56 results about "Ferrocenyl group" patented technology

The invention relates to the technical field of insulating materials, in particular to insulating powder and a preparation method thereof. The invention discloses a flame-retardant coating which comprises the following components in parts by weight: 15-25 parts of epoxy resin, 10-20 parts of aluminum hydroxide, 5-12 parts of nano boron nitride, 1-3 parts of a silane coupling agent KH-560, 3-8 parts of polytetrafluoroethylene micro powder, 2-6 parts of fluorine-modified montmorillonite, 4-9 parts of melamine cyanurate, 2-5 parts of nano titanium dioxide, 1-4 parts of a fluorine-modified graphene oxide-polyaniline composite material and 0.5-2 parts of pentaerythritol stearate. The anti-corrosion coating is prepared from the following components in parts by weight: 1 to 3 parts of nano zinc oxide, 5 to 10 parts of glass fiber, 2 to 5 parts of polyhedral oligomeric silsesquioxane-polyimide copolymer, 1 to 4 parts of ferrocenyl epoxy resin and 0.5 to 2 parts of perfluorooctyltriethoxysilane. The insulation powder is high in corrosion resistance, excellent in insulation, heat dissipation and mechanical performance, environmentally friendly in processing, good in adaptability, capable of prolonging the service life of equipment and reducing the cost, suitable for special environments and wide in popularization prospect.

The invention discloses an ethylene chain-based ferrocenyl covalent organic polymer and application thereof, and belongs to the technical field of biological medicines. The covalent organic polymer based on the ethylene chain ferrocenyl is a covalent organic polymer which is obtained by taking 1, 1 '-ferrocenedicarboxaldehyde, bromoethane and 2, 4, 6-trimethyl-1, 3, 5-triazine as monomers through polymerization and has a completely conjugated structure. The method comprises the following steps: adding 1, 1 '-ferrocenedicarboxaldehyde, bromoethane and 2, 4, 6-trimethyl-1, 3, 5-triazine into a mixed solvent under a protective atmosphere, uniformly stirring, carrying out solvothermal reaction in a closed environment, and washing and drying a product obtained by filtering to obtain the covalent organic polymer based on ethylene chain ferrocenyl. The novel COP material ITAFc-COP with a completely conjugated structure is synthesized, the photo-thermal activity of the novel COP material ITAFc-COP is enhanced by the completely conjugated structure of ITAFc-COP, and the novel COP material has a photo-thermal effect and pod-like activity at the same time.

The invention relates to the technical field of materials, and discloses an antibacterial material containing modified 3-aminofuran-2-methyl formate and a preparation method thereof.The preparation method comprises the steps that modified 3-aminofuran-2-methyl formate, acrylic resin and talcum powder are extruded and granulated in a double-screw extruder, then granules are subjected to compression molding in a press vulcanizer, and the antibacterial material containing modified 3-aminofuran-2-methyl formate is obtained. The antibacterial material containing the modified 3-amino furan-2-methyl formate is obtained. Benzoxazine in the modified 3-aminofuran-2-methyl formate can form a heat-resistant phenolic resin structure at a high temperature, so that the modified 3-aminofuran-2-methyl formate has a relatively good flame-retardant effect; a three-dimensional network structure formed by boron-oxygen bonds contained in the flame retardant has high flame retardance of high oxygen index, low toxicity, low smoke and low calorific value; the carbon nano tube also has a relatively good flame-retardant effect; wherein the ferrocene group and the 3-aminofuran-2-methyl formate in the compound have a relatively good antibacterial effect.

The invention provides ferrocenyl carboxylic acid anthracene methyl ester for photosensitive resin, and relates to the field of photopolymerization. The invention also comprises a photosensitive resin composition containing the ferrocenyl carboxylic acid anthracene methyl ester, a photosensitive dry film containing the ferrocenyl carboxylic acid anthracene methyl ester, and applications of the photosensitive resin composition and the photosensitive dry film. The ferrocenyl carboxylic acid anthracene methyl ester disclosed by the invention has the characteristics of photosensitivity and low migration, can improve the adhesive force of a photosensitive resin composition on various metal surfaces, and can be widely applied to the photocuring fields of dry films, paints, coatings, printing inks, molding materials and the like.

