The invention provides a preparation method of a curved surface electrode catalyst layer, which is characterized by comprising the following steps of: 1, preprocessing an electrode matrix; 2, carrying out electrochemical deposition on a catalyst: inserting the preprocessed electrode matrix into an electrochemical deposition pool, loading an electroplating bath containing catalyst cations in the electrochemical deposition pool, forming a three-electrode system with a reference electrode and a counter electrode with the electrode matrix as a working electrode, controlling the potential of the working electrode to be -0.7-0.5V relative to a standard hydrogen electrode for carrying out electrochemical deposition until the loading capacity of the catalyst on the electrode matrix reaches a preset loading capacity, then taking the electrode matrix out, rinsing with deionized water for drying in air for later use; 3, dipping in a perfluorinated sulfonic acid resin solution; 4, repeating the step 2 and the step 3 until the loading capacity of the catalyst on the electrode matrix reaches the set loading capacity of the catalyst, entering the step 5; and 5, activating an electrode.