2324 results about "Bisphenol A" patented technology

The invention relates to the field of electric heating materials, and provides a graphene-based heating coating and a preparation method thereof. The coating is prepared from functionalized graphene, a surface modified bismuth telluride nanobelt, polyaniline, bisphenol A epoxy acrylate, polyurethane acrylate, a dispersing agent, a flatting agent, a silane coupling agent, a defoaming agent and a propylene glycol methyl ether acetate / N-methyl pyrrolidone mixed solvent. The functionalized graphene is obtained by modifying a hyperbranched polyolefin-acryloyl-POSS copolymer, and carrying out ultrasonic stripping, centrifugal separation, gradient washing and vacuum drying; the surface-modified bismuth telluride nanobelt is modified by an amino silane coupling agent, so that the interfacial compatibility is improved. The preparation method comprises the steps of solvent premixing, nanofiller dispersion, ultrasonic homogenization, coupling agent modification, ultraviolet curing and thermocuring. The heating coating provided by the invention has high conductivity, excellent thermal stability and adhesive force, and can be widely applied to heating electric appliances and intelligent temperature control equipment.

The invention discloses a toughened epoxy resin and a curing method thereof, and relates to the technical field of epoxy resins, the toughened epoxy resin comprises the following components: 100 parts of an epoxy resin matrix, specifically a mixture of bisphenol A epoxy resin and alicyclic epoxy resin, 5-35 parts of a composite amine curing agent, and 5-20 parts of a nano toughening agent, in particular to core-shell rubber particles grafted with epoxy groups on the surfaces, the core layer of each core-shell rubber particle is cross-linked polybutadiene, the shell layer of each core-shell rubber particle is polymethyl methacrylate, 0.5-3 parts of an accelerant comprising a bi-component synergistic accelerant, 1-5 parts of an interface enhancer, and a mixture of gamma-glycidyl ether oxypropyl trimethoxy silane and a titanate coupling agent, a bisphenol A type epoxy resin and a specific proportion of alicyclic epoxy resin are combined to construct an epoxy resin matrix according to a mass ratio of 2: 1, the epoxy resin matrix is matched with a composite amine curing agent prepared by carrying out a special three-step reaction on long-chain polyether diamine, aromatic diamine and anhydride, and key parameters such as molecular weight, functionality and molar ratio of the components are accurately regulated and controlled.

The invention discloses a high-temperature-resistant epoxy insulating material for a transformer and a preparation method thereof, and belongs to the technical field of insulating materials. The high-temperature-resistant epoxy insulating material for the transformer is prepared from the following components in parts by weight: 50 to 60 parts of bisphenol A epoxy resin, 20 to 50 parts of anhydride curing agent, 10 to 20 parts of modified composite filler and 5 to 10 parts of epoxidized hydroxyl-terminated liquid polybutadiene, wherein the modified composite filler is a mixture of first boron nitride, second boron nitride and silicon nitride grafted with a silane coupling agent and dopamine, and the mass ratio of the first boron nitride to the second boron nitride to the silicon nitride is (1-2): (2-4): 1. The high-temperature-resistant epoxy insulating material for the transformer has excellent mechanical property, insulating property, heat-conducting property and high-temperature aging resistance.

The invention relates to a photo-thermal super-hydrophobic multifunctional anti-icing coating as well as a preparation method and application thereof. The photo-thermal super-hydrophobic multifunctional anti-icing coating comprises primer and finish paint, the primer comprises the following raw materials in parts by weight: 20-25 parts of bisphenol A type epoxy resin and / or fluorine modified epoxy resin, 10-20 parts of fluorine modified polyacrylic resin and / or polyurethane resin, 5-10 parts of a curing agent and 40-55 parts of a solvent; the finish paint comprises the following components in parts by weight: 2-5 parts of polytetrafluoroethylene, 1-3 parts of soluble polytetrafluoroethylene, 1-5 parts of polydimethylsiloxane and 85-90 parts of fluorinated MOF dispersion liquid. Compared with the prior art, the photo-thermal super-hydrophobic multifunctional anti-icing coating provided by the invention has the characteristics of super-hydrophobicity, rapid ice melting, wear resistance, reduction of ice adhesion strength and reduction of icing amount, can effectively solve the problem of icing of an aluminum conductor of a power transmission line of a power system, and can be applied to power equipment such as the aluminum conductor of the power transmission line.

