1555 results about "Carbon chain" patented technology

The invention belongs to the technical field of flame retardants, and particularly relates to a high-thermal-stability polyphosphate flame retardant and a preparation method thereof. The DOPO is modified through the polyethylene glycol acrylate, methyl methacrylate and dicumyl peroxide composite solution, double bonds of the polyethylene glycol acrylate and P-H bonds of the DOPO can be subjected to nucleophilic addition to form stable C-P bonds, and thermal migration of the DOPO is hindered; dOPO has polymerization double bonds of methyl methacrylate and long carbon chains of polyethylene glycol acrylate, so that the compatibility of the polyphosphate flame retardant and a polymer substrate is improved, and phase separation is avoided; maleic anhydride grafted silicone oil is connected to the surface of an amino modified gamma-cyclodextrin-modified DOPO inclusion compound, so that the polyphosphate flame retardant has high thermal stability and high compatibility after long-chain alkyl modification; amino groups in the modified gamma-cyclodextrin react with maleic anhydride grafted silicone oil to generate an amido bond cross-linked network, so that the thermal migration of DOPO is reduced together, and the high thermal stability of the polyphosphate flame retardant is improved.

The invention relates to a halogen-free intrinsic flame-retardant waterborne polyurethane material and a preparation method thereof, and belongs to the field of functional polymer materials and fine chemical engineering. The halogen-based flame-retardant waterborne polyurethane disclosed by the invention is prepared from diisocyanate, long-carbon-chain polyether polyol, a catalyst, a chain extender, deionized water and a salt-forming agent through reaction; the hydrophilic chain extender is prepared from pentaerythritol, phosphorus oxychloride and p-hydroxyphenylpropionitrile through a reaction, and is a flame-retardant chain extender of a diamine structure containing phosphorus and nitrogen flame-retardant elements. The waterborne polyurethane material prepared by the method has a certain flame-retardant effect, and is simple in preparation process, relatively low in cost, very good in practicability and economical efficiency and good in market prospect.

Provided is a composition including: (component A) a silane coupling agent including a carbon chain that contains at least one etheric oxygen atom; and (component B) a silane coupling agent including a siloxane structure.

The invention discloses a synthesis method of amphiphilic quantum dots and application of the amphiphilic quantum dots in nano oil displacement, and belongs to the field of nano oil displacement. The synthesis method comprises the following steps: heating a mixture containing a carbon source and a nitrogen source in an air atmosphere for reaction, and centrifuging, filtering and drying a reaction product to obtain the amphiphilic quantum dots, the carbon source is selected from at least one of glucose, mannose, citric acid, lignin, chitosan and starch; the nitrogen source is selected from at least one of alkylamine, and the carbon chain length of the alkylamine is C6 to C12. The synthesis method is simple, heating of a high-pressure reaction kettle is not needed, the technological process is simple, and the method is suitable for large-scale industrial production; the series of amphiphilic carbon quantum dots show better solubility and higher absolute fluorescence quantum yield in water and various organic solvents.

The invention discloses a soluble alkaline salt scale inhibitor and a preparation method thereof, and belongs to the technical field of oilfield chemistry. The soluble alkaline salt scale inhibitor is prepared from amphiphilic modified graphene oxide, a surfactant, inorganic salt and deionized water, the amphiphilic modified graphene oxide contains a large amount of carboxyl groups, sulfonic acid groups, hydroxyl groups and the like, and has good metal ion chelating property; meanwhile, through the hydrophobic association effect and hydrogen-bond interaction between modified graphene grafted long carbon chains, the bonding probability between sodium ions of the soluble saline-alkali salt and bicarbonate radicals, carbonate radicals and chloride ions is further weakened, and through the synergistic effect of the amphiphilic modified graphene oxide, the surfactant and the inorganic salt, the salt scale inhibition effect is further improved; the method is especially suitable for soluble alkali salt water quality conditions of high temperature, high alkali and high salinity, can solve the problems of oilfield water injection, fracturing flowback strata and wellbore salt deposition, and has a good popularization prospect.

