1590 results about "Adipic acid" patented technology

The invention discloses a method for preparing a modified PHA composite material by using a twin-screw extruder and application of the modified PHA composite material. The method comprises the following steps: carrying out in-situ melt blending on polyhydroxyalkanoate (PHA), poly (butylene adipate terephthalate)-poly (butylene adipate terephthalate) (PBAT), polyvinyl alcohol (PVOH) and chain extenders in a twin-screw extruder, so that the chain extenders such as polyfunctional group epoxy or isocyanate react with molecular terminal groups of the PHA, the PBAT and the PVOH to form a partially crosslinked or grafted structure; therefore, the compatibility is enhanced, the thermal stability is improved, and the barrier property is remarkably improved. Experiments prove that the obtained modified PHA composite material has the characteristics of high strength, high elongation, excellent water and oxygen resistance and biodegradability, and meets the strict requirements of multiple fields such as food packaging, agricultural plastic mulching films, medical consumables and the like on mechanical properties and barrier properties. The preparation method is simple, convenient and efficient, and large-scale continuous production can be achieved on existing double-screw extrusion equipment.

An absorbent retail paper product comprised of cellulosic fibers having a concentration of 1, 3-dichloro-2-propanol that is not detected to 50 ppb, as measured using the ACOC official method 2000.0150, a concentration of 3-monochloro-1, 2-propanediol that is not detected to 1000 ppb, as measured using the ACOC official method 2000.0150, as measured by the "adipic acid test", as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150. Polyaminoamide-epihalohydrin at a concentration of not detected to 0.09% has a lateral wet strength of from 80 n / m to 200 n / m wherein all of the cellulosic fibers contained in the absorbent paper product are non-synthetic, the cellulosic fibers and the absorbent paper product are substantially free of formaldehyde.

The invention discloses a flame-retardant high-temperature-resistant fiber and a preparation method thereof, and relates to the technical field of fibers. When the flame-retardant high-temperature-resistant fiber is prepared, 1, 6-hexamethylenediamine, 1, 6-adipic acid, tetrahydrodifuran [3, 4-B: 3 ', 4'-D] furantetraone and a phosphorus-sulfur composite flame retardant are copolymerized to generate a polyamide-polyamide acid solution; 4-aminopyridine and the polyamide-polyamide acid solution are subjected to a reaction, and modified polyamide is prepared; the modified polyamide is subjected to melt spinning, and polyamide fibers are prepared; the preparation method comprises the following steps: pretreating nano titanium dioxide by using 4-bromobutyl trimethoxy silane to prepare modified nano titanium dioxide; mixing the modified nano titanium dioxide and ethanol to prepare a light-resistant antibacterial finishing agent; and carrying out post-treatment on the polyamide fiber by using an anti-light antibacterial finishing agent to prepare the flame-retardant and high-temperature-resistant fiber. The prepared fiber is excellent in comprehensive performance, particularly outstanding in flame retardance and high temperature resistance, and suitable for the fields of special protective clothing, high-temperature filtering materials and the like.

The invention discloses a nylon elastomer preparation method, which comprises: S1, weighing preparation raw materials of a nylon elastomer according to a feeding ratio, and weighing the preparation raw materials by using a weighing device, the nylon elastomer is prepared from the following raw materials: tridecane diamine, tridecane dibasic acid, dodecanediamine, dodecanedioic acid, undecanediamine, undecanedioic acid, decamethylene diamine, sebacic acid, pentamethylene diamine, glutaric acid, hexamethylenediamine, adipic acid, caprolactam, and one or more of polyether amine and polyether alcohol; and S2, feeding the preparation raw materials weighed in the step S1. In the preparation process of the nylon elastomer, the nylon elastomer with different melting points, different crystallization temperatures, different strengths and different elongation at break is produced by adopting a multi-component copolymerization mode and adjusting the types and the molecular weights of polyether amine and polyether alcohol by adjusting the types and the proportions of binary acid and diamine, so that the nylon elastomer is suitable for different use environments; the utilization rate is improved.

