176 results about "Tetraphenylporphyrin" patented technology

The invention relates to a (1) or (2) and its application in preparation of organic EL device. M is Zn or Pt; three substituent group or R1, R2, R3 are different or the same and at least one of them is alkoxy substituent carbazole derivative shown as (3); R10 and R11 are different or the same, as alkyl of C1-4 (n=4-12); the other two substituent group is H and alkoxy and alkyl (C1-C4) or alkoxy substituent carbazole derivative shown as (3). The device made by the invention has high efficiency of EL, outstanding solubility and filmibility, easy to be mixed with polymer, benefiting for research to EL device, can be used to prepare red luminous, with simple technique, benefit for industrialized batch production .

The invention relates to a manufacturing method of a graphene-porphyrin modified electrode and application of the electrode, aiming to solve the problems of complex operation, long time and relatively high price in the conventional method for detecting the content of ascorbic acid in a living body. The method comprises the following steps: I, preparing pre-oxidized graphene; II, preparing a graphene oxide solid; III, preparing acyl-chlorinated graphene; IV, preparing tetraphenylporphyrin; V, preparing 5-(4-nitro)-10,15,20-triphenyl porphyrin; VI, preparing 5-(4-amino)phenyl-10,15-20-triphenyl porphyrin; VII, preparing a pure manganese porphyrin coordination compound; VIII, preparing a functional composite material of graphene oxide and porphyrin; IX, modifying a glassy carbon electrode. The modified electrode has excellent interference resistance, stability and reproducibility, and can be taken as a biosensor for detecting ascorbic acid in practical samples.

The invention discloses amino porphyrin-poly (N-isopropylacrylamide) europium coordination compound and a preparation method of the amino porphyrin-poly (N-isopropylacrylamide) europium coordination compound. The preparation method of the amino porphyrin- poly (N-isopropylacrylamide) europium coordination compound is characterized in that (NH2)n-TPP is prepared into an ATRP initiator which is NH2-TPP-X, wherein the X is halogen. The NH2-TPP-X is adopted to initiate NIPAM to be polymerized to obtain polymer which is (NH2)n-TPP-PNIPAM. The europium with tervalence is coordinated with the polymer (NH2)n-TPP-PNIPAM to obtain coordination compound which is (NH2)n-TPP-PNIPAM-Eu(III)-TTA through the TTA, wherein the n meets an equation that is n=1,2,3. The amino porphyrin- poly (N-isopropylacrylamide) europium coordination compound is characterized in that a short form of the amino porphyrin- poly (N-isopropylacrylamide) europium coordination compound is (NH2)n-TPP-PNIPAM-Eu(III)-TTA, wherein the TPP is tetraphenylporphyrin, wherein the shortened form of the tetraphenylporphyrin is porphyrin, the PNIPAM is the poly (N-isopropylacrylamide), the Eu(III) is the europium with the tervalence, and the TTA is alpha- thenoyltrifluoroacetone.

The invention provides an ultrathin fireproofing and flame-retardant double faced adhesive tape. The double faced adhesive tape comprises a base film layer, wherein flame-retardant layers are arrangedon two surfaces of the base film layer respectively, and adhesive layers are arranged on the surfaces, opposite to the base film layer, of the two flame-retardant layers. The double faced adhesive tape is characterized in that a flame retardant is arranged in the flame-retardant layers and the adhesive layers and contains ammonium dihydrogen phosphate and meso-tetraphenylporphyrin. The ultrathinfireproofing and flame-retardant double faced adhesive tape is applicable to the adhesion of parts of electronic products, particularly batteries and the like of intelligent mobile phones; by utilizing a dual fireproofing and flame-retardant technique, the fireproofing and flame-retardant effects are good; and the double faced adhesive tape is light and thin and has good applicability.

The invention provides a down washing and finishing agent which is characterized by being prepared from the following raw materials in parts by weight: 1-1.2 parts of tea saponin, 1-1.2 parts of sodium citrate, 2-2.4 parts of sodium dodecyl benzene sulfonate, 2-3 parts of ethyl acetate, 3-4 parts of ethylene glycol, 1.2-1.5 parts of tert-butyl hydroperoxide, 3-3.5 parts of morpholine, 1-1.2 parts of ning-emulsifier 31#, 1-1.2 parts of polyoxyethylene oleate, 2-3 parts of silane coupling agent KH-572, 1-2 parts of anti-aging agent TPPD (Tetraphenylporphyrin Dichloride), 2-3 parts of sodium bicarbonate, 3-4 parts of softening agent and 200 parts of water. The down washing and finishing agent is capable of effectively removing dirt on down, recovering the original elasticity and bulkiness of the down and keeping the original warmth retention property, strong in sterilizing effect and better in conditioning and nursing effects for the down.

