Provided is a composition comprising: A) an aliphatic
polyurethane which comprises a
reaction product of a first aliphatic polyisocyanate, a first
polyol, and a
thiol, optionally in the presence of a catalyst, and B) a urethane (
meth)
acrylate prepolymer, optionally a
reactive diluent, and a
photoinitiator, wherein the urethane (
meth)
acrylate prepolymer comprises a
reaction product of a second aliphatic polyisocyanate, a second
polyol and an
acrylate, wherein the
reactive diluent comprises a (
meth)acrylate
monomer, wherein the first aliphatic polyisocyanate and second aliphatic polyisocyanate may be identical or different, and wherein the first
polyol and the second polyol may be identical or different. Also provided is a process comprising combining: A) a
polyurethane which comprises a
reaction product of a first aliphatic polyisocyanate, a first polyol, and a
thiol, optionally in the presence of a catalyst, and B) a urethane (meth)acrylate
prepolymer, a
reactive diluent, and a
photoinitiator, wherein the urethane (meth)acrylate prepolymer comprises a reaction product of a second aliphatic polyisocyanate, a second polyol and an acrylate, wherein the reactive
diluent comprises a (meth)acrylate
monomer, wherein the first aliphatic polyisocyanate and second aliphatic polyisocyanate may be identical or different, and wherein the first polyol and the second polyol may be identical or different. The compositions of the invention may find use in 3D printing applications.