The invention discloses a
bimorph TiO2 composite carbon material which is prepared by the following steps: by taking Ti3AlC2 as a
raw material, preparing single-layer Ti3C2Ox through HF
etching, compounding the single-layer Ti3C2Ox with a
titanium-based
metal organic framework MIL-125 through a
hydrothermal reaction, and finally, oxidizing and then carbonizing to obtain the
bimorph TiO2 composite carbon material, namely TiO2 / C-TiO2 for short. The basic
microstructure of TiO2 / C-TiO2 is in the shape of a round cake, and the size of a single round cake is 0.5-1 [mu] m; and
rutile type TiO2 and
anatase type TiO2 exist in the TiO2 / C-TiO2 at the same time. The preparation method comprises the following steps: 1, preparing single-layer Ti3C2Ox; 2, preparation of Ti < 3 > C < 2 > O < x > / MIL-125; and 3, the preparation of TiO2 / C-TiO2 is carried out. When the positive
electrode material is used as a
lithium-
sulfur battery positive
electrode material, the initial
discharge specific capacity is 1200-1300mA h g <-1 > under the condition that the
current density is 0.2 C; and under the condition that the
current density is 0.2 C, after 200 times of charge-
discharge cycles, the residual specific capacity is 700-800 mA h g <-1 >, and the capacity
retention ratio is 55-60%.