The invention discloses a novel carbonized polybenzoxazine
aerogel and a preparation method thereof, the novel carbonized polybenzoxazine
aerogel is prepared by carbonizing a novel polybenzoxazine
aerogel, and the invention belongs to the technical field of aerogel materials. The preparation method comprises the following steps: preparing a polybenzoxazine solution; putting the polybenzoxazine solution into a mold to form wet gel; aging the wet gel, and
drying at normal pressure for 24 hours after aging; the aged wet gel is washed with N, N-
dimethylformamide, and wet conductive gel is obtained; and
drying the wet gel at normal temperature and normal pressure to obtain the novel polybenzoxazine aerogel. The polybenzoxazine aerogel is subjected to heat preservation for 6 hours at the temperature of 800 DEG C in an
argon environment to be carbonized, then furnace cooling is carried out, and the novel carbonized polybenzoxazine aerogel is obtained after the polybenzoxazine aerogel is cooled. The preparation method has the advantages that the
bisphenol F type benzoxazine
monomer is used as a
raw material, and the preparation method is simple through acid catalytic
polymerization and normal-pressure
drying; compared with other aerogel materials, the aerogel disclosed by the invention has excellent
electromagnetic shielding performance and relatively
high resistivity.