The application discloses an organic-inorganic
hybrid formaldehyde-free fixing agent and a preparation method and application thereof, and belongs to the technical field of
textile auxiliaries. The fixing agent is prepared by using dimethyl diallyl
ammonium chloride and methacryloyloxyethyl trimethyl
ammonium chloride as reaction monomers, N-vinyl pyrrolidone as an organic modifier, and
trisodium phosphate and
bismuth nitrate as inorganic modifiers, and the organic-inorganic
hybrid crosslinking structure is formed through a
polymerization reaction. The preparation method comprises the following steps: pre-complexing
bismuth nitrate and
citric acid, pre-activating a
silane coupling agent, mixing the components, and then performing stage
pH regulation, ultrasonic-assisted dispersion, high-temperature curing and other steps. The fixing agent is prepared by means of coordination crosslinking of an
organic polymer chain and
bismuth ions and covalent connection of a
silane coupling agent, so that a
double network structure is formed, the wet
rubbing fastness and the soaping fastness are significantly improved, the fabric is endowed with antibacterial and
ultraviolet resistance functions, the hydrophilicity and the hand feeling are improved, and the fixing agent does not contain
formaldehyde, and can be widely applied to post-treatment of
textile dyeing.