The invention discloses a nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and a preparation method of the nylon 66/polyaminated bismaleimide composite. The nylon 66/polyaminated bismaleimide composite comprises, by weight, 39-57 parts of nylon 66, 18-26 parts of polyaminated bismaleimide, 15-25 parts of poly(2(phenoxy) accidentally phosphorus nitrene), 24-32 parts of blast furnace water slag micro-powder, 2-4 parts of stannous chloride, 3-5 parts of N-methyl-p-toluenesulfonamide, 5-10 parts of potassium fluozirconate, 10-15 parts of dimethyl maleate, 4-8 parts of zinc hydroxystannate, 3-5 parts of cuproous bromide, 4-6 parts of oxidized polyethylene wax, 5-8 parts of perfluopolyether, 15-25 parts of colloidal graphite powder and 18-27 parts of flame retardant particles. The nylon 66/polyaminated bismaleimide is good in mechanical property, wear-resisting property and aging resistance.