A biodegradable polymer composite, a method of making the same and use for same are provided. The biodegradable polymer composite has about 30 to 99.5% by weight of a polymer selected from a group consisting of polybutylene adipate terephthalate (PBAT), polybutylene succinate (PBS), polyhydroxyalkanoates (PHA), and polycaprolactone (PCL) grafted with a compatibilizer selected from a group consisting of maleic anhydride, glycidyl methacrylate, pyromellitic anhydride, acrylic acid, polyacrylic acid, methylene diphenyl diisocyanate, poly(glycidyl methacrylate, copolymer(s) of glycidyl methacrylate; and about 0.5 to 50 % by weight a nano-filler or a micro-filler. The biodegradable polymer composite does not contain polylactic acid. Surfaces of the nano-filler or the micro-filler may be modified using a grafting agent so that the biodegradable polymer composite has enhanced mechanical properties, increased heat resistance, compostablity and / or improved processability. The biodegradable polymer composite may be used to make flexible articles, such as a freezer wrap and a farming sheet.

Disclosed in the present invention are a high-strength polylactic acid material, a preparation method therefor, and use thereof, belonging to the technical field of macromolecular materials. The high-strength polylactic acid material comprises the following components in parts by weight: 80-90 parts of polylactic acid, 10-20 parts of polybutylene adipate terephthalate, 1-5 parts of a nucleating agent, and 2-5 parts of a compatibilizing agent. The mesh number of the nucleating agent is 1500-2500 mesh; the compatibilizing agent is polycaprolactone, and the intrinsic viscosity thereof is 1.0-3.0 dL / g. The present invention lowers the melting temperature and shortens the melting time of PLA and PBAT, reduces the negative impact of polymer degradation and aging on mechanical properties, produces a heterogeneous nucleation effect, and performs the function of a crystallization nucleus in the cooling crystallization stage, improving crystallization speed and crystallinity, while causing the crystalline phase structure to tend toward a spherulitic state, improving the tensile strength of the polylactic acid material.

The invention relates to a biodegradable composition as well as a preparation method and application thereof, and belongs to the technical field of compositions of high-molecular compounds. The biodegradable composition disclosed by the invention is prepared from the following components in parts by weight: 44 to 90 parts of PBAT resin, 5 to 15 parts of amorphous resin and 5 to 40 parts of inorganic filler, based on the total molar weight of a terephthalic acid monomer unit and an adipic acid monomer unit in the PBAT resin, the molar ratio of the terephthalic acid monomer unit is 47-49%; the amorphous resin is at least one of PPC-P, PMMA (Polymethyl Methacrylate), PETG (Polyethylene Terephthalate Glycol) and PCTG; the inorganic filler comprises at least one of calcium carbonate and talcum powder; the particle size D50 of the calcium carbonate is less than 5 [mu] m, and / or the particle size D50 of the talcum powder is less than 8 [mu] m. The biodegradable film produced by adopting the biodegradable composition under a low blow-up ratio process has excellent dart falling performance, and can meet the requirement of ultra-long shelf life.

The invention relates to the technical field of wastewater resourceful treatment, in particular to a functional membrane for recycling precious metals in wastewater and a preparation method of the functional membrane. The specific preparation method comprises the following steps: preparing a polyamide spinning solution, carrying out electrostatic spinning on the spinning solution to form a polyamide fiber net, stably combining hollow mesoporous nano silicon dioxide on the fiber net through carboxymethyl chitosan, and grafting an epoxy silane coupling agent on the surface of the hollow mesoporous nano silicon dioxide to obtain the hollow mesoporous nano silicon dioxide fiber net. Finally, adipic dihydrazide is grafted on the hollow mesoporous nano silicon dioxide through a ring-opening reaction. Organic polyamide is used as a film forming substance, the raw material cost is low, the method is suitable for large-scale industrial production, the recovery rate of precious metal ions is high, and the film body has good mechanical strength and can stably operate for a long time.

The invention relates to the technical field of degradable fibers, and discloses a degradable bamboo fiber composite material master batch and a preparation method thereof. The composite material is prepared from the following raw materials: modified bamboo fibers, modified polylactic acid, polyadipic acid / butylene terephthalate, a lubricant, an antioxidant and a plasticizer. The preparation method comprises the following steps: 1) performing alkali treatment and tannic acid-metal ion compound modification on the bamboo fibers to form a hydrophobic surface; 2) blending and modifying polylactic acid and bio-based elastomer polyhydroxybutyrate to construct a tough matrix; and 3) carrying out melt blending on the modified bamboo fiber, poly (adipic acid) / butylene terephthalate, the modified polylactic acid and an auxiliary agent, and then carrying out extrusion granulation. The degradable bamboo fiber composite material master batch prepared by the invention has good processability and mechanical properties, and can be widely applied to the fields of disposable tableware, packaging materials, agricultural plastic mulching films and the like.

