2462 results about "Montmorillonite" patented technology

The invention relates to the technical field of cables, and discloses a multi-layer composite wrapped high-temperature-resistant anti-aging cable which sequentially comprises a conductor, an insulating cable core, a shielding layer, an outer insulating layer, a fireproof layer, a heat insulation layer, a buffer cushion layer, an armor layer, an anti-aging layer and an outer sheath layer from inside to outside. The fireproof layer is formed by alternately laminating synthetic mica tapes and ceramic boron silicone rubber tapes, a reliable fireproof barrier is formed, and the heat insulation layer is arranged to achieve efficient heat insulation and stable structure through cooperation of gradient pore nano aerogel, ceramic silicone rubber round rods and phase change capsules. The buffering cushion layer is combined with the composite layer, the aluminum oxide hollow ball array and the composite capsule, so that the mechanical buffering and auxiliary heat insulation functions are achieved; the armor layer is woven by stainless steel fibers, the mechanical protection capability is improved, and the anti-aging layer is of a double-layer structure composed of montmorillonite composite fluororubber and an anti-oxidation layer, so that thermal oxidation aging is delayed.

The invention discloses a microencapsulation repairing agent and an intelligent self-repairing ultrahigh-strength ultrahigh-toughness cement-based structural material, the microencapsulation repairing agent is mainly composed of a humidity-responsive outer layer, a pH-responsive middle layer and a temperature-responsive inner layer, and the outer layer is modified with a silane coupling agent. The intelligent self-repairing ultrahigh-strength ultrahigh-toughness cement-based structural material is mainly prepared from the microencapsulated repairing agent, nano carbon black, nano montmorillonite, nano cellulose and other raw materials. According to the invention, by introducing the self-repairing microcapsule with a specific structure and materials such as nano carbon black, nano montmorillonite and nano cellulose, the strength, toughness and durability of the concrete are remarkably improved, and the concrete has an intelligent self-repairing function.

The invention belongs to the technical field of engineering plastics, and particularly relates to a high-flame-retardant composite material and a preparation method thereof. The composite material comprises the following components: long-carbon-chain semi-aromatic nylon, a fiber reinforced filler, a flexibilizer, alkyl aluminum phosphinate, nano montmorillonite, a zinc ion ionomer, a coupling agent, a lubricant and an antioxidant. Alkyl aluminum phosphinate is used as a main flame retardant, and nano-montmorillonite and a zinc ion ionomer are used as auxiliary flame retardants. The nano-scale montmorillonite has certain adsorption performance, and can prevent the alkyl aluminum phosphinate flame retardant from being separated out in the processing process. The zinc ion ionomer is easier to disperse in a long-carbon-chain semi-aromatic nylon resin matrix relative to alkyl aluminum phosphinate and nano-montmorillonite, and ion groups contained in the zinc ion ionomer can generate an ionic crosslinking effect with ions in alkyl aluminum phosphinate and nano-montmorillonite, so that the mechanical property and the thermal stability of the composite material are improved; and moreover, the melt viscosity is improved, and the molten drop phenomenon during combustion is prevented.

The invention provides a degradable environment-friendly packaging material and a preparation process thereof, and belongs to the technical field of packaging materials. The preparation method comprises the following steps: preparing the modified nano montmorillonite; preparing a composite antibacterial additive; preparing a barrier additive; and preparing the degradable environment-friendly packaging material. The preparation method comprises the following steps: by taking methacrylic acid (2-dimethylaminoethyl) ester and acrylic acid as raw materials, modifying nano-montmorillonite under the initiation of benzoyl peroxide, performing quaternary ammonium salinization, and performing in-situ synthesis of nano-zinc oxide on the surface of the quaternary ammonium salinized montmorillonite through a hydrothermal reaction to prepare the composite antibacterial additive. When the composite antibacterial additive is added into polylactic acid to prepare a packaging material, the growth of various microorganisms such as bacteria and fungi can be effectively inhibited, the packaging material is endowed with strong antibacterial protection capability, and the composite antibacterial additive has a more lasting antibacterial effect so as to prolong the antibacterial validity period of the packaging material.

