedioic acid, decamethylene diamine, sebacic acid, pentamethylene diamine, glutaric acid, hexamethylenediamine, adipic acid, caprolactam, and one or more of polyether amine and polyether alcohol; and S2, feeding the preparation raw materials weighed in the step S1. In the preparation process of the nylon elastomer, the nylon elastomer with different melting points, different crystallization temperatures, different strengths and different elongation at break is produced by adopting a multi-component copolymerization mode and adjusting the types and the molecular weights of polyether amine and polyether alcohol by adjusting the types and the proportions of binary acid and diamine, so that the nylon elastomer is suitable for different use environments; the utilization rate is improved.

The invention relates to the technical field of textiles, in particular to a wear-resistant antibacterial flax blended yarn and a preparation process thereof. The method specifically comprises the following steps: S1, after performing ultraviolet irradiation on cotton fibers, putting the cotton fibers into a wear-resistant antibacterial solution, and performing dipping and drying to obtain wear-resistant fibers; s2: (1) modifying chitosan by using 6-maleimidohexanoic acid, so as to obtain modified chitosan; (2) sequentially reacting polyethylene glycol adipate with isophorone diisocyanate, modified chitosan and sodium 2-mercaptoethanesulfonate, and finally emulsifying to obtain a fiber treating agent; s3, (1) performing opening mixing, cotton carding, drawing, roving, spinning and spooling on the linen fibers and the wear-resistant fibers in sequence to obtain a linen blended yarn crude product; and (2) soaking the flax blended yarn crude product into the fiber treating agent, padding and drying to obtain the wear-resistant antibacterial flax blended yarn.

A biodegradable polymer composite, a method of making the same and use for same are provided. The biodegradable polymer composite has about 30 to 99.5% by weight of a polymer selected from a group consisting of polybutylene adipate terephthalate (PBAT), polybutylene succinate (PBS), polyhydroxyalkanoates (PHA), and polycaprolactone (PCL) grafted with a compatibilizer selected from a group consisting of maleic anhydride, glycidyl methacrylate, pyromellitic anhydride, acrylic acid, polyacrylic acid, methylene diphenyl diisocyanate, poly(glycidyl methacrylate, copolymer(s) of glycidyl methacrylate; and about 0.5 to 50 % by weight a nano-filler or a micro-filler. The biodegradable polymer composite does not contain polylactic acid. Surfaces of the nano-filler or the micro-filler may be modified using a grafting agent so that the biodegradable polymer composite has enhanced mechanical properties, increased heat resistance, compostablity and / or improved processability. The biodegradable polymer composite may be used to make flexible articles, such as a freezer wrap and a farming sheet.

The invention discloses a preparation method of a non-additive nitrogen-phosphorus-cerium synergistic flame-retardant polyurethane elastomer, and the polyurethane elastomer is prepared by taking isocyanate as a hard segment and poly (1, 4-butanediol adipate) as a soft segment, and compounding the hard segment and the soft segment with 2-amino-4-hydroxy-6-methylpyrimidine, a phosphorus reactive flame retardant and cerium oxide. The preparation method is simple, the process is easy to control, and the prepared polyurethane elastomer has good tensile strength; besides, the limit oxygen index of the polyurethane elastomer reaches 27.4, the polyurethane elastomer meets commercial standards of flame-retardant materials and UL-94 V-0 flame-retardant grade requirements, the ultraviolet band light transmittance is 0%, ultraviolet rays can be completely isolated, and the polyurethane elastomer has a good anti-oxidation function and can be applied to the industries of wires, cables, pipe profiles, films, general molding and the like.