The invention provides a low-warpage underfill adhesive for FC-BGA packaging, a preparation method thereof and a flip chip. The underfill adhesive comprises the following components in percentage by mass: 50%-60% of silicon dioxide, 24%-29% of epoxy resin, 16%-20% of a curing agent, 0.1%-0.2% of carbon black and 0.1%-0.2% of an accelerant. Wherein the epoxy resin is composed of high-purity bisphenol A epoxy resin, polyurethane modified epoxy resin and phenolic aldehyde modified epoxy resin. By adjusting the proportion of the high-purity bisphenol A epoxy resin, the polyurethane modified epoxy resin and the phenolic aldehyde modified epoxy resin and combining the curing agent and the accelerant, the stress of the underfill adhesive is integrally reduced, and the underfill adhesive with good fluidity and low warpage is obtained; therefore, the packaging yield and the packaging efficiency of chip packaging are improved.

The invention relates to the technical field of biodegradable materials, and discloses a full-biodegradable bamboo fiber film material and a preparation method thereof, the full-biodegradable bamboo fiber film material comprises the following raw materials by weight: 30-50 parts of modified bamboo fiber, 20-40 parts of a biodegradable polymer, 3-8 parts of a plasticizer, and 1-5 parts of a cross-linking agent. Acrylic acid grafted hydroxyethyl methylacrylate is grafted to epoxy resin containing azobenzene side chains to form a grafting product of a latticed structure, and the grafting product and hydroxyl groups on bamboo fibers form ether bonds to modify the bamboo fibers. The latticed structure can effectively improve the mechanical property of the film, and azobenzene is grafted to the side chain of bisphenol A epoxy resin, so that the epoxy resin has better degradability.

The invention discloses an application of an electronic waste pollution human body exposure fingerprint spectrum in exposure risk prediction, and the human body exposure fingerprint spectrum is composed of more than three of exposure markers of 2, 4, 6-tribromophenol, 2, 4, 5-trichlorophenol, 4-bromophenol, 1-hydroxypyrene and bisphenol A. The invention further discloses an application of the electronic waste pollution human body exposure fingerprint spectrum in exposure risk prediction. According to the method, a systematic method of urine pollutant exposure omics is adopted for the first time, comprehensive screening and characterization of pollutant exposure markers related to specific components and by-products are achieved in electronic waste exposure worker groups, and the method is the most systematic organic pollutant exposure research known in the field at present.

The invention provides an aerogel-based heat-preservation, heat-insulation and waterproof composite coating material for a building outer wall and a preparation method thereof, and belongs to the field of building materials. Through hydrophobic modified silicon dioxide aerogel, a lightweight heat insulation frame is provided, and the waterproofness and compatibility are improved; the mechanical property and the crack resistance are enhanced through the modified potassium titanate nanofibers, and self-adaptive heat insulation is achieved; the thermoelectric effect, the wear resistance and the thermal regulation performance are optimized through plasma treatment and polyaniline coated tungsten carbide nanoparticles; the heat management performance, the crack resistance and the comprehensive heat insulation and waterproof capacity are improved through graphene oxide composite modified boron nitride; the flexibility, the hydrophobicity and the interfacial compatibility are improved through organic silicon modified bisphenol A epoxy resin; and the performance of the coating is optimized through the synergistic effect of the components.

The invention relates to the technical field of new materials, and mainly relates to a double-component low-viscosity ultralow-temperature adhesive as well as a preparation method and a use method thereof. The double-component low-viscosity ultralow-temperature adhesive comprises a component A and a component B. The component A comprises the following components in percentage by mass: 20-40% of bisphenol A epoxy resin, 4-8% of aromatic epoxy resin, 6-10% of polyurethane modified epoxy resin, 1-2% of a rubber toughening agent, 5-20% of a diluent and the balance of an additive. And the component B comprises the following components in percentage by mass: 10-40% of a polyether amine curing agent, 10-40% of a fatty amine curing agent, 10-40% of an aromatic amine curing agent and 10-40% of a phenolic aldehyde amine curing agent. The adhesive provided by the invention has relatively strong compressive strength and excellent toughness, can keep good toughness in a low-temperature environment, is not easy to cause brittle rupture, can bear relatively large mechanical load, and is suitable for various industrial applications.

