117 results about "Nonylphenol" patented technology

The invention provides an amphiphilic carbon dot, a carbon nanofluid and application of the amphiphilic carbon dot and the carbon nanofluid, and belongs to the technical field of nanomaterial oil displacement, and the amphiphilic carbon dot is prepared by taking alkylphenol polyoxyethylene ether and glucose as raw materials to perform solvothermal reaction; the alkylphenol polyoxyethylene ether comprises octylphenol polyoxyethylene ether and / or nonylphenol polyoxyethylene ether; the mass ratio of the alkylphenol polyoxyethylene ether to the glucose is 1: (0.1-2). According to the invention, alkylphenol polyoxyethylene ether and glucose are taken as raw materials, and simple preparation of the amphiphilic carbon dots with high surface and interface activity is realized. The amphiphilic carbon dots provided by the invention show good surface and interface activity at high temperature and high salinity. According to the carbon nanofluid provided by the invention, the amphiphilic carbon dots and the zwitterionic surfactant are compounded, so that the stability of a carbon nanofluid oil displacement system at high temperature and high salt can be further improved, the crude oil recovery rate is increased, and efficient yield-increasing development of high-temperature and high-salt deep oil reservoirs is realized.

The invention provides a composite synergistic system for a shale gas old well and an immovable string production increasing process. The composite synergistic system mainly comprises the following substances: 10-12% of a wetting improver; 4%-6% of a scale remover; 2%-3% of a scale inhibition dispersant; 5%-10% of a resistance-reducing discharge aiding agent; 15%-20% of a synergistic accelerant; the wetting improver is a mixture of alkyl polyglucoside, an anionic surfactant sodium dodecyl benzene sulfonate and deionized water, the content of the alkyl polyglucoside in the wetting improver is 5%-10%, and the content of the anionic surfactant sodium dodecyl benzene sulfonate is 15%-18%; the descaling agent is a mixture of sodium alpha-olefin sulfonate and nonylphenol polyoxyethylene ether ammonium sulfate, and the mass ratio of the sodium alpha-olefin sulfonate to the nonylphenol polyoxyethylene ether ammonium sulfate in the descaling agent is (2: 1)-(3: 1). According to the composite synergistic system, through combination and reuse of different materials and different doses, the multifunctional composite synergistic system integrating vibration, permeation and dispersion effects is researched and developed, and therefore immovable tubular column yield increase construction of a shale gas old well is achieved.

The invention belongs to the technical field of oilfield auxiliaries, and particularly relates to an oil-soluble demulsifier for a heavy oil field and a preparation method of the oil-soluble demulsifier. The oil-soluble demulsifier for the heavy oil field, provided by the invention, is prepared from a block polymer emulsion, nonylphenol polyoxyethylene ether, modified nanoparticles and a cross-linking agent. According to the invention, methoxystyrene, dodecyl vinyl ether, N, N-dimethylaminopropyl acrylamide and 2-acrylamide-2-methylpropanesulfonic acid are adopted to prepare a quaternary block comb-shaped polymer, the quaternary block comb-shaped polymer and nonylphenol polyoxyethylene ether are subjected to molecular-level cross-linking through a cross-linking agent, nano modified particles are added, and the quaternary block comb-shaped polymer is prepared. The prepared demulsifier can be rapidly adsorbed on an oil-water interface and respectively adsorb an oil phase and a water phase, so that the tension of the oil-water interface is reduced, rapid separation of the oil phase and the water phase is realized, and the demulsification performance is improved.

The application discloses a thickened oil viscosity reducer for a main viscosity contribution component of colloid and a preparation method thereof. The thickened oil viscosity reducer comprises the following components in percentage by weight: diethylene glycol methyl ether 25-35%, propylene glycol formate 15-25%, dispersant 5-8%, chelating agent 2-4%, anti-coking agent 0.5-1%, anti-swelling agent 1-2% and corrosion inhibitor 1-2%; and the balance is water. The application is a polar + non-aromatic hydrocarbon solvent system; completely avoids high-risk substances such as nonylphenol polyoxyethylene ether, petroleum sulfonate sodium and organic chlorine; is designed in pertinence and can effectively inhibit metal-induced asphaltene bridging; can withstand working conditions from normal temperature to 250 DEG C and up to 300 DEG C; thermal stability is significantly enhanced, and residual carbon after aging is lower than 8%; viscosity reduction efficiency is higher; the system is more stable, flexible in compounding and suitable for field construction.

