1411 results about "Molybdenum disulfide" patented technology

The invention relates to a high / low-temperature-resistant wear-resistant tear-resistant fluorosilicone rubber compound and a preparation method thereof, and belongs to the technical field of special rubber materials, the high / low-temperature-resistant wear-resistant tear-resistant fluorosilicone rubber compound comprises the following components: raw fluorosilicone rubber, a reactive liquid rubber compatibilizer, a reinforcing filler, a tear-resistant aid, a high-temperature-resistant aid, a vulcanizing agent, an accelerant, an anti-aging agent and an anti-attrition filler, the provided reaction type liquid rubber compatibilizer contains vinyl carboxyl liquid fluorosilicone rubber, the tear-resistant auxiliary agent contains zinc polymethacrylate, the high-temperature auxiliary agent contains vinyl fluorosilane modified carbon nanotubes, and the anti-friction filler contains molybdenum disulfide and layered nano zirconium phosphate which are treated by oxygen plasma. The high and low temperature resistance stability, oil resistance, wear resistance and tear strength of the fluorosilicone rubber are synergistically improved by regulating and controlling the multi-cross-linked network structure of the fluorosilicone rubber, strengthening the interface action of the rubber and the filler and optimizing the composite vulcanization system, meanwhile, structuralization of a rubber compound is prevented by optimizing the preparation process, and the requirement for adaptability to severe working conditions is met.

The invention belongs to the technical field of ceramics, and discloses a preparation method of fracture-resistant and wear-resistant ceramics. The preparation method comprises the following steps: weighing the raw materials in parts by weight; the preparation method comprises the following steps: mixing 40 parts of potassium feldspar, 10 to 25 parts of albite, 1 to 10 parts of kaolin, 1 to 10 parts of serpentine, 5 to 25 parts of dolomite, 2 to 9 parts of nano zirconium oxide, 0.1 to 1 part of nano cerium oxide, 0.1 to 1 part of nano molybdenum disulfide, 0.1 to 0.8 part of silicon carbide fiber, 0.5 to 2.5 parts of polyethylene glycol, 0.1 to 0.6 part of fullerene trifluoromethyl derivative, 0.1 to 3 parts of sodium dodecyl sulfate, 0.1 to 2 parts of sodium tripolyphosphate and 10 to 60 parts of solvent to obtain slurry; and carrying out spray granulation to obtain a blank, carrying out compression molding to obtain a green body, and sintering to obtain the fracture-resistant and wear-resistant ceramic. The breaking strength of the breaking-resistant and wear-resistant ceramic can exceed 70 MPa, and the length of a grinding pit does not exceed 8.5 mm.

The present application relates to the technical field of catalysts and relates to a non-noble metal cathode hydrogen evolution catalyst for PEM water electrolysis and a use thereof. The present application provides a method for preparing a cathode hydrogen evolution catalyst. A nickel-molybdenum heteropoly acid having a specific structure is generated in situ on the surface of a porous carbon material carrier, and is used as a hydrogen evolution catalyst active component precursor, and an in-situ generated nickel-containing molybdenum sulfide active component is subjected to sulfidation treatment to prepare a non-noble-metal-supported cathode hydrogen evolution catalyst, wherein the in-situ generated nickel-containing molybdenum sulfide active component has a hydrogen adsorption free energy similar to that of Pt and catalytic hydrogen evolution activity, the dispersity is good, and the number of active sites is large, thereby reducing the costs of the catalyst; in addition, during the sulfidation treatment of the nickel-molybdenum heteropoly acid, nitrogen or phosphorus atoms in the carrier can be doped into the lattice of molybdenum disulfide, thereby reducing the hydrogen evolution Gibbs free energy of sulfur atoms on an MoS2 crystal basal surface, and more active sites are formed on a sulfur edge and a molybdenum edge, facilitating a hydrogen evolution reaction.

