2017 results about "Montmorillonite" patented technology

The invention relates to the technical field of cables, and discloses a multi-layer composite wrapped high-temperature-resistant anti-aging cable which sequentially comprises a conductor, an insulating cable core, a shielding layer, an outer insulating layer, a fireproof layer, a heat insulation layer, a buffer cushion layer, an armor layer, an anti-aging layer and an outer sheath layer from inside to outside. The fireproof layer is formed by alternately laminating synthetic mica tapes and ceramic boron silicone rubber tapes, a reliable fireproof barrier is formed, and the heat insulation layer is arranged to achieve efficient heat insulation and stable structure through cooperation of gradient pore nano aerogel, ceramic silicone rubber round rods and phase change capsules. The buffering cushion layer is combined with the composite layer, the aluminum oxide hollow ball array and the composite capsule, so that the mechanical buffering and auxiliary heat insulation functions are achieved; the armor layer is woven by stainless steel fibers, the mechanical protection capability is improved, and the anti-aging layer is of a double-layer structure composed of montmorillonite composite fluororubber and an anti-oxidation layer, so that thermal oxidation aging is delayed.

The invention discloses a high-strength polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-strength polyethylene film. The high-density polyethylene composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of high-density polyethylene, 25 to 35 parts of linear low-density polyethylene, 12 to 18 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of nano silicon dioxide, 3 to 7 parts of organic montmorillonite, 1.5 to 3.5 parts of hindered amine light stabilizer, 1.5 to 2.5 parts of antioxidant 1010, 0.8 to 1.2 parts of calcium stearate, 0.8 to 1.2 parts of zinc stearate, 0.8 to 1.2 parts of silane coupling agent and 4 to 6 parts of maleic anhydride grafted polyethylene. The composite material is prepared from the following components in parts by weight: 1.5-3.5 parts of a quaternized chitosan-nano silver compound, 6-9 parts of a modified toughening agent, 4-7 parts of a modified heat-resistant agent, 1.5-3.5 parts of a processing aid, 0.15-0.35 part of dibenzoyl peroxide and 0.5-1.5 parts of a nucleating agent DBS. The composite material is excellent in comprehensive performance, high in strength, good in flexibility and puncture resistance, excellent in aging resistance, heat resistance, chemical resistance and antibacterial property, good in processability, capable of meeting the requirements of multiple fields such as packaging and agriculture, scientific in preparation method and high in practical value.

The invention relates to the technical field of plastic packaging preparation, in particular to an anti-aging plastic packaging material and a preparation method thereof.The anti-aging plastic packaging material is prepared from, by mass, 100-140 parts of polylactic acid, 60-80 parts of PBAT, 2-5 parts of a composite anti-aging agent, 1-2 parts of a lubricant, 2-4 parts of a flame retardant and 3-6 parts of a compatilizer; the composite anti-aging agent comprises a modified anti-aging agent obtained by compounding functionalized montmorillonite and modified silicon dioxide, the functionalized montmorillonite is carnosic acid grafted rare earth ion modified montmorillonite, and the modified silicon dioxide is epoxy methyl oleate grafted silicon dioxide. According to the anti-aging plastic packaging material provided by the invention, a plastic material system with multiple protection mechanisms is constructed through the synergistic effect of all the components, and the prepared plastic packaging material not only keeps good biodegradability, but also has excellent ultraviolet light resistance and oxidation resistance.

The invention discloses a high-cold-resistance environment-friendly PVC decorative material and application thereof, belongs to the technical field of PVC preparation, and is used for solving the technical problem that the low temperature resistance and the environmental protection property of a PVC material in the prior art need to be further improved. The high-cold-resistance environment-friendly PVC decorative material specifically comprises the following raw materials in parts by weight: 80-100 parts of composite PVC, 8-10 parts of a bio-based plasticizer and 6-10 parts of an auxiliary additive; the preparation method comprises the following steps: modifying montmorillonite by using a silane coupling agent, loading magnesium hydroxide to prepare a composite filler, carrying out ring-opening polymerization, amine end capping and oxidation on cyclotrisiloxane to generate a low-temperature-resistant agent containing an epoxy group, introducing trimethoxysilane into PVC through sulfydryl substitution, carrying out hydrolytic condensation to form a Si-O-Si cross-linked network, and covalently binding the Si-O-Si cross-linked network with the filler and the low-temperature-resistant agent to obtain the low-temperature-resistant PVC composite material. And reacting the epoxidized soybean oil with glycine, and carrying out calcium coordination to generate a bio-based plasticizer, thereby finally preparing the PVC decorative material.