The invention relates to a gemini surfactant for thickened oil recovery and a preparation method thereof, and belongs to the technical field of thickened oil recovery. The preparation method of the gemini surfactant for thickened oil recovery comprises the following steps: dissolving ethylene glycol dihydric alcohol and paratoluensulfonyl chloride in a tetrahydrofuran solvent, and carrying out substitution reaction under an alkaline condition to obtain an intermediate I; adding nonyl phenol and the intermediate I into a mixed solvent of tetrahydrofuran and N, N-dimethylformamide, and carrying out etherification reaction under an alkaline condition to obtain a gemini precursor II; and mixing an alkylphenol polyoxyethylene ether surfactant, the gemini precursor II and a formaldehyde aqueous solution, and carrying out a phenolic aldehyde condensation polymerization reaction under an acidic condition to obtain the gemini surfactant. The gemini surfactant prepared by the preparation method has good temperature resistance and salt tolerance, the preparation method is simple, the synthesis cost is low, and the gemini surfactant has good economical efficiency and is beneficial to realizing large-scale industrial production.

According to the all-organic nonlinear insulating material based on the electron-donating group and the preparation method, polyolefin is used as a matrix of the material, and an organic small molecule filler containing the electron-donating group is introduced to form a uniformly dispersed composite structure, so that the nonlinear conductivity of the material is remarkably improved. The small organic molecules can be ethylene glycol diphenyl ether, nonylphenol polyoxyethylene ether, allyloxy polyoxyethylene ether or octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, and the mass fraction of the filler is 0.1-3 wt%. The preparation method comprises the following steps: melting the polyolefin matrix at 110-120 DEG C, adding the small organic molecule filler, and blending for 10-30 minutes at the rotating speed of 50-70 r / min. The material has excellent electric field homogenization capability in a high electric field, avoids the problem of inorganic filler agglomeration, has relatively low filler content and excellent processability, can be widely applied to the field of high-voltage electrical equipment such as transformers, switch equipment and mutual inductors, and effectively improves the insulating property and prolongs the service life of the equipment.

The invention discloses a neutral organic chelating cleaning agent for a boiler, and belongs to the field of chemical cleaning of boiler superheaters of thermal power plants. The cleaning agent is prepared from the following components in percentage by weight: 0.5%-5% of ethylenediamine tetraacetic acid ammonium, 0.1%-4% of acetic acid or ammonium acetate, 0.1%-3% of glycollic acid ammonium or glycollic acid, 0.1%-5% of a pH regulator, 0.1%-1% of a cosolvent, 0.2%-0.8% of a corrosion inhibitor SH369, 0.1%-0.6% of a reducing agent, 0.0%-0.3% of a defoaming agent, 0.0%-0.2% of a surfactant and 84%-93% of water, wherein the pH value of the cleaning agent is 6-8; the cosolvent is tartaric acid and / or hydroxybutyl diacid, the surfactant is nonylphenol polyoxyethylene ether, and the reducing agent is hydrazine. The cleaning agent disclosed by the invention has good dissolving capacity on oxide skin, does not generate precipitates to cause pipe blockage, is a neutral solution, is very small in corrosivity, does not generate intergranular corrosion, is beneficial to protecting various pipes of superheaters and reheaters, and is a safe and efficient superheater cleaning agent.