The invention relates to the technical field of corrosion inhibitors, and discloses a high-temperature-resistant corrosion inhibitor and a preparation method thereof.The high-temperature-resistant corrosion inhibitor is obtained by adding boric acid modified chitosan, a triazinyl corrosion inhibitor and deionized water into a reactor and stirring. Lone pair electrons provided by a large number of free hydroxyl groups in chitosan in the boric acid modified chitosan can be well adsorbed with metal, so that the metal is prevented from being eroded by a corrosive medium; the boron element forms a protective oxidation film or adsorption film on the metal surface, so that the corrosion process is inhibited; and the ferrocene group in the corrosion inhibitor also has a relatively good corrosion inhibition effect. A quaternary ammonium salt group and a sulfonic acid group in the triazinyl corrosion inhibitor can prevent further corrosion of metal.

The invention discloses a ferrocene-based D-A type multi-system conjugated small molecule synthesis method, which comprises: carrying out a heating reaction in an organic solvent by using a ferrocenyl compound and a bromophenyl compound as raw materials and using a palladium complex as a catalyst, and after the reaction is completed, carrying out extraction, column chromatography and recrystallization to prepare an intermediate; the obtained intermediate and a 4-pyridine boric acid compound are used as raw materials, a palladium complex is used as a catalyst, a heating reaction is conducted in an organic solvent, and after the reaction is finished, cooling, extraction, column chromatography and recrystallization are conducted to prepare the D-A type multi-system conjugated small molecules. The invention also discloses a memory device with a sandwich structure and application of the memory device to ultra-high density information storage. The small molecular material prepared by the invention not only can realize ternary information storage performance, but also greatly improves the stability of the device through stable redox cycle of the ferrocene group, and realizes long-time stable ultrahigh-density information storage.

The invention discloses application of ferrocenyl conjugated microporous polymers Fc-CMPs in a composite solid propellant and the composite solid propellant, the ferrocenyl conjugated microporous polymers Fc-CMPs are porous organic polymers which take ferrocenyl groups as conjugated functional units and are connected through covalent acetylenic bonds, and the ferrocenyl conjugated microporous polymers Fc-CMPs have excellent thermal stability and permanent porosity, and can be used for preparing the composite solid propellant. The material is solid powder, is insoluble in a traditional organic solvent and does not migrate, and a ferrocene unit serves as a constituent part of a polymer framework and an oxidation-reduction active site and is dispersed in a two-dimensional conjugated network structure of a composite solid propellant. When being used as a burning rate catalyst to be applied to AP decomposition, the ferrocene burning rate catalyst can obviously reduce the high-temperature decomposition peak temperature of AP, and solves the migration problem of a traditional ferrocene burning rate catalyst in a composite solid propellant system. The Fc-CMPs are applied to an AP decomposition catalysis scene for the first time, and a new direction is provided for development of a composite solid propellant burning rate catalyst.

The invention relates to a surface-imprinted combined modified electrode and its production method, comprising a novel chalcone-substituted cyclotriphosphazene (CBRG-Fe) and multi-walled carbon nanotube (MWCNT) composite, intended to be used as an electrochemically active sensor for the sensitive determination of ractopamine.

The invention discloses a kind of ferrocenyl-doped MOF-derived metal carbide electrocatalyst and its preparation method and application, preparation method includes:ZIF 8 is dissolved in anhydrous methanol to obtain solution A;Ferrocenyl monocarboxylic acid is dissolved in DMF to obtain solution B;Solution A and solution B are mixed uniformly to obtain reaction solution, and reaction solution is subjected to hydrothermal reaction;The product obtained after the reaction is centrifuged, washed, dried, calcined and carbonized to obtain the ferrocenyl-doped MOF-derived metal carbide electrocatalyst.The catalyst of the present invention has the advantages of being porous, having many active sites, further improves the catalytic performance of electrocatalyst, can be applied to disposable zinc-air battery as oxygen reduction catalyst, and has excellent electrochemical performance under alkaline conditions (0.1M KOH).

The invention discloses a novel method for synthesizing a ferrocenyl phosphine ligand compound, which comprises the following steps of: reacting a ferrocene compound serving as a starting material with a Grignard reagent and phosphorus trichloride under the action of tert-butyl lithium to generate a ferrocene phosphine ligand, and synthesizing a ferrocene diphosphine ligand in one step. The method is stable and high in practicability, and a novel method for synthesizing the ferrocene ligand compound is provided.