The invention relates to a production workshop carbon flow twinborn mapping method, and belongs to the technical field of carbon emission optimization. The method comprises the steps of collecting production workshop data in real time to perform multi-modal data fusion; constructing a carbon flow dynamic accounting mechanism model, and calculating the real-time carbon emission intensity of the process; constructing a carbon flow intensity tensor model, extracting multi-granularity carbon flow features based on the carbon flow intensity tensor model, and realizing real-time digital twinborn deduction of carbon flow propagation by using an intelligent prediction algorithm; establishing a differential equation to describe double-flow real-time interaction of the carbon flow and the value flow, constructing a carbon value incidence matrix, and performing carbon flow value analysis; and on the basis of the carbon value incidence matrix, a space-time carbon chain-oriented cooperative adjustment strategy is dynamically generated through a multi-objective optimization algorithm, a double-layer topological optimization model is constructed, and a closed-loop feedback mechanism is introduced to drive the economic sustainability of the control strategy in an industrial environment. The workshop carbon footprint can be displayed in real time, the workshop carbon emission condition can be truly reflected, and the carbon emission data can be analyzed and optimized in time.

The invention relates to a polyethylene and silica gel mixed material, a preparation method thereof and application of the polyethylene and silica gel mixed material in a composite optical cable silicon core tube. The composite material comprises the following components in parts by weight: high-density polyethylene, an ethylene-siloxane copolymer elastomer, a maleic anhydride grafted polyolefin elastomer, hydroxylated nano silicon dioxide, liquid paraffin, a crystallization nucleating agent, an ultraviolet light absorber, an auxiliary stabilizer, a processing aid and color master batch. The liquid paraffin is formed by blending dual-molecular-weight paraffin with different carbon chain lengths, and part of the liquid paraffin is grafted and modified by polybutylene so as to enhance the anchoring capacity of the lubricating phase; in addition, nano cellulose crystals grafted by a PEG-PCL (Polyethylene Glycol-Polycaprolactone) block copolymer are introduced, so that the dimensional stability and the interface structure integrity of the material are synergistically enhanced. The composite material has excellent low friction, thermal oxidation stability, creep resistance and ultraviolet aging resistance, and is suitable for preparation of a high-performance composite optical cable silicon core tube.

The invention relates to a water-soluble carbon chain substance for adjusting transmembrane transport and fluidity of a cell membrane, and preparation and application thereof. The water-soluble carbon chain substance comprises a carbon chain originally having certain water solubility, and the structure of the water-soluble carbon chain substance comprises at least one or more hydrophobic carbon chain parts and one or more hydrophilic groups or residues; the hydrophobic carbon chain part is coupled with water-soluble molecules to form a high-hydrophilicity compound; the water-soluble carbon chain can be used for preventing and treating infections including viruses, bacteria and fungi; anti-aging; the occurrence of neurodegenerative diseases such as Alzheimer's disease is prevented and reduced; by reducing the non-specific phagocytosis of the nano-drug by cells, the effect of the nano-drug on a target focus is enhanced.

The invention provides an active carrier, a supported metallocene catalyst, a preparation method and application. The invention relates to an active carrier, which is used for loading a metallocene compound to form a loaded metallocene catalyst, and comprises a carrier body and an ether-modified aluminoxane compound loaded on the carrier body, the ether-modified aluminoxane compound is modified with at least one of an alkyl ether having an alkyl carbon chain having 10 or more carbon atoms and a crown ether. The aluminoxane compound is modified by ether, so that the usage amount of the aluminoxane compound when the active carrier is used for preparing the supported metallocene catalyst can be reduced, the preparation cost of the supported metallocene catalyst is further reduced, and the supported metallocene catalyst can maintain relatively high catalytic activity.