The invention discloses a PA6 nylon composite material for a high-temperature-resistant filter screen and a preparation method of the PA6 nylon composite material, and relates to the technical field of composite materials. The invention discloses a PA6 nylon composite material for a high-temperature-resistant filter screen. The nylon material is prepared from the following raw materials in parts by weight: 60 to 80 parts of modified PA6 nylon, 10 to 20 parts of modified glass fiber, 2 to 5 parts of montmorillonite, 0.3 to 0.8 part of antioxidant 1010, 0.2 to 0.6 part of stearic acid, 0.5 to 1.0 part of ethoxylated fatty amine, 1 to 3 parts of nano titanium dioxide, 1 to 3 parts of polytetrafluoroethylene micro powder, 3 to 8 parts of aluminum hydroxide, 0.5 to 1.5 parts of chitosan, 1 to 3 parts of hyperbranched polyamide and 0.5 to 1.5 parts of urea-formaldehyde resin coated epoxy resin microcapsules. And 0.3 to 0.8 part of sodium polyacrylate. The PA6 nylon composite material for the high-temperature-resistant filter screen has remarkable advantages. The material disclosed by the invention is high in mechanical property, good in thermal stability and stable in size at high temperature; the self-cleaning, antibacterial and antistatic functions are realized, and the filtering efficiency is high; chemical corrosion resistance, wear resistance and low water absorption are achieved; part of the raw materials can be recycled, the environmental protection concept is met, and the use requirement of the high-temperature-resistant filter screen in a complex environment can be met.

The invention provides a polysilazane green special refractory ceramic coating and a preparation method thereof, and belongs to the field of ceramic coatings. The ternary core material composed of titanium carbide, zirconium boride and silicon nitride provides high hardness, oxidation resistance, thermal shock resistance and excellent thermal stability; the silicon dioxide-aluminum oxide composite shell layer remarkably improves the oxidation resistance and reliability of the coating through the synergistic oxidation resistance and crack self-repairing function; the multi-metal oxygen cluster network endows the coating with excellent electrical conductivity, thermal conductivity and corrosion resistance; the intercalated montmorillonite enhances the crack resistance and oxidation resistance through a layered structure and embedded active ions; and the boron nitride coated vanadium carbide particles provide lubricity, oxidation resistance and wear resistance. Through collaborative optimization of multiple components, the comprehensive performance of the coating is comprehensively improved in the aspects of oxidation resistance, thermal conductivity, interface stability, high-temperature performance, mechanical performance and the like, so that the coating shows excellent long-term stability and functionality in an extreme environment.

The invention discloses an anti-shrinkage light, soft and elastic sole foaming material and a preparation method thereof, and belongs to the technical field of footwear products. The light, soft and elastic sole foaming material is formed by chemically foaming an EVA (Ethylene Vinyl Acetate) composite raw material, the EVA composite raw material is prepared from 50 to 70 parts of EVA, 20 to 40 parts of olefin thermoplastic elastomer, 10 to 20 parts of styrene elastomer, 1.5 to 3 parts of maleic anhydride grafted ethylene-octylene copolymer compatilizer, 0.4 to 0.8 part of peroxide cross-linking agent, 3 to 4 parts of foaming agent, 1 to 1.5 parts of zinc oxide, 1 to 1.5 parts of polyethylene wax substance and 0.5 to 1.5 parts of poly (butylene succinate). 0.3 to 1 part of polyamide 12 microspheres and 2 to 3 parts of nano montmorillonite. The foaming material can resist shrinkage when being used as a shoe sole part, and has good rebound performance and the like, so that the high-quality requirement of sneakers, the mass production stability and the like are met.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PVB (Polyvinyl Butyral) film and a preparation method thereof. The PVB film provided by the invention is prepared from the following components in parts by mass: 100 parts of PVB resin, 33 to 36 parts of triethylene glycol di-2-ethylhexoate, 7 to 9 parts of integrated anti-radiation toughening filler, 1 to 2 parts of organic montmorillonite, 0.8 to 1.2 parts of composite coupling agent, 0.5 to 1 part of ultraviolet light absorber, 0.6 to 0.8 part of antioxidant and 0.8 to 1 part of heat stabilizer. The integrated anti-radiation toughening filler adopts a core-shell structure, the anti-radiation core is composed of bismuth oxide and tungsten oxide according to the mass ratio of 3: 1, and the elastic coating layer is maleic anhydride grafted modified POE. The preparation method comprises the steps of pre-dispersion treatment, component mixing, melt extrusion, film casting, graded cooling, two-way stretching and the like. Through the core-shell structure design of the integrated anti-radiation toughening filler and the optimized processing technology, the anti-radiation performance and the toughening performance are synergistically improved, and the prepared film has the advantages of excellent anti-radiation effect, high toughness and good transparency.