The present invention discloses a sound-activated ferrocene-based semiconductor polymer nano-drug, its preparation method and application, belonging to the field of nano-medicine. First, a ferroptosis prodrug DHU-CBA7 based on ferrocene was synthesized, and then the photosensitizer PFODBT and the ferroptosis prodrug DHU-CBA7 were encapsulated in an amphiphilic polymer shell DSPE-PEG and a ROS-responsive shell DSPE-PEG-TK. After connecting the anti-PD-L1 antibody (aPD-L1) externally, the final product was obtained. The preparation process of this nano-immunodrug is simple and highly safe, and can effectively enhance the effect of tumor immunotherapy through a series of cascade reactions, and is highly effective in anti-tumor applications.

The invention discloses a small molecular monomer containing azobenzene and ferrocenyl as well as a synthesis method and application thereof, and the synthesis method comprises the following steps: step 1, obtaining alkynyl functionalized azobenzene from 4, 4 '-dihydroxyazobenzene; step 2, carrying out a click reaction on the ferrocenecarboxylic acid-3-azidopropyl ester and the alkynyl functionalized azobenzene through CuAAC, so as to obtain ferrocene functionalized azobenzene; and 3, carrying out a substitution reaction on methacryloyl chloride and ferrocenyl functionalized azobenzene to obtain the small molecular monomer containing azobenzene and ferrocenyl. The synthesized monomer can be conveniently copolymerized with other functional monomers, so that a water-soluble polymer with a clear and uniform structure is obtained. The polymer can be used as a Fenton reagent, efficiently kills tumor cells through an oxidative stress mechanism, and is applied to chemodynamic therapy of tumors.

The invention relates to a preparation method of an organic sulfur copolymer electrode material. According to the method, ferrocenyl MOFs are grown on an MXene nanosheet by using a hydrothermal method, then sulfur and the ferrocenyl MOFs are copolymerized through a reverse vulcanization reaction, and an MXene-ferrocenyl MOFs-sulfur copolymer, namely the organic sulfur copolymer electrode material, is obtained. The obtained organic sulfur copolymer electrode material is used as a lithium-sulfur battery positive electrode material, the problem that MOFs catalytic active sites are lacked is solved, and electron transfer and lithium ion transportation of an organic sulfur copolymer positive electrode can be promoted; a battery assembled by using the electrode material shows the initial specific discharge capacity of 1335mAh g <-1 > at the multiplying power of 0.2 C, and the specific discharge capacity at the multiplying power of 5C is about two times that of a battery assembled by using a ferrocenyl MOFs-sulfur copolymer electrode.

The application discloses an anti-migration ferrocenyl hyperbranched polymer burning rate catalyst, a preparation method thereof and application thereof. The ferrocenyl hyperbranched polymer is prepared by one-pot method through amidation reaction with 1,1'-ferrocene dicarboxylic acid and tri(2-aminoethyl)amine as monomers. The ferrocenyl hyperbranched polymer has high anti-migration performance in a composite solid propellant and can reduce the thermal decomposition temperature of ammonium perchlorate.

The invention relates to a novel ferrocenyl hydrophobic label degradation agent targeting GPX4 as well as a preparation method and application of the novel ferrocenyl hydrophobic label degradation agent. The GPX4 protein degradation agent has a chemical structure as shown in a formula (I). Pharmacological experiments show that the derivative or salt disclosed by the invention can be used for remarkably degrading GPX4 protein in ferroptosis sensitive cells (such as HT1080, OS-RC-2, 4T1 and 786-O), and has very strong anti-proliferative activity on the four cell strains. The invention also provides a preparation method of the derivative and the pharmaceutically acceptable salt thereof, and an application of the derivative and the pharmaceutically acceptable salt thereof as a GPX4 degradation agent. Formula (I).

The present invention relates to the technical field of chemical synthesis, and in particular to a chiral nickel phosphine (II) complex with a one-dimensional supramolecular structure, and a preparation method and application thereof. A chiral nickel phosphine (II) complex with a one-dimensional supramolecular structure, the chemical formula of which is Ni(TFM-Josiphos)Cl2, wherein TFM-Josiphos is (R)-1-{(S)-2-[bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethylbis(trifluoromethyl)phosphine, the chiral nickel phosphine (II) complex crystal of the present invention belongs to the orthorhombic system, the P222 space group, the unit cell parameters are a=17.3946(7)Å, b=23.1260(7)Å, c=27.7424(6)Å, α=90°, β=90°, γ=90°, V=10736.8(3)Å 3 The preparation method of the chiral phosphine nickel (II) complex of the present invention is simple and convenient to operate, with high purity and good reproducibility. The chiral phosphine nickel (II) complex of the present invention has good thermal stability, exhibits good catalytic performance in the asymmetric catalytic hydrogenation reaction of the side chain of moxifloxacin, a chiral drug intermediate, and has good application prospects.