The invention discloses a high-strength polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-strength polyethylene film. The high-density polyethylene composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of high-density polyethylene, 25 to 35 parts of linear low-density polyethylene, 12 to 18 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of nano silicon dioxide, 3 to 7 parts of organic montmorillonite, 1.5 to 3.5 parts of hindered amine light stabilizer, 1.5 to 2.5 parts of antioxidant 1010, 0.8 to 1.2 parts of calcium stearate, 0.8 to 1.2 parts of zinc stearate, 0.8 to 1.2 parts of silane coupling agent and 4 to 6 parts of maleic anhydride grafted polyethylene. The composite material is prepared from the following components in parts by weight: 1.5-3.5 parts of a quaternized chitosan-nano silver compound, 6-9 parts of a modified toughening agent, 4-7 parts of a modified heat-resistant agent, 1.5-3.5 parts of a processing aid, 0.15-0.35 part of dibenzoyl peroxide and 0.5-1.5 parts of a nucleating agent DBS. The composite material is excellent in comprehensive performance, high in strength, good in flexibility and puncture resistance, excellent in aging resistance, heat resistance, chemical resistance and antibacterial property, good in processability, capable of meeting the requirements of multiple fields such as packaging and agriculture, scientific in preparation method and high in practical value.

The invention provides a robot joint dynamic cable made of a self-repairing polyurethane material and a preparation method of the robot joint dynamic cable, and belongs to the field of cables. Polytetrahydrofuran glycol and hexamethylene diisocyanate react to form a soft and hard segment structure, 1, 4-butanediol is added for chain extension, dopamine hydrochloride is introduced, the hard segment structure is enhanced, and a self-repairing hydrogen bond network is formed; carbon nanotubes are introduced, and through plasma treatment and silane coupling agent modification, the tensile resistance, fatigue resistance and electrical properties of the material are improved; montmorillonite is compounded with polyethyleneimine through organic treatment, so that the cracking resistance and wear resistance of the material are enhanced; epoxy groups are introduced to the surface of boron nitride, and dopamine hydrochloride is self-polymerized, so that excellent heat dissipation capability and dimensional stability are provided. Through the synergistic effect of the components, the composite material has excellent mechanical properties, electrical properties, heat dissipation, wear resistance and the like, is especially suitable for a dynamic cable of a robot, and can stably work in a complex environment for a long time.

The invention relates to the technical field of plastic packaging preparation, in particular to an anti-aging plastic packaging material and a preparation method thereof.The anti-aging plastic packaging material is prepared from, by mass, 100-140 parts of polylactic acid, 60-80 parts of PBAT, 2-5 parts of a composite anti-aging agent, 1-2 parts of a lubricant, 2-4 parts of a flame retardant and 3-6 parts of a compatilizer; the composite anti-aging agent comprises a modified anti-aging agent obtained by compounding functionalized montmorillonite and modified silicon dioxide, the functionalized montmorillonite is carnosic acid grafted rare earth ion modified montmorillonite, and the modified silicon dioxide is epoxy methyl oleate grafted silicon dioxide. According to the anti-aging plastic packaging material provided by the invention, a plastic material system with multiple protection mechanisms is constructed through the synergistic effect of all the components, and the prepared plastic packaging material not only keeps good biodegradability, but also has excellent ultraviolet light resistance and oxidation resistance.

