421 results about "Phosphite ester" patented technology

The invention discloses a rare-earth metal arylamine group compound as well as preparation method and application thereof. The invention discloses the rare-earth metal arylamine group compound which is characterized in that a general formula of the rare-earth metal arylamine group compound is (2,6-R12PhNH)5LnLi2(THF)2, wherein Ln is a rear-earth metal selected from one of neodymium, samarium, ytterbium or yttrium; R1 is selected from one of hydrogen, methyl or isopropyl. The rare-earth metal arylamine group compound has the advantages that the rare-earth metal arylamine group compound has a definite structure; raw materials used in the preparation method are simple, easily obtained and cheap; the reaction process is simple and easily operated; the rare-earth metal arylamine group compound product is conveniently purified and the yield of the product is high; the rare-earth metal arylamine group compound has a high activity when acting as a single component catalyst to catalyze a hydrogen phosphine reaction of aldehyde or ketone and phosphite ester; the use amount of the catalyst is less; the yield is high; a substrate has wide universality; a new and simple method is provided for synthesis of a-hydroxyphosphonate.

The invention relates to the technical field of high polymer materials, and particularly discloses a fluoride-free halogen-free flame-retardant polycarbonate material and a preparation method and application thereof.The fluoride-free halogen-free flame-retardant polycarbonate material is prepared from, by weight, 70-90 parts of polycarbonate resin, 8-15 parts of phosphorus-nitrogen flame retardant and 3-8 parts of silicon flame-retardant synergist, the composite material is prepared from the following raw materials in parts by weight: 20-30 parts of polypropylene, 2-5 parts of nano reinforcing filler, 0.1-0.5 part of hindered phenol antioxidant, 0.1-0.5 part of phosphite ester antioxidant and 0.1-0.5 part of pentaerythritol stearate. Through the synergistic effect of the composite flame-retardant system and the nanofiller, high flame retardance (UL94 V-0 level, 1.5 mm thickness), high heat resistance (the heat distortion temperature is greater than or equal to 130 DEG C) and excellent mechanical property are realized, the control is easy, the processing is stable, good balance of flame retardance and mechanical property is achieved on the premise of environmental protection, and the composite flame-retardant material is suitable for the fields of high-end household appliances and consumer electronics.

To provide synthetic fibers and a synthetic fiber treatment agent capable of improving heat resistance.SOLUTION: The synthetic fiber treatment agent contains (A) the following smoothing agent, and (B) organic phosphite ester. The smoothing agent contains at least one selected from (A1) a tri-fatty acid ester of glycerin and (A2) a tri-fatty acid ester of trimethylolpropane.SELECTED DRAWING: None

The invention discloses an antistatic agent for polyolefin film material production and a preparation method thereof. According to the invention, through reasonable molecular structure design, raw material selection and synthesis process optimization, the antistatic agent has multiple functions of high-efficiency antistatic property, oxidation resistance, antibacterial property, mechanical property enhancement and the like. The polyolefin material added with the multifunctional antistatic agent has good antistatic performance under different environmental conditions, and the oxidation resistance, the antibacterial property and the mechanical property are also remarkably improved. The antistatic agent has good adaptability with processing of a polyolefin film material and has wide application prospects and market competitive advantages, and the comprehensive performance of the polyolefin film material is remarkably improved through multi-component collaborative design. The composite system of the polyolefin quaternary ammonium salt and the graphene quantum dots strengthens the long-term effect of the antistatic effect, and meanwhile, the synergistic effect of the hindered phenol and the phosphite strengthens the antioxidant stability of the material in the processing and using processes.

The invention relates to the technical field of cables, in particular to a high-flexibility ethylene-propylene insulating rubber material for a charging pile cable and a preparation process. The composite material comprises an ethylene propylene diene monomer, a thermoplastic polyolefin elastomer, an ethylene-butylene copolymer, nanoscale magnesium hydroxide, a silane coupling agent, dicumyl peroxide, a hindered phenol antioxidant and a phosphite antioxidant. The ethylene propylene diene monomer and the ethylene-butylene copolymer form a flexible network skeleton, and the ethylene-butylene copolymer and the thermoplastic polyolefin elastomer are subjected to molecular-level blending, so that the elongation at break and the bending fatigue resistance are improved; silane coupling agent modified nano magnesium hydroxide is chemically bonded with a rubber matrix, so that the flame retardance and thermal aging resistance are enhanced, and the negative influence of filler agglomeration on flexibility is reduced; the compound antioxidant system effectively inhibits thermal oxidation degradation at high temperature, avoids insulation failure, realizes collaborative optimization of high flexibility and high heat resistance, and improves the reliability and applicability of the charging pile cable.