The invention discloses a preparation method and application of polyvinyl alcohol assisted molded aramid nanofiber aerogel. The preparation method of the aerogel comprises the following steps: pulping aramid pulp, homogenizing and centrifuging to obtain an aramid nanofiber aqueous dispersion; dissolving polyvinyl alcohol in deionized water to obtain a polyvinyl alcohol aqueous solution; and mixing the aramid nanofiber aqueous dispersion and the polyvinyl alcohol aqueous solution, placing the mixture in a container, and carrying out liquid nitrogen unidirectional freezing, freeze drying and low-temperature heat treatment to obtain the aerogel. According to the aerogel prepared by the method, due to the physical winding effect of a polyvinyl alcohol polymer chain and the chemical combination effect of a hydrogen bond, dispersion of the aramid nanofiber in a water-based solvent is synergistically promoted; therefore, the phenomena of agglomeration and adhesion, non-uniform forming, slag and powder falling and the like caused by Van der Waals interaction, hydrophilic and hydrophobic interaction and the like among the adjacent aramid nanofibers in the freezing casting process are avoided; the aramid nanofiber in the aerogel subjected to low-temperature heat treatment is close to single distribution, and a viscous polyvinyl alcohol molecular chain is converted into a conjugated carbon chain, so that the mechanical properties of compression, stretching and the like of the aerogel are remarkably improved. In addition, the aerogel can be used as a wave-absorbing material after being carbonized at a high temperature, has the advantages of thin thickness and light weight, and has the wave-absorbing capability of wide frequency band and strong absorption.

The invention discloses a double-85-resistant long carbon chain nylon material as well as a preparation method and application thereof. The double-85-resistant long carbon chain nylon material is prepared from the following components in percentage by mass: 5-12% of a compatilizer, 3-10% of epoxy resin, 3-10% of a nylon hot melt adhesive, 1-3% of a coloring agent, 0.2-1% of an antioxidant, 0.2-0.7% of a lubricant, 0.2-0.5% of a heat stabilizer and the balance of polyamide resin. Through the innovative material and process design, the bonding strength of the bonding layer between the long-chain nylon and the thermoplastic elastomer (TPE) can be remarkably improved, and it is ensured that the key connecting part can still maintain the excellent bonding performance without failure even though the key connecting part is subjected to long-term high-temperature, high-humidity and other extreme environments.

The invention relates to a (methyl) acrylate monomer as well as a preparation method and application thereof, the structural general formula of the (methyl) acrylate monomer is as follows: # imgabs0 #, n is an integer of 1-20, and R1 is methyl or hydrogen; r2 and R3 are selected from hydrogen, Br, phenyl, methyl or # imgabs 1 #, wherein A1 in the # imgabs 2 # is phenyl or methyl. According to the (methyl) acrylate monomer provided by the invention, the molecular size of the whole monomer is relatively small, the whole monomer has a plurality of branched chain structures, the carbon chain length of a main chain is controllable, and the (methyl) acrylate monomer has high refractive index and good intermiscibility with other components.

The invention belongs to the technical field of perovskite solar cells, and provides a dibenzofuranyl carbazole derivative and a preparation method and application thereof.The dibenzofuranyl carbazole derivative takes dibenzofuranyl carbazole as a functional group, molecular ordered accumulation is optimized, and hole mobility is remarkably improved; an alkyl carbon chain is used as a linking group, a phosphate group at the tail end is an anchoring group, perovskite interface defects can be effectively passivated, the energy loss at the interface can be reduced, single molecule self-assembly can be realized, the cell performance can be improved, and as a self-assembly monomolecular layer hole transport material, a perovskite solar cell has relatively high photoelectric conversion efficiency, and the photoelectric conversion efficiency can be improved. The service life is long; and the stability is high.