The invention belongs to the technical field of tertiary oil recovery, and particularly relates to a temperature-resistant and salt-resistant thickened oil viscosity-reducing oil-displacing agent as well as a preparation method and application thereof. The preparation method comprises the following steps: adding nonyl phenol, DMF (Dimethyl Formamide) and epoxy halopropane into a reactor, stirring and dissolving, carrying out a heat preservation reaction, and carrying out reduced pressure distillation to obtain a viscous solid; adding isopropanol into the viscous solid for dissolving, adding 8-aminonaphthalene-1, 3, 6-trisulfonic acid disodium salt, heating and refluxing for reaction, and performing reduced pressure distillation to obtain a viscous solid; and adding distilled water, heating for dissolving, filtering, adjusting the pH value, separating out solid, standing, separating out supernate, centrifuging the lower-layer solid, concentrating, and drying to obtain the product, namely the viscosity-reducing oil-displacing agent for the thickened oil. The viscosity-reducing oil-displacing agent for the heavy oil has the characteristics of low surface and interface tension, low critical micelle concentration and good viscosity-reducing effect.

The invention discloses a pre-crosslinking surface active copolymerized nano-microsphere profile control agent for oil extraction and a preparation method thereof, and belongs to the technical field of profile control and water shutoff of oil fields. The nano-microsphere profile control agent is prepared from the following components in parts by weight: 50 to 60 parts of acrylamide, 10 to 15 parts of acrylic acid, 5 to 10 parts of methacryloyloxyethyl trimethyl ammonium chloride, 2 to 4 parts of an emulsifier, 0.5 to 1 part of nonylphenol polyoxyethylene ether, 8 to 12 parts of coal-based Fischer-Tropsch liquid wax, 2 to 4 parts of 2-acrylamido-2-methylpropanesulfonic acid, 0.1 to 0.3 part of a cross-linking agent and 0.05 to 0.1 part of an initiator. The emulsifier is prepared by reacting pentaerythritol with linoleic acid to generate a tetraester compound, then generating an epoxy compound under the action of formic acid and H2O2, and then reacting with laurinol. The prepared copolymerized nano-microsphere profile control agent is relatively small in particle size and can enter the deep part of a stratum, and the microsphere solution can realize step-by-step plugging due to mild expansibility.

The invention belongs to the technical field of oilfield chemistry, and particularly relates to a viscosity-reducing paraffin inhibitor for oilfield oil well production and a preparation method of the viscosity-reducing paraffin inhibitor. Comprising the following components in percentage by mass: 15.08%-17.92% of maleic anhydride, 18.01%-26.88% of nonylphenol polyoxyethylene ether, 23.2%-25.4% of a benzylamine solution, 3.97%-5.0% of a 5% ferrous sulfate aqueous solution, 3.97%-5.00% of a 5% ammonium persulfate aqueous solution and 15.87%-17.19% of a sodium hydroxide aqueous solution. The viscosity-reducing paraffin inhibitor solves the problems that the density and viscosity of crude oil are increased in the later stage of development of most oil wells in oil fields, paraffin precipitation is serious, the repair-free period is short, and the effect of the existing paraffin inhibitor becomes poor year by year, prolongs the repair-free period of the oil wells, can effectively relieve frequent well repair caused by paraffin precipitation in production of the oil wells in the oil fields, does not contain chlorine, and is environment-friendly. The paraffin control and viscosity reduction effects are considered, and meanwhile, the influence on downstream refining equipment is avoided.

The invention discloses epichlorohydrin and a preparation method thereof. Comprising the following steps: feeding a mixed solution containing chloropropene, hydrogen peroxide and a nonionic surfactant and a titanium silicalite molecular sieve TS-1 catalyst in a fixed bed reactor at a mass space velocity of 0.5-10h <-1 >, and reacting at 20-90 DEG C to obtain the epichlorohydrin. The dosage of the catalyst is 0.1-10 wt% of the chloropropene; the nonionic surfactant is selected from at least one of alkyl glucoside, fatty glyceride, fatty acid sorbitan, polysorbate, polyoxyethylene fatty alcohol ether and nonylphenol polyoxyethylene ether; the molar ratio of the hydrogen peroxide to the nonionic surfactant is (1-50): 1; the molar ratio of chloropropene to hydrogen peroxide is (1-10): 1. The nonionic surfactant is added to promote mixing of the organic phase and the water phase, a large amount of solvent does not need to be added in a traditional process, and a large amount of energy consumption such as solvent evaporation and recovery is avoided; the conversion rate of hydrogen peroxide is greater than 95%, and the selectivity of epoxy chloropropane is 95-99%.

