1000 results about "Betaine" patented technology

The invention relates to a ring structure betaine and double-tailed hydrophobic association polymer fracturing thickening agent and a preparation method thereof. The thickening agent is formed by copolymerization of four monomers, namely acrylamide, 2-allyl methylamino sodium ethanesulfonate, methyl diallyl sulfoethyl betaine and hydrophobic monomer double-tailed long-chain alkyl methyl allyl ammonium chloride. The preparation method comprises the following steps: firstly adding distilled water, then sequentially adding acrylamide, 2-allyl methylamino sodium ethanesulfonate, methyl diallyl sulfoethyl betaine and a hydrophobic monomer double-tailed long-chain alkyl methyl allyl ammonium chloride, adjusting the total concentration, introducing N2 to remove oxygen, adding an initiator, and reacting to prepare an AM / AMES / MDASBA / DCnMAAC quadripolymer, namely the polymer fracturing thickening agent. The thickening agent provided by the invention has good water solubility, and shows good salt resistance in mixed brine with the mineralization degree of greater than or equal to 30000 mg / L. The prepared linear solution and gel formed after crosslinking have high viscosity retention capacity at the temperature of 150 DEG C and the shearing rate of 170 s <-1 >, and the actual construction requirement for fracturing yield increase with the on-site mineralization degree larger than or equal to 30000 mg / L is met.

The invention discloses a construction method and application of an electrochemical luminescence (ECL) antifouling sensor based on zwitter-ion hydrogel, and belongs to the technical fields of photoelectric sensing analysis, interface antifouling and environmental science. According to the invention, the hydrogel based on sulfobetaine methacrylate zwitterions and bovine serum albumin is used as the antifouling coating, so that the adsorption of biological proteins and bacteria is effectively hindered, and the service life of the sensor is prolonged. Meanwhile, the interior label Au (at) luminol is packaged in the antifouling hydrogel, so that the integration of interface antifouling and ratio detection is realized, the detection accuracy is improved, and the construction process of the ECL sensor is simplified. The constructed ECL anti-pollution sensor has high sensitivity to chloramphenicol detection, the detection limit is 0.39 pM, and the ECL anti-pollution sensor is suitable for trace detection of antibiotics in seawater.

The invention relates to the technical field of thickening agents, and discloses a preparation method of a high-temperature-resistant thickening agent for fracturing. According to the preparation method disclosed by the invention, acrylamide, sulfobetaine modified acrylamide and pyrrolidone modified naphthyl melamine are polymerized, so that the thickening agent for high-temperature-resistant fracturing is obtained. A triazine ring structure and naphthyl have high stability, the rigidity of a polyacrylamide molecular chain and the hydrophobic association effect between molecules are enhanced, the high temperature resistance and the salt resistance are improved, and due to the conjugation effect formed by two benzene rings in naphthyl, the thermal stability is further enhanced; by introducing vinyl pyrrolidone, hydrolysis of amido in polyacrylamide can be inhibited, and the temperature resistance and salt resistance of the thickening agent are improved; under a high-salt condition, due to weakening and shielding of mutual attraction of salt ions to anionic and cationic groups in the sulfobetaine, polyacrylamide molecules are more stretched, macroscopically, the viscosity is increased or reduced slightly, and the temperature resistance and salt resistance are improved.

The present invention uses commercially available 3-aminopropylsilane coupling agent, diallylamino polyether acrylate, and an alkylating agent, or γ-propanesultone, or γ-butyrolactone as raw materials, and through an aza-Michael addition reaction and a quaternization reaction, a multifunctional silane coupling agent containing one or more quaternary ammonium cations, or sulfobetaine, or carboxybetaine in its molecular structure is prepared, which is used for the surface modification of bioactive glass, and the bioactivity, antibacterial and antifungal properties, and hydrophilicity enhancement effects after the surface modification of bioactive glass are obtained.