The invention relates to a high-temperature-resistant welding slag-resistant cable sheath material, and belongs to the technical field of sheath material preparation. The sheath material is prepared from the following raw materials in parts by weight: 80 to 100 parts of TPU, 20 to 40 parts of modified montmorillonite, 18 to 35 parts of cross-linked resin, 0.1 to 1.5 parts of a processing auxiliary agent, 2 to 6 parts of an assistant cross-linking agent and 0.1 to 0.5 part of a reaction type catalyst, the cross-linked resin is prepared by mixing hexamethylene diisocyanate tripolymer and alcoholic hydroxyl group double-terminated silicone oil according to a molar ratio of (1-1.5): 1 in a first organic solvent and under an organic tin catalyst and reacting. Through introduction of the modified montmorillonite, the cross-linked resin and the assistant cross-linking agent, an interpenetrating network is formed in the composite material, and through triple high-temperature-resistant modification of the high-temperature-resistant characteristic of the montmorillonite, the high-temperature-resistant property of a silane chain and the temperature-resistant property of the interpenetrating cross-linked network, the obtained composite material can resist the temperature of a welding slag spot, so that the service life of the composite material is prolonged. And the surface of the material is not melted.

The invention discloses a high-cold-resistance environment-friendly PVC decorative material and application thereof, belongs to the technical field of PVC preparation, and is used for solving the technical problem that the low temperature resistance and the environmental protection property of a PVC material in the prior art need to be further improved. The high-cold-resistance environment-friendly PVC decorative material specifically comprises the following raw materials in parts by weight: 80-100 parts of composite PVC, 8-10 parts of a bio-based plasticizer and 6-10 parts of an auxiliary additive; the preparation method comprises the following steps: modifying montmorillonite by using a silane coupling agent, loading magnesium hydroxide to prepare a composite filler, carrying out ring-opening polymerization, amine end capping and oxidation on cyclotrisiloxane to generate a low-temperature-resistant agent containing an epoxy group, introducing trimethoxysilane into PVC through sulfydryl substitution, carrying out hydrolytic condensation to form a Si-O-Si cross-linked network, and covalently binding the Si-O-Si cross-linked network with the filler and the low-temperature-resistant agent to obtain the low-temperature-resistant PVC composite material. And reacting the epoxidized soybean oil with glycine, and carrying out calcium coordination to generate a bio-based plasticizer, thereby finally preparing the PVC decorative material.

The invention discloses a PA6 nylon composite material for a high-temperature-resistant filter screen and a preparation method of the PA6 nylon composite material, and relates to the technical field of composite materials. The invention discloses a PA6 nylon composite material for a high-temperature-resistant filter screen. The nylon material is prepared from the following raw materials in parts by weight: 60 to 80 parts of modified PA6 nylon, 10 to 20 parts of modified glass fiber, 2 to 5 parts of montmorillonite, 0.3 to 0.8 part of antioxidant 1010, 0.2 to 0.6 part of stearic acid, 0.5 to 1.0 part of ethoxylated fatty amine, 1 to 3 parts of nano titanium dioxide, 1 to 3 parts of polytetrafluoroethylene micro powder, 3 to 8 parts of aluminum hydroxide, 0.5 to 1.5 parts of chitosan, 1 to 3 parts of hyperbranched polyamide and 0.5 to 1.5 parts of urea-formaldehyde resin coated epoxy resin microcapsules. And 0.3 to 0.8 part of sodium polyacrylate. The PA6 nylon composite material for the high-temperature-resistant filter screen has remarkable advantages. The material disclosed by the invention is high in mechanical property, good in thermal stability and stable in size at high temperature; the self-cleaning, antibacterial and antistatic functions are realized, and the filtering efficiency is high; chemical corrosion resistance, wear resistance and low water absorption are achieved; part of the raw materials can be recycled, the environmental protection concept is met, and the use requirement of the high-temperature-resistant filter screen in a complex environment can be met.

The invention discloses a high-barrier degradable composite film and a preparation method thereof, and belongs to the field of film manufacturing. 15 to 30 parts of PBAT; 15 to 30 parts of PPC; 1 to 10 parts of montmorillonite; 0.2 to 1 part of an epoxy chain extender; 0.2 to 0.5 part of an aliphatic alcohol chain extender; and 1.5-15 parts of a low molecular weight aliphatic polyamide substance. According to the invention, biodegradable materials PLA, PBAT and PPC with excellent performance are selected as base materials, and a certain amount of auxiliary agents are added to modify and prepare the high-barrier degradable composite film. The prepared composite film has the advantages of high strength, high toughness, high barrier property, low cost, high biodegradability and the like. Besides the field of mulching films, the film can also be widely applied to high-end packaging fields with high barrier property requirements, such as packaging of high-tech fine instruments, food and medicine industries and the like, and the preparation method is simple, economical and environment-friendly.