The invention provides slick water fracturing fluid as well as a preparation method and application thereof. The slick water fracturing fluid comprises chitosan, a polymer matrix, paraformaldehyde and a solvent. In the slick water fracturing fluid provided by the invention, the chitosan and the polymer are fully dissolved, and the main chains of the two polymers are physically interpenetrated and wound. In the presence of paraformaldehyde, a polymer main chain is chemically crosslinked with paraformaldehyde to form a primary network structure. Then, chitosan and molybdenum disulfide can form coordination cross-linking sites, a secondary network structure is obtained, then a multi-network structure which cannot be split is formed, and the viscosity is high; moreover, the components have good solubility in the solvent, are easy to mix on line and are relatively low in preparation cost.

The invention discloses a carbon-doped titanium dioxide nanotube-molybdenum disulfide energy-storage antibacterial material and a preparation method thereof. The preparation method comprises the following steps: carrying out primary anodic oxidation on a clean titanium foil in a mixed electrolyte of ethylene glycol, water and ammonium fluoride; after ultrasonic treatment is carried out in a hydrochloric acid solution for set time, secondary anodic oxidation is carried out, and the mixed electrolyte of the secondary anodic oxidation is the same as that of the primary anodic oxidation; annealing the titanium foil subjected to anodic oxidation twice in an argon atmosphere, putting an annealed sample into a mixed solution of sodium molybdate, a sulfur source and glucose, and carrying out hydrothermal treatment; and the titanium foil subjected to hydro-thermal treatment is cleaned and dried, and the carbon-doped titanium dioxide titanium foil with the surface covered with molybdenum disulfide is obtained. The MoS2-coated carbon-doped titanium dioxide nanotube (TNT-C-atMoS2) with high biocompatibility developed by the invention has a synergistic effect of charge antibiosis and chemical sterilization, so that the problem of intractable biological fouling of a titanium-based metal material in ocean engineering equipment is effectively solved.

The invention discloses an application of a molybdenum disulfide-based piezoelectric catalytic material in a seawater uranium extraction material, and relates to the technical field of seawater uranium extraction, thiourea and sodium molybdate are used as precursors, and a MoS2 nanoflower with a specific 1T / 2H composite crystal structure is constructed through a hydrothermal synthesis technology. The method is placed in a uranyl nitrate solution, ultrasonic treatment is combined, efficient extraction of uranium can be achieved, and the method has potential application to extraction of uranium from seawater. The method is simple in process and environment-friendly, almost does not generate harmful waste in the synthesis process, does not need complex operation, and has good amplification preparation potential.

The invention relates to the field of design and preparation of powder metallurgy friction materials, in particular to a copper-based powder metallurgy friction material and a preparation method thereof. Raw materials used in the method comprise, by mass, 45%-55% of copper powder, 8%-20% of iron powder, 6%-15% of ferrochromium, 16%-22% of graphite, 0.5%-4% of molybdenum disulfide, 0.5%-4% of tin sulfide and 0.5%-4% of nickel-coated tungsten disulfide, and the mass ratio of the tin sulfide to the nickel-coated tungsten disulfide is (1-2): (1-2). In the nickel-coated tungsten disulfide, the content of nickel is 5-40%; the sum of the total amount of molybdenum disulfide, nickel-coated tungsten disulfide and tin sulfide is less than or equal to 5%. The preparation method comprises the following steps: weighing raw material powder according to the designed components, mixing, pressing and sintering to obtain the product. The composition design has the characteristics of scientificity, simple and controllable process and the like, and the obtained product has excellent tribological performance and completely meets the friction braking requirement of high-speed heavy-load equipment of 400km / h and above.