The invention provides a low-smoke halogen-free flame-retardant cable material and a preparation method thereof, and belongs to the field of cable materials. The low-smoke halogen-free flame-retardant cable material is prepared from the following chemical components: 32 to 40 parts of nitrile rubber, 22 to 27 parts of natural rubber, 8 to 12 parts of benzoxazole-siloxane copolymer containing phosphate dynamic bonds, 13 to 15 parts of core-shell-sheath three-stage structure flame retardant, 4 to 6 parts of hexaphenoxy cyclotriphosphazene modified carbon nanotubes, 2 to 3 parts of europium-doped mesoporous cerium dioxide and 3 to 4 parts of nano zinc oxide. The composite material is prepared from the following components in parts by weight: 3 to 4 parts of carbon nanotube grafted montmorillonite hybrid, 2 to 3 parts of lubricant, 0.8 to 1.2 parts of cross-linking agent, 0.3 to 0.4 part of accelerant, 0.4 to 0.6 part of dicumyl peroxide and 0.1 to 0.2 part of antioxidant. Unification of high flame retardance, low smoke, excellent mechanical property and processability of the cable material is realized.

The invention relates to the technical field of coatings, in particular to a modified FEVE fluorocarbon resin coating and a preparation method thereof. The problem that the FEVE fluorocarbon coating is poor in durability is solved. The preparation method comprises the following steps: modifying FEVE fluorocarbon resin with linoleic acid to obtain a granular material; stirring the modified FEVE fluorocarbon resin, polyisocyanate, montmorillonite and a composite solvent to obtain a prepolymer; pre-dispersing and grinding silicon carbide, modified zinc oxide, a dispersing agent and a composite solvent, adding nano composite particles for ultrasonic dispersion, and adding a prepolymer and a flatting agent to obtain the modified FEVE fluorocarbon resin coating. Wherein the FEVE fluorocarbon resin is modified, so that the crosslinking speed, the coating strength and the adhesive force are improved, the stain resistance, the weather resistance and the corrosion resistance are improved through the nano composite particles and the like, and finally the durability of the FEVE fluorocarbon resin coating is improved.

The invention relates to the technical field of power cables, in particular to a heat-aging-resistant crosslinked polyethylene insulated power cable and a preparation method thereof. The cable comprises conductor wire cores, an insulating layer, a filling layer, a composite function layer, a steel tape armoring layer and a sheath layer from inside to outside. The insulating layer is composed of semi-conductive crosslinked polyethylene, silicone resin, nano montmorillonite and an HALS light stabilizer; the filling layer is composed of plasticized glass fabric, polyphenylene sulfide and rare earth oxide; the composite functional layer sequentially comprises a heat-conducting inner layer, a flame-retardant middle layer and an anti-UV outer layer from inside to outside; the sheath layer is composed of polyolefin, white carbon black, ceramic silicone rubber, a flame retardant, polyethylene wax and an initiator. According to the cable, cross-linked polyethylene and silicone resin are preferably selected as heat-resistant materials, heat conduction / flame retardance / UV resistance / armored multi-layer synergistic protection is achieved, the mechanical barrier performance is improved, meanwhile, damage of thermal stress to internal materials is reduced, comprehensive improvement of thermal aging resistance is achieved, and the cable is suitable for high-temperature, high-humidity and frequent thermal cycle harsh environments.