The invention discloses a method for preparing a degradable anti-skid mat. Betaine, as a zwitterionic compound, imparts specific biocompatibility properties to polyurethane materials through the zwitterions of sulfobetaine; pyridine-nickel complex promotes the reaction of sulfur-containing compounds with polyurethane chains; nickel on the pyridine ring may coordinate with reaction intermediates; the addition of (ferrocenyl) hexanethiol not only provides sulfhydryl (-SH) to participate in click chemistry reactions; due to the introduction of betaine and other functional groups, the crosslinking density and network structure of the polyurethane adhesive are optimized, thereby significantly improving the wear resistance of the material; the polyurethane material itself has good waterproof and oil-resistant properties, and the introduction of groups such as betaine further enhances the anti-skid mat in a humid or greasy environment. The degradable anti-skid mat prepared by the present invention has a degradation cycle of only 56 days and has excellent environmental performance.

The application discloses a synthesis method of a D-A type multi-ary conjugated small molecule based on ferrocene, and comprises the following steps: taking a ferrocene-based compound and a bromophenyl compound as raw materials, taking a palladium complex as a catalyst, and performing a heating reaction in an organic solvent; after the reaction is completed, an intermediate is prepared through extraction, column chromatography and recrystallization; taking the obtained intermediate and a 4-pyridine boronic acid compound as raw materials, taking a palladium complex as a catalyst, and performing a heating reaction in an organic solvent; after the reaction is completed, a D-A type multi-ary conjugated small molecule is prepared through cooling, extraction, column chromatography and recrystallization. The application further discloses a sandwich structure memory device and applies the sandwich structure memory device to super-high-density information storage. The small molecule material prepared by the application can not only realize ternary information storage performance, but also greatly improve the stability of the device through the stable redox cycle of the ferrocene group, thereby realizing long-time stable super-high-density information storage.

The invention relates to a deep purification smelting method for high-purity steel, and relates to the technical field of high-purity steel smelting. The steel comprises the following chemical components in percentage by weight: 0.17%-0.18% of C, 0.65%-0.7% of Mn, 0.006%-0.01% of S, 0.006%-0.01% of P, 0.18%-0.23% of Si, 1.6%-1.65% of Cr, 1.5%-1.55% of Ni, 0.28%-0.29% of Mo, 0.1%-0.15% of Cu, 0.02%-0.025% of Al, 1.0 ppm-1.2 ppm of H, 10 ppm-15 ppm of O and 60 ppm-70 ppm of N. The method comprises the following operation steps: smelting crude molten steel in an electric arc furnace, performing vacuum refining, performing double-vacuum degassing, and performing gas protection die casting. The ferrocenyl intercalated talcum powder is prepared from talcum powder, gamma-mercaptopropyltrimethoxysilane, water, sodium p-styrenesulfonate, N-ferrocenyl-maleimide and sodium hydroxide, and the ferrocenyl intercalated talcum powder is prepared from the talcum powder, gamma-mercaptopropyltrimethoxysilane, water, sodium p-styrenesulfonate, N-ferrocenyl-maleimide and sodium hydroxide.

In some embodiments, the catalyst compound is represented by Formula (I): M is a Group 3-5 metal, a lanthanide metal atom, or an actinide metal atom. E is a substituted polycyclic aromatic hydrocarbon-based ligand bonded to M and is substituted with at least one ferrocenyl substituent bonded to the aromatic six-membered ring of the polycyclic aromatic hydrocarbon-based ligand. A is a monoanionic ligand bonded to M. And n is 0 or 1. T is bonded to A and E, and is a bridging group containing a Group 13, 14, 15, or 16 element, and is present when n is 1 and absent when n is 0. Each example of X is independently a monovalent anionic ligand, or two X are joined and bound to M to form a metal ring ring, or two X are joined to form a chelate ligand, a diene ligand, or an alkylene ligand.

