16 results about "Cadmium sulfide" patented technology

The invention discloses a method for synthesizing a Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst by adopting a solvothermal method, and belongs to the technical field of catalysts. The preparation method comprises the following steps: preparing copper molybdenum sulfide by using cuprous oxide as a template, synthesizing copper molybdenum sulfide with high purity and good crystallinity by combining a solvothermal method, preparing manganese cadmium sulfide by using manganese acetate, cadmium acetate, sodium hydroxide and thioacetamide as raw materials, adding copper molybdenum sulfide before a hydrothermal reaction, successfully modifying the manganese cadmium sulfide by constructing a heterojunction, and preparing the copper molybdenum sulfide modified manganese cadmium sulfide. The Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst is synthesized, and the photocatalytic hydrogen production rate of the cadmium manganese sulfide is improved. Moreover, the hydrogen production rate of the Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst prepared by the invention can reach 8233 mu mol / (g.h), which is 2.08 times of the hydrogen production rate of pure cadmium manganese sulfide, and 1.24 times of the hydrogen production rate of cadmium manganese sulfide loaded with 1% platinum.

A ZIF-derived zinc-cadmium sulfide photocatalyst, its preparation method, and its application are disclosed. The catalyst, by molar fraction, comprises: 35-50% 2-methylimidazole; 0-7.7% divalent cadmium ion compound; 0-7.7% divalent zinc ion compound; 7-10% thioacetamide; and 35-50% amines. The preparation method involves: preparing a 2-methylimidazole solution and a cadmium-zinc mixed solution separately; then preparing a ZIF precursor solution with cadmium and zinc as the central metals; adding thioacetamide to the precursor solution; transferring the solution to a polytetrafluoroethylene liner and hydrothermally treating it; finally collecting the hydrothermally treated solution, centrifuging, washing, drying, and grinding to obtain the ZIF-derived zinc-cadmium sulfide photocatalyst. The catalyst prepared by this invention has a large specific surface area and exhibits significant catalytic effects in photocatalytic water splitting for hydrogen production. Furthermore, the catalyst has a stable structure and can be recycled for a long period without a significant decrease in the hydrogen production rate.

The invention relates to the field of reversed-phase colloid dispersion systems, nanocrystals and coatings, in particular to a single-layer zinc cadmium sulfide nanocrystal coating and a preparation method thereof. The preparation method comprises the following steps: firstly, mixing a polymer aqueous solution, a metal salt aqueous solution and a solvent, and ultrasonically crushing to form a reversed-phase colloid containing nanocrystalline precursor metal ions; and spin-coating the obtained reversed-phase colloid on a quartz glass sheet for natural air drying, and irradiating by infrared light to form a coating film with the surface containing the nanocrystalline precursor. Placing the coating film in a polymer aqueous solution, carrying out ultrasonic cleaning, and then carrying out ultrasonic cleaning with the same polymer aqueous solution again; finishing the coating film containing the surface precursor from which the free metal ions are removed; finally, the coating film is placed in a sintering furnace with the temperature controlled by a program to be heated and sintered, and the single-layer zinc cadmium sulfide nanocrystalline coating film can be obtained. The coating film is prepared by adopting the reverse phase colloid, cadmium / zinc metal ions can be effectively chelated by using sulfydryl of a sulfydryl polyethylene glycol-block polycaprolactone functional group, and free metal ions are few.

The present invention provides a method for growing a double-layer two-dimensional material using cadmium sulfide as a sulfur source. The preparation method comprises: subjecting a transition metal source to a chemical vapor deposition reaction with cadmium sulfide powder in a protective gas, and controlling the temperature during deposition to 700-850°C to prepare a double-layer transition metal chalcogenide with AA stacking and AB stacking on the surface of a growth substrate. The size of the double-layer transition metal chalcogenide is 10-100 μm and the thickness is 1 to 3 nm. The present invention proposes for the first time the use of cadmium sulfide powder of a single sulfur molecule as a sulfur source for chemical vapor deposition growth of a double-layer two-dimensional material with a controllable stacking mode. The method of the present invention is simple and easy to operate, the process is controllable, the resulting material has a good morphology, and has broad application prospects.