The application belongs to the technical field of tertiary oil recovery, and relates to a heavy oil viscosity reducer and a preparation method and application thereof.The preparation method is as follows: p-nonyl phenol, 1-(4-fluorophenyl)piperazine, 40wt% formaldehyde and water are added into a reactor, stirring is carried out, temperature is increased to reflux, and temperature is kept;temperature is reduced to below 40 DEG C, extraction is carried out, the obtained product is placed in a high-pressure reactor, sodium hydroxide solid is added, nitrogen is introduced, vacuum is drawn, temperature is increased, vacuum drawing is stopped, ethylene oxide is slowly introduced, temperature is increased, and temperature is kept;viscous liquid is obtained through reduced pressure distillation, the obtained product is placed in a high-pressure reactor, pH is adjusted to 3-4, aminosulfonic acid powder is added, stirring and heating are carried out, temperature is kept, and the obtained product is cooled to below 40 DEG C;ethanolamine is added, pH is adjusted to 7-8, and the heavy oil viscosity reducer is obtained.The viscosity reducer has the advantages of low surface tension, low interfacial tension, low critical micelle concentration and good viscosity reduction effect.

A nonwoven, a method for making such a nonwoven, and the use of waste carbon to make such a nonwoven. The nonwoven has a total carbon content (TCC) from which 10% to 100% of the TCC of the nonwoven are derived from waste carbon. The nonwoven meets one or more of the criteria a) to e) by comprising less thana) 5000 μg / kg of iso-Nonylphenolhexaethoxylate;b) 500 μg / kg of iso-Nonylphenol;c) 4.0 ng / kg of Octachlorodibenzodioxin;d) 500 μg / kg of Di-2-ethylhexyl phthalate; and / ore) 25 μg / kg of Napthalene.

The application discloses an aluminum alloy cleaning agent and a preparation method and application thereof, and belongs to the technical field of cleaning agents. The aluminum alloy cleaning agent comprises the following raw materials in parts by weight: 7-12 parts of ionic surfactant A, 3.5-6 parts of non-ionic surfactant B, 0.2-3 parts of a dispersing solubilizing agent, 0.8-1.5 parts of a penetrating agent, 3-6 parts of a chelating agent, 0.2-2 parts of an inhibitor, 0.01-0.05 parts of a defoaming agent and 67-83 parts of deionized water. The non-ionic surfactant A comprises at least one of a fatty alcohol polyoxyethylene ether and a nonylphenol polyoxyethylene ether. The non-ionic surfactant B comprises a sorbitan fatty acid ester. The dispersing solubilizing agent comprises a polyhydric alcohol. The aluminum alloy cleaning agent can effectively improve cleaning power, avoid aluminum alloy tarnishing, and is environmentally friendly. The application further provides a preparation method and application of the aluminum alloy cleaning agent.

The application discloses a marine-derived cholesterol oxidase and a preparation method and application thereof, and relates to the technical field of biology. The amino acid sequence of the marine-derived cholesterol oxidase (SkChOx) is shown in SEQ ID NO. 1 or 3, the specific enzyme activity of the marine-derived cholesterol oxidase can reach 31.9 U / mg, the marine-derived cholesterol oxidase has excellent anti-reverse performance, maintains high stability in the pH range of 5.0-10.0, has good temperature tolerance, organic solvent tolerance and metal ion tolerance, and exhibits unique salt activation effect and salt tolerance. The enzyme is compounded with dithiothreitol (DTT) and nonylphenol polyoxyethylene ether (NP-40) to form a liquid enzyme preparation, and after incubation at 37 DEG C for 7 days under accelerated conditions, the catalytic activity of the liquid enzyme preparation still remains about 87%, the liquid enzyme preparation has excellent long-acting storage stability, and has wide application prospects in the fields of clinical diagnosis, food physical and chemical inspection, biosensor development and industrial preparation of steroid drugs.