The invention provides a ferrocenyl triazine photodegradation agent and an application of the ferrocenyl triazine photodegradation agent. Due to the combination of the ferrocene and the triazine ring, the disadvantage that the ferrocene can sublimate is improved; meanwhile, the photodegradation agent expands photoresponse to a visible light region through an intramolecular charge transfer effect, and the maximum photoresponse reaches 500 nm. The degradation agent is good in compatibility with materials and can be in full contact with the materials, seepage of the light degradation agent is reduced, and accurate regulation and control of the degradation rate are achieved. In addition, the degradation agent can be uniformly dispersed in a polyvinyl chloride matrix, stress concentration points formed by local enrichment are avoided, and the degradation agent can be efficiently utilized without excessive addition of compensation loss.

The invention relates to the technical field of composite nano materials, in particular to a preparation method and application of a ferrocenyl photo-thermal nano material, and the preparation method comprises the following steps: S1, preparing gamma-3-chloropropionyl-L-glutamate which is marked as CPLG; s2, preparing gamma-3-chloropropionyl-L-glutamic acid N-carboxylic acid anhydride, and recording the gamma-3-chloropropionyl-L-glutamic acid N-carboxylic acid anhydride as CPLG S3, preparing methoxy polyethylene glycol-b-poly (gamma-3-azidopropionyl-L-glutamic acid ester), and recording the methoxy polyethylene glycol-b-poly (gamma-3-azidopropionyl-L-glutamic acid ester) as mPEG-b-PAPLG; s4, preparing mPEG-block-poly (gamma-3-ferrocene propionyl-L-glutamic acid ester), and recording the mPEG-block-poly (gamma-3-ferrocene propionyl-L-glutamic acid ester) as MPF ( S5, preparing the ferrocenyl photo-thermal nano material; the prepared ferrocene-based photo-thermal nano material is used for photo-thermal therapy of tumors, an amphiphilic polymer and acetylene ferrocene are used for carrying out a click chemical reaction, the nano material has a nano particle core with higher hydrophobicity, leakage of an organic photosensitizer in the nano material can be effectively prevented, the nano material can cope with a complex in-vivo environment, and the photo-thermal therapy effect is improved.

The invention relates to the technical field of multi-component copolymerized adhesives, and aims to provide a preparation method and application of a multi-component copolymerized adhesive with high bonding performance and long-acting mildew resistance. A ferrocene group is introduced into a 1, 3, 4-oxadiazole molecular structure, the phenolic resin adhesive is combined, and the raw material ratio and the synthesis process are optimized, so that the stability, the cementing performance and the antibacterial and mildew-proof performance of the adhesive are remarkably improved. The preparation method comprises the steps of synthesis of a 1, 3, 4-oxadiazole ring, condensation reaction of a ferrocene group, recrystallization purification and the like. The obtained adhesive shows excellent performance in plywood application, the dry bonding strength reaches 2.39 MPa, the wet bonding strength reaches 2.12 MPa, the antibacterial rate reaches up to 90%, and the adhesive does not go mouldy within 180 days. The problems that a traditional trialdehyde adhesive is prone to mildewing and poor in stability are solved, the low-toxicity environment-friendly property is achieved, and the adhesive is suitable for the fields of artificial boards, wooden furniture and buildings and has remarkable application value and market prospects.

A high-voltage, high-power battery for efficient energy storage and delivery is provided. It includes at least one anode crafted from lithium metal or zinc metal, paired with an organic cathode featuring an active material, specifically (ferrocenylmethyl) trimethylammonium iodide (FcNI), a ferrocene backbone introduced with methyltrimethylammonium iodide groups, denoted by formula (1):The battery also includes at least one porous polymer separator, characterized by a porosity ranging from approximately 30% to 90%, facilitating ion transport while maintaining structural integrity. Furthermore, the battery incorporates an ether electrolyte, enabling optimal electrochemical performance. It is worth noting that the introduced methyltrimethylammonium iodide groups enhances the redox activity of Fe3+ / 2+ and acts as active dual-redox centers for multiple electron transfer. Particularly, Fe3+ / 2+'s discharging plateau is enhanced to 0.8 V by introducing the methyltrimethylammonium iodide groups, which regulates the electron energy of the redox potential of Fe.