The invention belongs to the technical field of photoelectric detection, and discloses a heterojunction dual-band photoelectric detector based on a two-dimensional material, which comprises a substrate layer, an insulating layer, a molybdenum disulfide layer, graphene, black phosphorus and a metal electrode, the insulating layer is formed above the substrate layer, the molybdenum disulfide layer is located above the insulating layer, the molybdenum disulfide layer is formed above the insulating layer, no less than two layers of graphene are arranged above the molybdenum disulfide layer, and the top layer is multi-layer black phosphorus; the molybdenum disulfide layer, the graphene and the black phosphorus are in contact through Van der Waals force, a source electrode and a drain electrode of a formed heterostructure are connected with the metal electrode, and the molybdenum disulfide layer and the black phosphorus are isolated through the graphene and do not make contact with each other. In the invention, the intrinsic dark current in direct proportion to the effective transmission volume of the device is greatly reduced, and meanwhile, the current carriers are limited in a two-dimensional plane and are very easy to regulate and control by a local electric field, so that the dark current of the device can be further reduced, and the problem that the detector prepared from most traditional materials needs refrigeration at present can be solved.

The invention relates to the technical field of wastewater denitrification, and discloses a composite carrier and a preparation method and application thereof.The composite carrier comprises molybdenum disulfide of a porous structure, a zirconium metal organic framework grows in situ in the porous structure of the molybdenum disulfide, and graphene is loaded on the surface of the molybdenum disulfide. The composite carrier disclosed by the invention not only can be used as a place for nitrogen removal by microorganisms, but also can improve the nitrogen removal efficiency of the microorganisms.

The invention relates to the technical field of friction plates for vehicles, and particularly discloses a resin-based friction plate for an aluminum-ceramic brake disc and a preparation method of the resin-based friction plate for the aluminum-ceramic brake disc. Steel fibers serve as a main reinforcing phase, the structural strength of the material is improved, and meanwhile the steel fibers are good friction increasing materials; the reduced iron powder can improve the heat-conducting property of the brake pad and reduce the decline of the friction coefficient at high temperature; the red copper powder and the brass powder are good lubricants, the stability of single braking can be improved, and meanwhile abrasion is reduced; the silicon carbide mainly plays a role in increasing the high-temperature friction coefficient; molybdenum disulfide is beneficial for improving the recovery performance after high-temperature decline and reducing abrasion; antimony sulfide is lubricated at high temperature, and the friction coefficient in the decline stage is increased; silicon carbide is a high-hardness material, so that the friction coefficient is increased; the potassium magnesium titanate lamellar crystal improves the damping characteristic of the material and absorbs vibration and reduces noise, and the resin-based friction plate has the advantages of being high in strength, good in heat conduction, stable in friction performance, resistant to abrasion, comfortable in braking and the like and meets the use requirement of an aluminum ceramic brake disc.

The invention provides a heat-storage warm-keeping down-locking layered fabric and a down jacket. The heat-storage warm-keeping down-locking layered fabric sequentially comprises a skin-friendly layer, a liner cloth layer and a heat-storage warm-keeping down-locking layer from inside to outside, and the heat-storage warm-keeping down-locking layer is prepared by napping a heat-storage warm-keeping fabric; yarns for weaving the heat-storage and warm-keeping fabric are heat-storage and warm-keeping fiber / hollow polyester fiber / wool fiber blended yarns; the heat-storage warm-keeping fiber comprises polyester and a heat storage agent, and the preparation method of the heat storage agent comprises the following steps: firstly loading a polyethylene glycol / nano molybdenum disulfide composite material by adopting porous silicon dioxide microspheres, then mixing with a mixture containing silica sol and nano metal silver, and performing vacuum drying to obtain the heat storage agent. The heat-storage warm-keeping down-locking layered fabric has excellent heat-storage warm-keeping effects, can lock down, has a good antibacterial effect, and has a very good application effect when being used as a lining fabric of a down jacket.