This invention provides an environmentally friendly, high-performance waterborne acrylic pressure-sensitive adhesive and its preparation method. The raw materials, by weight, include: 75-105 parts monomer, 1-5 parts functional monomer, 0.3-0.8 parts initiator, 0.05-0.2 parts buffer, 0.01-0.1 parts molecular weight regulator, 0.3-3 parts emulsifier, 0.05-0.5 parts defoamer, 0.05-0.2 parts pH adjuster, and 80-100 parts deionized water. The prepared pressure-sensitive adhesive is nonylphenol-free and meets RoHS and REACH standards. It exhibits high bonding strength and transparency, and can be used to prepare various transparent, printed, and colored BOPP packaging tapes, various double-sided tapes, and various labels.

This invention belongs to the field of packaging and printing materials, specifically relating to a high-temperature resistant water-based micro-crosslinked transfer coating. The raw materials for this high-temperature resistant water-based micro-crosslinked transfer coating consist of the following components: methacrylic acid, N-hydroxymethylacrylamide, butyl acrylate, methyl methacrylate, diallyl phthalate, 1,6-hexanediol diacrylate, tricyclodecanedimethylol diacrylate, trimethylolpropane triacrylate, di(trimethylolpropane)tetraacrylate, potassium persulfate, sodium bicarbonate, alkylphenol polyoxyethylene ether ammonium sulfate, nonylphenol polyoxyethylene ether, deionized water, ethanol, ammonia, wetting agent, defoamer, and film-forming agent. Its beneficial effects include a stable reaction process during the preparation of this high-temperature resistant water-based micro-crosslinked transfer coating, reducing the likelihood of slag formation or explosive polymerization; high gloss in the coating film; good adhesion to vacuum metallization; minimal fogging or whitening; high-temperature molding resistance up to 180℃; and easy peeling of PET film with a high yield.

The application relates to a grinding aid and a preparation method and application thereof, the grinding aid comprising a to-be-treated solution and a surfactant; the to-be-treated solution contains sodium acrylate, sodium hydroxide and sodium p-toluenesulfonate; and the surfactant comprises at least one of sodium dodecyl benzene sulfonate, sodium lignosulfonate, allyl polyether, fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether and nonyl phenol polyoxyethylene ether. The specific surfactant in the grinding aid cooperates with the to-be-treated solution, synergistically improves the interface wetting performance of the material, weakens the powder aggregation phenomenon, reduces the surface energy, and further improves the dispersibility of the material and the gradation and fluidity of the material.

The application relates to the field of immunohistochemical staining, in particular to a DAB buffer and a DAB staining solution kit for DAB color development. The application discloses a DAB buffer for DAB color development, and the main components are hydrogen peroxide, nonylphenol polyoxyethylene ether, magnesium sulfate and trisodium citrate. The metal ions in the DAB buffer can enhance the electron transfer speed between DAB and hydrogen peroxide, and improve the color development sensitivity. The nonylphenol polyoxyethylene ether can stabilize the hydrogen peroxide, so that the hydrogen peroxide can be stored for a longer time and the cost is saved. The application further discloses a DAB staining solution kit, which comprises a blocking agent, a reaction enhancer, an enzyme-labeled polymer IgG, a DAB concentrated solution, a DAB buffer and hematoxylin, and the above-mentioned DAB buffer for DAB color development. The DAB staining solution kit of the application can improve the detection sensitivity of immunohistochemical staining, and can also improve the storage stability of the DAB color development solution and reduce the cost.

The invention discloses modified impact-resistant ACR for polyvinyl chloride and a preparation method of the modified impact-resistant ACR, and relates to the field of impact-resistant modifiers. The modified impact-resistant ACR is prepared from the following raw materials: methyl methacrylate, butyl acrylate, 2-ethylhexyl acrylate, glycidyl methacrylate, acrylamide, divinyl benzene, maleic anhydride grafted nitrile rubber, methacrylic acid, an initiator, an emulsifier and a catalyst; the maleic anhydride grafted nitrile rubber is obtained by graft polymerization of maleic anhydride and nitrile rubber; the emulsifier is obtained by mixing lauryl sodium sulfate and nonylphenol polyoxyethylene ether. The preparation method of the modified impact-resistant ACR comprises the following steps: preparing maleic anhydride grafted nitrile rubber, preparing a pre-emulsion, carrying out emulsion polymerization, and preparing the modified impact-resistant ACR. The modified impact-resistant ACR prepared by the invention can effectively enhance the low-temperature notch impact strength and ultraviolet aging resistance of polyvinyl chloride.