The invention discloses a graphene nanometer heavy anti-corrosion coating and a preparation method thereof, and belongs to the technical field of anti-corrosion coatings. The coating is prepared from the following components in parts by mass: 50 to 70 parts of diallyl bisphenol A type epoxy resin, 8 to 15 parts of histidine modifier, 12 to 20 parts of graphene nano composite modified filler, 5 to 10 parts of curing agent, 0.5 to 2 parts of flatting agent and 0.3 to 1 part of defoaming agent. The preparation method of the histidine modifier comprises the following steps: carrying out a Schiff base reaction on 1-palmitoyl-2-oleoyl ethanolamine and N-formyl-L-histidine to generate an intermediate A; reacting with a spiro quaternization reagent to form a quaternary ammonium salt intermediate B; and then compounding with aminopropyltriethoxysilane and silicotungstic heteropoly acid salt to obtain the product. The graphene nano-composite modified filler is prepared by modifying the surface of a graphene oxide / bentonite mutual intercalation layer structure through allyl trimethoxy silane. The graphene nano heavy anti-corrosion coating prepared by the invention forms a high-density cross-linked network, and has excellent barrier property, strong adhesive force, impact resistance and long-acting anti-corrosion performance.

The invention discloses a glue solution for a copper-clad plate and a preparation method of the glue solution, and relates to the technical field of copper-clad plates. According to the prepared glue solution for the copper-clad plate, the composite epoxy resin, the curing agent, the accelerant, the solvent, the flexibilizer and the inorganic filler, the composite epoxy resin comprises bisphenol A epoxy resin, epoxy phenyl polysiloxane, itaconic acid polyaryletherketone and hydroxyl-terminated fluorine-containing vinyl polysiloxane, so that the interface bonding force with the copper plate is enhanced; the dielectric constant and the dielectric loss are effectively reduced, the peel strength and the toughness of the material are also remarkably improved, and the toughening agent is modified polyether sulfone microspheres; the modified polyethersulfone microspheres are prepared by coating polyethersulfone microspheres with hexamethylenediamine tetrapropionamide diamine, the hexamethylenediamine tetrapropionamide diamine is prepared by carrying out acylation condensation reaction on hexamethylenediamine tetramethyl propionate and ethylenediamine, and the polyethersulfone microspheres are prepared by carrying out electrostatic spinning on a spinning solution of polyethersulfone and vinylpyridine, so that the peel strength of the glue solution is remarkably improved.

The invention discloses a water-borne epoxy resin coating which comprises a component A and a component B, the component A is prepared from 60 to 80 parts of 50 percent modified water-borne epoxy resin emulsion, 5 to 15 parts of deionized water, 0.5 to 1 part of wetting dispersant, 0.2 to 0.8 part of defoaming agent, 5 to 10 parts of modified zinc phosphate, 3 to 5 parts of ion exchange antirust pigment, 4 to 6 parts of sericite powder, 3 to 5 parts of glass flake, 5 to 10 parts of precipitated barium sulphate, 1 to 5 parts of nano silicon dioxide and 0.5 to 1 part of rheological additive; 1 to 2 parts of modified organic bentonite slurry; 0.1 to 0.3 part of a pH conditioning agent; and 0.2 to 0.8 part of a flash rust inhibitor. The component B is prepared from 40 to 50 parts of waterborne epoxy-amine adduct, 20 to 30 parts of 50 percent modified polyamide curing agent, 5 to 15 parts of 60 percent Mannich base phenolic aldehyde amine curing agent, 0.5 to 1.5 parts of epoxy silane coupling agent, 1 to 2 parts of nonionic surfactant and 15 to 20 parts of deionized water. The emulsion stability of the waterborne epoxy resin coating is improved through a bisphenol A / F mixed epoxy emulsion and a grafted polyethylene glycol hydrophilic chain segment.