The invention belongs to the field of wastewater treatment technology and energy conservation and environmental protection, and particularly relates to a preparation method and application of aerogel for selectively separating radionuclide cesium in water. The preparation method comprises the following steps: preparing graphene oxide by using a hydrothermal technology, preparing molybdenum disulfide / GO aerogel by using a hydrothermal synthesis and ultrasonic technology, and inlaying and growing Prussian blue (PB) on the surface of the aerogel, so that the problems that PB and MoS2 are easy to agglomerate and difficult to recover are solved, the GO aerogel is endowed with multiple functions, and the constructed PB / MoS2 / GO aerogel is used for selectively separating radionuclide cesium in water. The selective separation performance of the aerogel on the radionuclide cesium in water under different conditions is investigated, efficient enrichment and recovery of the radionuclide cesium are effectively realized by utilizing the ultralight and highly porous characteristics of the aerogel, and the application potential of the aerogel in the aspects of reducing secondary pollution and improving the environmental treatment effect is proved. An efficient and environment-friendly solution is provided for radionuclide wastewater treatment, and the method has a wide market application prospect.

A molybdenum disulfide material having large lattice spacing and a preparation method therefor, a negative electrode, and a battery. The preparation method for a molybdenum disulfide material having large lattice spacing comprises: reacting a composite solution, in which a sulfur source, a molybdenum source and inducing metal ions are mixed, at a temperature maintained at 200-280°C, thereby obtaining a solid-liquid mixture after the reaction is finished; and separating out a solid substance in the solid-liquid mixture, thereby obtaining a molybdenum disulfide material having large lattice spacing, wherein the inducing metal ions are at least one of germanium ions, iron ions, gallium ions, nickel ions and manganese ions. The negative electrode material is prepared by using the preparation method. The negative electrode is prepared from the negative electrode material. The lithium-ion battery comprises the negative electrode. The molybdenum disulfide material having large lattice spacing prepared by using the preparation method has relatively large lattice spacing, and a battery assembled from a negative electrode prepared from same has relatively good electrochemical performance.

The invention discloses anti-attrition lubricating oil suitable for minimal quantity lubrication and a preparation method thereof, and belongs to the technical field of lubricating oil, molybdenum disulfide is nucleated and grows on the surface of porous cerium oxide nanosphere powder to form a cerium oxide and molybdenum disulfide compound, then modified silicon dioxide and tannic acid are pre-polymerized to form silicon dioxide prepolymer powder, and the silicon dioxide prepolymer powder is subjected to ball milling to obtain the anti-attrition lubricating oil suitable for minimal quantity lubrication. The preparation method comprises the following steps: taking a cerium oxide molybdenum disulfide compound as a core material, taking silicon dioxide prepolymer powder and an N-isopropylacrylamide polymer as a shell to obtain a composite temperature-sensitive microcapsule, and mixing the composite temperature-sensitive microcapsule with other raw materials to prepare the composite temperature-sensitive microcapsule. The outer-layer shell polymer chain of the composite temperature-sensitive microcapsule in the anti-attrition lubricating oil shrinks, the cerium oxide molybdenum disulfide compound inside is released, and controllable release of the inner core material is realized by using the temperature sensitivity of the shell polymer of the composite temperature-sensitive microcapsule and the external temperature change during operation.

The invention discloses a wide-temperature-range polyether-ether-ketone-based self-lubricating composite material part for LPBF and a forming method of the wide-temperature-range polyether-ether-ketone-based self-lubricating composite material part, and belongs to the technical field of additive manufacturing. The forming method comprises the steps that polyether-ether-ketone powder and molybdenum disulfide powder are pretreated according to different modes; after pretreatment, the two kinds of powder are mechanically mixed according to a specific proportion, and wide-temperature-range polyether-ether-ketone-based self-lubricating composite material powder is obtained; and carrying out printing forming on the polyether-ether-ketone-based self-lubricating composite material powder by adopting a laser powder bed melting (LPBF) specific process to obtain a wide-temperature-range polyether-ether-ketone-based self-lubricating composite material part. Molybdenum disulfide is adopted to enhance the friction and wear performance of polyether-ether-ketone in a wide temperature range, the printability of powder is improved through special pretreatment, and a high-performance wide-temperature-range polyether-ether-ketone-based self-lubricating composite material part suitable for high and low temperature extreme environments is obtained through forming by adopting specific LPBF processes such as multidirectional cross scanning and the like.