This invention discloses a method for synthesizing Mn using a solvothermal method. 0.43 Cd 0.57 This invention relates to a method for producing S / Cu2MoS4 photocatalysts, belonging to the field of catalyst technology. First, copper molybdenum sulfide is prepared using cuprous oxide as a template. A solvothermal method is then used to synthesize copper molybdenum sulfide with high purity and good crystallinity. Next, manganese cadmium sulfide is prepared using manganese acetate, cadmium acetate, sodium hydroxide, and thioacetamide as raw materials. Before the hydrothermal reaction, copper molybdenum sulfide is added, and manganese cadmium sulfide is successfully modified by constructing a heterojunction, thus synthesizing Mn. 0.43 Cd 0.57 The S / Cu2MoS4 photocatalyst improved the photocatalytic hydrogen production rate of manganese cadmium sulfide. Furthermore, the Mn prepared in this invention... 0.43 Cd 0.57 The S / Cu2MoS4 photocatalyst can produce hydrogen at a rate of 8233 μmol / (g·h), which is 2.08 times that of pure manganese cadmium sulfide and 1.24 times that of manganese cadmium sulfide loaded with 1% platinum.

The application relates to the cross field of photocatalytic composite materials and soil environment remediation technology, and specifically discloses a three-dimensional graphene aerogel loaded cadmium sulfide quantum dot composite material, a preparation method and application of the composite material in soil cadmium pollution remediation, the composite material is composed of a three-dimensional interconnected porous sulfur-doped graphene aerogel skeleton and in-situ anchored cadmium sulfide quantum dots, the cadmium sulfide quantum dots have a particle size of 2-10 nm, a loading amount of 10 wt%-25 wt%, a surface sulfur vacancy density of 5%-8%, the skeleton has a sulfur atom content of 2 at%-5 at%, and the two are connected through a carbon-sulfur-cadmium covalent bridge; the material has a hierarchical porous structure with longitudinal through macropores of 20-80 mu m and intrawall mesopores of 2-20 nm, the material is prepared by adopting a three-stage programmed hydrothermal method, and a sulfur source is released in stages by 30%-50% excess thioacetamide to drive the formation of an epoxy group nucleophilic ring-opening anchor point, in-situ nucleation of quantum dots and generation of surface sulfur vacancies.

The application belongs to the technical field of photoelectric materials, and particularly relates to a yttrium-doped CdS thin film and a preparation method and application thereof. The preparation method of the yttrium-doped CdS thin film comprises the following steps: adding a cadmium salt solution, ammonia water and a thiourea solution into water in sequence and stirring uniformly to obtain a mixed solution; immersing a conductive substrate on which a P-type chalcogenide compound absorption layer thin film is formed into the mixed solution, and performing initial deposition through water bath heating; taking out the conductive substrate after the initial deposition, immersing it into a yttrium salt solution first, and then depositing it in the mixed solution, repeating the immersing and depositing operations for 4-6 times, and washing and drying to obtain the yttrium-doped CdS thin film. The yttrium-doped CdS thin film prepared by the application is used as a buffer layer for a CZTSSe solar cell, and a photoelectric conversion efficiency of 15.19% is achieved.

The invention belongs to the technical field of photocatalysts, and particularly relates to a twin-crystal zinc cadmium sulfide nanosheet, a composite photocatalyst and a preparation method and application thereof.The preparation method of the twin-crystal zinc cadmium sulfide nanosheet comprises the following steps that a zinc source, a diethylenetriamine aqueous solution and a sulfur source are mixed, a first solvothermal reaction is conducted, and a second solvothermal reaction is conducted; a zinc sulfide-diethylenetriamine composite precursor is obtained; mixing the zinc sulfide-diethylenetriamine composite precursor, a cadmium source and an organic solvent, and performing a second solvothermal reaction to replace part of zinc ions in crystal lattices of the zinc sulfide-diethylenetriamine composite precursor with cadmium ions to obtain a zinc cadmium sulfide-diethylenetriamine composite precursor; and dispersing the zinc cadmium sulfide-diethylenetriamine composite precursor in water, and carrying out hydrothermal reaction to remove diethylenetriamine molecules, thereby obtaining the twin crystal zinc cadmium sulfide nanosheet. The twin crystal interface can provide a preferential carrier migration channel, so that photo-induced electron-hole separation is further promoted, and the photocatalytic hydrogen production performance is improved.