The invention discloses a polyporphyrin/nanogold modified glassy carbon electrode as well as a preparation method and application thereof. The polyporphyrin/nanogold modified glassy carbon electrode comprises a glassy carbon electrode, wherein nanogold particles are deposited on the surface of the glassy carbon electrode, and the surface of the glassy carbon electrode is coated with a polymerized tetraphenylporphyrin film layer. The preparation method comprises the following steps: 1, synthesizing and preparing a tetraphenylporphyrin solution; 2, preparing a chloroauric acid solution; 3, preparing a nanogold modified glassy carbon electrode; 4, preparing the polyporphyrin/nanogold modified glassy carbon electrode; 5, airing the electrode at the room temperature. The electrode can be applied to detection of a trace amount of lead ions. The electrode has the advantages that the electrode is high in detection sensitivity, good in repeatability, wide in linear range and low in detection limit in a process of detecting lead ions.

Cobalt (II) complexes of porphyrins are effective catalysts for intramolecular nitrene insertion of C—H bonds with arylsulfonyl azides. The cobalt-catalyzed process can proceed efficiently under mild and neutral conditions in low catalyst loading without the need of other reagents or additives, generating nitrogen gas as the only byproduct. Using the simple tetraphenylporphyrin (TPP) as the ligand, the cobalt-catalyzed intramolecular amidation can be applied to primary, secondary, and tertiary C—H bonds and suitable for a broad range of arylsulfonyl azides, leading to the syntheses of various benzosultam derivatives in excellent yields

The present invention is directed to low toxicity boronated compounds and methods for their use in the treatment, visualization, and diagnosis of tumors. More specifically, the present invention is directed to low toxicity halogenated, carborane-containing 5,10,15,20-tetraphenylporphyrin compounds and methods for their use particularly in boron neutron capture therapy (BNCT) and photodynamic therapy (PDT) for the treatment of tumors of the brain, head and neck, and surrounding tissue. The invention is also directed to using these halogenated, carborane-containing tetraphenylporphyrin compounds in methods of tumor imaging and/or diagnosis such as MRI, SPECT, or PET.

Low toxicity halogenated carborane-containing tetraphenylporphyrin compounds and methods for their use particularly in boron neutron capture therapy (BNCT), X-ray radiation therapy (XRT) and photodynamic therapy (PDT) for the treatment of tumors of the brain, head and neck, and surrounding tissue. The invention also includes methods of tumor imaging and/or diagnosis such as MRI, SPECT, or PET using these halogenated carborane-containing tetraphenylporphyrin compounds.

The invention relates to a preparation method and an application method of a cobalt-tellurium diatomic site catalyst. The method comprises the following steps: preparing the catalyst by adopting a space confinement-etching-pyrolysis strategy, and comprises the following three steps: (1) packaging and anchoring a Te precursor by using a molecular pore channel of a metal organic framework material (ZIF-8) as a cage so as to realize uniform space distribution of the Te precursor; (2) performing etching and ion exchange on the frame material by using a metal precursor to realize atomic dispersionof the metal precursor; (3) treating and removing the ligand by using a high-temperature pyrolysis method, carbonizing, stabilizing Co and Te atoms by using a derived carbon-nitrogen framework material, and preventing the Co and Te atoms from migration and agglomeration so as to realize the synthesis of the Co/Te diatomic site catalyst, wherein the precursor is Te powder and cobalt acetylacetonate/cobalt tetraphenylporphyrin/vitamin B12/cobalt nitrate. The method is simple in process, the preparation method is simple, conditions are mild, the obtained Co/Te diatomic site catalyst has a rich micro/mesoporous structure, the specific surface area is larger than 1000 m < 2 >/g, active sites are in atomic dispersion, excellent electro-catalytic hydrogen production and oxygen reduction performance can be shown, and the cobalt-tellurium diatomic site catalyst can be used as an efficient electrolysis (sea) water and metal-air battery catalyst.

The invention discloses a synthetic process and special equipment for substituted bis [tetraphenylporphinatoiron]. An organic solvent as well as materials comprising substituted tetraphenylporphine and ferric are added in a metallic reactor for heating and refluxing for 0.2-0.5h under the condition of inputting 1 atm of air to synthesize substituted tetraphenylporphyrins; then solid NaOH is added into the same reactor for continuously reacting for 0.5-2h to implement dimerization on the substituted tetraphenylporphyrins, and pure substituted bis [tetraphenylporphinatoiron] is obtained through crystallization and purification. The synthetic yield of the substituted bis [tetraphenylporphinatoiron] is more than 95 percent and the recovery rate of the organic solvent is more than 95 percent.