The invention discloses a preparation method of antistatic modified chinlon filaments, and relates to the field of chinlon filaments. When the antistatic modified chinlon filament is prepared, (formylmethyl) diethyl phosphate and 1-aminopyrrole react to prepare pyrrole diethyl phosphate; reacting the hydroxylated multi-walled carbon nanotube with pyrrole diethyl phosphate to obtain a modified multi-walled carbon nanotube; the preparation method comprises the following steps: reacting 2, 2 '-bipyridine-5, 5'-dicarboxylic acid with 2-amino-5-nitrophenol, and then reducing to obtain a benzoxazole diamine monomer; then, adipic acid, 1, 5-diaminopentane and a benzoxazole diamine monomer are subjected to a reaction, and modified polyamide is prepared; uniformly mixing the modified polyamide, the modified multi-walled carbon nanotubes, pyrrole, ferric trichloride and copper chloride, and performing melt spinning to obtain the antistatic modified polyamide filament. The antistatic modified chinlon filament prepared by the invention has excellent antistatic, flame-retardant, anti-aging and mechanical properties.

The invention aims to solve the manufacturing problem of a biodegradable air-conditioning film, and discloses a biodegradable air-conditioning film with a multilayer structure, the biodegradable air-conditioning film comprises a first surface layer, a middle layer and a second surface layer, the air-conditioning film is sequentially formed by the first surface layer, the middle layer and the second surface layer through a co-extrusion process, and the first surface layer and the second surface layer are prepared from polylactic acid (PLA), polycaprolactone (PCL), polylactic acid (PLA), polycaprolactone (PCL) and polylactic acid (PLA). The biodegradable plastic polyester is one or more of poly (butylene terephthalate) or butylene adipate (PBAT), poly (butylene succinate) (PBS) and polyhydroxyalkanoate (PHA), the functional master batch is used as an auxiliary material (the addition amount is greater than or equal to 1%), and a small amount of auxiliary agent (the addition amount is less than 1%) is added; the middle layer takes polycarbon dioxide (PPC) as a main material, takes functional master batch as an auxiliary material (the addition amount is greater than or equal to 1%), and is added with a small amount of auxiliaries (the addition amount is less than 1%). The composite film is produced through a three-layer film co-extrusion process, meanwhile, a co-blowing process can be carried out, in-mold compounding and out-mold compounding can be carried out, and operation is more convenient.

The invention discloses feruloyl esterase fermentation preparation and application of feruloyl esterase in polyester plastic degradation, and belongs to the field of environmental science. According to the method, feruloyl esterase FAE4 derived from Anerocephalum thermophilum is prepared through fermentation, and is compounded with polyester degrading enzymes which are different in source and are used for degrading polyester plastic oligomers, so that a compound reaction system which remarkably improves the degradation efficiency of poly (butylene adipate-co-terephthalate) or poly (butylene adipate-co-terephthalate) (PBAT) and the content proportion of a final product is obtained; good industrial prospects are realized.

The invention discloses an anti-freezing PE (polyethylene) film, a composite film of the anti-freezing PE film and a related preparation method, relates to the field of packaging films, and aims to solve the problem of low freezing resistance and puncture resistance in the prior art. Comprising anti-freezing layer components: low-density polyethylene, high-density polyethylene, metallocene linear low-density polyethylene resin, cold-resistant PA66 resin, composite phosphate, olefin block copolymer resin, a modified nanoscale silicon oxide coupling agent and a nanoparticle toughening agent, and barrier layer components: low-density polyethylene, linear low-density polyethylene and high-density polyethylene. The toughening heat-sealing layer comprises the following components: low-density polyethylene, sarin resin, metallocene linear low-density polyethylene resin, EVA (Ethylene Vinyl Acetate) modified bonding resin, a slipping agent, a nanoparticle toughening agent, a modified nanoscale silicon oxide coupling agent, dioctyl adipate and an antioxidant. The composite material can resist-38 DEG C ultra-low temperature freezing, and is puncture-resistant, cold-resistant and excellent in barrier property.