The invention discloses a graphene antistatic PC composite material and a preparation method thereof, and belongs to the technical field of composite materials. 150-160 parts of polycarbonate resin, 10-20 parts of modified graphene, 2-5 parts of light stabilizer, 2-5 parts of ultraviolet absorber, and 2-5 parts of lubricant are weighed by weight and added to a high-speed mixer, and sent into a twin-screw extruder after mixing evenly, and after melt extrusion, cooled and pelletized to obtain a graphene antistatic PC composite material. The modified graphene contains graphene, quaternary ammonium salt structure and hindered phenol structure, and the modified graphene contains lipophilic benzene ring and long carbon chain, so the modified graphene has good compatibility with the polycarbonate resin containing benzene ring and other raw materials, and the modified graphene can be evenly dispersed in the composite material, and is not easy to agglomerate, so that the modified graphene can fully play a role, giving the composite material excellent antistatic, antibacterial and anti-aging properties.

IR-sensitive lithographic printing plate precursors provide a stable print-out image using a unique IR radiation-sensitive composition in an infrared radiation-sensitive image-recording layer. This IR radiation-sensitive composition includes: (1) a free radical initiator composition that comprises an electron-donating agent; (2) a free radically polymerizable composition; and (3) a color-changing compound that is represented by the Structure (I) having a conjugated carbon chain between the aromatic terminal groups. The compound also has a —SO2—R3 group wherein R3 represents alkyl, aryl or heteroaryl groups. After IR imaging, these precursors exhibit desirable printout images both fresh and after dark storage. The precursors can be developed off-press or on-press.

A type of additive based on a fluorinated carbamate prepolymer, a preparation method therefor, and a use thereof in the preparation of a medical fluorinated anticoagulant polyurethane material. The preparation method of the additive comprises: reacting a polyester / polyether diol, a diisocyanate and a fluorinated small-molecule diol, to obtain a carbamate prepolymer having an isocyanate end group, and then capping with a monohydric alcohol having a fluorinated carbon chain, to obtain an additive based on a fluorinated carbamate prepolymer. The additive has a high fluorine content. After being blended with a polyurethane masterbatch, fluorine atoms having low surface energy can be enriched on the surface of the material, and the fluorine atom content on the surface of the material can be as high as 60%. This effectively reduces the adhesion of plasma proteins, cells and platelets on the surface of the material, providing the medical polyurethane material with an excellent anticoagulant effect. In addition, it maintains the excellent mechanical properties of polyurethane, and is thus widely applicable in the preparation of medical fluorinated anticoagulant polyurethane materials.

The invention relates to the technical field of coatings, and particularly discloses a photocuring anti-fog coating. The photocuring anti-fog coating comprises the following raw materials in parts by weight: 8 parts of a monomer; 30 parts of light-cured resin; 60 parts of a solvent; 0.8 part of a photoinitiator; 0.03 part of an auxiliary agent; the light-cured resin is a comb polymer with a hydrophobic long carbon chain main chain, a hydrophilic functional group branch chain and double bonds. The anti-fog coating can be used for the surfaces of optical products such as car windows and glasses, and has the advantages of lasting anti-fog effect, rapid light curing and the like.

The invention discloses low-cost double-network fluorinated silicone rubber and a preparation method thereof, and relates to the technical field of fluorinated silicone rubber. The double-network fluorosilicone rubber comprises the following raw materials: vinyl silicone resin, vinyl fluorosilicone resin, hydrogen-containing fluorosilicone oil, a solubilizing monomer, a multifunctional acrylate monomer, a reinforcing filler, a structured control agent, a free radical thermal initiator, a platinum catalyst and an inhibitor. The double-network fluorosilicone rubber is formed by constructing a carbon-carbon chain network and a siloxane network, the tensile strength, toluene swelling resistance and ATF oil resistance at the high temperature of 150 DEG C of the fluorosilicone rubber are obviously improved, the preparation cost of the fluorosilicone rubber is reduced, and a favorable support is provided for widening the application field of the fluorosilicone rubber.