This invention discloses a zinc-cadmium sulfide solid solution, its preparation method, and its applications. The preparation method of the zinc-cadmium sulfide solid solution of this invention includes the following steps: 1) dissolving a zinc source and a cadmium source in water to obtain a zinc-cadmium source solution; 2) dissolving a sulfur source in the zinc-cadmium source solution to obtain a precursor solution; 3) adding an alkaline solution to the precursor solution, followed by a hydrothermal reaction, and then separating, purifying, and drying the product to obtain the zinc-cadmium sulfide solid solution. The zinc-cadmium sulfide solid solution of this invention has advantages such as high catalytic efficiency and good stability, making it suitable for photocatalytic water splitting to produce hydrogen. Furthermore, its preparation method is simple, the reaction conditions are mild, the reproducibility is good, and the production cost is low, making it suitable for large-scale industrial production and application.

The invention discloses a high-efficiency and low-cost sulfide nanomaterial and a preparation method thereof. The nanomaterial is zinc sulfide or cadmium sulfide. The preparation method of the nanomaterial comprises the following steps: adding 0.001-0.002g of a surfactant to 20-50ml of water with a live bacteria content of 10,000-20,000 / ml, heating the mixture to 80-90°C, cooling the mixture to room temperature, adding 0.02-0.027g of a sulfur source, and stirring and mixing the mixture to obtain a material A; dissolving 0.1-0.3g of a zinc source or a sulfide source in 30-50ml of an aqueous solution containing 0.001-0.002g of a surfactant, and then adding 1-2mg of trypsin, stirring and mixing the mixture to obtain a material B; adding 2-4ml of octanol to the material A, mixing the mixture to obtain a mixed solution, and then allowing the mixture to stand, and dropwise adding 10ml of the mixed solution. 0.2 mol / L sodium hydroxide solution and material B are added dropwise for 5-8 min. After the addition is completed, the mixture is filtered, washed with water, washed with alcohol, and dried to obtain a nanomaterial. The present invention overcomes the shortcomings of the prior art, and the method is not only applicable to zinc sulfide, but also to cadmium elements in the same family as zinc, thereby expanding the scope of application of the method.

The invention provides a cobalt-doped cadmium sulfide aerogel material and a preparation method and application thereof, and belongs to the technical field of precious metal recovery, the cobalt-doped cadmium sulfide aerogel material comprises chitosan aerogel and cobalt-doped cadmium sulfide loaded on the chitosan aerogel, and the mass ratio of the chitosan aerogel to the cobalt-doped cadmium sulfide is 0.16: (0.1-0.15); the mass ratio of cobalt to cadmium sulfide in the cobalt-doped cadmium sulfide is 0.5: (2-3). According to the method, Co atoms are anchored on the surface of CdS, so that the electron density of active sites on the surface of the material is remarkably improved, the coordination adsorption capacity on gold ions is enhanced, and enrichment and reduction of the gold ions are promoted. And the three-dimensional structure material aerogel is combined, so that the contact efficiency of the material and the gold ions is remarkably improved, and efficient recovery of the gold ions is promoted. The adopted chemical reduction adsorption technology has a good recovery effect on gold in the thiosulfate gold leaching liquid, and the gold recovery rate close to 100% can be achieved.

The present application provides a kind of red pigment for ceramic inkjet printing ink, which is composed of frit powder, aluminum hydroxide and iron red; the D50 of the frit powder is 0.2-0.3 μm; the particle size of the aluminum hydroxide is 8000-10000 mesh; the iron red is red iron oxide, and the D90 of the iron red is less than 3 μm. The present application uses ultra-fine high-temperature transparent frit powder, ultra-fine aluminum hydroxide and ultra-fine iron red to form high-temperature coated pigment. The ceramic ink made of the pigment can produce bright red at high temperature of 1200℃, solving the problem that conventional silicon iron red and zirconium iron red pigments cannot produce color at high temperature after being prepared into ink. The ink can be applied in ceramic ink to replace coated red pigment ink or red-brown ink. Compared with the current cadmium sulfide / selenium coated red technology, it has the advantages of green environmental protection and the absence of cadmium, a highly toxic substance.

