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931 results about "Polybutylene" patented technology

Polybutylene (polybutene-1, poly(1-butene), PB-1) is a polyolefin or saturated polymer with the chemical formula (C₄H₈)ₙ. It should not be confused with polybutene, a low molecular weight oligomer. Polybutylene is produced by polymerisation of 1-butene using supported Ziegler–Natta catalysts. PB-1 is a high molecular weight, linear, isotactic, and semi-crystalline polymer. PB-1 combines typical characteristics of conventional polyolefins with certain properties of technical polymers.

Composite materials comprising polar polymers and single-wall carbon nanotubes

The invention relates to a composite comprising a weight fraction of single-wall carbon nanotubes and at least one polar polymer wherein the composite has an electrical and/or thermal conductivity enhanced over that of the polymer alone. The invention also comprises a method for making this polymer composition. The present application provides composite compositions that, over a wide range of single-wall carbon nanotube loading, have electrical conductivities exceeding those known in the art by more than one order of magnitude. The electrical conductivity enhancement depends on the weight fraction (F) of the single-wall carbon nanotubes in the composite. The electrical conductivity of the composite of this invention is at least 5 Siemens per centimeter (S/cm) at (F) of 0.5 (i.e. where single-wall carbon nanotube loading weight represents half of the total composite weight), at least 1 S/cm at a F of 0.1, at least 1×10−4 S/cm at (F) of 0.004, at least 6×10−9 S/cm at (F) of 0.001 and at least 3×10−16 S/cm (F) plus the intrinsic conductivity of the polymer matrix material at of 0.0001. The thermal conductivity enhancement is in excess of 1 Watt/m-° K. The polar polymer can be polycarbonate, poly(acrylic acid), poly(acrylic acid), poly(methacrylic acid), polyoxide, polysulfide, polysulfone, polyamides, polyester, polyurethane, polyimide, poly(vinyl acetate), poly(vinyl alcohol), poly(vinyl chloride), poly(vinyl pyridine), poly(vinyl pyrrolidone), copolymers thereof and combinations thereof. The composite can further comprise a nonpolar polymer, such as, a polyolefin polymer, polyethylene, polypropylene, polybutene, polyisobutene, polyisoprene, polystyrene, copolymers thereof and combinations thereof.
Owner:SAMSUNG ELECTRONICS CO LTD

Filler masterbatch used for increasing polarity of polypropylene and preparation method thereof

The invention discloses a filler masterbatch used for increasing the polarity of polypropylene and a preparation method thereof. The filler masterbatch is characterized by comprising the following components by weight percent: 50%-79% of inorganic filler, 15%-30% of carrier, 5%-17% of polar additive and 1%-3% of processing additive; and the polar additive is one or more of thermoplastic polyurethane resin (TPU), maleic anhydride grafted polypropylene, epoxy resin, ethylene acrylate, ethylene vinyl acetate, polyether amine and polybutylene polyol. In the preparation method of the invention, the added carrier can not improve the polarity of polypropylene, the inorganic filler is used to increase the rigidity of the material; the key is to introduce the polar additive with high unipolarity, thus the filler masterbatch used for increasing the polarity of polypropylene can be prepared; when the filler masterbatch is combined with the polypropylene material for production, the surface polarity of the filled and modified polypropylene material can be increased, the surface energy of the filled and modified polypropylene can be reduced, the dimension stability can be increased, the modified polypropylene material can have good paint adhesion and the material can be used to form exterior trimming parts such as bumpers and interior trimming parts such instrument panels.
Owner:KINGFA SCI & TECH CO LTD +3

Controllable fully biodegradable mulching film and preparation method thereof

The invention belongs to the technical fields of biodegradable material modification and application, and relates to a controllable fully biodegradable mulching film and a preparation method thereof.The controllable fully biodegradable mulching film comprises the following raw materials in parts by weight: 1-50 parts of high-crystallinity polylactic acid, 10-90 parts of polybutylene adipate / butylene terephthalate, 0-50 parts of poly propylene carbonate, 0.1-2 parts of a plasticizer, 0.1-2 parts of a chain extender, 0.1-1 part of a lubricant, 0.1-1 part of a dispersant, 0.1-1 part of an opening agent, 1-3 parts of a compatibilizer, 0.1-8 parts of a gas barrier, 0-1 part of an antioxidant, 0-1 part of a light stabilizer, 0.1-2 parts of an anti-hydrolysis agent and 0-3 parts of an antibacterial agent. The raw materials are pretreated and uniformly mixed, the controllable fully biodegradable mulching film is obtained by extrusion and blow molding, and the thickness of the mulching film is0.005 to 0.020 mm. The fully biodegradable mulching film provided by the invention has good mechanical properties, excellent heat preservation and moisture retention performance, and can be completely degraded by itself; the mulching film degradation rate can be regulated according to the 'mulching film function period' of different crop mulching films in different regions to meet the needs of different crops in different regions.
Owner:深圳利峰达科技发展有限公司