The invention discloses an acid liquid system based on synergistic interaction of a corrosion inhibitor and an iron stabilizer and a preparation method, and relates to the technical field of oilfield chemistry, the acid liquid system comprises the following components by mass: 10%-20% of an acid liquid, 0.5%-3% of a composite corrosion inhibitor, 0.5%-2% of an iron stabilizer, 0.1%-0.5% of a discharge aiding agent, 0.2%-0.8% of an acid thickening agent, and the balance of water; the main component of the composite corrosion inhibitor in the acid liquid system is long-chain alkyl bis-imidazoline-thiadiazole amide hydroxypropyl sulfobetaine, and the composite corrosion inhibitor contains a bis-imidazoline ring and a thiadiazole amide ring, and can form more stable multi-active-site adsorption on the metal surface to form a compact and stable protective film, so that the metal surface corrosion resistance is improved, and the metal surface corrosion resistance is improved. Long carbon chains in molecules can effectively block corrosive media, N, O and S heteroatoms in the molecules are adsorbed on the iron surface through lone pair electrons to inhibit corrosion, the slow-release effect is further enhanced, and therefore the slow-release efficiency is improved by 40% or above.

The present invention provides a method for preparing a bio-based fluorine-free water repellent for synthetic leather, which includes the following steps: 1) reacting a bio-based polyol with a special isocyanate to obtain a multi-functional end-capped intermediate; 2) subjecting the multi-functional end-capped intermediate to an ester exchange to obtain an outwardly extending bio-based long carbon chain end to obtain a bio-based fluorine-free water repellent. The present invention also creatively proposes a bio-based fluorine-free water repellent for synthetic leather, which is prepared by any of the above methods. The present invention selects bio-based raw materials and effectively regulates the functionality in the reaction process in the structure, designs the outwardly extending water-repellent chain segments, and makes the water repellent have good performance. The water repellent prepared by the present invention is fluorine-free and easier to degrade, low-carbon and environmentally friendly, and conforms to the concepts of green chemical industry and renewable.

The invention discloses an antistatic EVA foam material and a preparation method thereof, and belongs to the technical field of polymer composite materials. The preparation method comprises the following steps: weighing 90-100 parts of EVA, 15-25 parts of an ethylene-octylene copolymer, 10-18 parts of modified graphene, 2-4 parts of a foaming agent, 0.5-1 part of a lubricant, 0.5-1 part of zinc oxide and 0.1-0.5 part of a cross-linking agent, mixing in an internal mixer, mixing in an open mill, pressing the materials into sheets, finally putting the sheets into a preheated plate vulcanizing machine mold cavity, and carrying out mold pressing foaming to obtain the antistatic EVA foaming material. The modified graphene contains a lipophilic long carbon chain and a benzene ring, so that the modified graphene has good compatibility with the remaining raw materials, and the modified graphene containing the graphene, the hindered phenol structure and the quaternary ammonium salt structure can be highly dispersed in the EVA foaming material and fully plays a role, so that the EVA foaming material disclosed by the invention has efficient and lasting antistatic performance, antibacterial performance and anti-aging performance.

The invention discloses three-dimensional hydrophobic modified activated carbon, which is characterized in that hydrophobic carbon chains are grafted inside and outside activated carbon pores, and the hydrophobic carbon chains are trichlorosilane with different carbon chain lengths. The invention also discloses a preparation method of the three-dimensional hydrophobic modified activated carbon, and the preparation method comprises the following steps: (1) pretreatment: the activated carbon is firstly placed in distilled water for ultrasonic cleaning for 5-10 min, then soaked in a pretreatment activation solution for 5-10 min, and then placed in a drying oven for drying, and the pretreatment activation solution is an ammonia water solution with the pH value of 8-9; (2) three-dimensional modification: taking 5-10 parts by weight of a modifier, dropwise adding the modifier into 20-50 parts by weight of a solvent to obtain a modifier solution, soaking 10-15 parts by weight of pretreated activated carbon into the modifier solution, sealing the whole reaction system, and immediately soaking the reaction system in an ultrasonic environment for 2-4 hours; and (3) post-treatment: cleaning the impregnated activated carbon with a solvent, and carrying out vacuum drying in a vacuum drying oven at 100-150 DEG C for 5-12 hours to obtain the three-dimensional hydrophobic modified activated carbon.