Disclosed in the present invention are a high-strength polylactic acid material, a preparation method therefor, and use thereof, belonging to the technical field of macromolecular materials. The high-strength polylactic acid material comprises the following components in parts by weight: 80-90 parts of polylactic acid, 10-20 parts of polybutylene adipate terephthalate, 1-5 parts of a nucleating agent, and 2-5 parts of a compatibilizing agent. The mesh number of the nucleating agent is 1500-2500 mesh; the compatibilizing agent is polycaprolactone, and the intrinsic viscosity thereof is 1.0-3.0 dL / g. The present invention lowers the melting temperature and shortens the melting time of PLA and PBAT, reduces the negative impact of polymer degradation and aging on mechanical properties, produces a heterogeneous nucleation effect, and performs the function of a crystallization nucleus in the cooling crystallization stage, improving crystallization speed and crystallinity, while causing the crystalline phase structure to tend toward a spherulitic state, improving the tensile strength of the polylactic acid material.

The invention relates to a biodegradable composition as well as a preparation method and application thereof, and belongs to the technical field of compositions of high-molecular compounds. The biodegradable composition disclosed by the invention is prepared from the following components in parts by weight: 44 to 90 parts of PBAT resin, 5 to 15 parts of amorphous resin and 5 to 40 parts of inorganic filler, based on the total molar weight of a terephthalic acid monomer unit and an adipic acid monomer unit in the PBAT resin, the molar ratio of the terephthalic acid monomer unit is 47-49%; the amorphous resin is at least one of PPC-P, PMMA (Polymethyl Methacrylate), PETG (Polyethylene Terephthalate Glycol) and PCTG; the inorganic filler comprises at least one of calcium carbonate and talcum powder; the particle size D50 of the calcium carbonate is less than 5 [mu] m, and / or the particle size D50 of the talcum powder is less than 8 [mu] m. The biodegradable film produced by adopting the biodegradable composition under a low blow-up ratio process has excellent dart falling performance, and can meet the requirement of ultra-long shelf life.

The invention belongs to the technical field of polyurethane materials, and provides a high-damping anti-fatigue and anti-aging polyurethane elastomer and a preparation method thereof. The high-temperature-resistant polyurethane elastomer is prepared from the following raw materials in parts by weight: 20 to 30 parts of poly (diethylene glycol adipate) glycol (PDA), 30 to 50 parts of polytetrahydrofuran ether glycol (PTMEG), 5 to 15 parts of chain extender, 0.1 to 0.3 part of A33, 0.1 to 0.2 part of organic tin catalyst, 2 to 5 parts of hindered phenol antioxidant, 1 to 3 parts of hindered amine light stabilizer, 3 to 8 parts of nano particles and 30 to 50 parts of isocyanate prepolymer. The isocyanate prepolymer is prepared from 1, 4-phenyl diisocyanate (PPDI) and branched chain-containing polytetrahydrofuran glycol PTXG according to a mass ratio of 1: (1.8 to 2.2). The polyurethane elastomer is excellent in damping performance and fatigue aging resistance, and meets the use requirements under complex working conditions.

The invention relates to the technical field of wastewater resourceful treatment, in particular to a functional membrane for recycling precious metals in wastewater and a preparation method of the functional membrane. The specific preparation method comprises the following steps: preparing a polyamide spinning solution, carrying out electrostatic spinning on the spinning solution to form a polyamide fiber net, stably combining hollow mesoporous nano silicon dioxide on the fiber net through carboxymethyl chitosan, and grafting an epoxy silane coupling agent on the surface of the hollow mesoporous nano silicon dioxide to obtain the hollow mesoporous nano silicon dioxide fiber net. Finally, adipic dihydrazide is grafted on the hollow mesoporous nano silicon dioxide through a ring-opening reaction. Organic polyamide is used as a film forming substance, the raw material cost is low, the method is suitable for large-scale industrial production, the recovery rate of precious metal ions is high, and the film body has good mechanical strength and can stably operate for a long time.