The invention discloses an infrared detector with a Van der Waals complementary barrier structure, a preparation method and an application. The structure of the detector is as follows: a P-type Si substrate is used as a substrate of the detector; growing a SiO2 dielectric layer on the P-type Si substrate; the black phosphorus layer covers the SiO2 dielectric layer and is used as a conducting channel; one end of the molybdenum disulfide layer covers one end of the black phosphorus layer, and the other end of the molybdenum disulfide layer is arranged on the SiO2 dielectric layer; the drain electrode is directly prepared on the other end of the black phosphorus layer and is in contact with the black phosphorus layer; the source electrode is prepared at the other end, not overlapped with the black phosphorus layer, of the molybdenum disulfide layer, and electric connection is achieved through overlapping of the molybdenum sulfide layer and the black phosphorus layer. According to the invention, high-sensitivity room temperature detection, ultra-fast response and sensing of multiple physical quantities such as light intensity, polarization and gas are realized, and the method has an application prospect in a miniaturized, low-power-consumption and multifunctional infrared detection system.

The invention belongs to the technical field of all-vanadium redox flow battery diaphragms, and particularly discloses a sulfonated polyetheretherketone / polyaniline composite membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing polyetheretherketone and concentrated sulfuric acid, and carrying out water bath heating reaction to prepare a sulfonated polyetheretherketone solid; molybdenum disulfide and methylbenzene are mixed and subjected to ultrasonic treatment, 1, 3-propane sultone is added, oil bath heating is conducted, and sulfonated molybdenum disulfide powder is prepared; the preparation method comprises the following steps: mixing and stirring sulfonated molybdenum disulfide powder, polyaniline and a DMF (Dimethyl Formamide) solution, performing ultrasonic treatment, adding a sulfonated polyether-ether-ketone solid, stirring to obtain membrane casting slurry, coating a glass plate with the membrane casting slurry, drying to form a membrane, and soaking the membrane in a sulfuric acid solution and deionized water in sequence to obtain the sulfonated polyether-ether-ketone / polyaniline composite membrane. The invention discloses a sulfonated polyetheretherketone / polyaniline composite membrane as well as a preparation method and application thereof. The sulfonated polyetheretherketone / polyaniline composite membrane has high proton conductivity, can maintain relatively low vanadium ion permeability and can improve the electrochemical performance of an all-vanadium redox flow battery.

The invention relates to the field of wear-resistant materials, and provides a thermoplastic wear-resistant composite material as well as a preparation method and application thereof, and the thermoplastic wear-resistant composite material comprises the following raw materials in parts by weight: 65-75 parts of polytetrafluoroethylene, 25-35 parts of polyphenylene sulfide, 3-7 parts of modified aramid fiber and 1-5 parts of modified molybdenum disulfide. The thermoplastic wear-resistant composite material provided by the invention has the characteristics of good wear resistance, low friction and high toughness, and can be widely applied to wear-resistant parts related to pump bodies and bearings.

The invention relates to the technical field of wave absorbing materials, and to a preparation method of a flaky carbonyl iron / molybdenum disulfide composite wave absorbing material and corresponding materials, comprising: adding sodium dodecylbenzene sulfonate, sodium molybdate, and thiourea to an ethanol solution according to a ratio and stirring to obtain a precursor solution; placing the precursor solution in a reactor for hydrothermal reaction to obtain a hydrothermal reaction solution, centrifugally washing the hydrothermal reaction solution to obtain a hydrothermal reaction product, vacuum drying the obtained hydrothermal reaction product to obtain a molybdenum disulfide nanomaterial; mixing the molybdenum disulfide nanomaterial with flaky carbonyl iron according to a ratio and grinding to obtain a mixed powder, bonding the mixed powder to obtain a flaky carbonyl iron / molybdenum disulfide composite wave absorbing material. The preparation method of the flaky carbonyl iron / molybdenum disulfide composite wave absorbing material and the corresponding materials of the invention can prepare a wave absorbing material with excellent electromagnetic wave absorption performance and can meet the absorption requirements of different frequency bands.