The invention relates to a preparation method of a cadmium oxide / titanium nitride / sulfur indium cadmium heterostructure nano photocatalytic material, which comprises the following steps: by taking cadmium nitrate tetrahydrate and ammonium chloride as raw materials, depositing a cadmium hydroxide nano structure on the surface of conductive glass by adopting an electrochemical deposition method, and drying and calcining the cadmium hydroxide nano structure to obtain a cadmium oxide nano structure; coating the surface of the cadmium oxide nanostructure with a titanium nitride solution by adopting a spin-coating method, and drying to obtain a cadmium oxide / titanium nitride heterostructure; a water bath method is adopted, cadmium nitrate hydrate, thioacetamide and indium nitrate serve as raw materials, sulfur-indium-cadmium nanoparticles are loaded on the surface of the cadmium oxide / titanium nitride heterostructure, and the cadmium oxide / titanium nitride / sulfur-indium-cadmium heterostructure nanometer photocatalytic material is obtained after drying. Bidirectional hot electrons and carriers are generated by utilizing the surface plasma resonance effect of titanium nitride nanoparticles, and by combining a stepped charge channel of cadmium oxide and sulfur indium cadmium, the solar energy utilization rate and the photon-generated carrier separation efficiency are improved, and the performance of producing electricity and hydrogen by decomposing water through cadmium oxide is improved.

The application discloses a kind of polytriazine imide / cadmium sulfide quantum dot organic / inorganic photocatalytic composite material preparation method and application, belong to functional nanomaterial preparation, solar energy utilization and environmental protection technical field.The preparation of the composite material is: with urea as precursor, high crystallinity triazine imide is prepared using low-temperature molten salt method;Subsequently, in the anhydrous ethanol solution containing cadmium sulfide raw material, polytriazine imide is added, and the product obtained after heat preservation in hydrothermal reactor is the composite material.The application uses high crystallinity triazine imide as matrix, and grows cadmium sulfide quantum dots on the surface, effectively solves the problem of low utilization rate of polytriazine imide for visible light and difficult carrier separation of single-component material by constructing organic / inorganic heterojunction.The photocatalytic reduction material can be directly applied to the removal of pathogenic microorganisms in water under sunlight, solving the problem of low efficiency of traditional photocatalytic materials.

This invention belongs to the field of cadmium sulfide detection technology, specifically relating to a quantitative detection method for cadmium sulfide in a Tetrahymena culture system. The invention involves adding cadmium ions to Tetrahymena to form a Tetrahymena culture system sample, followed by ultrafiltration after disruption to separate cadmium ions into free cadmium ions (Cd). 2+ The sample was divided into two parts: cadmium sulfide (CdS) and cadmium sulfide (CdS). The cadmium content in the separated liquid sample was determined using a high-sensitivity detection technique (such as inductively coupled plasma mass spectrometry), thus obtaining the CdS content. 2+ The method not only provides information on the composition of cadmium in Tetrahymena but also dynamically monitors the efficiency of cadmium ion conversion to cadmium sulfide, providing reliable data support for assessing the remediation effect of Tetrahymena on cadmium pollution. Furthermore, this method has advantages such as ease of operation, high sensitivity, and good repeatability.

The invention belongs to the technical field of cadmium sulfide detection, and particularly relates to a quantitative detection method for cadmium sulfide in a tetrahymena culture system. The method comprises the following steps: adding cadmium ions into tetrahymena to form a tetrahymena culture system sample, crushing, carrying out ultrafiltration, separating cadmium in the sample into free cadmium ions (Cd < 2 + >) and cadmium sulfide (CdS), and determining the content of cadmium in the separated liquid sample by using a high-sensitivity detection technology (such as an inductively coupled plasma mass spectrometer). Therefore, the contents of Cd < 2 + > and cadmium converted into CdS are respectively obtained. The method not only can provide composition information of cadmium in tetrahymena, but also can dynamically monitor the conversion efficiency of cadmium ions to cadmium sulfide, and provides reliable data support for evaluating the remediation effect of tetrahymena on cadmium pollution. In addition, the method has the advantages of simplicity and convenience in operation, high sensitivity, good repeatability and the like.