The invention relates to the technical field of synthetic fibers, in particular to a high-elasticity textile fiber and a preparation process thereof. The high-elasticity textile fiber is prepared from the polyurethane-polyamide elastomer and the modified diatomite master batch through melt spinning, drafting and winding. According to the invention, hydroxyl-terminated polydimethylsiloxane is used as polyol, and the molar ratio of the polyurethane prepolymer to the polyamide prepolymer is controlled, so that the prepared polyamide-polyurethane elastomer slice has good heat resistance; the molar ratio of isocyanate to polyol and the molar mass ratio of caprolactam to adipic acid are controlled, so that the prepared textile fiber is excellent in mechanical property; 2, 2-dimethylolpropionic acid is used for a chain extension reaction, the molar ratio is controlled, the moisture regain of the prepared textile fiber is 8.58%, and the moisture absorption is high; the diatomite is modified by the quaternary ammonium salt compound, and the addition proportion is adjusted, so that the prepared spinning fiber has good antibacterial performance.

The invention relates to the technical field of degradable fibers, and discloses a degradable bamboo fiber composite material master batch and a preparation method thereof. The composite material is prepared from the following raw materials: modified bamboo fibers, modified polylactic acid, polyadipic acid / butylene terephthalate, a lubricant, an antioxidant and a plasticizer. The preparation method comprises the following steps: 1) performing alkali treatment and tannic acid-metal ion compound modification on the bamboo fibers to form a hydrophobic surface; 2) blending and modifying polylactic acid and bio-based elastomer polyhydroxybutyrate to construct a tough matrix; and 3) carrying out melt blending on the modified bamboo fiber, poly (adipic acid) / butylene terephthalate, the modified polylactic acid and an auxiliary agent, and then carrying out extrusion granulation. The degradable bamboo fiber composite material master batch prepared by the invention has good processability and mechanical properties, and can be widely applied to the fields of disposable tableware, packaging materials, agricultural plastic mulching films and the like.

The invention relates to the technical field of biodegradable materials, and particularly discloses a BBM-added bamboo powder biodegradable material and application thereof in beer bottles. The BBM-added bamboo powder biodegradable material is prepared from the following raw materials in parts by mass: 10 to 20 parts of poly (butylene succinate), 10 to 30 parts of poly (butylene adipate-co-terephthalate), 10 to 20 parts of bamboo powder, 1 to 3 parts of dopamine hydrochloride, 0.1 to 0.5 part of n-butylamine, 1 to 2 parts of hexadecyl trimethyl ammonium bromide, 1 to 5 parts of tetraethyl orthosilicate and 1 to 2 parts of tetrabutyl titanate. 1-2 parts of 3-aminopropyltriethoxysilane, 1-2 parts of an antioxidant and 1-2 parts of a plasticizer. The BBM obtained by the invention has excellent mechanical properties, improves the anti-ultraviolet intensity of a degradable material to a certain extent, and has very good biodegradability.

The invention relates to the technical field of fibers, and discloses an antibacterial and antistatic fiber material based on silver ions and halamine and a preparation method of the antibacterial and antistatic fiber material. The preparation method comprises the following steps: loading a methyl methacrylate-based polymer on the surface of a silver-loaded molecular sieve through an in-situ polymerization method, and grafting a halamine antibacterial monomer chlorinated piperidinol through an ester exchange reaction to obtain an antibacterial agent; the preparation method comprises the following steps: carrying out reaction polymerization on caprolactam, quaternized polyether, polyethylene glycol, 2, 6-dipicolinic acid and adipic acid to obtain an antistatic agent; an antibacterial agent, an antistatic agent and nano-silver are added into chemical fiber slices, the antibacterial and antistatic fiber material based on silver ions and halamine is prepared after melt spinning, and the chemical fiber slices are polyester slices or chinlon slices or polypropylene slices. The fiber material has excellent antibacterial and antistatic properties.