The invention relates to the technical field of insulating materials, in particular to insulating powder and a preparation method thereof. The invention discloses a flame-retardant coating which comprises the following components in parts by weight: 15-25 parts of epoxy resin, 10-20 parts of aluminum hydroxide, 5-12 parts of nano boron nitride, 1-3 parts of a silane coupling agent KH-560, 3-8 parts of polytetrafluoroethylene micro powder, 2-6 parts of fluorine-modified montmorillonite, 4-9 parts of melamine cyanurate, 2-5 parts of nano titanium dioxide, 1-4 parts of a fluorine-modified graphene oxide-polyaniline composite material and 0.5-2 parts of pentaerythritol stearate. The anti-corrosion coating is prepared from the following components in parts by weight: 1 to 3 parts of nano zinc oxide, 5 to 10 parts of glass fiber, 2 to 5 parts of polyhedral oligomeric silsesquioxane-polyimide copolymer, 1 to 4 parts of ferrocenyl epoxy resin and 0.5 to 2 parts of perfluorooctyltriethoxysilane. The insulation powder is high in corrosion resistance, excellent in insulation, heat dissipation and mechanical performance, environmentally friendly in processing, good in adaptability, capable of prolonging the service life of equipment and reducing the cost, suitable for special environments and wide in popularization prospect.

The invention relates to the technical field of cable materials, and provides a flexible EVA cable sheath material and a preparation method thereof. The cable sheath material is prepared from the following raw materials in parts by weight: 25 to 50 parts of ethylene-vinyl acetate copolymer EVA, 15 to 30 parts of ultra-low density polyethylene, 2 to 10 parts of grafted EVA, 2 to 10 parts of flame retardant, 2 to 10 parts of polydopamine modified montmorillonite-boron nitride fiber composite material, 0.5 to 3 parts of flexibilizer, 0.2 to 1 part of silicone and 0.2 to 1 part of organopolysiloxane. A grafting monomer for grafting EVA comprises maleic anhydride and / or an acrylate compound; the polydopamine modified montmorillonite-boron nitride fiber composite material is prepared from montmorillonite, boron nitride fibers, hydroxylated lignin, dopamine hydrochloride and polyethyleneimine through a reaction. Various functional raw materials are compounded, and the obtained cable sheath has good flexibility, flame retardance, thermal deformation resistance, aging resistance and mechanical performance.

The invention relates to the technical field of asphalt modifiers, and particularly discloses an asphalt regenerant as well as a preparation method and application thereof. The asphalt modifier comprises an oil phase, a polymer phase, a nano reinforced phase and a functional additive phase, wherein the oil phase comprises petrochemical oil and vegetable oil; the polymer phase comprises four-arm radiation star-shaped SBS and a rubber powder lysis solution; the nano reinforced phase comprises silane coupling agent modified nano montmorillonite and graphene; the functional additive phase comprises maleic anhydride grafted polyethylene and sucrose ester. The asphalt regenerant provided by the invention is suitable for various types of aged asphalt, in particular to aged polymer modified asphalt, each failure phase of the aged polymer modified asphalt is accurately repaired through a multi-phase synergistic mechanism, full-dimension regeneration of the aged polymer modified asphalt from a molecular scale to macroscopic performance is realized, and the asphalt regenerant has a wide application prospect. Excellent applicability and reliability are shown in regeneration of various types of aged asphalt, and a powerful guarantee is provided for high-quality implementation of road engineering.