The invention discloses hydrolysis-resistant liquid phosphite ester and a preparation method and application thereof.The hydrolysis-resistant liquid phosphite ester is prepared by the steps that 2, 2, 4-trimethyl-1, 3-pentanediol and phosphorus trichloride or phosphite triester serve as raw materials, a cyclization reaction is conducted firstly, and then the hydrolysis-resistant liquid phosphite ester is obtained; and then carrying out nucleophilic substitution on Cl or aryl and alkyl on the cyclized intermediate by using higher saturated monohydric alcohol with more than C8, wherein the molecular structure is as shown in formula I in the specification. The liquid phosphite ester is novel liquid phosphite ester, the main body of the liquid phosphite ester is of a six-membered ring structure, the basic structure of the phosphite ester is reserved to the maximum extent, and the anti-oxidation effect of the phosphite ester is guaranteed; hydrophobic aliphatic chain structures on phosphorus atoms and branched chains of the phosphorus atoms prevent water molecules from approaching P-O bonds, so that the phosphorus atoms and the branched chains are prevented from being attacked by the water molecules, and the hydrolysis resistance is improved under the conditions that any additional amine hydrolysis-resistant agent is not used and any steric hindrance group is not introduced; good practical value, economic value and market prospect are realized.

The application discloses a kind of high-performance coiled material powder coating and preparation method thereof, belong to powder coating technical field, the application is by the compounding of organosilicon modified epoxy resin and carboxyl-terminated polyester resin, after organosilicon modification, the segment of introduction-Si-O-Si in system has high flexibility, and synergistic effect with nano calcium carbonate, it is helpful to balance the adhesion and flexibility of coating, grafting modification graphene oxide, active chromium oxide is added again, can obviously improve the mechanical strength of coating;After then, phosphite group is grafted onto graphene oxide, and is applied in the present powder coating system, can form three-dimensional network structure in system, chemical bond effect, not only can improve its crosslinking stability in system, and the sheet structure of graphene oxide, also can play certain barrier property, can also give coating longer weather resistance, and active chromium oxide synergistic effect is further improved, and the weather resistance and corrosion resistance of coating.

The invention discloses a colored permanent antistatic PETG material applied to 3D printing. The colored permanent antistatic PETG material comprises the following components in parts by weight: 50-80 parts of a PETG material, 5-20 parts of a PC material, 10-30 parts of a permanent antistatic agent, 5-15 parts of a reinforcing agent, 1-5 parts of a lubricant, 1-5 parts of a compatilizer, 0.1-0.5 part of a coupling agent, 0.1-0.4 part of a hindered phenol antioxidant, 0.1-0.4 part of a phosphite antioxidant, 0.1-0.4 part of a plasticizer and 0.1-0.4 part of toner. The composite material has the beneficial effects that a PETG / PC alloy modification mode is used, so that the heat resistance, the mechanical property and the interlayer adhesive force of the PETG composite material are improved; the high-molecular permanent antistatic agent is used, so that the antistatic capacity of the material is improved under the condition that the color of PETG is not influenced, and the problem that a conventional carbon nanotube / conductive carbon black modified antistatic PETG material cannot be subjected to color matching is solved.

The invention discloses a high-performance coiled material powder coating and a preparation method thereof, and belongs to the technical field of powder paints.The high-performance coiled material powder coating has the advantages that organosilicon modified epoxy resin and carboxyl-terminated polyester resin are compounded, a-Si-O-Si-chain segment is introduced into a system after organosilicon modification, the flexibility is high, and the high-performance coiled material powder coating has a synergistic effect with nano calcium carbonate; the adhesive force and the flexibility of the coating are balanced, and the mechanical strength of the coating can be obviously improved by adding the grafted modified graphene oxide and the active chromic oxide; then, phosphite ester groups are grafted to the graphene oxide, the graphene oxide is applied to a powder coating system, a three-dimensional network structure and chemical bonding can be formed in the system, the crosslinking stability of the graphene oxide in the system can be improved, and a certain barrier property can be achieved due to the flaky structure of the graphene oxide; and the coating is endowed with long-acting weather resistance, and the weather resistance and the corrosion resistance of the coating are further improved through the synergistic effect with the active chromic oxide.