The invention discloses a monatomic-cluster double-active-site efficient ammonia cracking hydrogen production catalyst and a preparation method thereof, and belongs to the field of new energy catalytic materials. The catalyst comprises a 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier, a molybdenum disulfide nanosheet-loaded iron cluster carrier, monatomic active metal, cluster active metal and an auxiliary agent. Wherein the 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier is prepared by the following steps: stirring 2-methylimidazole, zinc acetate and cobalt nitrate hexahydrate in methanol to generate a ZIF-8 precursor, washing, drying, and calcining in an H2 / Ar mixed atmosphere, thereby obtaining the 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier; the molybdenum disulfide nanosheet loaded iron cluster carrier is prepared by carrying out hydrothermal reaction on ammonium molybdate and thiourea to generate MoS2 nanosheets and then loading iron clusters. The catalyst prepared by the invention has high activity, long service life and industrial applicability.

The invention discloses an insulating material with corrosion resistance and a production process thereof, and relates to the technical field of insulating materials. The invention discloses an insulating material with corrosion resistance. The invention discloses a flame-retardant coating which is prepared from the following raw materials in parts by weight: 60 to 80 parts of bisphenol A epoxy resin, 20 to 30 parts of polyether-ether-ketone, 10 to 15 parts of nano aluminum nitride, 5 to 10 parts of boron fiber, 4 to 8 parts of molybdenum disulfide, 3 to 6 parts of poly (p-phenylene benzobisoxazole), 2 to 5 parts of vinyl trimethoxy silane, 20 to 30 parts of dimethyl sulfoxide, 8 to 12 parts of melamine cyanurate, 6 to 10 parts of magnesium aluminum hydroxide, 1 to 3 parts of Chimassorb 944 and 10 to 20 parts of modified polyvinyl alcohol. The coating is prepared from the following components in parts by weight: 20-30 parts of modified cellulose, 8-15 parts of modified cellulose, 3-7 parts of nano-zirconia, 5-10 parts of polysiloxane elastomer and 7-12 parts of fluorine-containing acrylate copolymer. The raw materials of the insulating material have a synergistic effect, and the prepared insulating material not only has conventional electrical insulation, but also has excellent heat resistance, corrosion resistance and the like, integrates hardness, flexibility, flame retardance and self-repairing performance, greatly expands the application range of the insulating material, and provides powerful support for industry development.

The invention discloses an epoxy resin-based composite material with vibration damping performance and a preparation method and application thereof, and belongs to the technical field of carbon fiber reinforced composite materials. The carbon fiber reinforced epoxy resin matrix composite material is prepared from the following raw materials in parts by weight: 80-120 parts of epoxy resin, 10-50 parts of a curing agent and 5-10 parts of carbon nanotube / molybdenum disulfide and micron rubber co-embedded damping particles. The epoxy resin-based composite material disclosed by the invention is simple in raw materials, can be commercialized, and meets the low-altitude economic development requirements and the application requirements of aviation aircrafts; and the composite material has high specific strength, high damping vibration attenuation performance, electrical insulation performance and the like, and has a good application prospect in preparation of aircraft skin parts.