The invention discloses an antibacterial corrosion-resistant coating and a preparation method thereof, and relates to the field of coating materials. The coating is prepared from the following components in percentage by mass: 2 to 5 percent of nano silver ion loaded mesoporous silicon dioxide nano particle antibacterial aid, 5 to 10 percent of zinc powder-containing corrosion inhibitor, 3 to 8 percent of nano montmorillonite, 30 to 40 percent of modified epoxy resin, 20 to 30 percent of polyurethane prepolymer and other aids. The nano silver ion antibacterial auxiliary agent is loaded in mesoporous silica nanoparticles through an ion exchange method, the zinc powder corrosion inhibitor is prepared through stirring and ball milling dispersion, and the modified epoxy resin is modified by adopting a silane coupling agent. The preparation process of the coating comprises the stages of premixing, grinding and refining, initiating polymerization and post-treatment, wherein a grinding medium is zirconium oxide beads with the diameter of 0.5-2 mm. The coating has excellent antibacterial and corrosion-resistant performance, is suitable for metal surface protection, and can effectively solve the problems that an existing coating is not lasting in antibacterial effect, insufficient in corrosion-resistant performance and not ideal in comprehensive performance.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The present invention discloses a pH-responsive pesticide slow-release hydrogel sphere and a preparation method thereof, belonging to the technical field of slow-release pesticides. The present invention uses carboxylated nanocrystalline cellulose modified by polyethyleneimine as a raw material, which is self-assembled with modified montmorillonite through electrostatic binding, and then loaded with pesticides in an organic solvent. Then, sodium alginate is used as a coating material and anhydrous calcium chloride is used as a cross-linking agent to prepare a pH-responsive pesticide slow-release hydrogel sphere of nanocrystalline cellulose composite montmorillonite by dropping, which is used for the slow release of pesticides in the soil environment. Under the optimal conditions, the encapsulation rate of fipronil in the organic solvent by the hydrogel sphere of the present invention is above 64.1 wt%, and the loading rate is above 67.3 wt%. In the soil environment with different pH values, the highest release rate of pesticides after 120 h is above 59.7%, and the pesticide release rate increases with the increase of pH until the hydrogel skeleton completely breaks, and the purpose of adjusting the pesticide release rate can be achieved by adjusting the pH.

The invention discloses a multi-layer composite barrier film and a production process thereof, and belongs to the field of polymer composite materials. Aiming at the problems of obvious performance attenuation, poor interlayer binding force and low step-by-step compounding process efficiency of a barrier film in a humid and hot environment in the prior art, the invention provides a five-layer asymmetric structure design: an outer layer, a bonding layer, a barrier layer, a bonding layer and an inner layer. Wherein the barrier layer is formed by blending EVOH and MAH-PA6 and cooperating with nano montmorillonite to form a multi-barrier network, so that the oxygen permeability is smaller than or equal to 0.3 cm / (m.24h. 0.1 MPa), and the water vapor permeability is smaller than or equal to 1.5 g / (m.24h). The production process innovation comprises five-layer co-extrusion melt flow rate ratio control, three-roller gradient cooling and a bidirectional plasma processing technology, the continuous production speed is larger than or equal to 120 m / min, and the interlayer peeling strength is larger than or equal to 8 N / 15 mm. The barrier property stability is remarkably improved.

The invention relates to the technical field of composite materials, in particular to a nano-montmorillonite reinforced unsaturated polyester resin based composite material and a preparation method thereof. Comprising the following raw materials in parts by weight: 60-85 parts of orthophthalic unsaturated polyester resin, 3-15 parts of nano montmorillonite, 1-5 parts of a polyfunctional group intercalator, 1-4 parts of an initiator, 0.5-2 parts of dimethylaniline and 0.5-3 parts of gamma-aminopropyltriethoxysilane. The polyfunctional intercalator interacts with interlayer ions and surface groups of the nano-montmorillonite through multiple functional groups of the polyfunctional intercalator, and is effectively inserted into the interlayer of the nano-montmorillonite, so that the interlayer spacing is obviously increased, and favorable conditions are provided for subsequent insertion and compounding of resin; the functional groups not only can chemically react with active groups of unsaturated polyester resin to form stronger chemical bonding, but also can enhance the interface bonding force between two phases through physical entanglement, so that the overall performance of the composite material is remarkably improved.

The invention discloses a wear-resistant and high-temperature-resistant fluorocarbon powder coating and a preparation method thereof. Comprising the following steps: step 1, adding FEVE resin, a modified filler, a curing agent, a flatting agent and an antioxidant into a high-speed mixer, and mixing for 10-15 minutes until the materials are uniform to obtain a mixed raw material; and 2, transferring the mixed raw material into an extruder, extruding, tabletting, cooling, crushing, and screening with a standard sieve to obtain the fluorocarbon powder coating. The preparation method has the beneficial effects that the modified chitosan and the montmorillonite are compounded, the cerium salt is adopted for further modification, and after the obtained modified filler is added into a coating component, the wear resistance and the high-temperature resistance of a coating are remarkably improved.