The invention provides a polysilazane green special refractory ceramic coating and a preparation method thereof, and belongs to the field of ceramic coatings. The ternary core material composed of titanium carbide, zirconium boride and silicon nitride provides high hardness, oxidation resistance, thermal shock resistance and excellent thermal stability; the silicon dioxide-aluminum oxide composite shell layer remarkably improves the oxidation resistance and reliability of the coating through the synergistic oxidation resistance and crack self-repairing function; the multi-metal oxygen cluster network endows the coating with excellent electrical conductivity, thermal conductivity and corrosion resistance; the intercalated montmorillonite enhances the crack resistance and oxidation resistance through a layered structure and embedded active ions; and the boron nitride coated vanadium carbide particles provide lubricity, oxidation resistance and wear resistance. Through collaborative optimization of multiple components, the comprehensive performance of the coating is comprehensively improved in the aspects of oxidation resistance, thermal conductivity, interface stability, high-temperature performance, mechanical performance and the like, so that the coating shows excellent long-term stability and functionality in an extreme environment.

The invention discloses an anti-shrinkage light, soft and elastic sole foaming material and a preparation method thereof, and belongs to the technical field of footwear products. The light, soft and elastic sole foaming material is formed by chemically foaming an EVA (Ethylene Vinyl Acetate) composite raw material, the EVA composite raw material is prepared from 50 to 70 parts of EVA, 20 to 40 parts of olefin thermoplastic elastomer, 10 to 20 parts of styrene elastomer, 1.5 to 3 parts of maleic anhydride grafted ethylene-octylene copolymer compatilizer, 0.4 to 0.8 part of peroxide cross-linking agent, 3 to 4 parts of foaming agent, 1 to 1.5 parts of zinc oxide, 1 to 1.5 parts of polyethylene wax substance and 0.5 to 1.5 parts of poly (butylene succinate). 0.3 to 1 part of polyamide 12 microspheres and 2 to 3 parts of nano montmorillonite. The foaming material can resist shrinkage when being used as a shoe sole part, and has good rebound performance and the like, so that the high-quality requirement of sneakers, the mass production stability and the like are met.

The invention relates to the technical field of cable coating materials, and particularly discloses a B1-grade cable material as well as a preparation method and application thereof. The cable material provided by the invention comprises matrix resin, a compatilizer, a flame retardant, a lubricant, an antioxidant, a smoke suppression charring agent, nano silicon dioxide and a silane coupling agent, the matrix resin is a mixture of linear low density polyethylene resin, an ethylene-octylene copolymer, metallocene polyethylene and an ethylene-vinyl acetate copolymer; the flame retardant is a mixture of magnesium hydroxide, aluminum hydroxide and hydrotalcite; the smoke suppression charring agent is a mixture of hydrous magnesium silicate and modified montmorillonite; the silane coupling agent is a mixture of vinyl silane and diamino silane. According to the cable material provided by the invention, the specific matrix resin, the flame retardant, the smoke suppression charring agent and the silane coupling agent are combined with auxiliaries such as the compatilizer, the lubricant, the antioxidant and the nano silicon dioxide to serve as raw materials, so that the flame-retardant effect of the B1-grade cable material is greatly improved.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PVB (Polyvinyl Butyral) film and a preparation method thereof. The PVB film provided by the invention is prepared from the following components in parts by mass: 100 parts of PVB resin, 33 to 36 parts of triethylene glycol di-2-ethylhexoate, 7 to 9 parts of integrated anti-radiation toughening filler, 1 to 2 parts of organic montmorillonite, 0.8 to 1.2 parts of composite coupling agent, 0.5 to 1 part of ultraviolet light absorber, 0.6 to 0.8 part of antioxidant and 0.8 to 1 part of heat stabilizer. The integrated anti-radiation toughening filler adopts a core-shell structure, the anti-radiation core is composed of bismuth oxide and tungsten oxide according to the mass ratio of 3: 1, and the elastic coating layer is maleic anhydride grafted modified POE. The preparation method comprises the steps of pre-dispersion treatment, component mixing, melt extrusion, film casting, graded cooling, two-way stretching and the like. Through the core-shell structure design of the integrated anti-radiation toughening filler and the optimized processing technology, the anti-radiation performance and the toughening performance are synergistically improved, and the prepared film has the advantages of excellent anti-radiation effect, high toughness and good transparency.