The invention provides a preparation method of a molybdenum disulfide material with a biological fine hierarchical structure form, and relates to the technical field of nano materials, and the preparation method comprises the following steps: preparing a biological wing as a biological template; pretreating the biological template by using an ethylenediamine tetraacetic acid solution; molybdenum disulfide grows on a pretreated biological template through a hydrothermal method, and the molybdenum disulfide material of the biomorphic fine hierarchical structure is obtained. Organisms with fine hierarchical structures existing in the nature in quantity serve as the template, and the molybdenum disulfide material of the fine hierarchical structure is prepared through the hydrothermal method; the prepared metal material inherits the fine structure characteristics of an original biological template and has wide application value in the fields of photoelectron, photocatalysis and magnetic performance, compared with the original biological template, the thickness of the molybdenum disulfide layer can be further controlled by adjusting the hydrothermal time and temperature of a hydrothermal method, and the preparation method is simple and easy to implement. The molybdenum disulfide material with the multi-scale graded fine structure and different biological morphological structures is prepared.

The invention discloses a self-lubricating aluminum coating and a preparation method thereof.The preparation method comprises the steps that molybdenum disulfide is pretreated through a silane coupling agent, tetraethoxysilane mixed liquor is added, the pH is adjusted to be 9-10, a water bath reaction is conducted, and molybdenum disulfide-silicon dioxide microcapsules are obtained after high-temperature strengthening treatment; respectively adding a zinc nitrate solution and a hexamethylenetetramine solution, adjusting the pH value to 10-11, carrying out a high-temperature and high-pressure hydrothermal reaction to obtain zinc oxide nanorods, and carrying out ball milling treatment on the zinc oxide nanorods, microcapsules, stearic acid and zirconium oxide balls under the protection of argon to obtain doped microcapsules; after raw materials are pretreated, the raw materials and a dispersing agent solution are added into a mixer respectively, spraying powder, a pretreated base body and the spraying powder are obtained after mixing treatment, spraying treatment is conducted on the surface of the base body through a plasma spraying method, and the self-lubricating aluminum coating is obtained after vacuum annealing treatment. Therefore, the obtained self-lubricating aluminum coating is low in friction coefficient, high in performance and excellent in self-lubricating property.

According to the cobalt-doped molybdenum disulfide lithium-sulfur battery composite positive electrode material, the preparation method and the application, a cobalt-doped stable molybdenum disulfide defect structure composite nitrogen-doped graphene material is prepared by combining a solvothermal method and an annealing technology, and the process is mature; the method is simple, and the composite positive electrode material with high sulfur content is easy to obtain. According to the lithium-sulfur battery composite sulfur positive electrode material disclosed by the invention, the strong chemical adsorption effect and catalytic conversion effect of the cobalt-doped stable molybdenum disulfide defect structure composite nitrogen-doped graphene carrier on polar lithium polysulfide are utilized, so that the diffusion of the lithium polysulfide in an ether electrolyte is inhibited, and the electrochemical reaction kinetics is improved; therefore, the shuttling effect is slowed down, and the lithium-sulfur battery has the characteristics of high capacity and long service life.

The invention provides a preparation method of a catalytic material for removing new pollutants in a complex water environment. The preparation method comprises the following steps: step 10, preparing a metal organic framework material; step 20, preparing iron oxide particles in the metal organic framework material to obtain the confined iron nano material; and step 30, vertically growing molybdenum disulfide nanosheets on the surface of the confined iron nanomaterial to obtain the catalytic material. According to the preparation method of the catalytic material for removing the new pollutants in the complex water environment, provided by the invention, the prepared catalytic material has excellent anti-interference capability in the complex water environment, and the reaction activity is improved.

The invention relates to the technical field of sliding materials for shock absorption and isolation supports, and particularly discloses a composite sliding plate containing ultra-high molecular weight polyethylene as well as a preparation method and application of the composite sliding plate. The composite sliding plate containing the ultra-high molecular weight polyethylene comprises a working layer material and a base layer material from top to bottom, the working layer material comprises the following raw material components: ultra-high molecular weight polyethylene, trimethylolpropane modified polytetrafluoroethylene, a lubricant, an inorganic filler, a compatilizer and a coupling agent; the base layer material comprises the following raw material components: ultra-high molecular weight polyethylene, molybdenum disulfide coated carbon fibers, graphene and a coupling agent. The prepared composite sliding plate has high compressive strength, excellent wear resistance and excellent creep resistance. By means of the technical scheme, the problems that in the prior art, a sliding material for a seismic mitigation and isolation support is low in compressive strength, poor in wear resistance and poor in creep resistance are effectively solved.