The invention provides a phosphate-based gel electrolyte, and the phosphate-based gel electrolyte is prepared from a phosphate and / or phosphite monomer containing an acrylate-like structure through an in-situ cross-linking reaction. The network skeleton structure of the phosphate-based gel electrolyte can almost swell all the electrolyte, so that the phenomenon that the non-swelled electrolyte produces an over-thick SEI film on the surface of the lithium metal negative electrode is avoided, and the polarization of the positive electrode is delayed. Meanwhile, a phosphate group in the skeleton provides good flame retardance, and the safety performance of the lithium metal battery cell is improved.

The invention discloses a chemical-resistant PC / PBT alloy material and a preparation method thereof. The chemical-resistant PC / PBT alloy material is prepared from the following components in percentage by mass: 25 to 45 percent of polycarbonate, 20 to 35 percent of polybutylene terephthalate, 3 to 12 percent of maleic anhydride grafted ethylene-acrylate copolymer, 6 to 18 percent of sulfonated polytetrafluoroethylene and 4 to 19 percent of nano silicon dioxide coated silicone microspheres, the composite material is prepared from the following components in percentage by weight: 0.5 to 6 percent of triphenyl phosphate modified graphene oxide, 0.1 to 3.5 percent of bis (2, 4-di-tert-butylphenyl) pentaerythritol diphosphite, 0.2 to 3.2 percent of vinyl trimethoxy silane and 0.5 to 2.5 percent of mesoporous silicon dioxide; the total mass percentage of the components is 100%. Through component fine SPTFE chain segment regulation and control, core-shell microsphere interface optimization, graphene intercalation modification and process dynamic crosslinking, graded mixing and ultraviolet radiation assistance, the breakthrough improvement of the chemical resistance of the PC / PBT alloy material is realized.

There has been a need for a novel lubricating oil composition which has characteristics (for example, scuffing resistance and copper corrosion resistance) that are suitable for lubrication of various mechanisms that are incorporated in a device. The present invention provides a lubricating oil composition which contains (A) a base oil and (B) a phosphite ester that has at least one sulfur atom-containing group having 2 to 20 carbon atoms, the group having at least one —(S) x- group (wherein x is an integer of 1 or more) between two adjacent carbon atoms in the structure of an alkyl group, wherein: the content of a thiadiazole compound is less than 0.05% by mass based on the total amount of the lubricating oil composition; and the kinematic viscosity of the lubricating oil composition at 100° C. is 4.2 mm2 / s or more.

The invention belongs to the technical field of protective films, and discloses a photosensitive dry film protective film and a preparation method thereof. The photosensitive dry film protection film comprises an anti-sticking layer, a middle layer and a release layer, the anti-sticking layer is made of first low-density polyethylene, and the haze of the first low-density polyethylene is 10%-30%; the release layer comprises first linear low-density polyethylene and a release agent; the middle layer comprises second low-density polyethylene, second linear low-density polyethylene, nano silicon dioxide and an antioxidant, the antioxidant is obtained by compounding a hindered phenol antioxidant and a phosphite antioxidant, and the content of the antioxidant is smaller than or equal to 200 ppm. Common polyethylene is used as a main raw material, and nano silicon dioxide is used as a nucleating agent to realize crystal point control; the content of the antioxidant is strictly controlled, the influence of the antioxidant on the photosensitive dry film is reduced, and long-acting oxidation resistance is achieved through a specific hindered phenol antioxidant and phosphite ester antioxidant compound system under the low-content condition.

The invention relates to the technical field of batteries, in particular to molecular cage electrolyte for a sodium ion battery, a preparation method of the molecular cage electrolyte and the battery. The preparation method comprises the following steps: mixing a metal organic polyhedron with a safe solvent, and completing cage-entering coordination to obtain a prefabricated solution; mixing the pre-prepared solution with an electrolyte salt solution to prepare an electrolyte; wherein the metal organic polyhedron comprises at least one of a copper-based cage, a uranium-based cage, a zirconium-based cage, a chromium-based cage, a zinc-based cage, a magnesium-based cage, a rhodium-based cage and a lanthanum-based cage; the safe solvent comprises at least one of a phosphate ester solvent, a phosphite ester solvent, a sulfone solvent, a fluorosulfone solvent, a fluorophosphate ester solvent and a phosphazene solvent; the electrolyte salt solution comprises an electrolyte salt, an organic solvent and a functional additive. According to the electrolyte prepared by the preparation method, the thermal safety performance of the battery can be improved, and the electrochemical performance of the battery can also be improved.