The invention relates to the field of biomedical materials, and particularly discloses a manganese dioxide nano-enzyme for treating inflammatory bowel disease as well as a preparation method and application of the manganese dioxide nano-enzyme. The preparation method of the manganese dioxide nano-enzyme comprises the following steps: uniformly mixing an organic solution containing manganese nitrate hexahydrate with a montmorillonite aqueous solution to obtain a mixed reaction solution; the pH value of the mixed reaction solution is adjusted to be under the alkaline condition through alkali liquor, a synthetic reaction is carried out, then centrifugation and washing are carried out, the montmorillonite-loaded manganese dioxide nano-enzyme is obtained, and the manganese dioxide nano-enzyme is of a lamellar structure with the length being 20-400 nm. The manganese dioxide nano enzyme has excellent activity similar to superoxide dismutase, catalase and glutathione peroxidase; meanwhile, the compound also has the capability of removing various free radicals such as DPPH and ABTS, can be used for treating the inflammatory bowel disease, and has a wide application prospect.

The invention relates to the technical field of blocking medicine bottles, and particularly discloses a blocking medicine bottle and a preparation method thereof, aiming at the problems that the upper limit of the blocking performance of the existing blocking medicine bottle is low and the blocking performance is difficult to break through due to the fact that the blocking performance of the existing blocking medicine bottle is mostly realized through structural design. A bottle body of the blocking medicine bottle comprises an inner layer, a secondary inner layer, a middle layer, a secondary outer layer and an outer layer which are sequentially arranged in a covering mode. The inner layer comprises polyethylene; the secondary inner layer comprises an ethylene-methyl acrylate copolymer; the middle layer comprises an ethylene-vinyl alcohol copolymer, cyclic polyolefin and modified montmorillonite; the secondary outer layer comprises an ethylene-methyl acrylate copolymer; the outer layer comprises polyethylene, cyclic polyolefin and modified montmorillonite. The barrier medicine bottle is formed by compositing five layers of materials, the oxygen and water transmittance is low, the barrier property is high, and the barrier medicine bottle has great application value in packaging of medicine or food and the like.

The invention provides a low-smoke halogen-free flame-retardant cable material and a preparation method thereof, and belongs to the field of cable materials. The low-smoke halogen-free flame-retardant cable material is prepared from the following chemical components: 32 to 40 parts of nitrile rubber, 22 to 27 parts of natural rubber, 8 to 12 parts of benzoxazole-siloxane copolymer containing phosphate dynamic bonds, 13 to 15 parts of core-shell-sheath three-stage structure flame retardant, 4 to 6 parts of hexaphenoxy cyclotriphosphazene modified carbon nanotubes, 2 to 3 parts of europium-doped mesoporous cerium dioxide and 3 to 4 parts of nano zinc oxide. The composite material is prepared from the following components in parts by weight: 3 to 4 parts of carbon nanotube grafted montmorillonite hybrid, 2 to 3 parts of lubricant, 0.8 to 1.2 parts of cross-linking agent, 0.3 to 0.4 part of accelerant, 0.4 to 0.6 part of dicumyl peroxide and 0.1 to 0.2 part of antioxidant. Unification of high flame retardance, low smoke, excellent mechanical property and processability of the cable material is realized.