The invention relates to the technical field of packaging, and discloses an express waterproof bag and a preparation method thereof, the express waterproof bag comprises the following components by mass: 60-70 parts of polylactic acid, 20-30 parts of poly (adipic acid-butylene terephthalate), 5-10 parts of polyhydroxyalkanoate, 2-5 parts of nano cellulose, 1-3 parts of modified montmorillonite, 0.5-1.5 parts of a photosensitizer, 0.25-0.5 part of a bio-enzyme catalyst, and 0.5-1 part of a plasticizer. By combining polylactic acid, poly (butylene adipate-co-terephthalate) and polyhydroxyalkanoate (PHA), the biodegradability is remarkably improved while the mechanical strength of the waterproof bag is maintained, PLA is degraded into carbon dioxide and water through hydrolysis reaction, the degradation rate of PLA is adjusted through PBAT and PHA, premature degradation is avoided, rapid degradation after use is ensured, and the waterproof bag has the advantages of being environmentally friendly and free of pollution. Furthermore, the degradation rate is optimized, the stability and environmental friendliness of the material are balanced, and plastic pollution is avoided.

The invention discloses a high-stretching FPC (Flexible Printed Circuit) and a preparation method thereof, and the method comprises the steps: coating conductive silver paste on a flexible substrate film in a printing, dispensing or coating mode on the back of the flexible substrate film, and forming a metal circuit layer through low-temperature curing; the printing thickness of the conductive silver paste is controlled to be 8-20 [mu] m; pasting a protective layer on the metal circuit layer, and pressing; after the supporting film is torn off, shape punching is conducted, and the product is obtained. The initial paste of the conductive silver paste comprises the following components: 50 wt%-70 wt% of mixed silver powder, 10 wt%-15 wt% of acrylic resin, 10 wt%-15 wt% of dimethyl glutarate, 5 wt%-10 wt% of dimethyl adipate and 5 wt%-10 wt% of dimethyl succinate. The high-stretching FPC and the preparation process thereof have the characteristics of high efficiency and low cost, and large-scale production can be realized. And on the other hand, the operability is high, and the operability problems that flexible base materials such as TPU are prone to displacement in the silk-screen printing process, and printing is poor are solved.

The invention discloses a device for continuously preparing adiponitrile from adipic acid by supergravity, which is characterized in that a specially designed gas-in-liquid mixed feeding mode is firstly adopted, so that liquid of a falling film assembly is uniformly dispersed as far as possible, and meanwhile, by accurately controlling the reaction temperature in the falling film assembly, side reactions are reduced; secondly, the contact mode of gas and liquid of the falling film assembly is changed, the gas-liquid countercurrent contact mode is changed into gas-liquid parallel flow, and the liquid is prevented from being stopped in a pipeline through the gas-liquid parallel flow; and finally, mixing and mass and heat transfer effects of adipic acid and ammonia molecules in the reaction process are enhanced by using a supergravity assembly, so that adipic acid decomposition and coking in a bubbling section of a traditional reactor are effectively slowed down, the reaction efficiency and the product yield are improved, and side reactions are reduced.

The invention provides a copper-nickel alloy catalytic electrode and a preparation method and application thereof. The copper-nickel alloy catalytic electrode comprises a foamed nickel substrate and a copper-nickel alloy vertically loaded on the surface of the foamed nickel substrate, the molecular formula of the copper-nickel alloy is Cu < 0.81 > Ni < 0.19 >, and the copper-nickel alloy is of a dendritic nanostructure. The preparation method comprises the following steps: adding copper sulfate, nickel sulfate and ammonium sulfate into water, and uniformly stirring to obtain an electrolyte; taking a foamed nickel substrate as a working electrode, taking a saturated silver-silver chloride electrode as a reference electrode, taking a platinum sheet or a graphite rod electrode as a counter electrode, and applying constant current density to the working electrode to obtain a preset electrode; and alternately cleaning the preset electrode by using ethanol and distilled water, and carrying out vacuum drying to obtain the copper-nickel alloy catalytic electrode. According to the prepared copper-nickel alloy catalytic electrode, the copper-nickel alloy is in a dendritic morphology, has abundant active sites and a high specific surface area, and has excellent catalytic activity and stability in hydrogen preparation by coupling hydrogen evolution reaction for synthesizing adipic acid through electro-catalysis of cyclohexanone.