The embodiment of the invention discloses a degradable filling plastic master batch and a preparation method thereof. The degradable filling plastic master batch comprises the following components: a bio-based material, an accelerant, a lubricant, a modifier, an antioxidant, a cross-linking agent and a coupling agent, wherein the bio-based material is polylactic acid; the accelerant is modified starch; the plastic modified material is calcium carbonate; the modifying agent comprises pe wax and / or ebs; the lubricant comprises zinc stearate and POE (Polyolefin Elastomer); the antioxidant is a composition of lignin and phosphite ester; the cross-linking agent is triallyl isocyanate, and / or epoxidized soybean oil; the coupling agent is a silane coupling agent or an aluminic acid coupling agent, can provide the strength of the degradable filling master batch, is not prone to deformation during stretching, has an anti-oxidation effect, is more reinforced and durable, and can achieve the purpose of rapid degradation after waste treatment.

Disclosed in the present invention are a low-mold-fouling flame-retardant polyamide composite material, a preparation method therefor and a use thereof. The polyamide composite material comprises the following components in parts by weight: 40-60 parts of a polyamide resin; 13-30 parts of aluminum diethylphosphinate; 4-10 parts of a synergistic flame retardant; 15-40 parts of glass fibers; 0.1-5 parts of an ethylene-maleic anhydride copolymer; and 0.1-2 parts of a thermal stabilizing additive. The thermal stabilizing additive is a phosphite ester. The polyamide composite material of the present invention solves the problem of heavy mold fouling of flame-retardant polyamides, has high notched impact strength, and can meet the requirements of industries such as automobiles, electronics, energy storage, and connectors.

Bis-phosphites having 2-phenylphenol flanking structural units and their use in hydroformylation.

The present invention provides a lithium ion battery electrolyte, including an organic solvent, a lithium salt and an additive; the additive includes a first additive and a second additive; the first additive includes tris (2-cyanoethyl) phosphite; the second additive includes a fluorine-containing lithium phosphate salt compound; the fluorine-containing lithium phosphate salt compound has a structure as shown in formula (I). The present invention is creative using tris (2-cyanoethyl) phosphite as the first electrolyte additive and using a fluorine-containing lithium phosphate salt compound as the second additive; the two additives are used together, cooperate with each other, and act synergistically to generate inorganic lithium salt components such as "LiF" and "Li3PO4", and functional groups such as "P-O" and "-CN", which can suppress the precipitation of transition metal ions and the decomposition of the electrolyte, promote lithium ion conduction, thereby improving the comprehensive performance of the battery such as high voltage performance, high temperature performance and cycle performance.

The invention relates to the field of organic synthesis, in particular to a synthesis method of gamma-aminophosphine oxide compounds and derivatives thereof. According to the synthesis method disclosed by the invention, alpha, beta-unsaturated amide, diaryl phosphine oxide or phosphite ester is taken as raw materials, and under the action of acid, the gamma-aminophosphine oxide compound can be rapidly and efficiently synthesized by a one-pot method. The preparation method comprises the following steps of: generating conjugated nitrile positive ions or imine salt intermediates with strong electrophilicity from alpha, beta-unsaturated amide under the activation of acid, converting diaryl phosphine oxide or phosphite ester into strong nucleophilic three-coordination phosphorus species under the action of alkali, and further performing phosphorus-doped Michael addition reaction on the conjugated intermediates to finally generate the gamma-aminophosphine oxide compounds. According to the method disclosed by the invention, diaryl phosphine oxide or phosphite which is cheap, easy to obtain and stable in structural property is used as a phosphorus source, the substrate applicability is wide, and the economic cost is relatively low; in addition, the method realizes synthesis of a target product without participation of a metal catalyst, and is rapid and efficient.

The invention relates to the technical field of high-voltage cables, in particular to a crosslinked polyethylene insulated high-voltage direct-current cable, which is characterized in that an insulating layer contains a crosslinked polyethylene base material, a composite modifier, an antioxidant compound system, a nano nucleating agent, a tracking-resistant agent, a compatilizer and a smoke suppressant, the composite modifier is prepared by compounding an ethylene-vinyl acetate copolymer and a methyl methacrylate-butadiene-styrene copolymer, the antioxidant is prepared by compounding hindered phenol and phosphite ester, the nano nucleating agent is prepared from silane coupling agent KH-550 modified talcum powder and calcium carbonate, the tracking-resistant agent is prepared from melamine cyanurate and stearic acid activated magnesium hydroxide, and the lubricant is prepared from a lubricant and a lubricant. The compatilizer is maleic anhydride grafted polyethylene, and the smoke suppressant is compounded by ammonium molybdate and tin oxide. The components synergistically improve the flexibility, aging resistance and dielectric property of the insulating layer, the tracking resistance and smoke suppression are balanced, and the preparation process solves the problem of additive agglomeration, accurately controls the crosslinking degree, reduces the internal stress and improves the performance uniformity.