The invention relates to the field of polyurethane film materials for batteries, and discloses a TPU composite material for a new energy battery and a preparation method of the TPU composite material. A TPU composite material for a new energy battery is composed of a cloth film layer, an adhesive film layer and a TPU film layer, the TPU film layer is prepared by melting and casting TPU hot melt adhesive, and the TPU hot melt adhesive is prepared from the following raw materials in parts by weight: 60-80 parts of polyurethane elastomer, 20-30 parts of a toughening aid, 15-25 parts of a flame retardant, 8-15 parts of a heat conducting agent, 2-4 parts of a lubricant and 1-3 parts of an antioxidant; the toughening auxiliary agent is prepared from a POE (Polyolefin Elastomer), long carbon chain alkyl glycidyl ether, dibutyl itaconate and a vinyl dimethyl terminated dimethyl-methyl trifluoropropyl polysiloxane copolymer. The TPU composite material disclosed by the invention is applied to a new energy battery, has relatively good buffering and damping effects and puncture resistance, and is good in flame retardance and thermal conductivity.

The invention discloses a polycarbonate / styrene composite material as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The composite material is prepared from the following raw materials: polycarbonate, silicon copolymerized polycarbonate, styrene resin, a halogen-free flame retardant, a polynitroxide free radical compound, an anti-dripping agent, an antioxidant and a lubricant. The molecular structure of the multi-nitroxide free radical compound contains at least two nitroxide free radicals, and the molecular chain of the multi-nitroxide free radical compound has a flexible carbon chain structure. The polycarbonate / styrene composite material provided by the invention can realize 0.5-1.0 mm ultrathin halogen-free flame retardance under the combined action of the halogen-free flame retardant and the multi-nitroxide free radical compound, and can meet the molding of ultrathin parts, and the prepared product has excellent damp-heat aging resistance and weather resistance, and is suitable for industrial production. The shell can be widely applied to new energy battery shells, power bank shells and the like.

The invention provides a long carbon chain polyamide resin composition as well as a preparation method and application thereof, and the long carbon chain polyamide resin composition comprises the following components in parts by weight: 35-70 parts of long carbon chain polyamide resin, 4-22 parts of reinforcing filler, 10-40 parts of ceramic forming filler and 2.5-22 parts of ablation filler, the ceramic forming filler comprises boron nitride and / or aluminum nitride. According to the present invention, the long carbon chain polyamide resin composition has advantages of good ablation resistance, good flame retardant property, good mechanical property, and easy extrusion processing.

The invention relates to the technical field of secondary batteries, in particular to a dry-method electrode binder, a preparation method of the dry-method electrode binder and an electrode slice, and the dry-method electrode binder comprises the following active ingredients in parts by weight: 0.1-20 parts of a functional nano carbon material; 1 to 40.0 parts of ethylenically unsaturated carboxylic acid; 1 to 50.0 parts of an unsaturated water-soluble monomer; 1 to 80.0 parts of an unsaturated oil soluble monomer; 0.1 to 20.0 parts of an emulsifier; 0.1 to 10.0 parts of an initiator; and 1 to 40.0 parts of a pH regulator. According to the dry-method electrode binder provided by the invention, the acrylic acid copolymer is grafted on the functionalized nano carbon material, so that the binder adopts an acrylic acid structure of a saturated carbon chain and is electrochemically stable in low potential of a negative electrode, and the problems that the potential of PTFE (Polytetrafluoroethylene) in the negative electrode is unstable, lithium in a battery is consumed, and the adhesion effect and the battery capacity are influenced are solved.