The invention relates to the technical field of packaging, and discloses an express waterproof bag and a preparation method thereof, the express waterproof bag comprises the following components by mass: 60-70 parts of polylactic acid, 20-30 parts of poly (adipic acid-butylene terephthalate), 5-10 parts of polyhydroxyalkanoate, 2-5 parts of nano cellulose, 1-3 parts of modified montmorillonite, 0.5-1.5 parts of a photosensitizer, 0.25-0.5 part of a bio-enzyme catalyst, and 0.5-1 part of a plasticizer. By combining polylactic acid, poly (butylene adipate-co-terephthalate) and polyhydroxyalkanoate (PHA), the biodegradability is remarkably improved while the mechanical strength of the waterproof bag is maintained, PLA is degraded into carbon dioxide and water through hydrolysis reaction, the degradation rate of PLA is adjusted through PBAT and PHA, premature degradation is avoided, rapid degradation after use is ensured, and the waterproof bag has the advantages of being environmentally friendly and free of pollution. Furthermore, the degradation rate is optimized, the stability and environmental friendliness of the material are balanced, and plastic pollution is avoided.

The invention discloses a device for continuously preparing adiponitrile from adipic acid by supergravity, which is characterized in that a specially designed gas-in-liquid mixed feeding mode is firstly adopted, so that liquid of a falling film assembly is uniformly dispersed as far as possible, and meanwhile, by accurately controlling the reaction temperature in the falling film assembly, side reactions are reduced; secondly, the contact mode of gas and liquid of the falling film assembly is changed, the gas-liquid countercurrent contact mode is changed into gas-liquid parallel flow, and the liquid is prevented from being stopped in a pipeline through the gas-liquid parallel flow; and finally, mixing and mass and heat transfer effects of adipic acid and ammonia molecules in the reaction process are enhanced by using a supergravity assembly, so that adipic acid decomposition and coking in a bubbling section of a traditional reactor are effectively slowed down, the reaction efficiency and the product yield are improved, and side reactions are reduced.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention belongs to the technical field of polyurethane, and particularly relates to a low-swelling-rate hydrophilic polyurethane sponge composite material as well as a preparation method and application thereof. The low-swelling-rate hydrophilic polyurethane sponge composite material is prepared from a component A and a component B according to the mass ratio of 100: (50-55), and the component A comprises the following raw materials: a foaming agent, wollastonite powder, an antibacterial agent, emulsifying wax and a polyether type cross-linking agent; the component B comprises polyether ester polyol and toluene diisocynate; the polyether type cross-linking agent is prepared by taking triethanolamine as an initiator and carrying out ring-opening polymerization reaction with EO; the polyether ester polyol is prepared by taking polyethylene glycol, diethylene glycol, trimethylolpropane and adipic acid as raw materials through esterification reaction. The hydrophilic polyurethane sponge prepared from the composite material is good in hydrophilicity, high in aperture ratio, fine and smooth in foam hole, low in swelling ratio and excellent in mechanical property.

The invention discloses a power-on viscosity-reducing adhesive composition, a viscosity-reducing adhesive tape and a preparation method of the viscosity-reducing adhesive tape, and relates to the technical field of adhesive materials. The preparation method comprises the following steps: adding polyurethane acrylate and polybutylene adipate into a planetary stirring kettle, stirring, sequentially adding a PEDOT / PSS solution, a nano core-shell material, a dynamic cross-linking agent, hydrogenated rosin tackifying resin, TPU particles and butylated hydroxytoluene, stirring to obtain mixed glue, and carrying out vacuum defoaming to obtain the electrified viscosity-reducing glue composition. Coating a release film with the electrified viscosity-reducing adhesive composition, carrying out UV curing, and attaching the release film on the other side to obtain the electrified viscosity-reducing adhesive tape. The prepared electrified viscosity-reducing adhesive composition and viscosity-reducing adhesive tape have the advantages of being excellent in mechanical property, sensitive in response, remarkable in stripping force difference before and after electrification, stable at high temperature, stable in circulation, resistant to pollution and the like, nondestructive disassembly and reutilization of devices are achieved by regulating and controlling the adhesive force through an electric field, and the electrified viscosity-reducing adhesive composition and viscosity-reducing adhesive tape can be applied to an electric response assembly scene.