The application discloses a platinum complex with controllable activity and a preparation method and application thereof, which is formed by coordination of vinyl siloxane, modified ligand and chloroplatinic acid; the modified ligand is prepared by reaction of maleic anhydride, allylamine and hydroxymethyl dimethyl phosphite. The application introduces amide groups and phosphite groups into the molecular chain of maleic anhydride, uses the groups as coordination compounds to coordinate with vinyl siloxane and platinum, and can improve the normal-temperature storage stability of the platinum catalyst while still keeping high catalytic activity of the platinum catalyst on the hydrosilylation reaction; when the platinum complex is used for catalyzing preparation of addition-type liquid silicone rubber, no inhibitor needs to be added, and the silicone rubber has good mechanical properties.

The application provides a bidentate phosphite polymer, a preparation method and application thereof, and a method for olefin carbonyl synthesis reaction. The bidentate phosphite polymer provided by the application is shown in formula (I) and is copolymerized by a specific bidentate phosphite ligand and 2-vinyl naphthalene. The bidentate phosphite polymer can be used in catalyzing the olefin carbonyl synthesis reaction, can not only ensure the catalytic performance of the olefin carbonyl synthesis reaction, but also can improve the solvent swelling resistance of the polymer, thereby being beneficial to ensuring the catalyst form stability and being beneficial to the stable production of aldehydes synthesized by the olefin carbonyl synthesis.

The present invention pertains to a sustainable and efficient method for recycling lithium-ion batteries (LIBs) and producing lithium-ion battery precursor (pCAM) cathode precursors. In the recycling aspect, the invention introduces a green solvent mixture comprising Ethylene glycol phosphite (2-hydroxyethyl dihydrogen phosphite) and water, and not limited to the mixture Ethylene glycol, H3PO4 and water (H2O) or a mixture of Ethylene glycol, H2SO4 and water H2O, for leaching valuable metal ions from spent cathodes and ore minerals. This method exhibits outstanding extraction efficiency, with 99.9% recovery rates for nickel, cobalt, manganese, and 99.5% for lithium. In the pCAM synthesis aspect, a novel method that produces pCAM in the spherical hydroxide form using ammonium metal (ii) sulfate hexahydrate (NH4)2M(SO4)2·6H2O, where M represents nickel(II), manganese(II), and cobalt(II), or combinations thereof.

The invention belongs to the technical field of high polymer materials, and provides a modified PEEK material with good processing stability and a preparation method thereof, the modified PEEK material comprises the following raw materials by weight: 90-100 parts of polyether-ether-ketone, 8-15 parts of modified carbon nanotubes, 2.5-5 parts of modified titanium dioxide, 0.5-3.0 parts of a processing aid, 0.2-0.6 part of a hindered phenol antioxidant, and 0.1-0.3 part of a phosphite antioxidant. The preparation method comprises the following steps: step 1, drying PEEK, modified carbon nanotubes and modified titanium dioxide; step 2, mixing the dried PEEK, modified carbon nanotubes, modified titanium dioxide, a processing aid, a hindered phenol antioxidant and a phosphite antioxidant in a high-speed mixer to obtain a premix; and step 3, adding the premix into a twin-screw extruder, and carrying out melt blending, extrusion and granulation to obtain the modified PEEK material.

Electrolyte for a battery cell, battery cell for a vehicle, and method for forming an electrolyte. The electrolyte comprises a base electrolyte. The base electrolyte comprises a primary lithium salt, a carbonate solvent, and an organic sulfate additive. The electrolyte also comprises lithium bis(fluorosulfonyl)imide (LiFSI), present in the range of 0.1 wt% to 1 wt% of the total weight of the electrolyte, a phosphite ester oxygen scavenger, present in the range of 0.01 wt% to 1.5 wt% of the total weight of the electrolyte, and fluoroethylene carbonate, present in the range of 0.5 wt% to 2.0 wt% of the total weight of the electrolyte. The base electrolyte is the remaining wt% of the total weight of the electrolyte, and the total wt% of the electrolyte is 100 wt%.

