The invention relates to the technical field of membrane separation, in particular to a preparation method of a pH-step-by-step thermocuring regulation
sodium-
magnesium separation
nanofiltration membrane. The method comprises the following steps: (1) pre-treating a base membrane; (2) preparation and treatment of an aqueous phase solution: S1, preparing the aqueous phase solution according to
mass fraction: sequentially adding 1.2%-1.6% of
piperazine, 0.10%-0.14% of triaminopyrimidine and 0.14%-0.18% of
polyethylene glycol into deionized water, and stirring until the
piperazine, the triaminopyrimidine and the
polyethylene glycol are completely dissolved to form the aqueous phase solution; s2, adjusting the pH value of the water-phase solution to 10-11 by using
hydrochloric acid; s3, pouring the water-phase solution of which the pH is adjusted on the surface of the pretreated base membrane, standing, and blow-
drying to form a uniform water-phase layer; (3)
interfacial polymerization reaction: S1, preparing an
oil phase solution: adding 0.10-0.14% of trimesoyl
chloride into n-
hexane, and performing ultrasonic treatment until the trimesoyl
chloride is completely dissolved; s2, pouring the oil-phase solution on the surface of the base membrane subjected to water-phase treatment, and after reaction, pouring out redundant solution to form a
polyamide separation layer, so as to obtain a membrane sheet; (4) performing a step-by-step thermocuring process; and (5) cleaning and storing.