The invention discloses an anode material for adipic acid monoester electrolysis and a preparation method of the anode material, the electrode solves the key problems that a platinum layer is easy to fall off, the catalytic activity is low, the organic matter poisoning resistance is poor and the like of a traditional titanium platinum-plated electrode through multi-scale interface strengthening and nano structure regulation and control; the preparation method comprises the following core steps: constructing a porous ZrO2-TiO2 composite oxide layer on the surface of a titanium substrate by adopting a micro-arc oxidation-hydrothermal composite process, and generating platinum nanoparticles in situ to pre-fill pores, so that the anchoring effect of a platinum layer is remarkably enhanced; depositing a platinum / carbon nano tube (Pt / CNT) composite catalyst layer on the surface of the oxide layer through a pulse-ultrasonic synergistic electroplating technology, wherein the carbon nano tube is used as a conductive framework to inhibit platinum agglomeration; through vacuum annealing and electrochemical activation treatment, the interface bonding force and active site exposure are further optimized; the electrode shows excellent performance in an adipic acid monoester electrolysis system, and efficient electrocatalytic conversion from adipic acid monomethyl ester to dimethyl sebacate is achieved.

The invention discloses a preparation method of a completely biodegradable dustproof net based on modified bamboo powder, and belongs to the technical field of biodegradable new materials. The formula comprises the following components in parts by weight: 50-70 parts of poly (butylene adipate-co-terephthalate), 10-40 parts of bamboo powder, 0.1-2 parts of a silane coupling agent, 0.1-1 part of a surfactant, 0.1-1 part of an anti-blocking agent, 0.1-1 part of an antioxidant and 0.1-1 part of an ultraviolet light absorber. The dust screen prepared by the invention not only has biodegradability, but also has the characteristics of being green and environment-friendly by adopting the bio-based material bamboo powder. Meanwhile, in order to realize good combination of the bamboo powder and matrix plastic poly (butylene adipate-co-terephthalate), a silane coupling agent capable of combining the bamboo powder and the matrix plastic poly (butylene adipate-co-terephthalate) through a chemical reaction and a surfactant capable of combining the bamboo powder and the matrix plastic poly (butylene adipate-co-terephthalate) through a physical effect are sequentially adopted for composite modification of the bamboo powder; the dispersity of the bamboo powder and the compatibility of the bamboo powder and poly (butylene adipate-co-terephthalate) are effectively improved, and the prepared dustproof net has good mechanical properties.

The invention belongs to the technical field of electrode foil formation treatment, and particularly relates to an electrode foil and a preparation method thereof and an aluminum electrolytic capacitor, the preparation method of the electrode foil comprises the steps of performing multi-stage formation treatment on a corrosion foil, the number of stages of the formation treatment is at least two, and the formation treatment at least comprises first-stage formation and second-stage formation, first heat treatment is carried out after the second-stage formation; a formation liquid used in the second-stage formation is a mixed solution containing adipate and monopotassium phosphate. According to the preparation method provided by the invention, the formation liquid used in secondary formation is the mixed solution containing adipate and monopotassium phosphate, the limitation of traditional single formation liquid is broken through, and synchronous optimization of the structure, hydration resistance and electrochemical performance of the aluminum oxide film is realized through multi-stage formation, mixed solution synergy and the synergistic effect of formation and heat treatment; meanwhile, production cost is reduced, and environmental load is relieved.

The invention discloses a double-response collagen-based conductive hydrogel, a medicine and a preparation and application method of the double-response collagen-based conductive hydrogel. The preparation method of the double-response collagen-based conductive hydrogel comprises the following steps: carrying out chemical modification on polysaccharide through 3-aminophenylboronic acid, and then carrying out sodium periodate oxidation treatment to obtain a dialdehyde polysaccharide grafted aminophenylboronic acid copolymer; the preparation method comprises the following steps: performing hydrazide modification on collagen through adipic acid dihydrazide, and performing free radical polymerization with aniline to obtain a hydrazide collagen grafted polyaniline copolymer; the dialdehyde polysaccharide grafted aminophenylboronic acid copolymer and the hydrazide collagen grafted polyaniline copolymer are subjected to crosslinking, and the double-response collagen-based conductive hydrogel capable of responding to glucose and the pH value is obtained. Compared with single-response conductive hydrogel, the hydrogel can specifically respond to the microenvironment of chronic diabetic wound surfaces and release antibacterial and anti-inflammatory drugs, and high-quality healing of chronic wounds such as diabetic foot ulcers and the like is promoted.