The invention relates to the technical field of coatings, in particular to a modified FEVE fluorocarbon resin coating and a preparation method thereof. The problem that the FEVE fluorocarbon coating is poor in durability is solved. The preparation method comprises the following steps: modifying FEVE fluorocarbon resin with linoleic acid to obtain a granular material; stirring the modified FEVE fluorocarbon resin, polyisocyanate, montmorillonite and a composite solvent to obtain a prepolymer; pre-dispersing and grinding silicon carbide, modified zinc oxide, a dispersing agent and a composite solvent, adding nano composite particles for ultrasonic dispersion, and adding a prepolymer and a flatting agent to obtain the modified FEVE fluorocarbon resin coating. Wherein the FEVE fluorocarbon resin is modified, so that the crosslinking speed, the coating strength and the adhesive force are improved, the stain resistance, the weather resistance and the corrosion resistance are improved through the nano composite particles and the like, and finally the durability of the FEVE fluorocarbon resin coating is improved.

The invention relates to the technical field of power cables, in particular to a heat-aging-resistant crosslinked polyethylene insulated power cable and a preparation method thereof. The cable comprises conductor wire cores, an insulating layer, a filling layer, a composite function layer, a steel tape armoring layer and a sheath layer from inside to outside. The insulating layer is composed of semi-conductive crosslinked polyethylene, silicone resin, nano montmorillonite and an HALS light stabilizer; the filling layer is composed of plasticized glass fabric, polyphenylene sulfide and rare earth oxide; the composite functional layer sequentially comprises a heat-conducting inner layer, a flame-retardant middle layer and an anti-UV outer layer from inside to outside; the sheath layer is composed of polyolefin, white carbon black, ceramic silicone rubber, a flame retardant, polyethylene wax and an initiator. According to the cable, cross-linked polyethylene and silicone resin are preferably selected as heat-resistant materials, heat conduction / flame retardance / UV resistance / armored multi-layer synergistic protection is achieved, the mechanical barrier performance is improved, meanwhile, damage of thermal stress to internal materials is reduced, comprehensive improvement of thermal aging resistance is achieved, and the cable is suitable for high-temperature, high-humidity and frequent thermal cycle harsh environments.

The invention relates to the technical field of insulating materials, in particular to insulating powder and a preparation method thereof. The invention discloses a flame-retardant coating which comprises the following components in parts by weight: 15-25 parts of epoxy resin, 10-20 parts of aluminum hydroxide, 5-12 parts of nano boron nitride, 1-3 parts of a silane coupling agent KH-560, 3-8 parts of polytetrafluoroethylene micro powder, 2-6 parts of fluorine-modified montmorillonite, 4-9 parts of melamine cyanurate, 2-5 parts of nano titanium dioxide, 1-4 parts of a fluorine-modified graphene oxide-polyaniline composite material and 0.5-2 parts of pentaerythritol stearate. The anti-corrosion coating is prepared from the following components in parts by weight: 1 to 3 parts of nano zinc oxide, 5 to 10 parts of glass fiber, 2 to 5 parts of polyhedral oligomeric silsesquioxane-polyimide copolymer, 1 to 4 parts of ferrocenyl epoxy resin and 0.5 to 2 parts of perfluorooctyltriethoxysilane. The insulation powder is high in corrosion resistance, excellent in insulation, heat dissipation and mechanical performance, environmentally friendly in processing, good in adaptability, capable of prolonging the service life of equipment and reducing the cost, suitable for special environments and wide in popularization prospect.