The invention provides a method for biologically removing toxicity inhibition and intensively degrading typical medical organic wastewater under salt stress, and belongs to the technical field of sewage treatment. According to the method, efficient degradation of the high-salt medical organic wastewater is achieved by taking measures such as combination of salt-tolerant nascent-state functional flora and cofactor strengthening, the salt-tolerant nascent-state functional flora comprises obligate COD degradation anaerobic granular sludge and sludge domesticated by gradient salinity pressure of medical wastewater, and the cofactor is betaine, glutamic acid, trehalose or potassium chloride. According to the method, the anaerobic methanogenesis efficiency and TOC removal of organic matters in a degradation system under salt stress can be promoted, the inhibition effect of salt on flora can be relieved and broken through the addition of cofactors, effective metabolism of pollutant nitrogen heterocyclic rings and alkane substances is promoted, refractory characteristic components of wastewater are eliminated, and the biodegradability of the wastewater is improved.

The invention discloses a feed functional compound for improving salt-alkali stress resistance of macrobrachium rosenbergii and application of the feed functional compound, and belongs to the technical field of aquaculture. The feed functional compound for improving saline-alkaline stress resistance of macrobrachium rosenbergii provided by the invention comprises vitamin D3, betaine and sodium oleate. According to the invention, the absorption promotion effect of vitamin D3 on calcium and phosphorus ions is utilized, so that the ion metabolism disorder of macrobrachium rosenbergii under saline-alkali stress is improved; by utilizing the osmotic pressure regulation capability of betaine, osmotic pressure unbalance under saline-alkali stress is improved, and the energy consumption of osmotic regulation is reduced; the sodium oleate is used for improving energy supply, the membrane structure is adjusted to improve osmotic pressure adjusting capacity, and the three components act together to achieve the purpose of improving salt-alkali stress tolerance of macrobrachium rosenbergii.

The invention discloses a magnetic biochar-based saline-alkali soil conditioner as well as a preparation method and application thereof, after a biochar material is loaded on ferrous iron, the biochar material is subjected to alkaline oxidation to obtain ferroferric oxide and a porous biochar material in a stable state, and finally activated humic acid, betaine, trehalose and melatonin are combined with magnetic biochar. The magnetic charcoal-based saline-alkali soil conditioner is low in price and easy to obtain and has a good improvement effect on physicochemical properties of saline-alkali soil and promotion of rice growth, and the preparation process is simple and easy to operate.

The invention relates to a betaine type double-tailed hydrophobic association polymer fracturing thickening agent and a preparation method thereof. The thickening agent is prepared by the following steps: copolymerizing four monomers, namely acrylamide, 2-allyl methylamino sodium ethanesulfonate, methyl diallyl hydroxypropyl sulfobetaine and double-tailed long-chain alkyl allyl sulfoethyl betaine to form gel, chopping, hydrolyzing, neutralizing and purifying. The preparation method comprises the following steps: firstly adding distilled water, adding acrylamide, 2-allylmethylamino sodium ethanesulfonate, methyldiallyl hydroxypropyl sulfobetaine and other remaining raw materials, adjusting the total concentration, introducing N2 to remove oxygen, adding an initiator, reacting to prepare gel, chopping the gel, and hydrolyzing to obtain the water-soluble polymer. The fracturing thickening agent has good water solubility and shows good salt resistance in mixed saline water with the mineralization degree larger than or equal to 30000 mg / L, a prepared linear solution and jelly formed after crosslinking have high viscosity retention capacity at the temperature of 150 DEG C and the shearing rate of 170 s <-1 >, and the actual construction requirement for fracturing yield increase with the on-site mineralization degree larger than or equal to 30000 mg / L is met.

The invention relates to the technical field of oil and gas field development, in particular to a double-network CO2 response type gel particle and application thereof.The first-layer network is formed by covalent bonds between acrylamide, zwitterions and CO2 response monomers (composed of vinylpyridine and DMAEMA) in the gel particle and a cross-linking agent, and the first-layer network is formed by covalent bonds between Ca < 2 + > in mineralized water, pyridine, SO3 <-> in the zwitterionic monomers and coordinated water; coordination bonds exist among Mg < 2 + >, pyridine, carboxyl (acylamino is partially hydrolyzed) and coordinated water, a second-layer network is formed under the synergistic effect of pi-pi bonds among aromatic rings, and the strength of the gel is enhanced through the toughness of the double-network structure. Due to the introduction of an aromatic ring sulphobetaine monomer and water molecules carried by coordinate bonds, the strength of the gel particles in mineralization water is increased, and meanwhile, the gel particles show higher water-retaining property. Due to the introduction of CO2 response monomers with different pKa values, the particles have good CO2 responsiveness, and still have the dual-network structure in mineralized water after response.

