Embodiments of the present disclosure relate to advanced
polishing pads with tunable chemical, material and structural properties, and new methods of manufacturing the same. According to one or more embodiments of the disclosure, it has been discovered that a
polishing pad with improved properties may be produced by an additive manufacturing process, such as a three-dimensional (3D) printing process. Embodiments of the present disclosure thus may provide an advanced
polishing pad that has discrete features and geometries, formed from at least two different materials that include
functional polymers, functional oligomers, reactive diluents,
addition polymer precursor compounds, catalysts, and curing agents. For example, the advanced polishing pad may be formed from a plurality of polymeric
layers, by the automated
sequential deposition of at least one
polymer precursor composition followed by at least one curing step, wherein each layer may represent at least one
polymer composition, and / or regions of different compositions. Embodiments of the disclosure further provide a polishing pad with polymeric
layers that may be interpenetrating
polymer networks.