The present invention discloses a rubber sealing strip and a preparation method thereof, and relates to the technical field of sealing strip production, the rubber sealing strip comprises the following raw materials: base rubber, modified montmorillonite, modified carbon black, a plasticizer, a vulcanizing agent, an anti-aging agent and other assistants, the modified montmorillonite is subjected to oleic acid modification, and tetraethoxysilane is subjected to hydrolysis and condensation reaction to obtain the rubber sealing strip. A silicon dioxide coating layer can be formed on the surface of the carbon black, and the lamellar structure of the oleic acid modified montmorillonite and the silicon dioxide modified carbon black can be interwoven to form a more complex and compact physical barrier network, so that the processability of the rubber sealing strip is greatly improved.

The invention relates to the technical field of cable materials, and provides a flexible EVA cable sheath material and a preparation method thereof. The cable sheath material is prepared from the following raw materials in parts by weight: 25 to 50 parts of ethylene-vinyl acetate copolymer EVA, 15 to 30 parts of ultra-low density polyethylene, 2 to 10 parts of grafted EVA, 2 to 10 parts of flame retardant, 2 to 10 parts of polydopamine modified montmorillonite-boron nitride fiber composite material, 0.5 to 3 parts of flexibilizer, 0.2 to 1 part of silicone and 0.2 to 1 part of organopolysiloxane. A grafting monomer for grafting EVA comprises maleic anhydride and / or an acrylate compound; the polydopamine modified montmorillonite-boron nitride fiber composite material is prepared from montmorillonite, boron nitride fibers, hydroxylated lignin, dopamine hydrochloride and polyethyleneimine through a reaction. Various functional raw materials are compounded, and the obtained cable sheath has good flexibility, flame retardance, thermal deformation resistance, aging resistance and mechanical performance.

The invention relates to the technical field of asphalt modifiers, and particularly discloses an asphalt regenerant as well as a preparation method and application thereof. The asphalt modifier comprises an oil phase, a polymer phase, a nano reinforced phase and a functional additive phase, wherein the oil phase comprises petrochemical oil and vegetable oil; the polymer phase comprises four-arm radiation star-shaped SBS and a rubber powder lysis solution; the nano reinforced phase comprises silane coupling agent modified nano montmorillonite and graphene; the functional additive phase comprises maleic anhydride grafted polyethylene and sucrose ester. The asphalt regenerant provided by the invention is suitable for various types of aged asphalt, in particular to aged polymer modified asphalt, each failure phase of the aged polymer modified asphalt is accurately repaired through a multi-phase synergistic mechanism, full-dimension regeneration of the aged polymer modified asphalt from a molecular scale to macroscopic performance is realized, and the asphalt regenerant has a wide application prospect. Excellent applicability and reliability are shown in regeneration of various types of aged asphalt, and a powerful guarantee is provided for high-quality implementation of road engineering.

The invention discloses an antibacterial corrosion-resistant coating and a preparation method thereof, and relates to the field of coating materials. The coating is prepared from the following components in percentage by mass: 2 to 5 percent of nano silver ion loaded mesoporous silicon dioxide nano particle antibacterial aid, 5 to 10 percent of zinc powder-containing corrosion inhibitor, 3 to 8 percent of nano montmorillonite, 30 to 40 percent of modified epoxy resin, 20 to 30 percent of polyurethane prepolymer and other aids. The nano silver ion antibacterial auxiliary agent is loaded in mesoporous silica nanoparticles through an ion exchange method, the zinc powder corrosion inhibitor is prepared through stirring and ball milling dispersion, and the modified epoxy resin is modified by adopting a silane coupling agent. The preparation process of the coating comprises the stages of premixing, grinding and refining, initiating polymerization and post-treatment, wherein a grinding medium is zirconium oxide beads with the diameter of 0.5-2 mm. The coating has excellent antibacterial and corrosion-resistant performance, is suitable for metal surface protection, and can effectively solve the problems that an existing coating is not lasting in antibacterial effect, insufficient in corrosion-resistant performance and not ideal in comprehensive performance.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention relates to the field of film materials, and discloses a degradable antibacterial film material and a preparation method thereof.The film material comprises degradable matrix resin, a modified additive, a plasticizer and a lubricant; the modified additive is prepared by loading a natural antibacterial agent on a modified flame-retardant composite filler; the modified flame-retardant composite filler is prepared by reacting cinnamyl aldehyde with a flame-retardant composite filler and forming a complex with zinc acetate dihydrate; the flame-retardant composite filler is prepared by reacting epoxidized composite filler with 1, 5-naphthalene diamine and then further reacting with phytic acid; according to the invention, the natural antibacterial agent is loaded in the modified flame-retardant composite filler through a vacuum impregnation method, and the mechanical property, antibacterial property and flame-retardant property of the material are enhanced by adding the modifying additive, so that the flame-retardant and antibacterial composite material has the advantages that the flame-retardant and antibacterial properties of the material are improved, and the service life of the material is prolonged. Meanwhile, diffusion / permeation of gas and water molecules in the film is adjusted.