The invention relates to the technical field of optical protective materials, in particular to an anti-dazzle full-ultraviolet-proof optical protective material and a preparation method thereof.The anti-dazzle full-ultraviolet-proof optical protective material is formed by sequentially compounding a scratch-resistant hardened layer, a PET film layer a, a composite adhesive layer, a PET film layer b, an installation adhesive layer and a PET release film layer from top to bottom; the preparation method comprises the following steps: mixing organic silicon modified polyurethane acrylate, a pigment, a reactive diluent, a flatting agent, a photoinitiator, a solvent and modified nano silicon dioxide to prepare a photocurable scratch-resistant hardening coating liquid; in order to endow the optical material with excellent infrared barrier property and heat insulation property, cesium tungsten bronze is introduced into a composite adhesive layer as a filler, and in order to improve the adhesive power and water resistance of a composite adhesive solution, epoxy resin is taken as a base material, organic silicon modified polyurethane acrylate is introduced as a water-resistant component, acrylic acid is taken as tackifying resin, and a curing agent is taken as a curing agent. And bisphenol A ethoxylate dimethacrylate is used as a diluent.

The invention provides a high-reliability single-component bottom filling adhesive, a preparation method thereof and a flip chip. The bottom filling adhesive comprises the following components in percentage by mass: 50%-60% of spherical silicon dioxide, 28%-32% of epoxy resin, 13%-17% of a modified polyether amine curing agent, 0.1%-0.2% of carbon black, 0.3%-0.5% of a silane coupling agent and 0.2%-0.4% of an adhesion promoter. The epoxy resin is composed of bisphenol A epoxy resin and first epoxy resin, and the model of the first epoxy resin is NANOPOXE500 or NANOPOXE470. The thermal expansion coefficient and the storage modulus of the underfill adhesive are controlled by adjusting the proportion of the first epoxy resin, the bisphenol A epoxy resin and the modified polyether amine curing agent, so that the underfill adhesive is still in close contact with a chip in a high-low temperature environment for a long time, and the reliability of chip packaging is improved.

The invention relates to composite resin for packaging a Topcon component as well as a preparation method and application of the composite resin. Comprising an acrylate monomer, an aliphatic polyurethane acrylate oligomer, hydroxyl acrylate, bisphenol A acrylate, maleic anhydride modified epoxy acrylate, a light curing agent, a latent curing agent, a flame retardant A, a flame retardant B, a thixotropic agent, an anti-aging agent, a UV absorbent and a light stabilizer. The composite resin has the comprehensive performance of high viscosity, low shrinkage, super weather resistance and flame retardance, the aluminum-containing backboard prepared from the composite resin is high in water resistance and super weather resistance, due to the fact that light-heat double-stage curing is adopted for curing, the resin collapses and is cured to generate a solid phase, and in the follow-up aluminum foil hot-pressing curing process, the solid phase is solidified to form a solid phase; the resin is further infiltrated and cured, the porosity of the resin can be greatly reduced through a dual-curing system, water cannot enter the interior in the long-term use process, and voltage breakdown reduction of the aluminum-containing back plate under the long-term damp and hot condition is completely eradicated.

The invention discloses a solid waste-based cold-mixed asphalt mixture for preventive maintenance as well as a preparation method and application thereof, and belongs to the technical field of road engineering. The solid waste-based cold-mixed asphalt mixture is prepared from the following components in percentage by mass: 4.7 to 8.6 percent of modified cold-mixed asphalt adhesive, 85.8 to 93.9 percent of aggregate and 1.4 to 5.6 percent of composite filler, the modified cold-mixed asphalt adhesive is prepared from the following components in parts by weight: 86 to 96 parts of emulsified asphalt, 1 to 5 parts of bisphenol A type waterborne epoxy resin emulsion, 0.05 to 1 part of curing agent, 0.01 to 0.05 part of defoaming agent, 1.5 to 8 parts of waterborne polyurethane emulsion and 1 to 3 parts of hydroxypropyl methyl cellulose. The solid-waste-based cold-mixed asphalt mixture prepared by the method shows excellent comprehensive performance in high-temperature rut resistance, water damage resistance, freeze-thaw resistance, skid resistance, volume stability, interlayer shear resistance and the like, promotes reasonable utilization of solid waste resources, and has good economic and environmental benefits.