To provide a liquid detergent composition that does not become clouded even at room temperature and low temperatures of -5°C, while exhibiting excellent viscosity and foaming properties.SOLUTION: A liquid detergent composition contains an amino acid-based anionic surfactant (A), betaine (B) represented by the general formula (1), and water (W). A proportion of the surfactant (A) in the composition is 5 to 20 wt.%, and a proportion of the betaine (B) in the composition is 2 to 20 wt.%. Preferably, R1 is an alkyl group or an alkenyl group having 8 to 22 carbon atoms. Also preferably, the betaine (B) includes both a betaine in which the R1 is an alkyl group or an alkenyl group with 12 or less carbon atoms, and a betaine in which the R1 is an alkyl group or an alkenyl group with 14 or more carbon atoms.SELECTED DRAWING: None

The invention relates to a rapid detection kit for large yellow croaker pyramidal worm, and belongs to the field of pathogen biological diagnosis in aquaculture. The kit comprises a nucleic acid releasing agent and further comprises a primer and a probe which are used for detecting the large yellow croaker pyramidal worm. The kit comprises a nucleic acid releaser; the formula of the nucleic acid releasing agent comprises tris (hydroxymethyl) aminomethane hydrochloride with the final concentration of 100 mM, sodium chloride with the final concentration of 100 mM, sodium dodecyl sulfate with the final concentration of 1 wt%, sodium alpha-olefin sulfonate with the final concentration of 3 wt%, sodium lauroyl glutamate with the final concentration of 1.2 wt%, betaine with the final concentration of 1 wt% and water as a solvent. The sequences of the primer and the probe for detecting the Pseudosciaena crocea pyramidal are 5 '-TATGGGCAATTCTGAATCCT-3', 5 '-TCTTTTCTGATCCCTGAAT-3' and 5 '-FAM-GTCGGTGGAGTGATTTGTTTG-3'. The kit disclosed by the invention is simple to operate, provides a tool for diagnosis, prevalence monitoring, prevention and control of the Pseudosciaena crocea pyramidal, and has a very high application value.

The invention relates to multi-element modified nano SiO2 particles, a method for constructing a high-efficiency CO2 foaming agent and the CO2 foaming agent, temperature-resistant and salt-resistant particles with a foam stabilizing effect are prepared by carrying out two-step chemical modification on the nano SiO2 particles, and the high-efficiency CO2 foaming agent is constructed by the temperature-resistant and salt-resistant particles and a low-concentration betaine and alpha-olefin sulfonate composite surfactant. The nano SiO2 particles are subjected to multi-element modification such as chemical modification and physical modification, so that the nano SiO2 particles are adsorbed on the gas-liquid surface and are tightly arranged to form a firm interfacial film. The half-life period of CO2 foam formed by a foaming system composed of modified nano SiO2 particles, a betaine active agent and alpha-olefin sulfonate under the conditions that the temperature is 80 DEG C, the pressure is 10 MPa and the salt content in water is 3 * 10 < 4 > mg / L is 9 times or above longer than that of pure modified nano particles, and the half-life period of CO2 foam is 6 times or above longer than that of alpha-olefin sulfonate.

The invention relates to a betaine phosphate-containing feed additive for improving net energy level and a preparation method and application thereof, and belongs to the technical field of feed additives, the preparation method comprises the following steps: preparing composite betaine phosphate, preparing composite zinc methionine, and mixing; the preparation of the composite betaine phosphate comprises the following steps: preparing a betaine phosphate crude product, preparing a composite silicon dioxide carrier, and crystallizing; the preparation of the compound zinc methionine comprises the following steps: preparing an activated silicon dioxide carrier, adsorbing starch and adsorbing the zinc methionine; in the step of mixing, the compound betaine phosphate and the compound zinc methionine are mixed and then stirred at room temperature, and the betaine phosphate-containing feed additive capable of improving the net energy level is obtained. The feed additive prepared by the invention has a strong effect of improving the net energy level of broiler chickens, is not easy to have the problems of bonding and clustering, and is good in storage resistance.