The present invention relates to systems and methods for catalytic removal of oxidized contaminants (for example, nitrite, chromate, chlorate, trichloroethene, CFC-11, 4-nonylphenol, RDX, and perfluorooctanoate) from water and wastewater. In some aspects, the catalytic method of removing oxidized contaminants comprises using precious metal nanoparticles as catalysts to reduce the oxidized contaminants.

The invention provides a silicon nitride green body and a preparation method and application thereof.The silicon nitride green body comprises silicon nitride powder, a penetrating agent and a wetting agent, the penetrating agent comprises at least one of fatty alcohol-polyoxyethylene ether and nonylphenol polyoxyethylene ether, the wetting agent comprises at least one of glyceryl trioleate, glyceryl monooleate and polyoxyethylene ester, and the silicon nitride green body comprises silicon nitride powder, silicon nitride powder and silicon nitride powder. The total mass of the wetting agent and the penetrating agent is greater than or equal to 1% of the mass of the silicon nitride powder. Due to the special composition of the silicon nitride green body, the problems of warping, wrinkling and cracking can be effectively reduced while the high solid content is maintained.

The invention relates to the technical field of diamond functional structures and preparation, and discloses a preparation method and application of an oxygen-terminated hydrophobic nano-strip diamond film, and the preparation method comprises the following steps: step 1, grinding a silicon, molybdenum or titanium substrate with nano-diamond powder for 15-30 minutes, and placing the substrate in nano-diamond turbid liquid for ultrasonic treatment for 30 minutes; and 2, taking out the substrate slice, placing the substrate slice in a reaction chamber of a chemical vapor deposition (CVD) device, and taking hydrogen, methane and hydrogen carrying trimethyl borate as raw materials. According to the preparation method of the oxygen terminal hydrophobic nano-strip diamond film, coating films such as a copper film and a gold film are not needed, and the oxygen terminal hydrophobic diamond film can be obtained only by etching a non-diamond phase under the condition that diamond and non-diamond coexist; the oxygen terminal hydrophobic diamond film is used as a hydrophobic electrode of an electrochemical sensor, is applied to electrochemical detection of an endocrine disrupter-nonyl phenol, and has the advantages of lower cost, very good sensitivity and wide application prospect.

The present application relates to a kind of waste phosphoric acid tributylamine / kerosene pyrolysis incineration emulsification method, comprising: phosphorus solid agent, emulsifier, water are mixed uniformly to obtain lime milk, then TBP / OK waste liquid is added into lime milk and mixed uniformly, to obtain TBP / OK emulsified suspension;Wherein emulsifier is nonylphenol polyoxyethylene ether.Compared with prior art, the present application improves the processing efficiency of waste organic phase, reduces the input of time cost and labor cost, has greater economic benefit and environmental benefit.

The application discloses a kind of core-shell composite materials, electrochemical sensor and its preparation method and application, the core-shell composite materials include inner core and the shell layer of the inner core is wrapped, the inner core is metal organic framework PCN-222;The preparation method of the core-shell composite material includes: metal organic framework PCN-222 is dispersed in first solvent, and dispersion liquid A is obtained;Functional monomer, template molecule, crosslinking agent and initiator are added to dispersion liquid A, and polymerization reaction is carried out, and reaction product is obtained;Template molecule of the reaction product is removed using second solvent, and the core-shell composite material is obtained.The electrochemical sensor includes working electrode, and the surface of the working electrode is attached with the core-shell composite material, it has excellent conductivity and specific recognition site, and is applied to detect 4-nonyl phenol in environment, and shows high sensitivity and selectivity.