The invention provides a preparation method of water-based UV curing conductive ink, and relates to the technical field of polymer conductive material preparation, the preparation method comprises the following steps: respectively preparing modified water-based UV resin, nano-silver and a nano-silver-graphene composite material; and mixing the prepared modified water-based UV resin, nano-silver and a nano-silver-graphene composite material with a photoinitiator, 1, 6-hexanediol diacrylate and an auxiliary agent to obtain the water-based UV curing conductive ink. The preparation method comprises the following steps: firstly, synthesizing an unsaturated epoxy intermediate (EA) by utilizing acrylic acid (AA) and bisphenol A type epoxy resin E-51, then adding the epoxy intermediate EA into an intermediate PUA, and carrying out full end capping on the PUA to prepare light-cured resin; preparing nano-silver and a nano-silver-graphene composite material through a chemical reduction method; and finally, constructing a conductive network in the ink by virtue of a synergistic effect between the nano-silver and the nano-silver-graphene composite material, so as to prepare the water-based UV-cured high-performance conductive ink.

The invention relates to a sludge biochar modified layered bimetallic oxide, and a preparation method and application thereof. The modified layered bimetallic oxide is prepared from the following main raw materials: domestic sewage aeration tank sludge, NaOH, Na2CO3, FeCl3. 6H2O and MnCl2. 4H2O. The domestic sewage aeration tank sludge is used for preparing dry sludge, the ferric chloride solution and the manganese chloride solution are used for preparing sludge composite layered double hydroxides, and the final layered bimetallic oxide composite sludge biochar catalyst can be prepared by calcining the sludge composite layered double hydroxides. The modified layered bimetallic oxide prepared by the scheme of the invention can effectively degrade bisphenol A, has relatively strong reusability, and still keeps good degradation ability in a relatively wide pH environment.

The invention discloses modified epoxidized soybean oil, epoxy resin glue and a preparation method thereof. The modified epoxidized soybean oil is obtained through a reaction of a cyclodextrin-epoxidized soybean oil inclusion compound and citric acid, and the cyclodextrin-epoxidized soybean oil inclusion compound is obtained through a reaction of cyclodextrin and epoxidized soybean oil. The epoxy resin adhesive is prepared from bisphenol A epoxy resin, modified epoxidized soybean oil, an anhydride curing agent and a curing accelerator. The modified epoxidized soybean oil is added into the epoxy resin adhesive, so that the epoxy resin adhesive has better tensile strength, elongation at break, impact strength and low-temperature impact strength, and the toughening effect is remarkable.

The invention relates to the technical field of composite layer structures, in particular to flame-retardant fiber fireproof heat-preservation knitted composite cotton and a preparation process thereof.The knitted composite cotton comprises a knitted cotton base body layer, fiber layers are fixedly arranged on the upper surface and the lower surface of the knitted cotton base body layer, and the two fiber layers are formed by weaving polyester fibers and spandex fibers; resin layers are fixedly arranged on the outer surfaces of the two fiber layers, and are formed by mould pressing and curing of a resin complexing agent. The knitted composite cotton is formed by compounding a knitted cotton matrix layer, an upper fiber layer, a lower fiber layer, an upper resin layer and a lower resin layer, and a resin body in a resin complexing agent is prepared from bisphenol A epoxy resin, a dicyandiamide curing agent, 1-benzyl-2-methylimidazole and a silane coupling agent KH560 to form matrix liquid. The added glass beads and the magnesium hydroxide flame retardant are used as functional aids, and the modified glass fibers and the reinforcing agent are coordinated and synergic, so that the obtained knitted composite cotton has excellent heat preservation, flame retardance and fire resistance.

The invention discloses a high-temperature-resistant tough epoxy resin adhesive and a preparation method thereof, and relates to the technical field of epoxy resin, the high-temperature-resistant tough epoxy resin adhesive comprises the following components by mass: 30-60 parts of epoxy resin, 15-40 parts of a modified curing agent, 5-20 parts of a flexibilizer, 8-35 parts of an inorganic filler, 1-5 parts of a coupling agent, and 0.5-3 parts of an antioxidant; the epoxy resin is formed by compounding bisphenol A epoxy resin and novolac epoxy resin according to the mass ratio of (1-3): 1; the modified curing agent is prepared by modifying an imidazole curing agent with a silane coupling agent. The problem that high temperature resistance and toughness of an epoxy resin adhesive are difficult to consider at the same time can be solved.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention relates to the technical field of PC transparent flame-retardant toughening modification, in particular to phenolic hydroxyl-terminated modified polysiloxane with a side chain containing phenyl and sulfonate groups and a preparation method of copolymerized PC. The modified polysiloxane is prepared by the following steps: performing ring opening polymerization on phenol-containing double end sockets and cyclotetrasiloxane to obtain modified polysiloxane containing double bonds and phenyl functional groups, and grafting sulfonate through a thiol-ene click chemical reaction. Diphenyl carbonate, bisphenol A and the modified polysiloxane are used as raw materials, a polysiloxane-PC block copolymer is formed through copolymerization, efficient flame retardance and high transparency are achieved, and meanwhile extremely high low-temperature impact strength is achieved.