Process for continuously producing polybutylene terephthalate

Polybutylene terephthalate having good heat stability and excellent hydrolysis resistance is continuously produced in a series of a first reactor for reacting an aromatic dicarboxylic acid comprising terephthalic acid as a main ingredient or a derivative thereof with a glycol comprising 1,4-butanediol as a main ingredient, thereby producing an oligomer with an average degree of polymerization of 2.2 to 5, a second reactor for polycondensating the oligomer from the first reactor, thereby preparing a low polymerization product with an average degree of polymerization of 25 to 40, and a third reactor for further polycondensating the low polymerization product from the second reactor, thereby producing a high molecular weight polyester with an average degree of polymerization of 70 to 130, or followed by a fourth reactor for further polycondensing the polyester from the third reactor to an average degree of polymerization of 150 to 200, thereby producing a high molecular weight polyester. Another third reactor or a plurality of third reactors can be provided in parallel to the third reactor, thereby producing different kinds of polybutylene phthalate with different degrees of polymerization from that produced in the main line of the third and fourth reactors or adjusting operating conditions of each of a plurality of the third reactors to increase kinds, precise quality.
Owner:HITACHI LTD

Ultra quick quenching oil and preparation method thereof

InactiveCN102212662AFast coolingFast medium temperature cooling speedQuenching agentsPolybutyleneAntioxidant
The invention relates to ultra quick quenching oil and a preparation method thereof. The ultra quick quenching oil comprises the following raw materials in percentage by weight: 80 to 97 percent of refined mineral oil, 1 to 10 percent of cooling catalyst, 1 to 5 percent of antioxidant and 1 to 6 percent of anionic surfactant. The kinematic viscosity of the refined mineral oil at the temperature of 40 DEG C is 6 to 9 mm<2>/s; the cooling catalyst is a mixture of oily phenolic resin and polybutylene; the antioxidant is alkylated diphenylamine; and the anionic surfactant is petroleum sodium sulfonate. The preparation method of the ultra quick quenching oil is simple and convenient; the obtained quenching oil has the advantages of ultra high cooling speed, good thermal oxidation stability, long service life and continuous and stable property retention; little peculiar smell, smog and carbon deposit are produced, and the take-out consumption of a workpiece is low; and after the workpiece is quenched by adopting the quenching oil, the workpiece has the advantages of high and uniform surface hardness, deep quenching layer, low deformation, metallographic structure, good mechanical property and good brightness, the surface of the workpiece does not become black, and the workpiece is easily cleaned.
Owner:上海德润宝特种润滑剂有限公司

Industrial production method of high isotactic polybutylene and device for implementing method

ActiveCN103897080ADistillationPolybutylene
The invention discloses an industrial production method of high isotactic polybutylene and a device for implementing the method. The production method comprises the process flows of carrying out bulk polymerization on a liquid-phase butylene-1 monomer in a polymerization kettle at the temperature of 10 DEG C below zero to 70 DEG C above zero to synthesize isotactic polybutylene, and recovering part of unreacted butylene-1 into a butylene gasometer through primary pressure reduction after polymerizing for a certain period of time; then, transferring high isotactic polybutylene from the polymerization kettle to a flash distillation kettle, carrying out reduced-pressure flash distillation, and further recovering the unreacted butylene-1 monomer into the butylene gasometer; sequentially introducing nitrogen gas and air into the flash distillation kettle to replace, discharging a granular high isotactic polybutylene product through an emptying valve at the bottom of the kettle, and packaging. The device comprises a proportioning system, a polymerization system, a gas distribution system, a vacuum nitrogen system, a degassing and flash distillation system and a utility system. Through the industrial production method and the device, the industrial synthesis of the high isotactic polybutylene can be realized, and no organic solvents, waste gases, waste water and waste residues are discharged; in addition, the industrial production method belongs to a green and clean production process.
Owner:SHANDONG ORIENT HONGYE CHEM +1
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