The invention discloses a high performance liquid chromatography detection method for ethinylestradiol and nonyl phenol in soil. The method comprises the steps of S1, sample pretreatment, S2, sample extraction, S3, solid phase extraction and purification, S4, high performance liquid chromatography detection and S5, quantitative analysis. The detection method overcomes the defects of a method for synchronously and quantitatively detecting two typical endocrine disruptors in different types of farmland soil in the prior art by aiming at the industrial technical pain points of complex soil matrix, large polarity difference between ethinylestradiol and nonyl phenol and high trace enrichment difficulty; and a stable and reliable technical support is provided for pollution characteristic research, environment fate analysis and ecological risk assessment of ethinylestradiol and nonyl phenol in soil.

This application provides a preparation process for an ultra-high water-reducing polycarboxylate superplasticizer, belonging to the field of concrete admixture technology. An ultra-high water-reducing polycarboxylate superplasticizer comprises the following components: a polyether macromonomer, an unsaturated carboxylic acid, a hyperbranched wetting-anti-mud functional monomer, a pH-responsive slow-release crosslinking monomer, an oxidant, a reducing agent, a chain transfer agent, and deionized water. This application achieves anti-mud function through the coordination complexation of the phosphate ester groups of WSP-1 with clay, and the nonylphenol chain improves the wettability of manufactured sand; SREM-2 achieves long-term slump retention through the gradient release of dicarboxyl groups under alkaline conditions, realizing a synergistic effect of front-end anti-mud wetting, mid-stage strong anchoring, and rear-stage slow-release compensation relay.

The invention discloses a synthesis method of polyether polyol, and belongs to the technical field of chemical synthesis of fine chemicals. The method comprises the following steps: mixing 4-n-hexylresorcinol and a small molecular alcohol compound, adding an inorganic base catalyst for reaction, and then carrying out reduced pressure distillation treatment; adding a mixture of epoxypropane and ethylene oxide into the system for reaction; after the reaction is finished, introducing epoxypropane for reaction, and then introducing ethylene oxide for reaction; and after the reaction is finished, adding acid to adjust the pH value, and then carrying out filtration and reduced pressure distillation treatment to obtain the polyether polyol. The synthesis of the 4-n-hexylresorcinol-based special polyether polyol is realized under mild conditions, the viscosity, the hydroxyl value, the average molecular weight and the HLB value of the 4-n-hexylresorcinol-based special polyether polyol can be regulated and controlled, the 4-n-hexylresorcinol-based special polyether polyol can be used instead of environmental hormone chemical substances such as nonyl phenol and octylphenol polyoxyethylene ether, and the 4-n-hexylresorcinol-based special polyether polyol has remarkable environmental protection and application values.

The invention discloses fipronil missible oil and a preparation method thereof. Relates to the technical field of pesticide preparations. Comprising the following steps: stirring odorless kerosene and tributyl phosphate; adding nonylphenol polyoxyethylene ether, and stirring; adding dodecylbenzene sulfonic acid calcium salt, and stirring; adding polyoxyethylene nonylphenol phosphate, and stirring; and finally, adding fipronil, and continuously stirring to obtain the fipronil missible oil. The finished product is low in odor, clear, stable and good in water dilution and emulsification; through sand-based bioassay, under the same soil target concentration (g / g), the LC50 of the missible oil for 12 hours and 24 hours is obviously lower than that of the missible oil sold in the market, and the missible oil has a better lethal effect.

The invention discloses redispersible graphene powder, a preparation method and application of the redispersible graphene powder in anticorrosive paint, and belongs to the technical field of nano material dispersion and anticorrosive paint modification. The modified graphene powder comprises the following raw materials: 40%-90% of a solvent, 8%-50% of a modifier and 0.5%-10% of graphene powder; the modifier is one of fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, polysorbate and isomeric alcohol polyoxyethylene ether. According to the preparation method, specific nonionic surfactant modification and drying processes are carried out on graphene, so that the functionalized powder which can be directly added into a coating matrix is obtained. The graphene powder greatly reduces the packaging and transportation cost, keeps the excellent redispersibility of graphene after long-term storage (6 months), and can be used for preparing water-based and oil-based anticorrosive coatings. The invention provides a ready-to-use and high-durability anti-corrosion solution for harsh corrosion environments such as ocean engineering equipment, oil and gas field equipment pipelines, chemical equipment and the like.