The invention discloses high-strength concrete, a well lid and a preparation method of the well lid, and relates to the field of building materials. The high-strength concrete comprises cement, coarse aggregate, fine aggregate, modified steel fibers, a polycarboxylic acid water reducer and water. Wherein the coarse aggregate comprises broken stones with the continuous grading of 5-8 mm and broken stones with the continuous grading of 10-16 mm; the fine aggregate adopts medium-coarse sand with the particle size range of 1.8-2.2 mm; the preparation raw materials of the modified steel fiber comprise an amino silane coupling agent, an epoxy resin coating and steel fiber, and the preparation raw materials of the epoxy resin coating comprise bisphenol A epoxy resin, nanoparticles, hydroxy acrylic resin, a tertiary amine catalyst and a curing agent. According to the modified steel fiber, the reinforcing effect of the steel fiber on a concrete matrix can be fully exerted, so that concrete which is high in pressure resistance and bearing capacity and especially suitable for well lid manufacturing is obtained.

The invention provides a zirconium boride / graphene complex-phase wear-resistant and high-temperature-resistant ceramic material and a preparation method thereof, and belongs to the technical field of ceramics. The preparation method comprises the following steps: pretreating graphene, preparing titanium dioxide / graphene microspheres, modifying the titanium dioxide / graphene microspheres, functionalizing the titanium dioxide / graphene microspheres, preparing a ceramic mixture, molding and sintering. The step of functionalizing the titanium dioxide / graphene microspheres comprises the following steps: putting the modified titanium dioxide / graphene microspheres into xylene, adding bisphenol A epoxy resin and triphenylphosphine, raising the temperature, carrying out stirring reaction, filtering out, washing, putting into N, N-dimethylformamide, uniformly stirring, adding gallic acid and p-toluenesulfonic acid, and carrying out ultrasonic treatment to obtain the titanium dioxide / graphene microspheres. Raising the temperature for reaction, filtering, washing and drying after the reaction is finished, so as to prepare functionalized titanium dioxide / graphene microspheres; the prepared ceramic material is high in strength, good in wear resistance and excellent in high temperature resistance.

The invention discloses an organic wastewater adsorbent as well as a preparation method and application thereof, and belongs to the technical field of sewage treatment. Comprising the following steps: carrying out nitration reaction on styrene porous microsphere resin, and then carrying out reduction reaction to obtain amino-modified porous microsphere resin; the preparation method comprises the following steps: carrying out polymerization reaction on high-nitrogen-content amino organic small molecules and aldehyde group small molecules under the action of a basic catalyst in an adsorption polymerization manner to generate a nitrogen-doped organic porous polymer, and coating the surface of amino-modified porous microsphere resin with the nitrogen-doped organic porous polymer to obtain the organic wastewater adsorbent. The porous microsphere resin adsorbent with large adsorption capacity and high organic matter removal rate is synthesized by using the carrier advantage of styrene microsphere resin and introducing a porous heteroatom polymer on the microsphere resin. When the adsorbent is used, the adsorbent is directly added into an organic wastewater solution, and the removal rate of bisphenol A, aniline and tetracycline can reach 90% or above.