The invention relates to the technical field of adipic acid production, in particular to adipic acid production conveying equipment which comprises an upper driving assembly, a lower driving assembly, a chain, a first pipeline and a second pipeline, a plurality of chain pieces are evenly arranged on the chain at intervals, and the chain and the chain pieces are arranged in the upper driving assembly, the lower driving assembly, the first pipeline and the second pipeline in a penetrating mode. The upper driving assembly and the lower driving assembly are used for controlling the chain to move in the first pipeline and the second pipeline, and flexible sleeves are fixedly arranged on the outer surfaces of the chain pieces. The device has the beneficial effects that the contact assembly is attached to the pipe wall of the first pipeline and the pipe wall of the second pipeline, so that the extrusion part can reduce the gap between the flexible sleeve and the pipe wall in real time according to the position of the pipe wall, and the flexible sleeve can be perfectly matched with the pipeline when passing through the arc-shaped section; the material leakage condition caused by too large gaps is effectively avoided, and the phenomenon that the chain pieces are not well attached to the pipe wall to cause blockage or material accumulation is avoided.

The invention discloses a low-temperature polyether demulsifier for oil and gas gathering and transportation and a preparation method thereof, and relates to the technical field of petrochemical engineering, and the preparation method is characterized by comprising the following steps: compounding cardanol, pentaethylenehexamine and bisphenol F according to a specific molar ratio to obtain an initiator, and carrying out formaldehyde condensation to prepare a composite initiator; epoxypropane and ethylene oxide are grafted through staged block copolymerization to form a polyether skeleton; introducing a fluorine-containing epoxy monomer to carry out terminal fluorination modification; finally, adipic acid and epichlorohydrin are subjected to chain extension crosslinking, and the demulsifier with the molecular weight being 8000-12000 Da, the fluorine content being 5.5-6.5 wt% and the PDI being smaller than or equal to 1.3 is prepared. The low-temperature demulsifying agent has the effects of realizing efficient demulsification at low temperature, improving the demulsifying efficiency and reducing the dosage through coordination of the composite initiator, super-hydrophobic permeation of the fluorinated block and accurate regulation and control of the molecular weight, solving the problems of low-temperature failure and easiness in emulsification of a traditional demulsifying agent, and meeting the requirements of low-temperature working conditions of oil and gas gathering and transportation.

The present application relates to the technical field of bio-based polymer material, and more particularly to a full bio-based PBAT-PLA copolymer, a preparation method and an application thereof, which is prepared by melt mixing bio-based polybutylene adipate terephthalate, bio-based polylactic acid and bio-based multi-epoxy chain extender through a twin-screw extruder, so that the tensile strength of the full bio-based PBAT-PLA copolymer is 31.5-44.3 MPa, and the elongation at break is 85-498%. The bio-based multi-epoxy chain extender prepared by specific selection can simultaneously improve the tensile strength and elongation at break of the full bio-based PBAT-PLA copolymer, and solve the technical problems of poor compatibility of traditional bio-based polylactic acid and non-bio-based polybutylene adipate terephthalate, and the technical problem that the addition of existing chain extenders cannot simultaneously improve the tensile strength and elongation at break of the copolymer.

The invention discloses a preparation method of an environment-friendly degradable single-sided perspective sticker, and belongs to the technical field of modified nano materials. The method comprises the following steps: (1) preparation of a multi-layer composite structure: mixing polylactic acid and poly (butylene succinate), adding nano-montmorillonite and a surface modifier, and carrying out melt blending to form a first-layer melt; stirring poly (butylene adipate-co-terephthalate) and fluorescent carbon nanodots to form a second layer of melt; the first layer, the pressure-sensitive adhesive layer and the second layer are co-extruded and compounded to form a film blank. And (2) construction of the nano-film: biaxially stretching the film blank, imprinting a micropore array, dipping in the silver nanoparticle suspension, and drying to obtain the nano-film. And (3) coating functionalization treatment: immersing into a fluorine-containing nano coating solution, and curing. And (4) post-treatment: carrying out secondary curing. The obtained single-sided perspective sticker is suitable for the fields of buildings, vehicle privacy films and the like, and solves the problems of serious pollution and slow degradation of a traditional sticker.

