The invention discloses a synthesis method of polyether
polyol, and belongs to the technical field of
chemical synthesis of fine chemicals. The method comprises the following steps: mixing 4-n-
hexylresorcinol and a small molecular
alcohol compound, adding an inorganic base catalyst for reaction, and then carrying out reduced pressure
distillation treatment; adding a mixture of epoxypropane and
ethylene oxide into the
system for reaction; after the reaction is finished, introducing epoxypropane for reaction, and then introducing
ethylene oxide for reaction; and after the reaction is finished, adding acid to adjust the pH value, and then carrying out
filtration and reduced pressure
distillation treatment to obtain the polyether
polyol. The synthesis of the 4-n-
hexylresorcinol-based special polyether
polyol is realized under mild conditions, the
viscosity, the
hydroxyl value, the average molecular weight and the HLB value of the 4-n-
hexylresorcinol-based special polyether polyol can be regulated and controlled, the 4-n-hexylresorcinol-based special polyether polyol can be used instead of environmental
hormone chemical substances such as nonyl
phenol and octylphenol
polyoxyethylene ether, and the 4-n-hexylresorcinol-based special polyether polyol has remarkable
environmental protection and application values.