The invention relates to a crop drought-resistant agent, a method for improving crop drought resistance and / or promoting crop growth and development and application of the crop drought-resistant agent, and belongs to the technical field of agricultural production. The crop drought-resistant agent is prepared from the following components: arginine, chitosan, salicylic acid, diethyl aminoethyl hexanoate, betaine, brassinolide and water. The crop drought-resistant agent can promote normal growth and development of crops under drought conditions, improve plant biomass accumulation and cell antioxidant enzyme activity and reduce toxicity of ROS to the plants, so that adaptability, tolerance and resistance of the crops to drought stress are improved, and the crop drought-resistant agent has the advantages of being good in drought-resistant effect, high in stability and high in safety.

The invention discloses a salt-resistant foam scrubbing agent for oilfield exploitation and a preparation method thereof, and belongs to the technical field of foam scrubbing agent preparation. The salt-resistant foam scrubbing agent for oilfield exploitation is prepared from the following components in parts by weight: 15 to 25 parts of a main surfactant, 5 to 10 parts of cocamidopropyl betaine, 0.1 to 0.6 part of a cosurfactant, 1 to 4 parts of EDTA (Ethylene Diamine Tetraacetic Acid) disodium, 0.05 to 0.12 part of nano silicon dioxide and 3 to 6 parts of isopropanol. The foam scrubbing agent prepared by the invention has excellent salt resistance and stability.

The invention belongs to the field of composite ink coatings, and particularly discloses a high-thermal-conductivity and high-adhesiveness copper foil coating ink coating as well as a preparation method and application thereof. The ink coating is prepared from the following components in parts by weight: 15 to 25 parts of epoxy resin, 10 to 20 parts of polyurethane resin, 5 to 12 parts of modified cellulose, 30 to 45 parts of heat-conducting filler, 8 to 15 parts of aliphatic polyisocyanate curing agent, 20 to 35 parts of solvent, 2 to 5 parts of silane coupling agent and 0.5 to 3 parts of pigment. The modified cellulose is prepared by modifying halogen-free betaine hydroxide, and can cooperate with the double-resin matrix to enhance the interface bonding force and construct a three-dimensional heat-conducting network. After the surface of an electrolytic or rolled copper foil is coated with the ink coating, the heat conductivity coefficient of the coating is larger than 0.4 W / (m.K), the dyne value is larger than 38, the cross-cut test is larger than or equal to 4B, alcohol wiping resistance is achieved, falling is avoided, the color difference delta E is smaller than 1, and the ink coating is suitable for a high-frequency circuit substrate and a lithium battery current collector.

The invention relates to a bisulfonate hydrophobic association polymer oil-displacing agent with a benzene ring structure and a preparation method thereof. The polymer oil-displacing agent is formed by copolymerization of three monomers, namely acrylamide, sodium 2-allyl methylamino ethanesulfonate and long-chain alkyl disulfoethyl (4-vinyl benzyl) betaine which is a hydrophobic monomer with the benzene ring structure. The preparation method comprises the following steps: firstly adding distilled water, sequentially adding acrylamide, 2-allylmethylamino sodium ethanesulfonate and long-chain alkyl disulfoethyl (4-vinyl benzyl) betaine, adding water to adjust the total concentration, introducing N2 to remove oxygen, adding an initiator, and reacting at a certain temperature to obtain the terpolymer. The polymer oil-displacing agent prepared by the invention has good water solubility and good temperature resistance and shear resistance, shows good salt resistance in saline water with the degree of mineralization being greater than or equal to 30000 mg / L, shows a good oil-displacing effect in heterogeneous rock cores, and can improve the crude oil recovery rate by 10% or above.