The invention discloses a high-barrier antibacterial packaging material, a preparation method thereof and a packaging bag, and belongs to the technical field of packaging, the packaging material comprises the following raw materials by weight: 75-85 parts of polylactic acid, 15-25 parts of poly (butylene succinate), 2-6 parts of epoxidized urushiol, and 1-3 parts of benzyl quaternary ammonium salt modified montmorillonite; the epoxidized urushiol is prepared by carrying out epoxidation reaction on urushiol and organic peroxy acid; the packaging material further comprises the following raw materials: 2-5 parts of sepiolite fiber loaded magnesium oxide; according to the invention, biodegradable polylactic acid and poly (butylene succinate) are taken as base materials, and epoxidized urushiol is taken as a reactive compatilizer, so that the compatibility between polylactic acid and poly (butylene succinate) is improved, and meanwhile, the binding property between a polymer matrix and benzyl quaternary ammonium salt modified montmorillonite and sepiolite loaded magnesium oxide is enhanced; the packaging material with good mechanical property, barrier property and antibacterial property is obtained.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention relates to the technical field of high polymer material and polymer modification, in particular to modified asphalt based on nano material reinforcement and a preparation method, the modified asphalt comprises matrix asphalt subjected to molecular cutting and compounding, a nano titanium dioxide-graphene-carbon nano tube ternary composite material, zwitter-ion and silane synergistically modified nano montmorillonite, the rubber powder subjected to special treatment, the bio-based and traditional compound plasticizer and the 2-mercaptobenzimidazole and sulfur compound stabilizer are synergistically modified. The modified asphalt has the advantages of excellent performance, high-temperature stability, low-temperature crack resistance, strong aging resistance, efficient and environment-friendly preparation process, low energy consumption, short period and good nanometer material dispersion, and adopts the bio-based plasticizer to promote the green development of the asphalt industry.

The invention discloses a high-strength hoop and a processing method thereof in the technical field of mechanical connection fasteners. The high-strength hoop comprises the following raw materials: modified carbon fibers, a modified epoxy resin matrix, chopped glass fibers, an antioxidant and an aluminate coupling agent. Cleaning the modified carbon fibers with acetone to remove oil stains, oxidizing the modified carbon fibers with concentrated nitric acid at 80-85 DEG C to generate polar functional groups containing hydroxyl and carboxyl, washing the modified carbon fibers with water until the modified carbon fibers are neutral, drying the modified carbon fibers, immersing the modified carbon fibers into an absolute ethyl alcohol solution of an aluminate coupling agent for ultrasonic dispersion, and curing the modified carbon fibers at 100-105 DEG C; the modified epoxy resin matrix is prepared by heating and melting epoxy resin, adding nano montmorillonite, stirring and dispersing, adding polyamide, an accelerant and a flexibilizer, and carrying out vacuum defoaming at 100-105 DEG C. The hoop has the advantages of high strength, weather resistance and the like by modifying and enhancing interface bonding and matrix toughness, and is suitable for connection under complex working conditions.

The invention relates to a porous carbon material as well as a preparation method and application thereof. The specific surface area of the porous carbon material is 1500-3000m < 2 > / g, and pore channels are intensively distributed in a range of 0.6-2.0 nm. The preparation method of the porous carbon material comprises the following steps: (1) montmorillonite acid treatment; (2) uniformly mixing the acid-treated montmorillonite obtained in the step (1) with asphalt, and carrying out carbonization treatment to obtain a carbonized material; and (3) under the inert atmosphere condition, mixing the carbonized material with an activating agent for activation, and then washing and drying. The porous carbon material obtained by the invention has the advantages of large specific surface area, reasonable pore size distribution, high ion transmission speed and the like, and is a super-capacitor carbon material with excellent rate capability.

The invention relates to a nanoscale grouting method for illite-smectite mixed layer surrounding rock, which is characterized by comprising the following steps of: S1, combined detection of a borehole television and a ground penetrating radar or a geological radar: carrying out rock mass structure detection in a manner of combining the borehole television and the ground penetrating radar or the geological radar, and obtaining a deformation rule of a roadway and surrounding rock in an area; s2, arranging grouting pipes and an exhaust pipe: arranging two long and short grouting pipes and one exhaust pipe in the grouting hole according to the deformation rule of the roadway and the surrounding rock in combination with numerical simulation of rock mass mechanics and the result of the numerical simulation; s3, grouting is conducted, specifically, grouting is conducted in a deep and shallow hole matching grouting mode; s4, secondary splitting grouting reinforcement is conducted, specifically, the mine illite-smectite mixed layer surrounding rock is reinforced through a secondary splitting grouting technology, the unfilled part in the primary grouting process is made up, and it is ensured that all gaps are filled with grout; and the illite smectite mixed layer surrounding rock can be grouted well.