The invention relates to the technical field of biomass liquid fuels, in particular to a biomass liquid fuel and a preparation method thereof, and the biomass liquid fuel comprises the following components by weight: 40-60 parts of biomass-based methanol; 10 to 20 parts of biomass-based ethanol; 5 to 15 parts of biomass-based n-butyl alcohol; 5 to 10 parts of dimethyl ether; 10 to 20 parts of biodiesel; 1-5 parts of a lignin derivative; 0.1 to 0.5 part of an antioxidant; 0.1 to 0.5 part of a stabilizing agent; 0.5-2 parts of a purification dispersant; 1-3 parts of bio-based glycerol n-butyl ether; according to the invention, a plurality of alcohols (methanol, ethanol and n-butyl alcohol) are synergistically used, so that a series with the carbon chain length gradually increasing from C1 to C4 is formed. According to the design, the volatility and the energy density of the fuel are balanced, the oxygen content of the fuel is increased through hydroxyl (-OH) in alcohol molecules, and more complete combustion is promoted.

The invention provides a semi-aromatic polyamide material easy to process and form and a preparation method thereof. Comprising the following components in parts by weight: 40-78 parts of PA MXD6, 4-15 parts of long carbon chain nylon, 0.3-3 parts of polyethyleneimine, 20-60 parts of a reinforcing material, 0.2-5 parts of other auxiliaries and 0-50 parts of a filling material. The long carbon chain nylon with a specific length and the polyethyleneimine with a specific molecular weight are fully utilized to be matched, so that more shear sensitivity characteristics are obtained, and the problems of poor flowability of the aromatic ring nylon PA MXD6 material, lack of glue in thin-wall multi-cavity processing, tape casting, scorching, appearance fiber floating and the like are solved.

Disclosed in the present invention are a branched-chain-containing long-carbon-chain polyester elastomer based on biomass-based 2,5-furandicarboxylic acid, and a preparation method therefor. Monomers for preparing the polyester elastomer comprise 2,5-furandicarboxylic acid or 2,5-furandicarboxylic acid ester, a dihydric alcohol and a branched-chain-containing long-carbon-chain dibasic acid. The preparation method comprises: (1) performing a melting reaction on furandicarboxylic acid or an ester thereof, a branched-chain-containing long-carbon-chain dibasic acid and a dihydric alcohol to prepare an oligomer; and (2) performing melt polycondensation on the oligomer to synthesize a furandicarboxylic acid-based branched-chain-containing long-carbon-chain polyester elastomer. By means of the branched-chain-containing long-carbon-chain polyester elastomer of the present invention, the molecular structure can be effectively designed, and the molecular weight can be regulated, thereby optimizing mechanical properties, thermal properties, barrier properties, etc. The preparation process thereof is simple, convenient and safe, and the equipment requirements and catalysis cost are relatively low. The raw material 2,5-furandicarboxylic acid used in the present invention is a potential substitute for terephthalic acid, is derived from biomass, has a wide range of sources and is environmentally friendly.

The invention discloses polyurethane resin with a super-hydrophobic surface and a preparation method of the polyurethane resin, and belongs to the technical field of modified polyurethane materials. According to the invention, 2, 2 '-diallyl bisphenol A and a fluorine-containing thiol monomer react to introduce a fluorine-containing carbon chain, and then fluorinated modified 2, 2'-diallyl bisphenol A and tetramethoxysilane are used for treating nano zinc oxide, so that the content of active oxygen groups is reduced, a siloxane network structure is formed, the action with water molecules is reduced, and the hydrophobicity is improved. Secondly, the 2, 2 '-diallyl bisphenol A reacts with amino propyl isobutyl POSS to generate a benzoxazine structure, the POSS structure is introduced, the nano-size effect of the benzoxazine structure fills limited movement between molecular chains, a cage-shaped structure serves as a cross-linking point, the mechanical property is improved, and hydrophobicity is achieved. When polyurethane is prepared, 3, 3-bis (hydroxymethyl) azetidine and a benzoxazine structure are subjected to ring opening crosslinking, bonding, dispersity and stability of fluorinated modified nanoparticles and a matrix are enhanced, a complex network structure is formed, the surface roughness is increased, the water contact area is reduced, and super-hydrophobicity is achieved.