The invention relates to the technical field of waterproof materials, and particularly discloses a high-elasticity waterproof emulsion and a preparation method thereof. The invention discloses a high-elasticity waterproof emulsion. The water-based paint is prepared from the following raw materials in parts by mass: 40 to 60 parts of modified acrylic resin emulsion, 25 to 40 parts of waterborne polyurethane, 3 to 6 parts of hydroxyethyl methylacrylate, 0.5 to 1 part of mercaptopropionic acid, 6 to 8 parts of fluorinated mica sheet, 3 to 6 parts of organic silicon emulsion, 2 to 4 parts of fluorocarbon surfactant, 0.8 to 1.5 parts of adipic dihydrazide, 0.3 to 0.8 part of dynamic cross-linking agent, 3 to 8 parts of compatilizer, 0.5 to 1 part of antioxidant, 0.5 to 1 part of anti-aging agent, 0.5 to 1.5 parts of defoaming agent and 40 to 55 parts of solvent. The modified acrylic resin emulsion is prepared from a monomer comprising diacetone acrylamide. The high-elasticity waterproof emulsion prepared by the invention has relatively good elasticity, waterproof performance and aging resistance.

The invention discloses a bamboo powder bio-based degradable material and a preparation method thereof, and belongs to the technical field of bio-based composite materials. The material comprises the following components in parts by weight: 35-65 parts of bamboo powder, 20-45 parts of poly (adipic acid) / butylene terephthalate, 5-15 parts of modified chitosan, 3-10 parts of a composite plasticizer, 2-8 parts of an inorganic filler, 0.5-3 parts of a composite antioxidant and 0.3-2 parts of a light stabilizer. The preparation method comprises the steps of material preparation, pretreatment, mixing, granulation, forming and the like, bamboo powder is subjected to compound modification through an alkali liquor-silane coupling agent, and sectional temperature control is adopted in mixing. The 180-day soil degradation rate of the material is greater than or equal to 60%, the tensile strength is greater than or equal to 18MPa, the problem that degradation and mechanical properties of an existing material are difficult to consider can be solved, and the material is suitable for the fields of packaging, tableware and the like.

A method for preparing direct melt-spun high-viscosity PBAT / low-viscosity PET two-component elastic fiber and a high-viscosity PBAT polymerization reactor. This method uses two production lines respectively used to produce a high-viscosity PBT melt and a low-viscosity PET melt, which are then spun. The high-viscosity PBAT production line comprises a first esterification reactor, a second esterification reactor, a first prepolymerization reactor, a second prepolymerization reactor, and a high-viscosity PBAT polymerization reactor. The polymerization reactor is designed with a special disc structure in a parallel two-shaft disc reactor, and the two shafts are rotated in opposite directions, improving the devolatilization effect and self-cleaning, significantly increasing the viscosity. By using this method, the cost is low and the production capacity is high, the process flow is shortened, the fiber strength can reach 2.55˜2.85 cN / dtex, the crimp shrinkage rate can reach 25%˜60%, and the crimp stability can reach 58%˜70%.

The invention relates to a supergravity adiponitrile production system and method, the system comprises a supergravity nitrile reactor, a separation tower, a semi-nitrile evaporator and a refining device, the middle part of the supergravity nitrile reactor is communicated with the lower part of the separation tower through a main pipeline, and the top of the supergravity nitrile reactor is communicated with a main ammonia gas pipeline; the top of the separation tower is respectively communicated with an ammonia recovery pipeline and a water recovery pipeline, and the upper part of the separation tower is communicated with the refining device through a pipeline; and the top of the semi-nitrile evaporator is respectively communicated with the bottom of the separation tower, the main pipeline and the main ammonia gas pipeline through pipelines. The reactor has the beneficial effects that the characteristics of structure, technology and the like of the supergravity reactor are utilized, the reverse concentration gradient of ammonia gas and molten adipic acid is formed in the radial direction of the rotor from inside to outside, the gas-liquid contact specific area is increased, the mass transfer driving force is increased, the reaction rate is increased, reaction products are separated out in the reaction process, and the reaction is accelerated and pushed.