The invention relates to the technical field of composite plastic wood, and discloses an environment-friendly composite plastic wood plate and a preparation method thereof.The environment-friendly composite plastic wood plate is prepared from bamboo powder, poly (butylene adipate-co-terephthalate), polylactic acid, a compatilizer, filler, a lubricant, functional fibers and a composite additive, the functional fibers are added, so that the prepared environment-friendly plastic-wood plate has excellent mechanical properties and antibacterial properties, and the situation that the composite plastic-wood plate is eroded by bacteria and molds, and the appearance and the performance of the composite plastic-wood plate are affected badly can be avoided; by adding the composite additive, the prepared environment-friendly plastic-wood plate has excellent impact resistance and ultraviolet resistance, energy can be better absorbed and dispersed when the environment-friendly plastic-wood plate is impacted by external force, and the situation that the service life of the composite plastic-wood plate is shortened due to ultraviolet irradiation in the long-term use process is avoided.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention discloses a recycling method of polyethylene glycol terephthalate (PET). According to the method, organic acid is used as a catalyst for hydrolysis of PET, the organic acid is selected from one or more of adipic acid, lactic acid and glycollic acid, and then hydrolysis products are directly polymerized with additional monomers and polymerization catalysts to prepare the biodegradable copolyester without any separation treatment step. The prepared copolyester has biodegradability, so that the non-degradable PET is converted into the biodegradable copolyester by the recycling method, and the recycling method has important significance for relieving the problem of environmental pollution.

The invention belongs to the technical field of polyurethane, and particularly relates to a low-swelling-rate hydrophilic polyurethane sponge composite material as well as a preparation method and application thereof. The low-swelling-rate hydrophilic polyurethane sponge composite material is prepared from a component A and a component B according to the mass ratio of 100: (50-55), and the component A comprises the following raw materials: a foaming agent, wollastonite powder, an antibacterial agent, emulsifying wax and a polyether type cross-linking agent; the component B comprises polyether ester polyol and toluene diisocynate; the polyether type cross-linking agent is prepared by taking triethanolamine as an initiator and carrying out ring-opening polymerization reaction with EO; the polyether ester polyol is prepared by taking polyethylene glycol, diethylene glycol, trimethylolpropane and adipic acid as raw materials through esterification reaction. The hydrophilic polyurethane sponge prepared from the composite material is good in hydrophilicity, high in aperture ratio, fine and smooth in foam hole, low in swelling ratio and excellent in mechanical property.

The invention discloses a power-on viscosity-reducing adhesive composition, a viscosity-reducing adhesive tape and a preparation method of the viscosity-reducing adhesive tape, and relates to the technical field of adhesive materials. The preparation method comprises the following steps: adding polyurethane acrylate and polybutylene adipate into a planetary stirring kettle, stirring, sequentially adding a PEDOT / PSS solution, a nano core-shell material, a dynamic cross-linking agent, hydrogenated rosin tackifying resin, TPU particles and butylated hydroxytoluene, stirring to obtain mixed glue, and carrying out vacuum defoaming to obtain the electrified viscosity-reducing glue composition. Coating a release film with the electrified viscosity-reducing adhesive composition, carrying out UV curing, and attaching the release film on the other side to obtain the electrified viscosity-reducing adhesive tape. The prepared electrified viscosity-reducing adhesive composition and viscosity-reducing adhesive tape have the advantages of being excellent in mechanical property, sensitive in response, remarkable in stripping force difference before and after electrification, stable at high temperature, stable in circulation, resistant to pollution and the like, nondestructive disassembly and reutilization of devices are achieved by regulating and controlling the adhesive force through an electric field, and the electrified viscosity-reducing adhesive composition and viscosity-reducing adhesive tape can be applied to an electric response assembly scene.