The invention discloses a trinuclear ferrocene-based metal composite material and a preparation method and application thereof, and belongs to the field of burning rate catalysts.The preparation method comprises the steps that ferrocenyl acetaldehyde and ferrocenyl dihydrazone are dissolved, then heating reflux is conducted, purification treatment is conducted, a trinuclear ferrocene ligand is prepared, the trinuclear ferrocene ligand is dissolved in a solvent, a mixed solution A is prepared, and the mixed solution B is prepared; dividing the mixed solution A into three equal parts, and respectively adding a Co salt solution, a Fe salt solution and a mixed solution of Co salt and Fe salt to respectively prepare the trinuclear ferrocene-based metal composite materials of Fc3N4 / Co, Fc3N4 / Fe and Fc3N4 / CoFe. The technical problem that a burning rate catalyst prepared by an existing preparation method is not high in pyrolysis catalytic performance on ammonium perchlorate is solved.

The invention provides a yolk shell structure metal organic framework-based halogen-free flame retardant as well as a preparation method and application thereof, and belongs to the technical field of nano composite flame-retardant materials. The flame retardant is a metal organic framework with a yolk shell structure, and the surface of the metal organic framework with the yolk shell structure is grafted with a ferrocene group and a 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) group; the yolk shell structure comprises an inner core, an outer shell and a cavity located between the inner core and the outer shell. When the flame retardant is applied to epoxy resin, the limit oxygen index of a composite material can reach up to 31.5% only by adding 10 wt% of the flame retardant, the peak heat release rate is reduced by 58.2% when the composite material passes the UL-94 V-0 grade, and release of smoke toxic gas is remarkably inhibited. Meanwhile, the composite material has excellent mechanical properties, the retention rate of tensile strength is greater than 90% (up to 65.4 MPa), and the bending strength is up to 84.2 MPa. According to the invention, halogen-free and low-addition-amount efficient flame retardance and balance of mechanical properties are realized.

The invention relates to an electrostatic spraying process for a flame-retardant electrical cabinet metal plate, and belongs to the technical field of electrical cabinet surface treatment. The electrical cabinet sheet metal part is sequentially subjected to degreasing, acid pickling, phosphating, water washing and drying treatment; the preparation method comprises the following steps: putting epoxy resin, a modified aliphatic amine curing agent, 4-ferrocenyl butyl methacrylate, 4, 4 '-dimercaptodiphenyl sulfide, benzoyl peroxide, a composite flame retardant, a pigment filler, a carboxyl-terminated nitrile rubber flexibilizer, an acrylate leveling agent, an antioxidant and a diluent into a mixing machine, and mixing to obtain plastic spraying powder; the pretreated sheet metal part is placed in a spraying room, electrostatic spraying, curing forming and aftertreatment are conducted on the surface of the sheet metal part, and the flame-retardant electrical cabinet sheet metal part is obtained; the prepared plastic spraying coating is high in oxygen index, the vertical combustion grade reaches the V-0 grade, the flame retardant effect is excellent, and combustion accidents caused by high temperature and electric sparks of an electrical cabinet can be effectively prevented.

The present application relates to the technical field of probabilistic bit device, and especially relates to a probabilistic bit device based on bias control and a preparation method thereof. The probabilistic bit device comprises an electrode pair and a probabilistic bit molecule, and the probabilistic bit molecule is connected between the electrode pair. The skeleton core is a symmetric or near-symmetric biferrocene group, and the two ferrocene units are equivalent redox active centers, and the redox potential is similar, which lays a foundation for state reversible switching and uniform charge delocalization. The ferrocene unit has excellent chemical stability and no thermal degradation problem; the intermediate bridging group can control the electronic coupling strength, which ensures the charge migration across the sites and avoids the coupling of the strong state merging. The results show that in the bias range of 260 mV-400 mV, the probabilistic bit molecule can be switched between the reduced state and the mixed valence state, and then the high and low state ratio of the device is changed, and finally a stable and controllable bias control type probabilistic bit device is constructed.

The invention provides a ferrocenyl dynamic covalent network monomer, 3D printing resin containing the same and application. According to the ferrocenyl dynamic covalent network monomer, a ferrocene unit is introduced into the monomer, a material can be endowed with paramagnetism, reversible fracture and recombination characteristics are endowed through dynamic covalent bonds, a dynamic covalent network can be constructed by introducing the monomer into a polymer network, and the material has photocuring activity, paramagnetism and dynamic responsiveness; and the method has a remarkable application prospect when being used for preparing intelligent functional devices through photocuring 3D printing.