A polymeric compound having a backbone structure including an addition product of a (meth)acrylate compound and a nucleophile of a cobalt porphyrin complex including a tetraphenylporphyrin derivative represented by Formula 1 coordinated to a cobalt metal,

The invention relates to a preparation method of a carbon nanotube/paraffin microcapsule with light absorption performance. The preparation method comprises the following steps: first acidifying and grafting a carbon nanotube to obtain a polyhydroxy carbon nanotube; nitrifying and reducing tetraphenylporphyrin to obtain amino porphyrin; secondly, placing the polyhydroxy carbon nanotube in a round-bottom flask with distilled water, ultrasonically dispersing, and adding melamine, urea and a formaldehyde solution into the system to prepare a prepolymer; then adding the amino porphyrin into molten paraffin, ultrasonically dispersing, adding an emulsifier and distilled water, and preparing an emulsion; and finally mixing the prepolymer, the emulsion, sodium chloride, glacial acetic acid and a curing agent, and reacting to obtain the microcapsule. The phase change potential heat is increased, and the carbon nanotube is uniformly dispersed in the compound paraffin to increase the heat conductivity, so that the stability of the emulsion is improved; the heat conducting performance of a wall material is improved, and the heat storage and release efficiency of the microcapsule is improved; and meanwhile, the microcapsule has an obvious absorption peak in a visible light zone, and has a photosensitive property.

The invention discloses an in-situ self-assembly preparation method of a ZnTPP (zinc tetraphenylporphyrin)/ZnO composite membrane nanomaterial. The method comprises the following steps: 1) synthesizing a nest-like ZnO membrane nanomaterial on ITO conducting glass; 2) synthesizing H2TPP (tetraphenylporphyrin); 3) dissolving H2TPP in a trichloromethane solvent; 4) impregnating the ZnO membrane nanomaterial attached to the ITO conducting glass in the H2TPP solution to realize uniform spin coating adhesion immediately; 5) calcining the ITO conducting glass in a tube furnace. During preparation, ZnTPP is formed through in-situ self-assembly on ZnO surface, the obtained organic matter and inorganic matter composite is clean in interface and good in chemical bonding and stability, the visible light absorption spectrum of the composite is broadened, separation efficiency of photogenerated charges is increased, photocatalytic degradation efficiency is increased substantially, and the composite shows hydrophobicity and obvious organic dye selectivity.

A method is provided for synthesizing a metal (M) meso-tetraphenylporphyrin polymer. The method begins with the provision of a free-base (H₂)-meso-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (H₂-tetra-C≡C-TriAS-TPP) including a trialkylsilyl (TriAS) moiety attached to an ethynyl termini. In response to a reaction with a metal (M)-containing material, the H₂-tetra-C≡C-TriAS-TPP is converted to a metal (M)-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (M-tetra-C≡C-TriAS-TPP). Then, the M-tetra-C≡C-TriAS-TPP is converted to a M-tetra-4-ethynylphenylporphyrin (M-tetra-C≡C-TPP) monomer by removing the trialkylsilyl (TriAS) moiety from the ethynyl termini. Finally, a plurality of M-tetra-C≡C-TPP monomers are coupled together to supply a metal (M)-meso-tetraphenylporphyrin polymer (M-poly-meso-TPP), whereby meso-phenyl groups of adjacent M-tetra-C≡C-TPP monomers in the M-poly-meso-TPP are connected through a butadiyne linking moiety. In one aspect, the metal is zinc.

The invention discloses a photosensitive medicinal preparation containing amino poly-carboxylic acid modification tetraphenylporphyrin compound. Each unit dose contains 1mg-100mg of the amino poly-carboxylic acid modification tetraphenylporphyrin compound. The each unit dosage is the total amount of the medicinal preparation used everyday. The amino poly-carboxylic acid modification tetraphenylporphyrin compound can be used in combination with other medicine or is singly used. Through addition of a drug carrier which is acceptable in pharmacy, the amino poly-carboxylic acid modification tetraphenylporphyrin compound accounts for 0.5%-40% the total weight of the medicinal preparation and can be prepared to any dosage form accepted clinically. The invention further provides application of the medicinal preparation on preparation of photosensitive antitumor drug and in the near infrared fluorescence imaging filed. The photosensitive medicinal preparation containing the amino poly-carboxylic acid modification tetraphenylporphyrin compound is low in toxicity, convenient to apply, wide in tumor suppression spectrum, good in tumor control rate, good in effect of malignant tumor treatment through photodynamic therapy, high in fluorescence quantum yield and optical stability in a near-infrared area, good in biocompatibility, capable of having a certain ability of penetrating the biological barrier, and wide in application prospect in the near infrared fluorescence imaging field.

A novel inclusion compound obtained by including in albumin a tetraphenylporphyrin metal complex represented by the following chemical formula (1) and having 2-position side chains:

• where R1 is a cyclohexyl group or the like; R2 represents a substituent; M represents a transition metal atom or metal ion belonging to Groups 6 to 10 of the periodic table; X⁻ represents a halogen ion; and the number of X⁻ is obtained by subtracting 2 from a valence of the metal ion.