The invention relates to a low-cost high-stability urease inhibitor and a preparation method and application thereof.The preparation method includes the steps that montmorillonite is modified with inorganic acid to obtain inorganic acid modified montmorillonite, then hydrogen ions in the inorganic acid modified montmorillonite are exchanged with a cationic surface active agent to obtain quaternary ammonium salt surface active agent modified organic montmorillonite, and the quaternary ammonium salt surface active agent modified organic montmorillonite is used for preparing the urease inhibitor. After montmorillonite is subjected to organic modification, the hydrophobicity is greatly improved, and the organic modified montmorillonite has hydrophilicity and hydrophobicity. The organic modified montmorillonite interacts with amino acid residues in a urease flap region due to the hydrophobic effect, so that the amino acid residues are gathered in the organic modified montmorillonite due to the hydrophobic effect, urease conformational change is caused, catalytic activity on urea is lost, and the organic modified montmorillonite has a remarkable urease inhibition effect, is stable in chemical property and non-toxic in material, and can be used for preparing a novel urease inhibitor. The fertilizer is easy to disperse in fertilizer and soil and low in price.

The invention relates to the technical field of preparation of building external wall thermal insulation materials, in particular to a building external wall thermal insulation board based on pearl wool and a preparation method of the building external wall thermal insulation board. The core layer is prepared from the following raw materials in parts by weight: 40 to 60 parts of pearl wool particles, 5 to 15 parts of graphene-loaded expanded graphite, 3 to 10 parts of nano silicon dioxide aerogel, 10 to 20 parts of ammonium polyphosphate, 5 to 12 parts of pentaerythritol, 3 to 8 parts of melamine, 15 to 25 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride grafted polyethylene, 2 to 6 parts of nano montmorillonite and 1 to 5 parts of silicon carbide whisker; the composite material is prepared from the following components in parts by weight: 0.5-2 parts of a silane coupling agent KH560, 0.2-0.8 part of an antioxidant 1010, 3-8 parts of amino-terminated polyether and 0.3-1 part of a hindered amine light stabilizer 770. The thermal insulation board is excellent in thermal insulation, mechanical property and flame retardant property, good in weather resistance, stable in size and high in construction adaptability, pearl wool can be recycled, and the thermal insulation board has practical and environment-friendly values.

The present invention relates to the technical field of coatings and discloses a method for preparing an EVA waterproof coating. Activated montmorillonite reacts with toluene diisocyanate to obtain isocyanate-modified montmorillonite. EVA is hydrolyzed under the catalysis of potassium hydroxide to obtain hydroxylated EVA. An epoxy trisiloxane intermediate reacts with terephthalic acid under ring-opening esterification with benzyltriethylammonium chloride to obtain p-hydroxytrisiloxane benzoate. P-hydroxytrisiloxane benzoate, hydroxylated EVA, and isocyanate-modified montmorillonite are cross-linked with toluene diisocyanate under the catalysis of stannous octoate, and a defoamer and a dispersant are added thereto and stirred uniformly to obtain an EVA waterproof coating. The EVA waterproof coating prepared by the present invention has good mechanical properties and waterproof properties.

The invention belongs to the technical field of agricultural biology, and particularly relates to a compound bacterial fertilizer with a soil structure repairing function and a preparation method thereof. The three-layer embedding structure is more beneficial to improving the survival rate of strains, the limitation of traditional single-layer embedding is broken through through the three-stage structure design of inner core slow release, middle layer regulation and control and shell adsorption, integration of salt adsorption, structure improvement and flora colonization is achieved through cooperation of multiple materials including PGA, biochar and montmorillonite, and saline-alkali soil can be well repaired and improved. Besides, compared with conventional Aspergillus niger, the Aspergillus niger GRJC004 provided by the invention is suitable for survival in a saline-alkali environment, and is especially suitable for restoration and improvement of saline-alkali soil in combination with the three-stage structural design of the Aspergillus niger GRJC004.