The invention discloses bacillus pumilus, a complex microbial inoculant and application of the complex microbial inoculant in a saline-alkali soil four-dimensional improvement method, and belongs to the technical field of microorganism application. According to the invention, a strain of bacillus pumilus is screened, and the bacillus pumilus has excellent saline-alkaline tolerance, has multiple functions of producing organic acid, proline, siderophore, trehalose, IAA and betaine and the like, and has obvious advantages in saline-alkali soil improvement; the stress resistance of plants is improved through multiple mechanisms, nutrient absorption is promoted, the soil structure and chemical environment are improved, the stability and diversity of soil microbial communities are enhanced, and then effective treatment on the saline-alkali soil is achieved. According to the four-dimensional improvement method for the saline-alkali soil, the microbial technology, the physical technology, the chemical technology and the nutrition technology are combined, the saline-alkali soil is improved from the four dimensions of physics, chemistry, biology and nutrition, soil can be effectively improved, and repeated planting is not likely to happen.

The present invention provides an organic phosphonic acid betaine and a preparation method thereof, specifically an ammonium phosphonic acid betaine containing a glycidyl group. The organic phosphonic acid betaine can be used as a functional monomer for free radical grafting modification of the surface of a polymer material such as polyolefin, or can be mixed with acrylate, acrylonitrile or other olefin monomers for copolymerization to prepare an amphoteric ionomer. The organic phosphonic acid betaine can also be used for ring-opening grafting modification of polymer materials such as starch, cellulose, polyurethane, and polyamide containing amino or hydroxyl groups in their structures. At the same time, the phosphonic acid betaine imparts functional effects such as zwitterionization, hydrophilicity, antibacterial properties, and antifouling properties to the obtained polymer material. The organic phosphonic acid betaine also has high chemical stability in acidic and alkaline water environments.

The invention discloses a plant multi-effect stress-resistant agent and a preparation method thereof, the plant multi-effect stress-resistant agent comprises the following raw materials by weight: 30-40 parts of a modified carrier, 20-30 parts of zeolite powder, 5-10 parts of plant ash, 5-7 parts of compound amino acid, 5-10 parts of a seaweed extract, 15-25 parts of humic acid, 3-5 parts of betaine, 2-3 parts of rhamnolipid, and 0.5-0.8 part of trace elements. The plant multi-effect stress-resistant agent is prepared by compounding a plurality of raw materials according to a scientific ratio, so that the resistance of plants to a plurality of stresses is effectively improved, the growth vigor of the plants is enhanced, and the yield increase and quality improvement of crops are promoted.

The invention discloses a thickening agent, a salt-resistant and high-temperature-resistant fracturing fluid prepared by using the thickening agent as well as a preparation method and application of the salt-resistant and high-temperature-resistant fracturing fluid, and belongs to the technical field of oil and gas development. The problems that in the current oil and gas reservoir exploitation process, the flow-back fluid utilization rate is low, and a thickening agent and fracturing fluid prepared from the thickening agent are high in thickening cost, poor in efficiency, insufficient in temperature resistance and salt resistance and the like are solved. The amphoteric polyacrylamide copolymer is synthesized by using acrylamide, diacetone acrylamide and alkyl sulfobetaine, the copolymer is used as a thickening agent and can be used for preparing the fracturing fluid together with the fracturing flow-back fluid containing high salt, and the fracturing fluid which is high in consistency, resistant to high temperature and salt and high in viscosity can be obtained under the low concentration of the obtained fracturing fluid. And better rheological property and sand-carrying effect are achieved. In addition, an anti-swelling agent can be added into the fracturing fluid to prevent clay from swelling. Meanwhile, an auxiliary surfactant can be added into the fracturing fluid, so that the dissolving speed of the fracturing fluid is adjusted, and the surface tension is reduced.

The invention relates to the technical field of rubber asphalt, in particular to a pavement rubber asphalt crack pouring adhesive and a preparation method thereof. The pavement rubber asphalt crack pouring adhesive is prepared from the following components in parts by mass: asphalt, rubber powder, a compatilizer, modified silicon dioxide, a silane coupling agent and an auxiliary agent, according to the pavement rubber asphalt crack pouring adhesive, asphalt, rubber powder and modified silicon dioxide are compounded; the preparation method comprises the following steps: treating nano silicon dioxide by adopting a KH570 silane coupling agent, introducing unsaturated double bonds into the nano silicon dioxide, then carrying out free radical polymerization on the nano silicon dioxide, alpha-octadecene and sulfobetaine methacrylate under the catalysis of BPO, and respectively introducing long-chain alkyl, sulfo and betaine groups into the modified nano silicon dioxide, so as to obtain the modified nano silicon dioxide. The interfacial compatibility among the components is improved, so that the high-temperature stability and the mechanical property of the crack pouring adhesive are improved.

