Controllable fully biodegradable mulching film and preparation method thereof

A degradable mulch film and all-biological technology, which is applied in the field of controllable fully biodegradable mulch film and its preparation, can solve the problem that the fully biodegradable mulch film is greatly affected by light, temperature, moisture and soil environment, and hinders the movement of water and nutrients in the soil. Biodegradable mulch is not suitable for other problems, so as to achieve the effects of large-scale mechanized film laying, improved water vapor barrier performance, and excellent film-forming properties

Inactive Publication Date: 2019-10-15
深圳利峰达科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Due to its function of heat preservation and moisture conservation, the transparent PE plastic mulch covering the crops can increase production and income, but because it is not degradable, it also brings flooding "white pollution"
[0003] Due to the widespread use of ultra-thin plastic film and the lack of residual film recovery technology and mechanism, the recovery rate of plastic film in my country is less than 2 / 3, and a large amount of plastic film left in the soil destroys the soil structure, hinders the movement of water and nutrients in the soil, and affects crop growth and development
[0009] The degradation process of fully biodegradable mulch is greatly affected by light, temperature, moisture and soil environment. A specific biodegradable mulch can only meet the requirements of a certain crop in one area, but in another area, due to different environments and crop growth. Depending on the environmental requirements, this biodegradable mulch may not be suitable for

Method used

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  • Controllable fully biodegradable mulching film and preparation method thereof
  • Controllable fully biodegradable mulching film and preparation method thereof
  • Controllable fully biodegradable mulching film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] The "film function period" of tobacco-covered mulch in low-altitude areas in Southwest China is about 40 days

[0056] The raw materials of the fully biodegradable plastic film of the present embodiment weigh each component by the following parts by weight:

[0057] 25 parts of high crystallinity polylactic acid, 75 parts of polybutylene adipate / terephthalate, 0.3 parts of epoxy soybean oil, 0.6 parts of polyethylene glycol-8000, 0.6 parts of hexamethylene diisocyanate, stearin 0.2 parts of calcium carbonate, 0.3 parts of oxidized polyethylene wax, 0.4 parts of oleic acid amide, 0.03 parts of dicumyl peroxide, 1.5 parts of styrene-maleic anhydride random copolymer, 3 parts of organically modified nano-montmorillonite, 0.3 parts of composite antioxidant, 1.5 parts of diphenylmethane diisocyanate, 2 parts of 4,5-dichloro-N-octyl-3-isothiazolinone.

[0058] Preparation steps and conditions are:

[0059] 1) Dry high crystallinity polylactic acid and polyadipate / butylene t...

Embodiment 2

[0069] The "film function period" of peanut-covered mulch in the Liaohe Plain in Northeast China is about 65 days

[0070] The raw materials of the fully biodegradable plastic film of the present embodiment weigh each component by the following parts by weight:

[0071] High crystallinity polylactic acid 15 parts, polyadipate / butylene terephthalate 80 parts, polymethylethylene carbonate 5 parts, acetyl tributyl citrate 0.3 parts, polyethylene glycol-4000 0.4 parts , 0.8 parts of ethylene-methyl acrylate-glycidyl methacrylate terpolymer, 0.2 parts of stearic acid, 0.4 parts of glyceryl monostearate, 0.3 parts of ethylene bisstearic acid amide, grafted olefin copolymer 1.8 parts of glycidyl methacrylate, 4 parts of organic bentonite, 0.5 parts of composite antioxidant, 0.6 parts of composite light stabilizer, 1.2 parts of aromatic polycarbodiimide, N-n-octyl 1,2-benzoiso Thiazolin-3-one 1.5 parts.

[0072] Preparation steps and conditions are:

[0073] 1) Dry polylactic acid wi...

Embodiment 3

[0082] The "film function period" of the cotton-covered plastic film in the western margin of the Junggar Basin in Xinjiang is about 75 days

[0083] The raw materials of the fully biodegradable plastic film of the present embodiment weigh each component by the following parts by weight:

[0084] High crystallinity polylactic acid 15 parts, polyadipate / butylene terephthalate 70 parts, polymethylethylene carbonate 15 parts, tributyl citrate 0.3 parts, polyethylene glycol-6000 0.5 parts, 1 part of epoxy chain extender, 0.3 part of zinc stearate, 0.5 part of cosmetic grade white mineral oil, 0.2 part of erucamide, 0.05 part of dibenzoyl peroxide, styrene-maleic anhydride random copolymer 2 6 parts, 6 parts of organic coated potassium aluminum silicate, 0.5 part of composite antioxidant, 0.7 part of composite light stabilizer, 1 part of 2-oxazoline compound, 2 parts of chlorothalonil.

[0085] Preparation steps and conditions are:

[0086] 1) Dry polylactic acid with high crysta...

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Abstract

The invention belongs to the technical fields of biodegradable material modification and application, and relates to a controllable fully biodegradable mulching film and a preparation method thereof.The controllable fully biodegradable mulching film comprises the following raw materials in parts by weight: 1-50 parts of high-crystallinity polylactic acid, 10-90 parts of polybutylene adipate / butylene terephthalate, 0-50 parts of poly propylene carbonate, 0.1-2 parts of a plasticizer, 0.1-2 parts of a chain extender, 0.1-1 part of a lubricant, 0.1-1 part of a dispersant, 0.1-1 part of an opening agent, 1-3 parts of a compatibilizer, 0.1-8 parts of a gas barrier, 0-1 part of an antioxidant, 0-1 part of a light stabilizer, 0.1-2 parts of an anti-hydrolysis agent and 0-3 parts of an antibacterial agent. The raw materials are pretreated and uniformly mixed, the controllable fully biodegradable mulching film is obtained by extrusion and blow molding, and the thickness of the mulching film is0.005 to 0.020 mm. The fully biodegradable mulching film provided by the invention has good mechanical properties, excellent heat preservation and moisture retention performance, and can be completely degraded by itself; the mulching film degradation rate can be regulated according to the 'mulching film function period' of different crop mulching films in different regions to meet the needs of different crops in different regions.

Description

technical field [0001] The invention belongs to the technical field of modification and application of biodegradable materials, and in particular relates to a controllable fully biodegradable plastic film and a preparation method thereof. Background technique [0002] Due to its function of heat preservation and moisture conservation, the transparent PE plastic mulch covering the crops can increase production and income, but because it is not degradable, it also brings flooding "white pollution". [0003] Due to the widespread use of ultra-thin plastic film and the lack of residual film recovery technology and mechanism, the recovery rate of plastic film in my country is less than 2 / 3. A large amount of plastic film left in the soil destroys the soil structure, hinders the movement of water and nutrients in the soil, and affects crop growth and development. As the amount of mulch left in the soil climbs, the mulch that would have boosted crop yields is starting to lead to lo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L67/04C08L69/00C08L91/00C08L71/02C08L23/30C08L23/08C08L35/06C08K13/06C08K3/34C08K5/098C08K5/20C08K5/14C08K5/47C08K9/10C08J5/18A01G13/02
CPCA01G13/0275C08J5/18C08J2367/02C08J2423/08C08J2423/30C08J2435/06C08J2467/04C08J2469/00C08J2471/02C08J2491/00C08K3/34C08K3/346C08K5/098C08K5/14C08K5/20C08K5/47C08K9/10C08K13/06C08K2201/011Y02A40/28
Inventor 穆正洋栗国民
Owner 深圳利峰达科技发展有限公司
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