The invention discloses a degradable express bag material and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a degradable express bag material. The composite material is prepared from the following raw materials in parts by weight: 40 to 50 parts of poly (butylene adipate-co-terephthalate), 20 to 30 parts of polycaprolactone, 5 to 8 parts of modified bamboo fiber, 2 to 4 parts of modified nano montmorillonite, 3 to 6 parts of tributyl citrate, 0.1 to 0.3 part of antioxidant 1076, 1 to 2 parts of iron dithiocarbamate master batch, 2 to 3 parts of maleic anhydride grafted poly (butylene adipate-co-terephthalate) and 0.3 to 0.6 part of zinc stearate. 0.1 to 0.3 part of baicalein; and 1 to 3 parts of chitosan-sorbitol composite coating liquid. According to the degradable express bag material, poly (butylene adipate-co-terephthalate) and polycaprolactone are used as main degradable raw materials, modified bamboo fibers and modified nano-montmorillonite are matched to enhance the mechanical property, an antioxidant 1076, baicalein and the like are added to guarantee the stability and functionality, temperature is accurately controlled in the preparation process, multi-step modification is adopted for optimizing component combination, and the degradable express bag material is prepared. The performance is improved through the composite coating, degradability is achieved, and good usability is achieved.

The invention discloses unsaturated polyester resin for an optical cable reinforcing core and a preparation method thereof, and belongs to the technical field of unsaturated polyester resin. The composition is composed of the following components: PG, IPA, a catalyst, maleic anhydride, AA, styrene, an antioxidant, a first polymerization inhibitor, a second polymerization inhibitor and a third polymerization inhibitor. The ratio of alcohol to acid is (1.08-1.12): 1; the activity is (3.4-3.8): 1; the molar ratio of AA to IPA is 1: (12-16); the preparation method comprises the following steps: 1) uniformly mixing propylene glycol, a catalyst and isophthalic acid; 2) raising the temperature, preserving the heat and raising the temperature again; cooling, sequentially adding a first polymerization inhibitor, maleic anhydride and adipic acid, heating, keeping the temperature, and heating again; 3) cooling and adding a second polymerization inhibitor, and 4) cooling and adding styrene, a third polymerization inhibitor and an antioxidant, uniformly mixing, and cooling to less than or equal to 60 DEG C to obtain the unsaturated polyester resin for the optical cable reinforcing core. The unsaturated polyester resin for the optical cable reinforcing core has the characteristics of high bending strength and high temperature resistance.

The invention discloses an anti-wrinkle wear-resistant flax blended yarn and a processing technology thereof, and relates to the technical field of textiles. The prepared flax blended yarn comprises natural fibers, modified polylactic acid fibers and ultra-high molecular weight polyethylene fibers. Wherein the natural fibers are obtained by performing degumming pretreatment on linen fibers and bamboo fibers and then mixing the linen fibers and the bamboo fibers with cotton fibers; graphene oxide is deposited on the surface of the fiber through dopamine polymerization, so that the wear resistance of the yarn is improved; the modified polylactic acid fibers are obtained through melt spinning of polylactic acid, poly (adipic acid) / butylene terephthalate and modified chitin nanofibers, the compatibility of the chitin nanofibers and the polylactic acid is improved through polyethylene glycol, and the polylactic acid fibers are enhanced; coarse yarns are obtained through combing, drawing, roving and spinning, the coarse yarns are soaked in a finishing agent, and finally the finished blended yarns are obtained and have good wear resistance and wrinkle resistance.

The invention discloses dibutyl adipate as well as a preparation method and application thereof, preparation raw materials comprise adipic acid, n-butyl alcohol and a catalyst, and the molar ratio of the adipic acid to the n-butyl alcohol to the catalyst is 1: (3-8): (0.001-0.005). Excessive n-butyl alcohol obtained through distillation and kettle residues obtained after vacuum rectification can be directly applied to the next batch of reaction, continuous circular reaction can be achieved by supplementing a small amount of catalyst, maximum utilization of raw materials is achieved, and the production cost is reduced. Compared with the product obtained by the prior art, the content of the product obtained by simple rectification is higher, the content of dibutyl adipate in the product is 99.8% or above, the risk of trace activated carbon residue after activated carbon adsorption treatment is avoided, and the cosmetic grade product standard is met.