The invention discloses a copper-titanium etching solution and a preparation method thereof, and belongs to the technical field of etching solution preparation. The etching solution is prepared from the following components in percentage by mass: 4.5-7.5% of potassium peroxymonosulfate composite salt, 1.2-2.8% of sodium percarbonate, 1.2-2.8% of benzotriazole-2, 3, 4-triazole-2, 3, 4-triazole-2, 3, 4-triazole-2, 3, 4-triazole-2, 3- The cleaning agent is prepared from the following components in percentage by weight: 1.2%-1.8% of 1, 3-dicarboxylic acid, 0.3%-0.8% of 5-aminotetrazole, 0.15%-0.45% of ethylenediamine tetraacetic acid tetrasodium salt, 0.15%-0.45% of hydroxyethylidene diphosphonic acid, 0.15%-0.45% of cocamidopropyl betaine, 0.3%-0.8% of benzotriazole, 0.15%-0.45% of 2-mercaptobenzothiazole, 0.02%-0.08% of poly-N-isopropylacrylamide, 0.7%-1.8% of potassium perchlorate and the balance of ultrapure water. According to the etching solution, the copper-titanium etching rate can be accurately regulated and controlled, back cutting and titanium residues are effectively inhibited, the stability of the etching solution is improved, and the service life of the etching solution is prolonged.

The invention discloses a zwitter-ion modified acrylate dielectric elastomer film and a preparation method thereof. Zwitter-ions can be selected from sulfobetaine methacrylate (SBMA), carboxyl betaine methacrylate (CBMA), sulfobetaine acrylamide (SBAA) and the like. The acrylate monomer can be butyl acrylate (BA), dodecyl acrylate (LA), isoamyl acrylate (EHA) and the like. Zwitterions (special compounds which simultaneously carry equal positive and negative charges on the same molecule and are electrically neutral on the whole) are copolymerized into an acrylate dielectric elastomer through photo-initiated free radical polymerization reaction, zwitterionic clusters uniformly distributed in the dielectric elastomer can construct traps for capturing high-energy electrons, the leakage current of the material is reduced, and the dielectric property of the material is improved. And the intrinsic breakdown field strength of the material is improved. In addition, the mutual attraction effect between dipole ions with positive and negative charges in the structure provides driving force for intrinsic self-repairing. And after being electrically and mechanically damaged, the material can be self-recovered, so that the service life of the material is prolonged.

The invention provides a betaine succinate eutectic crystal as well as a preparation method and application thereof, and belongs to the technical field of eutectic crystal manufacturing. The structural formula of the succinic acid betaine eutectic crystal is shown as a formula I, the molecular formula of the succinic acid betaine eutectic crystal is C28H56N4O16, in the succinic acid betaine eutectic crystal, the molar ratio of succinic acid to betaine is 1: 2, and the succinic acid betaine eutectic crystal has low irritation and excellent effects.

The metabolic marker can be used for early diagnosis of heart failure, has the advantages of high sensitivity, rapidness, convenience and accurate and reliable result, provides a basis for clinical decision, provides a certain basis for subsequent fundamental research and clinical research, and has potential application and research values. The metabolic marker comprises one or more of 1-(4-nitrophenyl) piperidine, sphingolipid d19: 3 / 23: 0, phosphatidyl ethanolamine 16: 1e / 22: 5, phosphatidyl ethanolamine 16: 1e / 22: 6, sphingolipid d14: 0 / 22: 1, 3-phosphoglyceric acid, phosphatidylcholine 15: 0 / 20: 4, phosphatidylcholine o-16: 1 / 18: 0, phosphatidylcholine 14: 0e / 20: 1, phosphatidylcholine 17: 0 / 18: 5, betaine, phosphatidylcholine 15: 0 / 18: 2 and phosphatidylcholine 18: 5e / 20: 4.