The application provides a lithium ion battery positive electrode with high rate and high safety performance and a preparation method thereof. The preparation method comprises the following steps: S1, polymerizing a phosphite monomer containing trivalent phosphorus, a functional monomer with a phosphine oxide group and a methacrylate monomer to obtain a thermal expansion polymer inner core; adopting a liquid deposition and electrostatic self-assembly process to coat a solid lithium ion conductor and a carbon-based material on the surface of the inner core to form a brittle composite conductive shell layer, thereby preparing a core-shell structure flame-retardant microsphere; S2, coating a primer slurry containing a pyrolysis gas binder and a conductive agent on the surface of a current collector and drying the primer slurry at a temperature lower than the decomposition temperature of the binder to form a thermal trigger safety primer layer; and S3, mixing a positive electrode active material, a binder, a conductive agent and the core-shell structure flame-retardant microsphere to prepare a slurry, coating the slurry on the surface of the primer layer and drying the slurry through gradient temperature rising to obtain the positive electrode. The lithium ion battery positive electrode realizes the simultaneous consideration of high rate and high safety performance.

The application discloses a kind of high-activity green cleaning agent, its preparation method and application, the high-activity green cleaning agent includes stock solution and diluent liquid;The stock solution is formed by esterification reaction by mixing and heating 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid according to weight ratio 1.8-3:1;And / or the stock solution includes 2-ethylhexanol, phosphite, acetic acid-2-ethylhexyl ester, polyisobutylene succinic anhydride and ethylhexyl phosphate;The diluent liquid is formed by mixing according to weight ratio 1:4-3:7 by content >99% formaldehyde and oligomeric water cluster;The weight percentage of the stock solution is 0.8%-1.3%.The application also discloses fuel containing the above-mentioned high-activity green cleaning agent.The high-activity green cleaning agent of the application is a pure petroleum product, is a new type of fuel modifier, by changing the physical properties of fuel to achieve its synergistic effect, oil saving, carbon cleaning, emission reduction effect, suitable for popularization and application.

The invention discloses an alpha-aminophosphoryl derivative as well as a preparation method and application thereof. The method comprises the following steps: by taking a quinoline derivative as a raw material and tetrahydrofuran (THF) as a solvent, adding boron trifluoride diethyl etherate in a nitrogen system at the reaction temperature of 0 DEG C, stirring for 15 minutes, reducing the temperature of the reaction system to T1 (-60 DEG C to-30 DEG C), adding a Grignard reagent into the reaction system, and reacting for 30 minutes to obtain a solution A; dissolving a phosphorus reagent in the organic solvent at room temperature in a nitrogen atmosphere to obtain a solution B; and adding the solution A into the solution B, reacting for 6-15 hours at the reaction temperature T2 (0-50 DEG C), and after the reaction is finished, extracting, concentrating and carrying out column chromatography to obtain the target product alpha-aminophosphoryl derivative. The invention provides a novel synthetic route for preparing the alpha-aminophosphonyl derivative, and various phosphorus reagents such as diaryl phosphorus oxide and phosphite ester can be compatible with the reaction. The alpha-aminophosphoryl derivative synthesized by the invention has a good antibacterial effect on gram-positive bacteria, especially staphylococcus aureus.

The application discloses a high-elongation-strength anti-fatigue TPU blended material and a preparation method thereof, and relates to the field of polymer materials. In the preparation of the high-elongation-strength anti-fatigue TPU blended material, phosphorus chloride is reacted with 4'-vinyl-[1,1'-biphenyl]-4-alcohol and p-phenylphenol to obtain a phosphite antioxidant; nano-silicon dioxide is sequentially reacted with trimethoxysilane and the phosphite antioxidant to obtain modified silicon dioxide; a modified polyurethane elastomer is prepared by reacting hydroxyl-terminated polysiloxane, 1,4-butanediol, isophorone diisocyanate and adipic dihydrazide; polyether amide elastomer and the modified polyurethane elastomer are mixed, mixed with a compatilizer, modified silicon dioxide and antioxidant 1010, dried, mechanically mixed, and melt-blended to obtain the high-elongation-strength anti-fatigue TPU blended material. The high-elongation-strength anti-fatigue TPU blended material prepared by the application has the abilities of self-repairing, durability and flame resistance.

Bisphosphites with tert-butyl radicals on the central unit and substituted outer unit.