The invention discloses a miniature multi-ion sensing system based on a non-gate array and a preparation method thereof, and belongs to the technical field of electrochemical sensing, and the miniature multi-ion sensing system comprises a multi-ion sensing unit and a molybdenum disulfide non-gate array; the multi-ion sensitive unit comprises a metal electrode array, an ion sensitive film array and a liquid storage tank, multiple ions are detected through the ion sensitive film array at the same time and converted into electric signals, and the electric signals are transmitted to the molybdenum disulfide non-gate array through the metal electrode array; the molybdenum disulfide NOT gate array comprises a plurality of molybdenum disulfide NOT gates, and each molybdenum disulfide NOT gate comprises a metal electrode layer, a molybdenum disulfide layer, a NOT gate input end and a NOT gate output end, so that two field effect transistors are formed, received electric signals are amplified, the Nernst limit is broken through a NOT gate structure, and tiny changes of ion concentration are accurately detected. The sensitivity is higher; molybdenum disulfide is used as a channel material of the NOT gate, so that the size and power consumption of the NOT gate are effectively reduced, the integration level of the system is improved, and the service life of the system is prolonged.

The invention discloses a nano-diamond reinforced powder metallurgy brake pad friction body material and a preparation method thereof, and relates to a brake pad friction body material and a preparation method thereof. The problem that in the prior art, the stability of a braking system of a train at a high running speed cannot be achieved is solved. The friction body material comprises a matrix component, a lubricating component, a friction component and a basic reinforcing component, wherein the sum of the mass percentages of the matrix component, the lubricating component, the friction component and the basic reinforcing component is 100%; wherein the mass percent of the copper powder in the matrix component is 50%-70%, and the mass percent of the iron powder in the matrix component is 10%-30%; the mass percent of the lubricating component is 10%-20%; the mass percent of the friction component is 1%-5%; the mass percent of the nano-diamond in the enhanced component is 0.1%-1%; the friction component is composed of one or more of silicon dioxide, aluminum oxide, titanium carbide, tungsten carbide, silicon carbide powder and zirconium oxide powder; the lubricating component is composed of one or more of graphite, carbon nanotubes and molybdenum disulfide. Belongs to the technical field of powder metallurgy.

The invention discloses a molybdenum disulfide acid leaching purification process, relates to the technical field of molybdenum disulfide purification, and aims to solve the problems of waste acid recycling, wastewater treatment and equipment corrosion in the molybdenum disulfide purification process. The molybdenum disulfide acid leaching purification process comprises the following steps: S1, acid purification: adding a molybdenum concentrate raw material into a reaction kettle; adding reaction acid into the reaction kettle according to a certain solid-to-liquid ratio, heating the reaction kettle to react for a period of time, and cooling to dissolve impurities in the molybdenum concentrate; s2, filter pressing and cleaning: conveying the acid-washed material to a plate frame for filter pressing to form a filter cake, cleaning the filter cake with clear water for 2-4 times until the wastewater is neutral, and conveying the filter cake to the plate frame for filter pressing again; s3, repeating acid purification and filter-pressing cleaning for several times until various acids are used up in the process; and S4, drying: putting the cleaned filter cake into a drying system for drying to obtain the high-purity molybdenum disulfide with the purity of more than or equal to 99%. According to the acid leaching purification process, impurities in molybdenum disulfide are selectively dissolved, the purity of molybdenum disulfide is remarkably improved, and the industrial application requirement is met.