The invention discloses a fracturing imbibition system for refracturing a low-permeability tight oil reservoir and a preparation method of the fracturing imbibition system, and belongs to the technical field of fracturing fluids, the fracturing imbibition system comprises: an acid liquid base fluid: hydrochloric acid, hydrofluoric acid, EDTMPS and deionized water; an amphoteric betaine viscoelastic surfactant; biologically modifying the nanoparticles; a Gemini cationic surface active agent; a corrosion inhibitor; and an organic silicon defoaming agent and a fluorocarbon discharge aiding agent. According to the fracturing imbibition system, through the integrated design of the multifunctional surfactant, the problems that a traditional acid fracturing fluid is insufficient in silicate mineral dissolving capacity, high-temperature viscosity is attenuated, and corrosion inhibitor dependence is caused are solved.

The invention discloses a preparation method of a eutectic solvent for separating and recycling metals in waste crystalline silicon photovoltaic panels. According to the method, betaine hydrochloride is used as a hydrogen bond acceptor, ethylene glycol is used as a hydrogen bond donor to prepare a deep eutectic solvent with high solubility, and copper chloride is used as an oxidizing agent to leach metal silver and metal aluminum in the waste photovoltaic panel crystal silicon wafer. The leaching system is easy to operate, strong acid and strong alkali used in traditional wet recovery do not participate in the leaching system, and the problem of discharge of waste gas and waste water is solved. In the recovery process, the used ammonia water and water can be reused after rotary evaporation. Compared with a traditional crystalline silicon photovoltaic panel recycling route, the method has the advantages that the technological process is shortened, the cost is reduced, and an effective method is provided for recycling the waste crystalline silicon photovoltaic panel.

The invention relates to the technical field of preparation methods of biomimetic enzyme reactors, and particularly discloses a preparation method and application of a biomimetic enzyme aerogel reactor, and the preparation method specifically comprises the following steps: step S1, firstly preparing titanium dioxide nanofibers (TiNFs) through solvent heat treatment; step S2, carrying out freeze casting and vacuum drying on an aqueous dispersion containing titanium dioxide nanofibers (TiNFs), chitosan methacrylate (CSMA) and a cross-linking agent to obtain a bionic C / TiNFs aerogel reactor with vertically arranged channels; step S3, carrying out polymerization and modification on glycidyl methacrylate (GMA), methacryloylethyl sulfobetaine (SBMA) and an N, N '-methylene bisacrylamide (MBA) cross-linking agent on a skeleton of the simulated gas gel reactor; and step S4, covalently immobilizing tannase in the bionic gas gel reactor under a mild condition, so as to obtain the bionic tannase-pGSC / TiNFs enzyme reactor. The bionic tannase-pGSC / TiNFs enzyme reactor disclosed by the invention is composed of TiNFs, CSMA (Carboxymethyl Methacrylate), polyglycidyl methacrylate (PGMA), polymethylacryloyl ethyl sulphobetaine (PSBMA) and immobilized tannase, has vertically arranged channels, and can be used as a tissue cell reactor.

The invention belongs to the field of oilfield chemistry, and discloses a surfactant composition for improving recovery efficiency through tertiary oil recovery steam thermal recovery, and a preparation method and application thereof. The surfactant composition comprises alpha-olefin sulfonate (AOS) as shown in a formula (2), a betaine surfactant with a polyether fragment as shown in a formula (2), a polyether anionic surfactant as shown in a formula (3) and water, formula (3): # imgabs0 # R7O-(CH2CH2O) m1-(CH (CH3) CH2O) n1-(CH2CH2O) m2-R8COOM, and formula (4): (4): (4): (4): (4): (4): (4): (4): (5 The surfactant composition provided by the invention is suitable for tertiary oil recovery steam thermal recovery, has strong foaming ability, good foam thermal stability and relatively high salt resistance, is particularly stable when meeting divalent ions, can meet the recovery requirements of high-temperature and high-mineral-degree thickened oil, can reduce the viscosity of the thickened oil and extra-thickened oil, can reduce the interfacial tension, and can improve the recovery efficiency of the thickened oil and extra-thickened oil. And the recovery efficiency of thermal recovery of thickened oil is improved.