The invention provides a fuel
cell, a
membrane electrode assembly and a preparation method thereof. The
electrode assembly comprises an outer frame and an inner frame, the outer frame is arranged on the outer side of the
gas diffusion layer, the outer frame and the
gas diffusion layer are arranged at an interval, and the outer frame comprises a first outer frame and a second outer frame which clamp the edge of the catalyst layer
coating film; the inner frame is arranged between the outer frame and the
gas diffusion layer and comprises a first inner frame and a second inner frame which are positioned on two sides of the
proton exchange membrane; the side faces, facing the gas
diffusion layer, of the first outer frame and the second outer frame are each provided with a first recess, the side faces, facing the outer frame, of the two sub-
layers are each provided with a second recess, one parts of the first inner frame and the second inner frame are located in the first recesses, and the other parts are located in the second recesses. The contact surface of the catalyst layer
coating film and the outer frame and the contact surface of the gas
diffusion layer and the inner frame are both glued, the catalyst layer
coating film abuts against the contact surface of the inner frame, the
membrane electrode assembly can effectively overcome the transverse stress, and the durability of the membrane
electrode sealing frame is remarkably enhanced.