The invention relates to a preparation method of a fullerene/tetraphenyl ferriporphyrin self-assembled structure oxygen reduction electrocatalyst. The preparation method comprises the following steps: carrying out condensation reflux on tetraphenyl porphyrin, iron nitrate nonahydrate and a DMF solvent, and carrying out vacuum drying to obtain tetraphenyl ferriporphyrin; preparing a fullerene toluene solution, mixing the fullerene toluene solution with the isopropyl alcohol suspension of tetraphenyl ferriporphyrin, performing standing, carrying out suction filtration, washing, and carrying out vacuum drying to obtain a sample with a self-assembly structure; taking a self-assembled sample and flatly spreading in a magnetic boat, putting the magnetic boat into a quartz tube protected by hydrogen and argon mixed gas, performing a heat preservation reaction at the temperature of 600-800 DEG C, performing natural cooling to the room temperature, and obtaining the fullerene/tetraphenylferriporphyrin self-assembled structure oxygen reduction electrocatalyst. The process for preparing the C60/FeTPP self-assembly structure through a liquid-liquid interface precipitation method is mature, simple to operate, low in production cost and easy for industrial production. A donor-acceptor system with charge transfer can be effectively constructed, and the half-wave potential of the donor-acceptor system can reach 0.86 V (vs.RHE).

The invention discloses an organic multi-component carrier lead ion selective electrode and a preparation method thereof. The organic multi-component carrier lead ion selective electrode comprises a selective film, a polrvinyl chloride pipe, an Ag/AgCl internal reference electrode, internal filled liquid and an electrode lead. The preparation method is characterized by comprising the following steps of: sufficiently mixing macrocyclic compounds such as calixarene, tetraphenylporphyrin and 18-crown ether-6 and organic matters containing soft active atoms (O, S, P), such as triphenylphosphine and dimethyl sulfide, to prepare a physical blending carrier; and dissolving the blending carrier, polrvinyl chloride powder, dibutyl phthalate and sodium tetraphenylborate into tetrahydrofuran, and carrying out ultrasonic dispersion to obtain a lead ion selective film. The purpose of carrier modification is achieved through physical mixing, so that the property of the lead ion selective electrode is extremely high, and the carrier is avoided being subjected to chemical modification with a complicated chemical synthesis process and a large quantity of organic reagents. The organic multi-component carrier lead ion selective electrode has the advantages of simple manufacturing, Nernst response, good selectivity and high stability and can be used for quickly and accurately detecting lead ions in a solution.

The invention discloses a proton exchange membrane applied to a direct methanol fuel cell and a preparation method thereof. The method comprises steps of adding porphyrin compound into a Nafion resin solution according to the mass ratio of porphyrin compound to Nafion resin to be 5-50:1000, wherein the porphyrin compound comprises tetraphenyl porphyrin, tetra-sulpho-phenyl porphyrin and tetra-amino-phenyl porphyrin; and carrying out membrane methods such as casting method, pasting method and gumming method on the Nafion resin solution of the porphyrin compound to prepare the modified proton exchange membrane. In the invention, molecules of porphyrin compound, which are not penetrated through methanol and conduct ions are embedded or bonded into the ion channel of a nafion membrane of a perfluorosulfonic membrane by physical or chemical methods to form a structure of hydrogen ion sieve, thereby maintaining higher protons conduction ability and reducing the methanol through rate greatly.

The invention discloses beta-(2,3-dihydro-naphthyl[1,2,e]-m-oxazinyl)tetraphenylporphyrin of which the structural general formula is disclosed as Formula (I) or Formula (II), and a preparation method and application thereof. The preparation method comprises the following steps: 1) preparing 5,10,15,20-tetraphenyl porphyrin from pyrrole and benzaldehyde, carrying out coordination with copper to obtain 5,10,15,20-tetraphenyl copper porphyrins, carrying out regioselective nitration to obtain beta-nitro-substituted-5,10,15,20-tetraphenyl copper porphyrins, carrying out decoppering and reduction to obtain beta-amino-substituted-5,10,15,20-tetraphenyl porphyrins, and reacting with acetate to obtain beta-amino-substituted-tetraphenyl metalloporphyrins (beta-NH2-MTPP); 2) carrying out condensation reaction on the beta-NH2-MTPP, formaldehyde and 2-naphthol, separating the product by column chromatography to obtain a beta-(2,3-dihydro-1H-naphthyl[1,2,e]-m-oxazinyl)-substituted tetraphenyl porphyrin metal complex; and decoppering to obtain the beta-(2,3-dihydro-naphthyl[1,2,e]-m-oxazinyl)tetraphenylporphyrin. The compounds can be used for preparing photodynamic-therapy photosensitizers and antineoplastic drugs with small toxic and side effects and high activity.