The invention relates to the technical field of coatings, and discloses a flame-retardant epoxy resin coating and a preparation method thereof.The flame-retardant epoxy resin coating is prepared by adding bisphenol A type epoxy resin, propylene glycol, phosphorus-containing modified imidazolyl benzoxazine, a chitosan-based flame retardant, titanium dioxide, a BYK-071 defoaming agent, a BYK-345 flatting agent, a BYK-220S wetting dispersant and water into a stirrer, stirring, adding a curing agent, stirring, adding a curing agent, and stirring to obtain the flame-retardant epoxy resin coating. The flame-retardant epoxy resin coating is obtained after the reaction is finished. Phosphorus, silicon and benzoxazine structures in the phosphorus-containing modified imidazolyl benzoxazine and the chitosan-based flame retardant all have better flame-retardant effects, and the phosphorus, silicon and benzoxazine structures in the phosphorus-containing modified imidazolyl benzoxazine and the chitosan-based flame retardant have better flame-retardant effects. Chitosan in the chitosan-based flame retardant also has a good flame retardant effect and an antibacterial effect. Benzoxazine can form a heat-resistant phenolic resin structure at high temperature, so that the benzoxazine has a relatively good flame-retardant effect; and an imidazole group in the phosphorus-containing modified imidazolyl benzoxazine also has a relatively good antibacterial effect.

The invention discloses a high-temperature-resistant adhesive for a motor iron core punching sheet and a preparation method of the high-temperature-resistant adhesive, and the high-temperature-resistant adhesive comprises the following components in parts by mass: 60-80 parts of solid polyfunctional novolac epoxy resin; 5 to 15 parts of polyurethane modified epoxy resin; 5 to 15 parts of solid bisphenol A epoxy resin; 5-20 parts of a heat-resistant thermoplastic resin; 1 to 4 parts of a silane coupling agent; 2-8 parts of a filler; 4-10 parts of a curing agent; 0.05 to 0.2 part of an accelerant; the solvent is used for dissolving and mixing the components; according to the high-temperature-resistant adhesive for the motor iron core punching sheet, an organic-inorganic toughening mode is combined, three kinds of organic resin including polyurethane modified epoxy resin, solid bisphenol A type epoxy resin and heat-resistant thermoplastic resin are adopted, and an inorganic filler is used in a matched mode, so that the solid polyfunctional epoxy resin is subjected to toughening modification. According to the technical scheme, the problem that high toughness and high temperature resistance are difficult to consider under the condition that an existing motor iron core punching sheet adopts a modified epoxy adhesive to improve the toughness and peel strength of the adhesive is solved.

The invention relates to a high-impact-resistance light-weight high-strength composite board and a preparation method thereof.The preparation method comprises the following steps that S1, a first glass fiber cloth is arranged between two thermoplastic polyurethane films, hot pressing is conducted, and a glass fiber cloth reinforced polyurethane film is obtained; placing the polyamide-polyether block copolymer film between two adjacent layers of glass fabric reinforced polyurethane films, and performing hot pressing to obtain a high-toughness surface layer; s2, adding the modified hollow glass microspheres, bisphenol A epoxy resin, polyurethane modified epoxy resin, dicyandiamide and an accelerant into a solvent to obtain a resin solution; immersing second glass fiber cloth into the resin glue solution, taking out the second glass fiber cloth after the second glass fiber cloth is completely immersed, and baking the second glass fiber cloth to obtain an epoxy glass fiber prepreg; s3, stacking the plurality of epoxy glass fiber prepregs to obtain a low-density core layer; and S4, stacking the low-density core layer between two adjacent high-toughness surface layers, and performing hot pressing to obtain a target product. The high-strength and high-impact-resistance building material has the advantages of light weight, high strength and high impact resistance.

The invention discloses a double-atom catalyst screening method, an iron / vanadium double-atom catalyst, and a preparation method and application of the iron / vanadium double-atom catalyst. The screening method comprises the following steps: S1, taking adsorption energy and electron transfer amount as descriptors for evaluating the PMS adsorption and activation capability of a catalyst, carrying out first-step screening on M-MXene loaded with monatomic metals according to a sequence of adsorption energy from high to low, obtaining M-MXene which is ranked as top n, and screening to obtain n metals M; step S2, pairing n kinds of metals M in pairs to obtain a diatomic pairing carrier M1-M2-MXene group; and S3, carrying out differential charge calculation, and screening out the M1-M2-MXene with the highest electron transfer amount as the diatomic catalyst. The iron / vanadium diatomic catalyst with the MXene as the substrate prepared by screening can activate PMS, has high and stable removal rate and removal efficiency for bisphenol A, can completely remove 20 mg / L of BPA within 6 min, and has a maximum reaction rate constant of 0.98 min <-1 >. The method is simple in screening step, easy to control, high in practicability and suitable for efficient screening of the diatomic catalyst.