The present invention discloses a pH-responsive pesticide slow-release hydrogel sphere and a preparation method thereof, belonging to the technical field of slow-release pesticides. The present invention uses carboxylated nanocrystalline cellulose modified by polyethyleneimine as a raw material, which is self-assembled with modified montmorillonite through electrostatic binding, and then loaded with pesticides in an organic solvent. Then, sodium alginate is used as a coating material and anhydrous calcium chloride is used as a cross-linking agent to prepare a pH-responsive pesticide slow-release hydrogel sphere of nanocrystalline cellulose composite montmorillonite by dropping, which is used for the slow release of pesticides in the soil environment. Under the optimal conditions, the encapsulation rate of fipronil in the organic solvent by the hydrogel sphere of the present invention is above 64.1 wt%, and the loading rate is above 67.3 wt%. In the soil environment with different pH values, the highest release rate of pesticides after 120 h is above 59.7%, and the pesticide release rate increases with the increase of pH until the hydrogel skeleton completely breaks, and the purpose of adjusting the pesticide release rate can be achieved by adjusting the pH.

The invention discloses a multi-layer composite barrier film and a production process thereof, and belongs to the field of polymer composite materials. Aiming at the problems of obvious performance attenuation, poor interlayer binding force and low step-by-step compounding process efficiency of a barrier film in a humid and hot environment in the prior art, the invention provides a five-layer asymmetric structure design: an outer layer, a bonding layer, a barrier layer, a bonding layer and an inner layer. Wherein the barrier layer is formed by blending EVOH and MAH-PA6 and cooperating with nano montmorillonite to form a multi-barrier network, so that the oxygen permeability is smaller than or equal to 0.3 cm / (m.24h. 0.1 MPa), and the water vapor permeability is smaller than or equal to 1.5 g / (m.24h). The production process innovation comprises five-layer co-extrusion melt flow rate ratio control, three-roller gradient cooling and a bidirectional plasma processing technology, the continuous production speed is larger than or equal to 120 m / min, and the interlayer peeling strength is larger than or equal to 8 N / 15 mm. The barrier property stability is remarkably improved.

The invention relates to the technical field of composite materials, in particular to a nano-montmorillonite reinforced unsaturated polyester resin based composite material and a preparation method thereof. Comprising the following raw materials in parts by weight: 60-85 parts of orthophthalic unsaturated polyester resin, 3-15 parts of nano montmorillonite, 1-5 parts of a polyfunctional group intercalator, 1-4 parts of an initiator, 0.5-2 parts of dimethylaniline and 0.5-3 parts of gamma-aminopropyltriethoxysilane. The polyfunctional intercalator interacts with interlayer ions and surface groups of the nano-montmorillonite through multiple functional groups of the polyfunctional intercalator, and is effectively inserted into the interlayer of the nano-montmorillonite, so that the interlayer spacing is obviously increased, and favorable conditions are provided for subsequent insertion and compounding of resin; the functional groups not only can chemically react with active groups of unsaturated polyester resin to form stronger chemical bonding, but also can enhance the interface bonding force between two phases through physical entanglement, so that the overall performance of the composite material is remarkably improved.